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1.
1INTRODUCTION The construction of metal-organic coordination polymers based on covalent interactions[1]or supra-molecular contacts such as hydrogen-bonding and/orπ-πinteractions)[2]is now of great interest not only due to the enormous variety of intriguing structural topologies themselves,but also to their unexpected physical and chemical properties for potential prac-tical applications as functional materials.Many N-containing ligands,such as4,4?-bipyridine,2,2?-bi-pyridine and1,10-phen… 相似文献
2.
The coordination polymer {[Co(phth)(phen)(H2O)]·(C2H5OH)}n (phth = phthalate, phen = 1,10-phenanthroline) with formula C22H20CoN2O6 (Mr = 467.33) was synthesized by the solvothermal method under low temperature, and its crystal structure was determined by singlecrystal X-ray diffraction. The complex belongs to monoclinic system, space group P21/n with a =12.7352(16), b = 8.8125(11), c = 18.677(2) (A), β = 102.633(2)°, V = 2045.3(4) (A)3, Z = 4, Dc =1.518 g/cm3,μ = 0.882 mm-1, F(000) = 964, S = 1.053, the final R = 0.0401 and wR = 0.0984 for 3135 observed reflections (I > 2σ(I)). Single-crystal X-ray analysis revealed that the Co(Ⅱ) ion is six-coordinated. The cobalt complex forms a one-dimensional chain structure via phthalate bridging ligand. In the cobalt complex, a 3D network structure is formed by π-π stacking interaction of 1,10-phenanthroline as well as intermolecular hydrogen bonding interactions. 相似文献
3.
WANG Feng-Wu ② WEI Yi-Jun ZHU Qi-Yong 《结构化学》2006,25(10):1179-1182
1 INTRODUCTION Schiff base ligands have played an important role in the development of coordination chemistry as they readily form stable complexes with most metal ions[1~4]. These complexes are very interesting in many fields, such as catalysis and enzymatic reac- tions[5, 6], magnetism and molecular architectures[7~9]. The complexes derived from the similar tridentate Schiff base ligand 2-[(2-dimethylaminoethylimino)- methyl]phenol[10, 11] and its derivatives[12~14] have been widely … 相似文献
4.
1INTRODUCTION Over the past decades,olefin oligomerization and polymerization based on late transition metal catalysts have been the most exciting developments in the area of organometallic chemistry and polymer science[1~3].In this broad context,neutral nickel(II)complexes have attracted much attention for their less sensitivity to protonic solvents and polar mon-mers.The most typical one is the SHOP-type cata-lyst[4~6],which contains an anionic[P,O]chelate ring and shows high activ… 相似文献
5.
A novel complex [Zn(FcCOO)2(2,2′-bipy)(H2O)]2·H2O (Fc = (η5-C5H5)Fe(η5-C5H4), 2,2′-bipy = 2,2′-bipyridine) has been synthesized and characterized by elemental analysis, IR and X-ray diffraction. It crystallizes in monoclinic system, space group P21/c with a = 6.8187(4), b = 21.7155(13), c = 19.7411(12) (A), α = 90, β = 97.7420(10), γ = 90°, C64H58Fe4Zn2N4O11, Mr = 1413.28, V = 2896.4(3) (A)3, Dc = 1.620 g/cm3, Z = 2, F(000) = 1444, μ(MoKα) = 1.857 mm-1, R = 0.0523 and wR = 0.0982 for 3219 observed reflections (I > 2σ(I)). Structural analysis shows that the zinc atom is coordinated with three oxygen atoms from two ferrocenemonocarboxylates and one water molecule together with two nitrogen atoms from 2,2′-bipyridine, giving a distorted square-pyramidal coordination geometry. The complex molecules are linked to form an infinite one-dimensional chain by both intermolecular hydrogen bonds and π-π stacking interactions of the bipyridine rings. 相似文献
6.
A novel complex [Zn(FcCOO)2(2,2′-bipy)(H2O)]2·H2O (Fc = (η5-C5H5)Fe(η5-C5H4), 2,2′-bipy = 2,2′-bipyridine) has been synthesized and characterized by elemental analysis, IR and X-ray diffraction. It crystallizes in monoclinic system, space group P21/c with a = 6.8187(4), b = 21.7155(13), c = 19.7411(12) (A), α = 90, β = 97.7420(10), γ = 90°, C64H58Fe4Zn2N4O11, Mr = 1413.28, V = 2896.4(3) (A)3, Dc = 1.620 g/cm3, Z = 2, F(000) = 1444, μ(MoKα) = 1.857 mm-1, R = 0.0523 and wR = 0.0982 for 3219 observed reflections (I > 2σ(I)). Structural analysis shows that the zinc atom is coordinated with three oxygen atoms from two ferrocenemonocarboxylates and one water molecule together with two nitrogen atoms from 2,2′-bipyridine, giving a distorted square-pyramidal coordination geometry. The complex molecules are linked to form an infinite one-dimensional chain by both intermolecular hydrogen bonds and π-π stacking interactions of the bipyridine rings. 相似文献
7.
The title compound, [Zn(Pybta)Cl2]n (Pybta = 1-(2-pyridylmethyl)benzontriazole), has a zigzag chain structure. It crystallizes in the monoclinic system, space group P21/c with a = 9.0103(11), b = 17.0276(18), c = 9.2288(11) A, β = 101.309(6)°, Mr= 346.51, V= 1388.4(3) (A)3, Z= 4, Dc= 1.658 g/cm3, F(000) = 696, μ = 2.143 mm-1, the final R = 0.0492 and wR = 0.1236 for 2545 observed reflections with Ⅰ 2σ(Ⅰ). The Zn atom is four-coordinated by two N and two Cl atoms, forming a slightly distorted tetrahedral geometry. Each zigzag chain links its adjacent symmetry-related equivalents via multiple π-π interactions, which are not frequently observed in the previously reported architectures. 相似文献
8.
Introduction Cation-πinteractions have come to be appreciated as an important noncovalent binding force in many areas of modern chemistry, such as material design, molecular biology, host-guest and supramolecular chemistry[1-3]. 相似文献
9.
A novel complex [Zn(FcCOO)2(2,2'-bipy)(H2O)]2·H2O (Fc = (η5-C5H5)Fe(η5-C5H4), 2,2'-bipy = 2,2'-bipyridine) has been synthesized and characterized by elemental analysis, IR and X-ray diffraction. It crystallizes in monoclinic system, space group P21/c with a = 6.8187(4), b = 21.7155(13), c = 19.7411(12) A, α = 90, β = 97.7420(10), γ = 90o, C64H58Fe4Zn2N4O11, Mr = 1413.28, V = 2896.4(3) A3, Dc = 1.620 g/cm3, Z = 2, F(000) = 1444, μ(MoKα) = 1.857 mm-1, R = 0.0523 and wR = 0.0982 for 3219 observed reflections (I > 2σ(I)). Structural analysis shows that the zinc atom is coordinated with three oxygen atoms from two ferrocenemonocarboxylates and one water molecule together with two nitrogen atoms from 2,2'-bipyridine, giving a distorted square-pyramidal coordination geometry. The complex molecules are linked to form an infinite one-dimensional chain by both intermolecular hydrogen bonds and π-π stacking interactions of the bipyridine rings. 相似文献
10.
Complex [Zn(L)(SO4)]·0.5H2O (L= 2-(2-chloro-6-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline) has been synthesized under hydrothermal conditions. The compound was characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction. It crystallizes in monoclinic, space group P21 /n with a = 9.9916(7), b = 12.3834(9), c = 29.259(2) , β = 97.7720(10)°, V = 3587.0(4)3 , Z = 2, C76H41Cl4F4N16O9S2Zn2 , Mr = 1734.91, Dc = 1.606 g/cm 3 , F(000) = 1754, μ(MoKa) = 0.959 mm -1 , R = 0.0492 and wR = 0.1385. The asymmetric unit of 1 contains one Zn(II) atom, two L ligands, one sulfate anion and half a water molecule. Each Zn(II) atom is five-coordinated by four nitrogen atoms from two different L ligands and one sulfate oxygen atom in a tetragonal pyramidal coordination environment. The N-H···O hydrogen bonds link the discrete structure of 1 into a 2D supramolecular architecture. The photoluminescent property of 1 has also been studied in the solid state at room temperature. 相似文献
11.
The reaction of 4,4′-diaminodiphenylmethane (dadm), malonic acid (H2mal) and Cu(NO3)2 in aqueous solution results in a discrete binuclear Cu(II) macrocycle: [Cu(dadm)(mal)- (H2O)]2(2H2O. It crystallizes in monoclinic, space group P21/c with a = 15.231(3), b = 11.847(2), c = 9.801(2)A,Z= 106.75(3)o, V = 1693.5(6)A3, Z = 2, C32H40Cu2N4O12, Mr = 799.76, Dc = 1.568 g/cm3, λ(MoK() = 0.71073A, μ = 1.325 mm-1, F(000) = 828, the final R = 0.0531 and Wr = 0.1244 for 3421 observed reflections with I > 2σ(I). Each Cu(II) is coordinated by two oxygen atoms from a mal ligand, two nitrogen atoms from two dadm ligands and a water oxygen atom to form a triangle bipyramidal motif. The title compound possesses a distorted macrocycle enclosed by dadm with approximate dimensions of 8.3A× 5.9A. 相似文献
12.
Synthesis and Crystal Structure of a Coordination Polymer {[Co(phth)(phen)(H_2O)]·(C_2H_5OH)}_n 总被引:1,自引:0,他引:1
1 INTRODUCTION Metal-organic coordination polymer has particu- lar and special structure characters with some caves, holes and channels[1], and can be used in selected catalysis, molecular recognition, reversible exchan- ge of host-guest molecules (ions), super purity sepa- ration, biological conductor[2~5], etc. In the past ten years, polymers with bridging ligand have been widely investigated[6, 7]. The development of supra- molecular architectures of inorganic-organic hybrid molecules … 相似文献
13.
A novel two-dimensional supramolecular complex [Mn(phen)(DPZDA)(H2O)]·2H2Ohas been synthesized by the reaction of Mn(CH3COO)2, 1,10-phenanthroline (phen) and H2DPZDA (3,5-dimethyl-pyrazine-2,6-dicarboxylic acid). Elemental analysis, IR spectra and X-ray singlecrystal diffraction were carried out to determine the composition and crystal structure of the title complex. Crystal data: triclinic system, space group P-1, a = 7.7474(13), b = 9.3381(15), c =15.146(3)(A), α = 93.872(3), β = 102.451(11), γ = 105.261(11)°, C20H20MnN4O7, Mr = 483.34, Z = 2,F(000) = 498, V = 1023.2(3)(A)3, Dc = 1.569 g/cm3, μ = 0.697 mm-1, -9≤h≤9, -11 ≤k≤ 10, -18≤l≤12, R = 0.0365 and wR = 0.0901 for 3585 independent reflections (Rint = 0.0165) and 2923observed reflections (I > 2σ(I)). Structural analysis indicates that Mn(Ⅱ) adopts a distorted octahedral geometry. The 2-D framework supramolecular structure of the title complex is constructed from hydrogen bonds and π…πinteractions. 相似文献
14.
The title compound, [Zn(Pybta)Cl2]n (Pybta = 1-(2-pyridylmethyl)benzontriazole), has a zigzag chain structure. It crystallizes in the monoclinic system, space group P21/c with a = 9.0103(11), b = 17.0276(18), c = 9.2288(11) , β = 101.309(6)o, Mr = 346.51, V = 1388.4(3) 3, Z = 4, Dc = 1.658 g/cm3, F(000) = 696, μ = 2.143 mm1, the final R = 0.0492 and wR = 0.1236 for 2545 observed reflections with I > 2σ(I). The Zn atom is four-coordinated by two N and two Cl atoms, forming a slightly distorted tetrahedral geometry. Each zigzag chain links its adjacent symmetry- related equivalents via multiple π-π interactions, which are not frequently observed in the previously reported architectures. 相似文献
15.
A new Gd(Ⅱ) complex [Gd2(μ-phth)3(b-pd)(H2O)5]n (phth = o-phthalato, b-pd = N,N- bipyridine) has been synthesized by the reaction of GdO2 with o-phthalate, H2O and 2,2′-bipyridine. The crystal structure has been determined by single-crystal X-ray diffraction. The crystal is of triclinic, space group P with a = 11.82920(10), b = 13.53550(10), c = 13.7381(2)(A), α = 88.99, β = 66.9120(10), γ = 66.2370(10)°, V = 1826.02(3)(A)3, Dc = 1.915 g/cm3, C34H30N2O17Gd2, Mr = 1053.10, F(000) = 1024, μ = 3.680 mm-1, Z = 2, R = 0.0612 and wR = 0.1320 for 6259 observed reflections (I > 2σ(I)). In the title complex, the Gd(II) ions are bridged by o-phthalate ligands in a bidentate mode, producing a 1D infi- nite chain structure. Each eight-coordinated Gd(Ⅱ) center is coordinated by eight oxygen atoms from phth to give a distorted dodecahedral geometry, and each nine-coordinated Gd(Ⅱ) center is coordi- nated by two N atoms from b-pd and seven oxygen atoms from phth to give a distorted geometry of capped square antiprism. The chains are linked by π-π interactions and hydrogen bonds between oxy- gen atoms of carboxylate groups and H2O molecules and hydrogen atoms of H2O, b-pd and o-phth molecules, forming an unusual three-dimensional coordination polymer. 相似文献
16.
1 INTRODUCTION In recent years, extensively attention has been fo- cused on the design and synthesis of d10 metal- based complexes[1, 2]. A series of d10 metal-organic frame- works have been described not only because of their intriguing structures but also due to their ptential ap- plications in photoluminescent fields[3~7]. Although phthalate ligand was successfully used to design and synthesize a wide variety of metal complexes, those containing Cd(II) complex are less considered[8~… 相似文献
17.
《Journal of Coordination Chemistry》2012,65(11):967-973
Reaction of a freshly prepared Ni(OH)2?2 x (CO3) x ·yH2O with maleic acid in H2O at room temperature afforded [Ni(H2O)6][Ni(H2O)2(C4H2O4)]·4H2O, which consists of [Ni(H2O)6]2+ cations, [Ni(H2O)2(C4H2O4)]2? anions and lattice H2O molecules. Ni atoms in cations are octahedrally coordinated and Ni atoms in anions are each octahedrally coordinated by bidentate chelating maleato ligands and two water molecules at trans positions. Cations and anions are interlinked by hydrogen bonds to form 1D chains, which are hexagonally arranged and connected by the lattice water molecules. When heated in a flowing argon stream, the compound decomposes, with complete dehydration being followed by dissociation of nickel maleate into NiO and maleic anhydride. 相似文献
18.
A binuclear complex [Cu2(phen)2(ip)(Hip)2]·4H2O has been synthesized by the reaction of Cu(CH3COO)2·H2O, phen(1,10-phenanthroline) and isophthalic acid (H2ip) under hydrothermal condition. Elemental analysis, IR spectra and X-ray single-crystal diffraction were carried out to determine the composition and crystal structure. Crystal data for this complex: monoclinic, space group C2/c, a = 19.214(3), b = 10.6973(14), c = 22.567(3) (A), β = 105.081(2)°,C24H19N2O8Cu, Mr= 526.95, Z = 8, F(000) = 2160, V= 4478.6(10)(A)3, Dc = 1.563 g/cm3, μ = 1.030mm-1, -24≤h≤16, -13 ≤k≤ 13, -28≤l≤28, R = 0.0369 and wR = 0.0819 for 4615 (Rint = 1.0357)independent reflections and 3290 observed ones (I> 2σ(Ⅰ)). Structural analysis shows that coordination geometry of Cu(Ⅱ) is a planar square, and the title complex exhibits a 2-D framework supramolecular structure by hydrogen bonds and π-π stacking interactions. 相似文献
19.
A transition metal substituted polyoxotungstate,[Cu(en)2(H2O)]2{PW11.5Cu0.5O40 [Cu(en)2]}·2H2O1 based on Keggin frameworks ,has been hydrothermally synthesized and charac-terized by IR,TGA and single-crystal X-ray structural analysis.It is interesting to find that the structure unit contains two different valence cations,namely,one[Cu(1)(en)2(H2O)] and one [Cu(2)(en)2(H2O)]2 .Data for the crystal:orthorhombic system,space group Pbca,a=21.585(2),b=20.695(2),c=26.137(3)(A),V=11675(2)(A)3,Z=8,Mr=3428.23,Dc=3.901 g/cm3,F(000)=12156,μ(MoKα)=23.932mm-1,the final R=0.0468 and wR=0.0969 for 6927 observed reflections(Ⅰ>2σ(Ⅰ)). 相似文献
20.
The title compound, α,α,β,β-5,10,15,20-tetrakis(2-aminophenyl)porphyrin, has been obtained and characterized by single-crystal X-ray diffraction.The crystal belongs to the monoclinic system, space group C2/c with a = 31.804(6), b = 19.314(4), c = 12.872(3) -, β = 90.592(3)°, Z = 4, V = 7907(3) -3, Dc = 1.193 g/cm3, Mr = 1419.67, λ(MoKα) = 0.71073 -, μ = 0.073 mm-1, F(000) = 2984, R = 0.0773 and wR = 0.2045.The crystallographic analysis indicates the existence of N-H…( intermolecular interactions and hydrogen bonds which link the complex molecules into a 3D network structure. 相似文献