铁基合金激光熔覆层的高温磨损性能

为提高40Cr钢表面耐磨性,采用预置激光熔覆法在40Cr基体表面制备Fe基涂层,利用HT-500摩擦磨损实验机测定干摩擦条件下,基体和熔覆层的摩擦因数随温度变化的规律。利用表面粗糙度轮廓仪测量磨痕的深度和宽度,SEM观察熔覆层以及磨痕的显微组织形貌,使用HV-1000型显微硬度仪检测基体和熔覆层结合部分的硬度。研究结果表明:熔覆层平均显微硬度值达到373.8HV(0.2);显著高于基体硬度198.4HV(0.2)。在干摩擦条件下,随着温度升高,磨损过程逐渐变平缓,平均摩擦因数降低,磨损率增加,耐磨性下降;在350~400 ℃之间,熔覆层磨损性能优于基体。     

铁基合金激光熔覆层高温润滑磨损性能

为提高40Cr合金钢的表面耐磨性,采用预置激光熔覆法在40Cr基体表面制备铁基合金涂层, 利用扫描电镜观察分析熔覆层显微组织形貌,用显微硬度仪测试熔覆层截面显微硬度,用摩擦磨损试验机测定在润滑条件下基体、熔覆层的摩擦系数随温度变化的规律。研究结果表明:熔覆层与基体实现良好冶金结合,熔覆层横截面微观组织呈现平面晶、树枝晶和胞状晶分布;熔覆层硬度值介于617.5~926.6 HV0.2之间,基体硬度介于205.2~278.2 HV0.2之间;在200 ℃以下,熔覆层摩擦系数在磨程中趋于平稳,在0.1附近轻微波动,小于基体平均摩擦系数;当温度超过200 ℃,油膜分解,引发润滑失效,磨损方式向干摩擦转化,磨损机理从微切削磨损主导向粘着磨损、磨粒磨损和氧化磨损复合磨损方式转化。     

40Cr钢表面激光熔覆层的磨损性能

为研究模具钢熔覆层的磨损性能,采用铁基粉在40Cr钢表面进行激光熔覆,以激光熔覆层为上试样,GCr15钢珠为下试样,采用HT－500磨损试验机进行摩擦磨损试验,并与40Cr基体的磨损性能相对比。利用表面形貌仪测量磨痕深度和宽度。研究结果表明：载荷小于250 g时,相同载荷下基体的摩擦系数大。载荷小于300 g时,随磨损时间延长,熔覆层、基体的摩擦系数都随着载荷增加而减小。当载荷为300 g时,基体的摩擦系数在0.563～0.589之间变化,平均值为0.576,且随时间逐渐升高,耐磨性变差;熔覆层的磨擦系数在0.431～0.457之间变化,平均摩擦系数为0.444,磨痕深度和宽度分别是0.65 mm和1.096 μm,且随时间逐渐下降,表现了良好的耐磨性能。当载荷增加到500 g时,平均摩擦系数和磨痕深度比300 g时分别增加了75％和47倍,且摩擦系数逐渐升高,磨损性能下降。     

40Cr钢表面激光熔覆层的磨损性能

 为研究模具钢熔覆层的磨损性能,采用铁基粉在40Cr钢表面进行激光熔覆,以激光熔覆层为上试样,GCr15钢珠为下试样,采用HT－500磨损试验机进行摩擦磨损试验,并与40Cr基体的磨损性能相对比。利用表面形貌仪测量磨痕深度和宽度。研究结果表明：载荷小于250 g时,相同载荷下基体的摩擦系数大。载荷小于300 g时,随磨损时间延长,熔覆层、基体的摩擦系数都随着载荷增加而减小。当载荷为300 g时,基体的摩擦系数在0.563～0.589之间变化,平均值为0.576,且随时间逐渐升高,耐磨性变差;熔覆层的磨擦系数在0.431～0.457之间变化,平均摩擦系数为0.444,磨痕深度和宽度分别是0.65 mm和1.096 μm,且随时间逐渐下降,表现了良好的耐磨性能。当载荷增加到500 g时,平均摩擦系数和磨痕深度比300 g时分别增加了75％和47倍,且摩擦系数逐渐升高,磨损性能下降。     

钛合金表面激光熔覆TiC_p/Ni基合金复合耐磨涂层

采用激光熔覆技术在TC4合金表面制备TiC颗粒增强的Ni基合金复合材料涂层,测试了熔覆层的硬度和滑动摩擦磨损性能,分析了熔覆层的强化机制。结果表明,熔覆层中存在颗粒强化、固溶强化和细晶强化等多种强化作用,熔覆层的显微硬度达HV900～1100,耐磨性能比TC4合金显著提高。     

激光熔覆TiC-Ni复合涂层的摩擦磨损性能和磨损机制研究

利用光学显微镜和扫描电镜观察了钛合金表面TiC-Ni激光熔覆层的宏观形貌和微观组织,测试了激光熔覆层的硬度、摩擦系数和磨损量。利用SEM观察了磨损的表面形貌和磨屑的形貌,分析了激光熔覆层的磨损机制。结果表明:激光熔覆层组织致密,无气孔和裂纹,硬度为基材的3倍;激光熔覆层的摩擦系数随环境压力的降低而提高,磨损量随环境压力的降低、法向载荷的增加而增加;低载时为轻微的磨粒磨损,高载时为严重的剥层磨损。     

耐酸不锈钢表面激光熔覆层耐腐蚀研究

本文研究了在耐酸不锈钢基体上采用激光熔覆和等离子喷焊二种工艺形成的涂层对耐腐蚀性的影响。使用５ｋＷ横流ＣＯ２激光器对预置在基体上的Ｃｏ基自熔合金粉末进行熔覆加工,得到的熔层与等离子焊层对比：激光熔层缺陷率低,被机体稀释率更小,成品率更高。其组织致密均匀,晶粒细小,熔层硬度与强韧性更高。性能试验证明：激光熔层有更好的耐腐蚀性能。     

斜齿轮激光熔覆Fe基合金组织与性能研究

采用激光熔覆技术在斜齿轮钢表面制备Fe基熔覆层.通过光学显微镜、显微硬度计对熔覆层进行金相组织与显微硬度分析,采用磨损机对熔覆层和基材进行摩擦实验.结果表明:当激光功率为750W,送粉速率为20g/min,扫描速度10mm/s,离焦量为16.4mm时,铁基熔覆层与基体结合界面有明显的白亮带,激光熔覆效果较好,熔覆层的显...     

42CrMo轧辊激光熔覆TiC-VC增强铁基熔覆层性能

采用同步送粉方式,在42CrMo轧辊基材上利用钛铁、钒铁和石墨等通过激光熔覆原位自生反应,制备了成型良好、致密无气孔、无裂纹、与基体呈冶金结合的TiVC2增强铁基熔覆层。利用X射线衍射、电子探针、显微硬度计、电化学工作站研究了熔覆层的显微组织及性能。结果表明,熔覆层中碳化物为TiVC2,TiVC2大小约0.5~2.0 m,呈多角块状均匀分布,碳化物对应两种不同的形核机制：以氧化铝异质形核和碳化物自发形核。随着熔覆合金粉末中TiC-VC数量的增加,熔覆层硬度并不呈简单的线性增加,熔覆层的耐蚀性逐渐变差。     

Cr对TiC-VC增强铁基熔覆层耐蚀性及耐磨性的影响

通过X射线衍射、扫描电子显微镜、能谱仪、极化曲线和磨粒磨损实验分析,研究了不同Cr加入量对TiC-VC增强铁基激光熔覆层耐蚀性和耐磨性能的影响。结果表明：熔覆层中物相主要为-Fe,TiC,VC和TiVC2。随着Cr加入量的增加,伴随有残余奥氏体及Cr3C2的出现,且Cr3C2呈长条状部分聚集、部分单独分布。熔覆层的耐蚀性与耐磨性随Cr加入量的增加呈现先增加后降低的趋势。熔覆粉末中加入适量的Cr元素能显著提高熔覆层的硬度与耐蚀性。当添加质量分数为3.0%的Cr时,熔覆层硬度高达1090HV0.2,且相同磨损条件下熔覆层磨损失重仅约为Q235钢的1/26;当添加质量分数为9.0%的Cr时,所得熔覆层的耐蚀性最好,约为不添加Cr时的3.26倍。     

Unusual flow behavior of Fe-based soft magnetic amorphous ribbons under high temperature tensile loading

The viscous thermal flow behavior and mechanical property of [Fe_0.6Co_0.15B_0.2Si_0.05] _(100−x)Ta_x (x = 0, 1, 2, 3, 4, and 5) soft magnetic amorphous ribbons were studied. The characteristics of melt-spun amorphous ribbons were measured by using vibration sample magnetometer (VSM), nanoindentation, differential scanning calorimetry (DSC) and thermo-mechanical analysis (TMA) to study the effects of Ta content variation on the thermal stability, mechanical, and soft magnetic properties. We observed that the nanoindentation hardness, Young's modulus, and glass transition and crystallization temperatures were improved by the addition of Ta. Using dilatometry measurement, TMA, by heating at a constant rate under tension mode, we examined not only the glass transition and crystallization behaviors but also the possibility of coexistence of multiple amorphous phases.     

TiN对Co基合金激光熔覆层组织与性能的影响

采用5 kW CO2激光器在低碳钢表面熔覆Co基合金涂层及TiN/Co基合金复合涂层,研究了两种涂层的组织、显微硬度以及滑动磨损性能。结果表明,Co基合金涂层主要组成相为γ-Co,ε-Co,Cr23C6等,TiN/Co基合金复合涂层组成相为γ-Co,ε-Co,Cr23C6,TiN和TiC等。Co基合金涂层由发达的γ-Co枝晶和其间共晶组织所组成,TiN/Co基合金涂层典型组织为等轴固溶体以及细小的共晶组织。TiN对熔覆层的组织有显著的改善作用,促使其组织细化,树枝晶向等轴晶转化,同时可显著提高Co基合金涂层的显微硬度及耐磨性能。     

Bi，Sb及稀土元素对AZ91镁合金高温性能影响机理研究

利用大角重位点阵概念建立了AZ91镁合金基体(α相)和镁［0001］对称倾斜晶界原子结构模型,应用实空间的连分数方法计算了体系的结构能,环境敏感镶嵌能以及相互作用能.结果发现,在镁合金基体中,Al和稀土形成团簇时比较稳定,Al,Bi或Sb与稀土形成团簇时不稳定.Bi或Sb和稀土元素同时存在于AZ91镁合金中时,一方面Bi或Sb将可与RE结合形成RE₂Bi(RE₂Sb)或RE-Bi(RE-Sb)化合物弥散分布于晶界,另一方面镁合金基体中会形成Al_{11关键词： 电子理论 晶界偏聚 合金元素 高温性能}     

Microstructure evolution of Fe-based WC composite coating prepared by laser induction hybrid rapid cladding

Fe + 50 wt.% WC composite coating was prepared by laser induction hybrid rapid cladding (LIHRC) on steel substrate. The phase and microstructure of the composite coating were investigated by X-ray diffraction (XRD), environmental scanning electron microscope (ESEM) and energy dispersive spectrum (EDS). The results showed that WC particles were dissolved almost completely to precipitate the coarse herringbone M₆C eutectic carbides and the fine dendritic M₆C carbides, and that the partially dissolved WC particles with an alloyed reaction layer were occasionally observed in the whole coating. The phases of the composite coating were composed of supersaturated solid solution α-Fe, retained austenite, Fe₃C, W₂C, M₆C and M₇C₃. The microstructure evolution in the composite coating was represented by the transformation of three parts such as Fe-based metallic matrix, dispersed carbides and incompletely dissolved WC particles. The microhardness of Fe-based WC composite coating was three times much higher than that of the substrate, but was relatively lower than that of Ni-based WC composite coating by LIHRC.     

高温高压下Ag-Mg-Zn合金中金属间化合物的微观结构与热动力学性质的第一性原理计算

采用基于密度泛函理论的第一性原理计算方法,研究了Ag-Mg-Zn合金中金属间化合物AgMg,Mg4Zn8和Ag8Mg4Zn4在高温高压下的结构稳定性、弹性性能和热动力学性质.理论计算结果与实验值和其他的理论结果符合得非常好.研究表明:金属间化合物AgMg,Mg4Zn8和Ag8Mg4Zn4在零温零压下是力学稳定的;Mg4Zn8和Ag8Mg4Zn4为延性相,而AgMg则为脆性相;在这三种金属间化合物中,Ag8Mg4Zn4的塑性最好,AgMg的塑性最差.利用准谐Debye模型,讨论了高温高压下Ag-Mg-Zn合金中金属间化合物的摩尔振动内能Uvib,m,摩尔Helmholtz振动自由能Avib,m,摩尔振动熵Svib,m,摩尔定容热容Cv,m,摩尔定压热容Cp,m,热膨胀系数α,Griüneisen 参量γ和Debye温度(O).     

Annealing temperature effect on microstructure,magnetic and microwave properties of Fe-based amorphous alloy powders

Fe₇₄Ni₃Si₁₃Cr₆W₄ amorphous alloy powders were annealed at different temperature (T) for 1.5 h to fabricate the corresponding amorphous and nanocrystalline powders. The influences of T on the crystalline structure, morphology, magnetic and microwave electromagnetic properties of the resultant samples were investigated via X-ray diffraction, scanning electron microscopy, vibrating sample magnetometer and vector network analyzer. The results show that the powder samples obtained at T of 650 °C or more are composed of lots of ultra-fine α-Fe(Si) grains embedded in an amorphous matrix. When T increases from 350 to 750 °C, the saturated magnetization and coercivity of the as-annealed powder samples both increase monotonously whereas the relative real permittivity shows a minimal value and the relative real permeability shows a maximal value at T of 650 °C. Thus the powder samples annealed at 650 °C show optimal reflection loss under −10 dB in the whole C-band. These results here suggest that the annealing heat treatment of Fe-based amorphous alloy is an effective approach to fabricate high performance microwave absorber with reasonable permittivity and large permeability simultaneously via adjusting T.