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1.
Microwave-assisted synthesis of calix[4]resorcinarenes by cyclocondensation of various aldehydes and resorcinol catalysed by 12-tungstophosphoric acid type Keggin (H 3PW 12O 40·13H 2O) or concentrated HCl is described. Excellent isolated yields (up to 90%) were attained within short reaction times (typically, 3-5 min) when the reaction was performed under microwaves irradiation. 相似文献
2.
Calix[4]resorcinarene reacts with N, N, N", N"-tetraethyl- P-ethylphosphonous diamide to give dioxaphosphocines, whose hydrolysis with intracavity water yields phosphinoyl derivative of calix[4]resorcinarene. 相似文献
3.
Photoswitchable calix[4]resorcinarenes with different numbers of azo groups in the upper rim were synthesised by the reaction of bromomethylcavitand with 4-aminoazobenzene. UV-vis, 1H and 13C NMR, MALDI TOF-MS spectral data have been used to elucidate the structures of compounds. 相似文献
4.
The Mannich reaction involving calyx[4]resorcinarenes, aminoacetals, and formaldehyde in the molar ratio 1:4:4 yields calixarenes
containing aminoacetal fragments on the upper molecule rim. Four oxazinyl rings formed with the retention of acetal groups
as the formaldehyde amount was twofold increased. 相似文献
5.
The electrochemical oxidation of a number of aminomethylated calix[4]resorcinarenes (AMC) with different substituents at the nitrogen atom and the kinetics of nucleophilic substitution reactions of these compounds with p-nitrophenyl bis(chloromethyl)phosphinate were studied. The reactivity of the ionic associates of AMC in the nucleophilic substitution and the behavior of AMC in electrooxidation are determined by the same factors, namely, the amino-group basicity and the nature of the substituents at the nitrogen atom. These factors influence the ratio of the zwitter-ionic and anionic forms of AMC. 相似文献
6.
As a special subset of calix[4]arene, calix[4]resorcinarene is an excellent molecular platform which could be modified by introducing functional groups to multiple sites at the upper and lower rims. There are mainly three ways to build functionalized calix[4]resorcinarene derivatives: (1) modification on the C-2 sites of calix[4]resorcinarenes; (2) modification on the phenolic hydroxyl groups of calix[4]resorcinarenes; (3) modification on the bridging methylenes at lower rim of calix[4]resorcinarenes. Functionalized calix[4]resorcinarene derivatives play an important role in the development of self-assembly chemistry, among which hydrogen bonding and metal coordination are the two most common interactions to obtain multicomponent structures. Moreover, due to the excellent topological structures and various active substituents of functionalized calix[4]resorcinarene derivatives, their applications in various fields, such as nanoparticles, catalysts, fluorescent materials, and sensors, have been briefly presented in this paper. 相似文献
7.
Calixarenes (CAs) and calix[4]resorcinarenes are cavity compounds, chiral analogues of which have the potential to be used as reagents for the differentiation of enantiomers in NMR spectroscopy. The nature of the substituent groups attached to the cavity permits the preparation of organic- or water-soluble analogues. In NMR applications, chirality of the CAs or calix[4]resorcinarene is usually achieved through the attachment of enantiomerically pure substituent groups. The use of inherently chiral analogues for chiral differentiation is less common. The range of CAs and calix[4]resorcinarenes that have been used for chiral analysis in NMR spectroscopy is reviewed. 相似文献
8.
NMR methods are employed to study the effects of inorganic salts, solvents, and guest molecules of methylviologen (MV 2+) and choline (Ch +) on the aggregation properties of water-soluble tetramethylene-sulfonate-substituted calix[4]resorcinarenes containing methyl ( 1), amyl ( 2), and heptyl ( 3) substituents in the lower rim. It is established that, in aqueous solutions at concentrations of 1?C10 mM, compound 1 exists in the monomeric form; the size of aggregates of amphiphilic compound 2 gradually increases (aggregation number varies from 1 to 20); and hydrophobic compound 3 dissolves only in slightly alkaline aqueous solutions to form large micellar aggregates. For macrocycles 2 and 3, which are inclined to aggregation, the aggregate sizes depend on the concentration, pH, and ionic strength of solutions, as well as on the presence of organic solvents. Macrocycle 1 binds guest molecules Ch + and MV 2+ to yield inclusion complexes. In the presence of aggregates of substance 2, the binding of guest molecules is more efficient and they are encapsulated between the rim of one molecule and the tail of another molecule of compound 2. The presence of guest molecules enhances the aggregation of macrocycle 2. In the case of compound 3 solutions, guest Ch + molecules are predominantly localized in the hydrophobic environment of alkyl substituents of the host. 相似文献
9.
Russian Chemical Bulletin - Some features of the complexation of [Rh2(OAc)4?2H2O] with calix[4]resorcinarenes functionalized by aminoalkyl groups in the upper or lower rims in EtOH and Me2CO... 相似文献
10.
Iodine catalyzes the cyclocondensation of various aldehydes with resorcinol to give tetrameric cyclic products, resorcinarenes. Through the reaction of resorcinol with aromatic aldehydes, the product is obtained as a mixture of two isomers, the all- cis isomer (rccc) and the cis- trans- trans isomer (rctt), whereas a single diastereomer, the all- cis, is formed with aliphatic aldehydes. Besides excellent isolated yields, the use of iodine makes this procedure simple, convenient, cost-effective and practical. 相似文献
11.
Capacity titration and 1H NOESY 2D NMR were applied to investigation of intermolecular interactions and aggregation of amphiphilic calix[4]resorcinarenes (CRA 1, 2) modified with 1,2,4-triazine ( 1) and oxazine ( 2) functions in chloroform in the presence of cationic ( 3) and non-ionic ( 4) surfactants (SAA). Critical concentrations of micelle formation (CMC) indicate that the ability of CRA 1, 2 to form supramolecular aggregates like micelles or hybrid micelles with SAA 3, 4 only weakly depends on the constitution of CRA functional groups. In the case of the hybrid micelles, when CMC are defined by the nature of surfactants 3 or 4, the methyl and methylene groups of the hydrophobic fragments (CRA 1, 2) were found to interact with the hydroxy groups of SAA 3 and ethylene oxide moieties of SAA 4. 相似文献
12.
Supramolecular nanoaggregates formed through the association of amphiphilic sulfonatomethylated calix[4]resorcinarenes with different substituents on the lower rim (methyl, pentyl, heptyl) and number of aromatic, aliphatic, and cationic guests differing in their shapes and sizes were investigated in aqueous solution by various NMR techniques ((1)H, 2D NOESY, FT-PGSE). It was shown that slight variations of the alkyl chain length on the lower rim of calixresorcinarenes dramatically change their aggregation behavior. Unlike the other calixresorcinarenes studied, the "head-to-tail" packing mode is observed for calixresorcinarene with pentyl moieties on the lower rim, which is unusual for amphiphilic calixarene aggregates. This calixresorcinarene demonstrates the stronger binding capacity toward the guest molecules due to their encapsulation into the capsule-like aggregate subunits. The guest-host complexation modifies the properties of both components, with the size of the resulted colloid particles being controlled by the guest nature. 相似文献
13.
Water-soluble calix[4]resorcinarenes containing 3- and 4-hydroxyproline, d-nipecotic acid, (S)-2-(methoxymethyl)pyrrolidine, (S)-2-pyrrolidine methanol, and (S,S)-(+)-2,4-bis(methoxymethyl)pyrrolidine substituents are synthesized and evaluated as chiral NMR solvating agents. The derivatives with the hydroxyproline groups are especially effective at causing enantiomeric discrimination in the spectra of water-soluble cationic and anionic compounds with pyridyl, phenyl, and bicyclic aromatic rings. Binding studies show that mono- and ortho-substituted phenyl rings associate within the cavity of the calix[4]resorcinarenes, as do naphthyl rings with mono-, 2,3-, and 1,8-substitution patterns. Anthracene derivatives with an amino or sulfonyl group at the 1-position bind within the cavity, as well. Aromatic resonances of the substrates exhibit substantial upfield shifts because of shielding from the aromatic rings of the calix[4]resorcinarene. The effectiveness of the reagents at producing chiral recognition in 1H NMR spectra is demonstrated with sodium mandelate, the sodium salt of tryptophan, and doxylamine succinate. While no one reagent is consistently the most effective, the calix[4]resorcinarenes with trans-4-hydroxyproline and trans-3-hydroxyproline moieties generally produce the largest nonequivalence in the 1H NMR spectra of the substrates. 相似文献
14.
Kinetics of the reaction of alkylated polyethylene imines with 4-nitrophenyl bis(chloromethyl)-phosphinate in chloroform in the absence and in the presence of substituted calix[4]resorcinarenes were studied by UV spectrophotometry. It was shown that calixarenes forming mixed aggregates with polyethylene imines have a catalytic effect on the polymer phosphorylation process. The catalytic effect depends on the structure of polyethylene imine and the component ratio in the system. 相似文献
15.
Russian Journal of General Chemistry - 相似文献
16.
Aggregation of amphiphilic calix[4]resorcinarenes (CRA) modified by carboxymethyl ( 1), 2-hydroxyethyl ( 2), methylamino acetal ( 3), and aminomethyl ( 4) fragments and their interaction with some synthetic ( 5, 6) and natural ( 7, 8) surfactants in the low-polarity solvent (chloroform) were studied by permittivity measurements and FT-IR spectroscopy. Compounds
1–4 and surfactants form aggregates at critical micelle concentrations (CMC) of 2.0·10 −5–7.5·10 −5 and 1.7·10 −5–2.0·10 −3 mol L −1, respectively. The CMC values of CRA—surfactant mixed aggregates depend on the surfactant structure and the structure and
concentration of CRA. Analysis of the IR spectra of solutions of a series of amphiphilic CRA ( 2–4, 9, 10) and their mixtures with the cationic surfactant N-cetyl- N,N-dimethyl- N-(2-hydroxyethyl)ammonium bromide ( 5) showed that an increase in the concentration of the solutions in individual and mixed systems is accompanied by a decrease
in the molar integral intensities and intensities in the maxima of the absorption bands of the O—H and C—H bonds down to the
CMC point, after which these values change slightly. The discovered effect, which is differently pronounced for all systems
studied, indicates that both the polar “head” groups and nonpolar fragments of CRA and surfactant are involved in the formation
of supramolecules of the reverse micelle type in all cases.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 459–466, March, 2007. 相似文献
17.
A simple synthesis of novel and known calix[4]resorcinarenes derivatives has been achieved by the condensation of resorcinol and different aromatic aldehydes in the presence of catalytic amounts of Fe 3O 4 nanoparticles under solvent-free conditions.The experimental conditions have been thoroughly optimized and established,allowing significant rate enhancements and good to excellent yields.The reactions can be run safely without using any toxic organic solvents under mild reaction conditions.The Fe 3O 4 nanoparticles were characterized by powdered X-ray diffraction(XRD),transmission electron microscopy(TEM) and FT-IR spectroscopy. 相似文献
18.
杯芳烃是一类由对位取代的苯酚与甲醛缩合而成的环状低聚物[1],其结构的下缘排列着数个羟基,上缘则具有疏水空穴;最大的特点是具有由苯环单元组成的富电子的、大小可调的三维空腔和环形排列的氧原子,既可络合离子又可包结中性分子,与冠醚一般只络合离子、环糊精只包结中性分子相比,杯芳烃在分子识别方面更有发展潜力,被誉为超分子化学中继环糊精、冠醚之后的第三代主体分子[1-3]。壳聚糖是一种天然高分子化合物,其分子中含有羟基和氨基,具有较强的吸附和螯合作用。改性壳聚糖现已被广泛应用于金属分离、废水处理等领域。[4-10]本文将杯… 相似文献
19.
The condensation of 1,1-bis(chlorocarbonyl)metallocenes and p-tert-butylcalix[4]arene in toluene leads to novel metallocene calix[4]arenes in which the metallocene subunit bridges the opposite hydroxy groups of the parent calixarene.Presented at the Fourth International Symposium on Inclusion Phenomena and the Third International Symposium on cyclodextrins, Lancaster, U.K., 20–25 July 1986. 相似文献
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