一种新型红敏光致聚合物全息特性研究

对一种新合成的红敏光致聚合物进行了一系列研究 ,实验表明用该材料制作的全息干板获得了近 70 %的实时衍射效率 ,从理论上解释了曝光量与衍射效率的关系曲线 ,并研究了该材料的其它特性。这些结果表明 ,该红敏光致聚合物材料具有较好的实时全息记录特性。     

新型含偶氮侧链聚合物中光致各向异性及偏振全息记录

研究了偶氮侧链聚合物中光致各向异性和偏振全息, 确认在这种聚合物中分析光致各向异性动力学过程时, 必须考虑光漂白效应的影响, 测量表明该聚合物具有大的光致双折射（Δｎ ＝７．８×１０－ ３）, 并在其中记录了高衍射效率（η＝ １９．３％ ）的偏振全息图     

掺杂PbSe/PVA量子点的光致聚合物全息特性

通过原位合成法以聚乙烯醇辅助合成了6.5nm、10nm和15nm的PbSe量子点,研究了掺杂PbSe量子点的光致聚合物的全息特性.将三种尺寸的PbSe量子点按不同浓度分别掺入光致聚合物中,制成无机-有机复合型光致聚合物膜,并对其全息性能进行研究.复合聚合物膜的UV-Vis吸收光谱表明掺入的PbSe量子点并未与聚合物中的有机组分发生化学反应.采用氩氪离子激光器输出的647nm红光研究了复合聚合物膜的透过率和全息记录光栅的布喇格偏移与衍射效率.透过率曲线表明PbSe量子点在复合聚合物膜中分散良好,膜表面均匀.由于PbSe量子点在聚合物链中起支撑作用,复合聚合物膜在全息记录过程中不易发生形变,从而增加了聚合物膜的抗缩皱能力.衍射效率曲线表明掺入PbSe量子点的复合聚合物膜的衍射效率比未掺杂的有所提高.此外,体系存在一个最优值,当掺入平均粒径为10nm且浓度为3.6×10-6 mol/L的PbSe量子点时,样品的透过率达到84%,衍射效率从67.2%提升到89.7%,缩皱率降低到0.8%,极大提高了材料的全息性能.     

掺杂TiO2纳米颗粒的抗缩皱光致聚合物全息特性的研究

报道了一种掺杂亲水性TiO₂纳米颗粒的丙烯酰胺基光致聚合物厚膜的全息特性.实验结果表明,掺杂TiO₂纳米颗粒后的聚合物材料不仅在曝光过程中厚度缩皱有了明显的降低,而且衍射效率和其他性能参数都有了一定的改善,同时存在一个最佳的掺杂浓度,使得材料的最大衍射效率可以达到92.3%,最大折射率调制度达到2.09×10^-3,体积缩皱降低至0.80%. 关键词： 全息 光致聚合物 衍射效率 布拉格偏移     

番红花红T光敏感光致聚合物全息存储材料

制备了一种以番红花红T为光敏剂的新型全息存储材料,主要用Ar⁺激光器的514.5nm波长的绿光研究材料的全息特性.研究表明,该材料具有较高的衍射效率、曝光灵敏度和较大的折射率调制度,衍射效率近40%,灵敏度为7.22×10^-4cm²/mJ,折射率调制度为3.65×10^-4,同时,在读出时必须考虑布拉格偏移对全息存储的影响.在介质膜中存储了全息图像,再现图像较为清晰,说明该材料适合用作高密度全息存储介质. 关键词： 全息存储 光致聚合物 衍射效率 布拉格偏移     

绿敏光致聚合物的制备及其光全息存储性能研究

报导了一种新型的对绿光敏感的光致聚合物材料。该材料以丙烯酰胺为单体，由光引发剂，共引发剂，成膜物等组成。本材料记录的全息图衍射效率可达55％。在光聚物上采用角度复用技术存储了10幅图像，得到的再现像信噪比较高。说明该材料适合于大容量体全息存储。     

含双引发剂的光致聚合物全息特性研究

制备了一种三乙醇胺与N-苯基苷氨酸为共同引发剂的丙烯酰胺基光致聚合物全息存储材料,并用He-Ne 激光器633 nm波长的光对样品进行曝光测试.实验表明,与单引发剂的光致聚合物相比,薄膜的质量有一定的提高,在曝光灵敏度变化不大的情况下,衍射效率有很大提高.优化两种引发剂浓度后,此种共同引发的光致聚合物材料呈现的衍射效率达到54%,曝光灵敏度为1.85×10－2cm2/mJ.还研究了此种光致聚合物的透过率随曝光时间和曝光强度的变化,说明此种光致聚合物材料内部均匀性好,对光的散射小.     

丙烯酰胺基光致聚合物全息光栅的动力学研究

研究了光致聚合物的光化学反应和单体扩散反应的理论模型及动力学参数. 合成了以聚乙烯醇为粘结剂,三乙醇胺为引发剂,藻红B敏化的丙烯酰胺基光致聚合物全息存储材料,通过对测定的透过率和衍射效率进行曲线拟合,分析了染料浓度对光致聚合物的摩尔吸收系数ε、量子产率Φ和光化漂白速率常数k等光化动力学参数的影响规律,以及曝光强度对聚合反应速率k₀、扩散时间常数τ_D和最大折射率调制度Δn等扩散动力 关键词： 光致聚合物 透过率 衍射效率 动力学参数     

可擦除光存储教学实验的开设

研究了在聚甲基丙稀酸甲脂（PMMA）中掺杂羚羟基亚甲基苯胺N-salicylideneaniline(SA)样品的可擦除光存储特性，依据相干光调制光强分布诱导光异构形成相位光栅和光异构产生压力梯度引起质量输运形成表面光栅机理，分析了两光栅的相位关系，合理解释了写入过程和擦除过程中衍射信号强度随时间的变化关系，通过阐述上述复杂的分析过程，培养和提高学生分析问题与解决问题的能力。     

Annealing effects on the surface morphologies of thin PS/PMMA blend films with different film thickness

The surface morphology evolution of three thin polystyrene (PS)/polymethyl methacrylate (PMMA) blend films (<70 nm) on SiO_x substrates upon annealing were investigated by atomic force microscopy (AFM) and some interesting phenomena were observed. All the spin-coated PS/PMMA blend films were not in thermodynamic equilibrium. For the 67.1 and the 27.2 nm PS/PMMA blend films, owing to the low mobility of the PMMA-rich phase layer at substrate surfaces and interfacial stabilization caused by long-range van der Waals forces of the substrates, the long-lived metastable surface morphologies (the foam-like and the bicontinuous morphologies) were first observed. For the two-dimensional ultrathin PS/PMMA blend film (16.3 nm), the discrete domains of the PS-rich phases upon the PMMA-rich phase layer formed and the secondary phase separation occurred after a longer annealing time.     

吲哚俘精酰胺的偏振全息图像光存储实验研究

在吲哚俘精酰胺/PMMA薄膜上记录了同偏振全息和正交偏振全息图，获得了它们的再现衍射像.实验结果表明：吲哚俘精酰胺具有光致各向异性，可以进行正交偏振全息记录.在偏振全息中，衍射光的偏振方向依赖于物光和再现光的偏振方向，衍射像的噪声主要来源于再现光照射到样品上引起的散射.正交偏振全息可以得到比同偏振全息更高信噪比的衍射像.存储于样品上的全息图在室温下黑暗处至少可以保存五个月而衍射效率无明显下降.结果表明，吲哚俘精酰胺是一种可用于偏振全息的可擦重写记录介质. 关键词： 偏振全息 光致各向异性 俘精酸酐 光致变色     

Pixel-matched holographic data storage with megabit pages

Digital data-page holograms consisting of 1024 x 1024 arrays of binary pixels have been stored and subsequently retrieved with an optical exposure consistent with a data rate 1 Gbit /s. Each input pixel was precisely registered with a single detector pixel, and a raw bit-error rate as low as 2.4 x 10(-6) was demonstrated with global-threshold detection. To our knowledge, this is the first demonstration of the often-cited goal of holographic data storage of megabit data pages and a gigabit-per-second data rate.     

二芳烯材料在重复擦写体全息存储中的应用研究

二芳烯材料是一种性能优异的光致色变材料,具有很好的抗疲劳性能,一般能重复擦写上万次,而不损失其性能。通过体全息光栅记录实验、角度复用体全息存储实验、重复擦写及强光记弱光读等实验,对二芳烯材料在重复擦写体全息存储中的应用进行了系统研究。由于二芳烯材料具有很高的折射率调制度(Δn=1.15×10-3)、可多次重复擦写、强光记弱光读的准非易失等性能,在可重复擦写的体全息存储中具有广阔的应用前景。     

Fabrication and characterization of poly(methyl methacrylate) photopolymer doped with 9,10-phenanthrenequinone (PQ) based derivatives for volume holographic data storage

We present our studies on the photopolymer of poly(methyl methacrylate) (PMMA) doped with 9,10-phenanthrenequinone based derivatives for volume holographic storage. By introducing different functional groups on the side-chain of 9,10-phenanthrenequinone molecule, the holographic characteristics of the material can be modified. The photoreaction involved with the holographic recording in the samples was investigated by measuring UV-Vis absorption spectrum and mass spectrum. The experimental results show that the similar behaviors were exhibited in these photopolymers. It is found that phase hologram recording in our PQ derivatives doped PMMA photopolymer involves a structure change of the quinone based molecule, which induces a strong change of the refractive index. Experimental characterizations on holographic data storage, including material sensitivity, dynamic range (M#) and bit-error-rate have been performed. We found that, by selecting appropriate functional groups, an improvement in sensitivity and M# for holographic data storage can be achieved.     

用飞秒激光脉冲在PMMA内页面式写入三维光存储的研究

用微透镜阵列聚焦放大的钛宝石飞秒激光脉冲到PMMA内部，在每个微透镜的焦点处造成光学损伤，通过改变焦点的位置，实现了三维数据的写入，用800 μJ 1 kHz重复率的飞秒激光记录速度达到20Mbit/s.阐述了数据信息的调制、写入和读出，分析了微透镜阵列参数对存储密度、数据记录速度和能量阈值的影响，建议了提高存储密度的两种有效途径. 关键词： 三维光存储 微透镜阵列 飞秒激光 PMMA     

Ruggedized digital holographic data storage with fast access

Recent investigations in holographic mass memory systems have produced proof-of-concept demonstrations that have highlighted their potential for providing unprecedented capacity, data transfer rates and fast random access performance (Heanue et al. 1994; Hong et al. 1995; Psaltis and Mok 1995; Bernal et al. 1996; McMichael et al. 1996). The exploratory nature of most such investigations has been largely confined to benchtop experiments which have ignored the practical constraints of packaging and environmental concerns. We have embarked on an effort to demonstrate the holographic mass memory concept by developing a compact prototype system geared for avionics and similar applications which demand the following features (mostly interdependent factors): (1) solid state design (no moving parts), (2) fast data seek time, (3) robust with respect to environmental factors (temperature, vibration, shock). In this paper, we report on the development and demonstration of two systems, one with 100 MB and the other with more than 1 GB of storage capacity. Both systems feature solid state design with the addressing mechanism realized with acoustooptic deflectors that are capable of better than 50 sec data seek time. Since the basic designs for the two systems are similar, we describe only the larger system in detail. The operation of the smaller system has been demonstrated in various environments including hand-held operation and thermal/mechanical shock; a photograph of the smaller system is provided, as well as actual digital data retrieved from the same system.     

球面波条件下体全息存储的衍射特性分析

从理论上推导了球面波作为参考光和读出光时体全息存储的相对衍射效率和晶体旋转角度之间的关系,对得到的衍射效率的理论公式进行了数值模拟,并且对模拟的结果进行了分析。结果表明,球面波系统的存储容量更高,角度选择性更好,并且有利于系统的小型化。     

Multiplexed phase-conjugate holographic data storage with a buffer hologram

We describe and demonstrate a volume holographic storage system in which a phase-conjugate object beam is reconstructed by the same reference beam that was used for recording. An intermediate hologram is used as a temporary buffer, recorded with its own reference beam and the data-bearing object beam. Reading this buffer hologram with the phase conjugate of its reference beam reconstructs the phase conjugate of the object beam, which can then be recorded into the desired volume hologram for long-term storage. This method combines the immunity to lens aberrations provided by phase-conjugate readout with the simplicity of using the same multiplexed reference beam for both recording and readout. Only a single pair of phase-conjugate reference beams is required. Experimental results are shown with a single LiNbO(3):Fe crystal used as both buffer and storage holograms and a self-pumped phase-conjugate mirror in BaTiO(3) that provides the pair of phase-conjugate reference beams.