Quantum kinetic equation for nonequilibrium dense systems

Using the density matrix method in the form developed by Zubarev, equations of motion for nonequilibrium quantum systems with continuous short range interactions are derived which describe kinetic and hydrodynamic processes in a consistent way. The T-matrix as well as the two-particle density matrix determining the nonequilibrium collision integral are obtained in the ladder approximation including the Hartree-Fock corrections and the Pauli blocking for intermediate states. It is shown that in this approximation the total energy is conserved. The developed approach to the kinetic theory of dense quantum systems is able to reproduce the virial corrections consistent with the generalized Beth-Uhlenbeck approximation in equilibrium. The contribution of many-particle correlations to the drift term in the quantum kinetic equation for dense systems is discussed.     

Theory of fluctuations in non-equilibrium Fermi gas

We present the equations for the equal-time two-particle correlation functions in degenerate electron gas. In association with the Onsager-type equation for the time-displaced correlation function, the equations constitute the basis of the theory of fluctuations in non-equilibrium degenerate electron gas. Thanks to the prevalence of the small-angle inter-electron scattering, the theory takes a rather simple form.     

Fluctuations and stability of stationary non-equilibrium systems in detailed balance

A generalized thermodynamic potential for Markoffian systems with detailed balance and far from thermal equilibrium has been derived in a previous paper. It was shown that the principle of detailed balance is equivalent to a set of conditions fulfilled by this potential (“potential conditions”). The properties of this potential allow us to extend the validity of a number of thermodynamic concepts well known for systems in or near thermal equilibrium to stationary states far from thermal equilibrium. The concept of symmetry breaking phase transitions for these systems is introduced in analogy to thermal equilibrium systems by considering the dependence of the stationary probability density of the system on a set of externally controlled parameters {λ}. A functional of the time dependent probability density of the system is defined in close analogy to the Gibb's definition of entropy. This functional has the properties of a Ljapunov functional of the governing Fokker-Planck equation showing the stability of the stationary probability density. The Langevin equations connected with the Fokker-Planck equation are considered. It is shown that, by means of the potential conditions, generalized “thermodynamic” fluxes and forces may be defined in such a way that the smoothly varying part of the Langevin equations (kinetic equations) constitutes a linear relation between fluxes and forces. The matrix of coefficients is given by the diffusion matrix of the Fokker-Planck equation. The symmetry relations which hold for this matrix due to the potential conditions then lead to the Onsager-Casimir symmetry relations extended to systems with detailed balance near stationary states far from thermal equilibrium. Finally it is shown that under certain additional assumptions the generalized thermodynamic potential may be used as a Ljapunov function of the kinetic equations.     

Structural evolution of the Tropical Pacific climate network

An attempt is made to develop an equilibrium kinetic equation for a weakly non ideal inhomogeneous gravitational system utilizing the Bogoliubov-Born-Green-Kirkwood-Yvon (BBGKY) hierarchy of equations. It is shown that the pair correlational function explicitly depends upon the nature of binary interaction between particles. The corresponding kinetic equation containing pair correlation corrections is devoid of the degeneracy present in the collisionless Boltzmann equation with respect to the nature of the two particle interactions, unlike the Vlasov equation that cannot recognize the nature of two particle interaction. A net effect of the particle correlations can be realized only if the spatial symmetry of the correlation interaction is broken due to a spatial inhomogeneity. Such an inhomogeneity is inherently present in a bulk gravitational system in view of the unshielded long range nature of the two-particle interactions. In a finite gravitational system, the effects of pair correlations in the first order kinetic equation can be expressed in terms of the macroscopic gravitational potential to obtain a modified Boltzmann distribution that includes the effects of correlations.     

Non-equilibrium 2PI potential and its possible application to evaluation of bulk viscosity

Within non-equilibrium Green’s function technique on the real-time contour and the two-particle irreducible Φ-functional method, a non-equilibrium potential is introduced. It naturally generalizes the conventional thermodynamic potential with which it coincides in thermal equilibrium. Variations of the non-equilibrium potential over respective parameters result in the same quantities as those of the thermodynamic potential but in arbitrary non-equilibrium. In particular, for slightly non-equilibrium inhomogeneous configurations a variation of the non-equilibrium potential over volume is associated with the trace of the non-equilibrium stress tensor. The latter is related to the bulk viscosity. This provides a novel way for evaluation of the bulk viscosity.     

A simulation study of the pore size dependence of transport selectivity in cylindrical pores

The equilibrium adsorption and transport properties of mixtures of methane and carbon dioxide, modelled as spherical molecules, have been studied in cylindrical model pores with graphitic properties over a range of cylinder radii. The equilibrium isotherms exhibit packing transitions similar to those observed for single adsorbates; as a consequence, optimum separation factors are found at particular radii, depending on the fugacity (or pressure) in the system. The equations of non-equilibrium thermodynamics have been developed so as to represent the flux of each component in a Fickian form, as a coefficient multiplying the gradient of the total density. Diffusion coefficients were calculated from streaming velocity correlations and NEMD was used to obtain the ‘apparent’ viscous component. The results show that diffusion coefficients from equilibrium molecular dynamics and viscous diffusion coefficients from non-equilibrium calculations are identical within the errors of the calculation. It follows that equilibrium and dynamic separation factors have the same values over a range of pore sizes.     

Three-dimensional nonlinear dynamics of thin liquid films

Using a general two-body exponential parametrization for the wave function, the Nakatsuji two-particle density equation [Phys. Rev. A 14, 41 (1976)] is transformed into a set of nonlinear algebraic equations in which the number of unknowns precisely equals the number of equations. Since the Nakatsuji two-particle density equation is equivalent to the time-independent Schrodinger equation for Hamiltonians containing up to two-body interactions, the answer to the title question is affirmative, provided the equations have solutions. Practical implications of the parametrization and possible approximation schemes are briefly discussed.     

Two-particle Green's functions in non-equilibrium matter

The method of the derivation of two-particle Green's functions in non-equilibrium matter is developed. The closed set of equations for the vertex functions and also for the two-particle Green's functions is obtained by means of the summation of the series of irreducible diagrams. The solution of such equations completely defines the two-particle Green's functions in matter.     

Two-particle Green's functions in non-equilibrium matter

The method of derivation of two-particle Green's functions in the non-equilibrium matter has been developed. The closed set of equations for the vertex functions, as well as for the two-particle Green's functions, is obtained by means of the summation of the series of indecomposable diagrams. The solution of such equations completely determines the two-particle Green's functions in the matter.     

Off-diagonal long-range order and currents in weakly coupled superconductors

Within the framework of quasi equilibrium approximation, Josephson’s expression for current in a weakly coupled superconducting system is derived without the use of any specific microscopic model. It is based only on the existence of the off-diagonal long-range order in the two-particle reduced density matrix. Allowing for deviations from the quasi equilibrium approximation, generalised Josephson equations are obtained which include ohmic terms. The effect of relaxation and thermal fluctuations is examined in detail to emphasise the physical origin of various terms in the expression for current.     

Kinetics of exciton-exciton annihilation in molecular crystals

The theoretical investigation of the time dependence of the concentration of incoherent excitons formed by pulsed pumping is carried out. The basis of this investigation is a system of an infinite number of coupled equations for multiparticle distribution functions. Using the Kirkwood method of uncoupling, this system is reduced to a system of differetial equations for one- and two-particle distribution functions. The algorithm for calculating these equations by means of an electronic computer is developed.A simple phenomenological differential equation for exciton density has been obtained. The solution of this phenomenological equation coincides with good accuracy with the solution obtained by numerical integration of the above-mentioned system of differential equations for one- and two-particle distribution functions.     

Relativistic bound-state equations for fermions with instantaneous interactions

In thispaper three types of relativistic bound-state equations for a fermion pair with instantaneous interaction are studied, viz., the instantaneous Bethe-Salpeter equation, the quasi-potential equation, and the two-particle Dirac equation. General forms for the equations describing bound states with arbitrary spin, parity, and charge parity are derived. For the special case of spinless states bound by interactions with a Coulomb-type potential the properties of the ground-state solutions of the three equations are investigated both analytically and numerically. The coupling-constant spectrum turns out to depend strongly on the spinor structure of the fermion interaction. If the latter is chosen such that the nonrelativistic limits of the equations coincide, an analogous spectrum is found for the instantaneous Bethe-Salpeter and the quasi-potential equations, whereas the two-particle Dirac equation yields qualitatively different results.     

Recurrence equations for the computation of correlations in the 1/r2 quantum many-body system

In a previous paper the two-particle distribution function and one-particle density matrix for the quantum many-body system with the 1/r ² pair potential have been expressed as limiting cases of Selberg correlation integrals. Recurrence equations are derived which allow rapid evaluation of these multidimensional integrals. The exact results for the two-particle distribution are compared with the harmonic approximation.     

Non-equilibrium thermal entanglement for a three spin chain

The dynamics of a chain of three spins coupled at both ends to separate bosonic baths at different temperatures is studied. An exact analytical solution of the master equation in the Born-Markov approximation for the reduced density matrix of the chain is constructed. It is shown that for long times the reduced density matrix converges to the non-equilibrium steady state. Dynamical and steady state properties of the concurrence between the first and the last spin are studied.     

Master Equation in Phase Space for a Uniaxial Spin System

A master equation, for the time evolution of the quasi-probability density function of spin orientations in the phase space representation of the polar and azimuthal angles is derived for a uniaxial spin system subject to a magnetic field parallel to the axis of symmetry. This equation is obtained from the reduced density matrix evolution equation (assuming that the spin-bath coupling is weak and that the correlation time of the bath is so short that the stochastic process resulting from it is Markovian) by expressing it in terms of the inverse Wigner-Stratonovich transformation and evaluating the various commutators via the properties of polarization operators and spherical harmonics. The properties of this phase space master equation, resembling the Fokker-Planck equation, are investigated, leading to a finite series (in terms of the spherical harmonics) for its stationary solution, which is the equilibrium quasi-probability density function of spin “orientations” corresponding to the canonical density matrix and which may be expressed in closed form for a given spin number. Moreover, in the large spin limit, the master equation transforms to the classical Fokker-Planck equation describing the magnetization dynamics of a uniaxial paramagnet.     

Decay of correlations in spin systems

We investigate the decay of initial correlations in a spin system where each spin relaxes independently by an intramolecular mechanism. The equation of motion for the spin density matrix is assumed to be the Redfield equation, which is of the form of a quantum mechanical master equation. Our analysis of this problem is based on the techniques of Shuler, Oppenheim, and coworkers, who have studied the decay of correlations in systems which can be described by classical stochastic master equations. We find that the off-diagonal elements of the reduced spin density matrices approach their equilibrium values faster than the diagonal elements. The Ursell functions, which are a measure of the correlations in the system, decay to their zero equilibrium values faster than the spin density matrix except for the furthest off-diagonal elements. Far off-diagonal matrix elements of the spin density matrix approach equilibrium at the same rate as the Ursell functions, which is the important difference between the quantum mechanical model studied here and the classical models studied earlier.Supported in part by the National Science Foundation.     

Condensates in annuli: dimensionality of the variance

Static and dynamic properties of Bose-Einstein condensates in annular traps are investigated by solving the many-boson Schrödinger equation numerically accurately using the multiconfigurational time-dependent Hartree for bosons method. We concentrate on weakly-interacting bosons exhibiting low depletion. Analysis of the mean-field position variance, which accounts for the shape of the density only, and the many-body position variance, which incorporates a tiny amount of excitations through the reduced two-particle density matrix, shows that the former behaves essentially as a quasi-one-dimensional quantity whereas the latter as a two-dimensional quantity. This brings another dimension to the physics of bosons in ring-shaped traps.     

自旋梯可积模型的研究

通过对自旋梯可积模型的研究,求出该模型的能量本征值和两体散射矩阵.用可积模型中的坐标Bethe Ansatz方法,首先由薛定谔方程求得能量的本征方程.设定波函数的具体形式,求出本征能量,然后利用能量本征方程和波函数的连续性求出两体散射矩阵.求出单粒子、双粒子和N₀个粒子的本征能量,同时求得粒子的两体散射矩阵.自旋梯可积模型的本征能量和两体散射矩阵可通过Bethe Ansatz的方法求得.