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Two steroids, 3-oxo-chol-4-ene-24-oic acid (2) andi ts unsaturated analog 4 have been isolated from the dorid nudibranch Aldisasanguineacooperi, and the acid 2 has been shown to have antifeedant properties.  相似文献   

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Four novel fusicoccane diterpenoids, fusicoplagins A, B, C, and D, have been isolated from the liverwort Plagiochilaacanthophylla subsp. japonica and the structures determined by spectroscopic methods, chemical transformations, and X-ray crystallographic analysis.  相似文献   

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All four isomers of substituted 3-alkylthio-4-hydroxybutenes have been synthesised: both the geometry of the double bond and the relative stereochemistry of the two chiral centres are controlled.  相似文献   

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The new compounds 14 and 8 have been isolated from cultures of Aspergillusduricaulis  相似文献   

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The amino acid tyrosine has been shown to be the specific precursor of the isonitrile acid 1 produced by Trichodermahamatum (Bon.) Bain. aggr.  相似文献   

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A new ichthyotoxic toxin was isolated from the unialgal culture of the deleterious Florida red tide organism, Gymnodiniumbreve Davis (Syn. Ptychodiscusbrevis), and its structure was elucidated.  相似文献   

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Sterepolide and dihydrosterepolide, new sesquiterpenes isolated from the fungus Stereumpurpureum, are assigned structures 4 and 7, respectively. The assignments are based mainly on spectroscopic studies and similarities to isolactarorufin (5). A possible mode of biogenesis of these isolactarane type sesquiterpenes is discussed.  相似文献   

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The structure of the alkaloid buddamin, isolated from Buddleyadavidii cannot be correct, based upon the reported spectral data. An alternate structure is proposed, which also suggests that buddamin is an artifact of the isolation procedure.  相似文献   

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