Fluctuation theorems from non-equilibrium Onsager-Machlup theory for a Brownian particle in a time-dependent harmonic potential

We discuss the case of a Brownian particle which is harmonically bound and multiplicatively forced-namely bound by V(x,t)=1/2 a(t)x ² where a(t)is externally controlled-as another instance that provides a generalization of Onsager-Machlup’s theory to non-equilibrium states, thus allowing establishment of several fluctuation theorems. In particular, we outline the derivation of a fluctuation theorem for work, through the calculation of the work probability distribution as a functional integral over stochastic trajectories.      

Initial condition effects for a Brownian particle in a harmonic chain

The influence of initial deviations from bath equilibrium on the motion of a Brownian particle in a harmonic chain is investigated by exact calculation. These initial condition effects, which are excluded by convention in standard projection operator treatments of relaxation processes, are found to be relatively long-lived, contrary to usual assumption. For weak, localized initial deviations from bath equilibrium these effects on the motion are small in magnitude and may be accounted for by a modified initial condition on the particle velocity. For initial deviations involving many bath particles these effects are more substantial and retention of their time dependence in the particle equation of motion is generally required.For a correction to Ref. 2a see Ref. 3.     

The propagator for a time-dependent mass subject to a harmonic potential with a time-dependent frequency

We find the quantum propagator of the harmonic oscillator with a time-dependent mass solving directly the Schrödinger equation through a change of variable and a time reparametrization.     

Exact solution of the time-dependent harmonic plus an inverse harmonic potential with a time-dependent electromagnetic field

In this paper, the problem of the charged harmonic plus an inverse harmonic oscillator with time-dependent mass and frequency in a time-dependent electromagnetic field is investigated. It is reduced to the problem of the inverse harmonic oscillator with time-independent parameters and the exact wave function is obtained.     

Scaling dynamics for a particle in a time-dependent potential well

Some dynamical properties for a classical particle confined in an infinitely deep box of potential containing a periodically oscillating square well are studied. The dynamics of the system is described by using a two-dimensional non-linear area-preserving map for the variables energy and time. The phase space is mixed and the chaotic sea is described using scaling arguments. Scaling exponents are obtained as a function of all the control parameters, extending the previous results obtained in the literature.     

Scaling properties for a classical particle in a time-dependent potential well

Some scaling properties for a classical particle interacting with a time-dependent square-well potential are studied. The corresponding dynamics is obtained by use of a two-dimensional nonlinear area-preserving map. We describe dynamics within the chaotic sea by use of a scaling function for the variance of the average energy, thereby demonstrating that the critical exponents are connected by an analytic relationship.     

Brownian motion of a particle in a double well potential

The frequency dependent mobility of a Brownian particle moving in a double well potential is calculated for different damping parameters and temperatures by means of continued fraction approximations. These results are remarkably well reproduced by a simple memory function ansatz. Applications to the motion of Ag⁺ ions in Ag₃SX(X =I, Br) crystals are indicated.     

Thermodynamics of a colloidal particle in a time-dependent nonharmonic potential

We study the motion of an overdamped colloidal particle in a time-dependent nonharmonic potential. We demonstrate the first lawlike balance between applied work, exchanged heat, and internal energy on the level of a single trajectory. The observed distribution of applied work is distinctly non-Gaussian in good agreement with numerical calculations. Both the Jarzynski relation and a detailed fluctuation theorem are verified with good accuracy.     

Brownian motion under a time-dependent periodic potential proportional to the square of the position of a particle and classical fluctuation squeezing

A general stationary case of a Brownian particle with a time-dependent periodic potential proportional to the square of the position of the particle is treated. Even though the vigorous change of the time-dependent proportionality coefficient is applied, there are cases where the fluctuation of the particle decreases in contrary to our intuition, which is called classical fluctuation squeezing. We obtain time-average variances analytically for general cases of an arbitrary change in the coefficient and find conditions favorable for classical fluctuation squeezing. We introduce an asymmetric function behaves like trigonometric cosine one and consider its behavior explicitly.     

Escape rate of an active Brownian particle in a rough potential

We discuss the escape problem with the consideration of both the activity of particles and the roughness of potentials. We derive analytic expressions for the escape rate of an active Brownian particle in two types of rough potentials by employing the effective equilibrium approach and the Zwanzig method. We find that activity enhances the escape rate, but both the oscillating perturbation and the random amplitude hinder escaping.     

Brownian diode: Molecular motor based on a semi-permeable Brownian particle with internal potential drop

A model of an autonomous isothermal Brownian motor with an internal propulsion mechanism is considered. The motor is a Brownian particle which is semi-transparent for molecules of surrounding ideal gas. Molecular passage through the particle is controlled by a potential similar to that in the transition rate theory, i.e. characterized by two stationary states with a finite energy difference separated by a potential barrier. The internal potential drop maintains the diode-like asymmetry of molecular fluxes through the particle, which results in the particle?s stationary drift.     

外部信号驱动下胶原粒子在谐振势场中的协作效应

基于朗之万方程研究了一个运动在简谐势场中胶原粒子的热力学行为,给出了其在周期信号驱动下的有效温度和耗散功的解析表达式.结果表明：外部周期搅拌能够聚合环境热能传递给胶原粒子,使其有效温度大幅度增加,这是势场、外部信号及噪声的协作机理所引起;但是在共振条件下,外界所作的耗散功也达到极大. 关键词： 耗散功 有效温度 周期信号 协作效应     

Testing the energy diffusion approximation for the escape of a Brownian particle from a potential pocket

For the first time, the energy diffusion approximation is confronted at the percent level with the exact numerical modeling of thermal decay of a metastable state. This model is useful in many branches of natural sciences: e.g. in biology, nuclear physics, chemistry, etc. The exact (within the statistical errors about 2%) quasistationary decay rates result from the Langevin equations for the coordinate and conjugated momentum. For the energy (or action) diffusion approach, a Langevin-type equation for the action is constructed, validated, and solved numerically. The comparison of these two approaches is performed for four potentials (two of which are anharmonic) in a wide range of two dimensionless scaling parameters: i) the governing parameter G reflecting how high is the barrier with respect to the temperature and ii) the damping parameter φ expressing the friction strength. It turns out that the energy diffusion approach produces the rate which comes into 50%-agreement with the exact one only at φ < 0.02. Thus, we quantify, for the first time by our knowledge, the condition φ ≪ 1 known in the literature.     

Development of particle multiplicity distributions using a general form of the grand canonical partition function

Various phenomenological models of particle multiplicity distributions are discussed using a general form of a unified model which is based on the grand canonical partition function and Feynman's path integral approach to statistical processes. These models can be written as special cases of a more general distribution which has three control parameters which are a,x,z. The relation to these parameters to various physical quantities are discussed. A connection of the parameter a with Fisher's critical exponent τ is developed. Using this grand canonical approach, moments, cumulants and combinants are discussed and a physical interpretation of the combinants are given and their behavior connected to the critical exponent τ. Various physical phenomena such as hierarchical structure, void scaling relations, Koba–Nielson–Olesen or KNO scaling features, clan variables, and branching laws are shown in terms of this general approach. Several of these features which were previously developed in terms of the negative binomial distribution are found to be more general. Both hierarchical structure and void scaling relations depend on the Fisher exponent τ. Applications of our approach to the charged particle multiplicity distribution in jets of L3 and H1 data are given.     

Brownian motion of a quantum harmonic oscillator

The problem of describing the Brownian motion of a quantum harmonic oscillator or free particle is treated in the formalism of quantum dynamical semigroups. Certain inequalities involving the friction and diffusion coefficients and Planck's constant are derived. The nature of the quantum Langevin equation is discussed.     

Work distribution function for a Brownian particle driven by a nonconservative force

We derive the distribution function of work performed by a harmonic force acting on a uniformly dragged Brownian particle subjected to a rotational torque. Following the Onsager and Machlup’s functional integral approach, we obtain the transition probability of finding the Brownian particle at a particular position at time t given that it started the journey from a specific location at an earlier time. The difference between the forward and the time-reversed form of the generalized Onsager-Machlup’s Lagrangian is identified as the rate of medium entropy production which further helps us develop the stochastic thermodynamics formalism for our model. The probability distribution for the work done by the harmonic trap is evaluated for an equilibrium initial condition. Although this distribution has a Gaussian form, it is found that the distribution does not satisfy the conventional work fluctuation theorem.     

Photodetachment dynamics of H~- ion in a harmonic potential plus a time-dependent oscillating electric field

The photodetachment dynamics of H~- ion in a harmonic potential plus an oscillating electric field is studied using the time-dependent closed orbit theory. An analytical formula for calculating the photodetachment cross section of this system is put forward. It is found that the photodetachment cross section of this system is nearly unaffected for the weak oscillating electric field strength, but oscillates complicatedly when the oscillating electric field strength turns strong. In addition, the frequency of the harmonic potential and the oscillating electric field(the frequency of the harmonic potential and the frequency of the oscillating electric field are the same in the paper, unless otherwise stated.) can also affect the photodetachment dynamics of this system. With the increase of the frequency in the harmonic potential and the oscillating electric field, the number of the closed orbits for the detached electrons increased, which makes the oscillatory structure in the photodetachment cross section much more complex. Our study presents an intuitive understanding of the photodetachment dynamics driven by a harmonic potential plus an oscillating electric field from a space and time dependent viewpoint.This study is very useful in guiding the future experimental research for the photodetachment dynamics in the electric field both changing with space and time.     

Information theories for time-dependent harmonic oscillator

Information theories for the general time-dependent harmonic oscillator are described on the basis of invariant operator method. We obtained entropic uncertainty relation of the system and discussed whether it is always larger than or equal to the physically allowed minimum value. Shannon information and Fisher information are derived by means of density operator that satisfies Liouville–von Neumann equation and their characteristics are investigated. Shannon information is independent of time, but Fisher information is explicitly dependent on time as the time functions of the Hamiltonian vary. We can regard that the Fisher information is a local measure since its time behavior is largely affected by local arrangements of the density, whilst the Shannon information plays the role of a global measure of the spreading of density. To promote the understanding, our theory is applied to special systems, the so-called quantum oscillator with time-dependent frequency and strongly pulsating mass system.     

Brownian particle in an optical potential of the washboard type

Experimental observations of the fluctuation-driven net transport of silica microspheres are presented in a two-dimensional optical potential of circular symmetry created by a Bessel light beam. The optical field is tailored to break symmetry and create a static tilted periodic (washboard) potential. As the tilt of potential exceeds a threshold, a transition between locked and running modes is observed. The running mode manifests itself by the rapid accumulation of particles at the beam center.