共查询到19条相似文献,搜索用时 203 毫秒
1.
Mg2+对Fe:LiNbO3晶体光折变响应时间的影响 总被引:3,自引:3,他引:0
在Fe:LiNbO3中掺进3mol%和6mol%MgO,生长了Mg:Fe:LiNbO3晶体.测试了Mg:Fe:LiNbO3晶体抗光致散射能力、衍射效率、响应时间和光电导.推导响应时间与光电导之间的关系.在Fe:LiNbO3晶体中掺进6mol%的Mg2+,它的抗光致散射能力比Fe:LiNbO3晶体提高一个数量级,响应速度比Fe:LiNbO3晶体提高四倍. 相似文献
2.
Mg:Fe:LiNbO3晶体的生长及光学性能研究 总被引:6,自引:6,他引:0
在Fe:LiNbO3中掺进MgO和Fe2O3以提拉技术生长Mg:Fe:LiNbO3晶体.对晶体进行极化和还原处理.测试晶体的吸收光谱,Mg:Fe:LiNbO3晶体吸收边相对Fe:LiNbO3晶体发生紫移.测试晶体的红外光谱,Mg:(5 mol%)Fe:LiNbO3晶体OH-吸收峰由Fe:LiNbO3晶体的3482 cm-1移到3534 cm-1.采用锂空位模型阐述Mg:Fe:LiNbO3晶体,吸收边和OH-吸收峰移动的机理.测试晶体的抗光致散射能力.Mg:(5 mol%)Fe:LiNbO3晶体抗光致散射能力比Fe:LiNbO3晶体提高一个数量级以上.测试晶体的衍射效率和响应时间.Mg:Fe:LiNbO3晶体响应速度比Fe:LiNbO3晶体提高四倍. 相似文献
3.
掺镁铌酸锂晶体抗光损伤机理的研究 总被引:3,自引:1,他引:2
通过测试Mg(5mol%):LiNbO3、Mg(4m0l%):LiNbO3和LiNbO3等晶体的光损伤阈值、红外透射光谱、倍频性能等,研究了Mg2+在Mg:LiNbO3晶体中所处的状态以及高掺镁抗光损伤能力增强的机理。 相似文献
4.
In∶Nd∶LiNbO3晶体倍频性能的研究 总被引:1,自引:1,他引:0
在 LiNbO3中掺进In2O3和Nd2O3, 以Czochralski技术生长了In∶Nd∶LiNO3晶体. 通过光斑畸变法测得In∶Nd∶LiNbO3晶体的光损伤阈值为1.98×104 W/cm2, 比Nd∶LiNbO3晶体的1.6×102 W/cm2高两个数量级以上;晶体吸收光谱的测试表明, In∶Nd∶LiNbO3晶体的吸收边相对Nd∶LiNbO3晶体发生紫移. 研究了In∶Nd∶LiNbO3晶体的倍频性能, 结果表明, In∶Nd∶LiNbO3晶体的相位匹配温度在室温附近, 倍频转换效率比Nd∶LiNbO3晶体提高二倍. 相似文献
5.
采用改进的坩埚下降法成功地生长了Tm/Yb共掺氟化钇锂单晶. 该单晶体具有每吸收一个蓝色光子并能发射出2个1000 nm近红外光子的下转换发光效应. 测定了样品的激发光谱、发射光谱和荧光衰减曲线. 在465 nm蓝光激发下观察到由Yb3+:2F5/2→2F7/2能级跃迁所致的960~1050 nm 波段的发射带,此发光带源于Tm3 对Yb3 离子的能量下转换过程. 应用Inokuti-Hirayama模型,研究了晶体的能量转换过程,结果表明Tm3 向Yb3 的能量传递是一个电偶极子相互作用机制过程. 当Tm3 与Yb3 离子的掺杂浓度为0.49mol%与5.99mol%时,单晶的量子剪裁效率达到最大值167.5%. 相似文献
6.
本文引入与浓度和厚度有关的kNL待定参数, 在J-O理论基础上, 对Er3+/Yb3+掺杂的LiNbO3和LiTaO3单晶衬底上 的多晶水热外延样品进行了基于吸收光谱的拟合计算. LiNbO3:Ω2=2.34× 10-20 cm2, Ω4=0.77× 10-20 cm2, Ω6=0.31×10-20 cm2, kNL=4.32× 10-2 mol·m-2. LiTaO3:Ω2=1.68×10-20 cm2, Ω4=0.84×10-20 cm2, Ω6=0.45×10-20 cm2, kNL=9.17×10-3 mol· m-2. 该方法可尝试推广到粉体或胶体等难以直接获得浓度和厚度数据的体系. 经上转换发光测试及光谱参数计分析认为Er3+/Yb3+离子的掺杂浓度比为1:1的情况下, 样品呈现绿色上转换发光光谱; 可尝试以降低基质声子能量的方法提高4I13/2能级 对2H11/2和4S3/2能级的量子剪裁效率. 相似文献
7.
Ce:Co:LiNbO3晶体光折变性能研究 总被引:4,自引:4,他引:0
在LiNbO3中掺进CeO2和Co3O4,以Czchralski技术首次生长Ce:Co:LiNO3, Ce:LiNbO3, Co:LiNbO3晶体.通过测试Ce:LiNbO3, Co:LiNbO3和Ce:Co:LiNbO3晶体的指数增益系数, 位相共轭反射率和响应时间,计算晶体的有效载流子浓度和光电导.Ce离子能提高LiNbO3晶体光折变灵敏度,Co离子能提高LiNbO3晶体的响应速度和抗光致散射能力,从而Ce:Co:LiNbO3晶体具有较高的指数增益系数,位相共轭反射率,响应速度.Ce:Co:LiNbO3晶体具有优良的光折变性能. 相似文献
8.
利用高能离子研究了110 keV 的He+注入Al2O3单晶及随后230 MeV的208Pb27+辐照并在不同温度条件下退火样品的光致发光的特性. 从测试结果可以清楚地看到在375 nm,390 nm,413 nm 和450 nm 出现了强烈的发光峰. 经过600 K退火2 h后测试结果显示,390 nm发光峰增强剧烈,而别的发光峰显示不明显. 在900 K退火条件下,390 nm的发光峰开始减弱相反在510 nm出现了较强的发光峰,到1100 K退火完毕后390 nm的发光峰完全消失,而510 nm的发光峰相对增强. 从辐照样品的FTIR谱中看到,波数在460—510 cm-1间的吸收是振动模式,经过离子辐照后,吸收带展宽,随着辐照量的增大,Al2O3振动吸收峰消失,说明Al2O3振动模式被完全破坏. 1000—1300 cm-1之间为Al-O-Al桥氧的伸缩振动模式,辐照后吸收带向高波数方向移动. 退火后的FTIR谱变化不大. 相似文献
9.
LiIO3晶体的受激拉曼散射 总被引:1,自引:0,他引:1
采用腔外单次通过方式,测量了LiIO3晶体在532 nm皮秒脉冲下的受激拉曼散射。实验中观察到3级斯托克斯线(556.07,582.30, 611.76 nm)和1级反斯托克斯线(509.57 nm),由此可计算出其频率间隔为820 cm-1。测量了LiIO3晶体各级拉曼散射谱线的阈值和增益系数,受激拉曼散射的整体转换效率达到56%。基于LiIO3晶体实现了皮秒外腔式拉曼激光器的运转,双波长输出总转换效率为27%,最大输出能量1.4 mJ。 相似文献
10.
一种印刷型薄膜太阳能电池p-n结调制技术 总被引:1,自引:0,他引:1
能带值为0.5~0.85 eV材料的稀缺是多结太阳能电池面临的一个主要挑战,本文使用非真空的机械化学法合成了能带值为0.83 eV的Cu2SnS3化合物,使用印刷技术将其制备成吸收层薄膜,并采用superstrate太阳能电池结构(Mo/Cu2SnS3/In2S3/TiO2/FTO glass)对其光伏特性进行了研究.实验表明所制备的太阳能电池短路电流密度、开路电压、填充因子和转换效率分别为12.38 mA/cm2、320 mV、0.28和1.10%.此外,为更好地满足多结太阳能电池对电流匹配的需求,本文对所制备太阳能电池的Cu2SnS3/In2S3 p-n结进行了分析.通过在p-n结界面植入一层薄的疏松缓冲层,使调制后的太阳能电池短路电流密度从最初的12.38 mA/cm2增加到了23.15 mA/cm2,相应太阳能电池转换效率从1.1%增加到了1.92%.该p-n调制技术对印刷型薄膜太阳能电池具有重要借鉴意义. 相似文献
11.
Zuo Xiaoxi 《Optik》2005,116(7):361-364
Fe:LiNbO3 and In:Fe:LiNbO3 crystals were grown by Czochralski method. The absorption spectra were measured to investigate their defect structure. The photo damage resistance and photorefractive properties were measured. The photo damage resistance of the In:Fe:LiNbO3 crystal in which the In concentration is above the threshold value is one order of magnitude higher than that of the Fe:LiNbO3 crystal. The mechanisms of the violet shift of the absorption edge and the enhancement of the photorefractive effect of In:Fe:LiNbO3 crystals were investigated. 相似文献
12.
Doping MgO, MnO and Fe2O3 in LiNbO3 crystals, tri-doped Mg:Mn:Fe:LiNbO3 single crystals were prepared by the conventional Czochralski method. The UV-vis absorption spectra were measured and the shift mechanism of absorption edge was also investigated in this paper. In Mg:Mn:Fe:LiNbO3 crystal, Mn and Fe locate at the deep level and the shallow level, respectively. The two-photon holographic storage is realized in Mg:Mn:Fe:LiNbO3 crystals by using He-Ne laser as the light source and ultraviolet as the gating light. The results indicated that the recording time can be significantly reduced for introducing Mg2+ in the Mg:Mn:Fe:LiNbO3 crystal. 相似文献
13.
以掺杂4 mol%Hf4+的LiNbO3:Fe:Hf系列晶体([Li]/[Nb]比变化)为研究对象,研究了系列晶体的可见吸收光谱,在632.8nm的写入光下晶体的衍射效率、灵敏度和抗光散射能力在不同[Li]/[Nb]下的变化规律.研究发现Hf4+的浓度达到阈值浓度后,随着[Li]/[Nb]比的增大,晶体的可见吸收边会发生红移,而且晶格中[Fe2+]/[Fe3+]也会增加,这就导致随着[Li]/[Nb]比的增加,样品的衍射效率逐渐减小,写入时间缩短,灵敏度增大.同时,在晶体中,随着[Li]/[Nb]的增大,陷阱中心Fe2+Li数量增大会使得晶体抗光散射能力减弱. 相似文献
14.
Xiangli Liu 《Optik》2014
Congruent Zn(7 mol%):Ce:Cu:LiNbO3 single crystal was grown by the Czochralski method in air. The occupation mechanism of the Zn2+ was discussed by an infrared transmittance spectrum. The nonvolatile holographic recording in Zn(7 mol%):Ce:Cu:LiNbO3 single crystal was measured by two-photon fixed method. Zn(7 mol%):Ce:Cu:LiNbO3 single crystals present the faster recording time and higher light-induced scattering resistance ability comparing with Ce:Cu:LiNbO3 single crystals. 相似文献
15.
Undoped and MgO doped Lithium niobate single crystals were grown by the Czochralski technique. Comparative study of the optical properties of undoped and 7 mol% MgO doped LiNbO3 crystal was undertaken. The effect of doping on refractive indices as well as second harmonic generation has been experimentally analyzed. The results of the polarization characteristics of second harmonic generation (SHG) support the major contribution of Li-O bonds to optical nonlinearity. MgO doping reduces the number of localized excitons and the grown LiNbO3 crystal approaches the stoichiometric composition. This causes blue shift in the absorption edge of the crystals. 相似文献
16.
The new non-volatile holographic storage materials, Zn:Mn:Fe:LiNbO3 crystals, were prepared by Czochralski technique. Their microstructure was measured and analyzed by infrared (IR) transmission spectra. The optical damage resistance of Zn:Mn:Fe:LiNbO3 crystals was characterized by the transmitted beam pattern distortion method. It increases remarkably when the concentration of ZnO is over a threshold concentration. Its value in Zn(7.0 mol%):Mn:Fe:LiNbO3 crystal is about three orders of magnitude higher that in Mn:Fe:LiNbO3 crystal. The photoinduced birefringence change was measured by the Sénarmont's method. It decreased with ZnO concentration increasing. The dependence of the defects on the optical damage resistance was discussed. 相似文献
17.
Hongxin Shi Xiudong Sun Suhua Luo Yongyuan Jiang Qingxin Meng 《Optics & Laser Technology》2010,42(7):1118-1121
A series of Hf:Fe:LiNbO3 crystals were grown by the Czochralski technique with various doping concentrations of HfO2. Their defect structures were analyzed by the UV-visible absorption spectra and infrared absorption spectra. The optical damage resistance of Hf:Fe:LiNbO3 crystals was measured by the photo-induced birefringence change and the transmitted light spot distortion method. The results show that the optical damage resistance ability of Hf:Fe:LiNbO3 crystals enhances remarkably with the HfO2 concentration increasing when the HfO2 concentration is lower than its threshold concentration (4 mol%). However, when the HfO2 concentration exceeds its threshold concentration, the optical damage resistance ability of the crystals returns to decrease. This unusual behavior is explained by using the photovoltaic field produced in the crystals. 相似文献
18.
In this paper, a series of Hf,Ce co-doped lithium niobate crystals with various HfO2 concentrations were grown by Czochralski method. The ultraviolet-visible absorption spectra and the infrared transmittance spectra were measured to study defect structure of the crystals. The optical damage resistance was measured by the transmitted facula distortion method. The results showed that the optical damage resistance of Hf:Ce:LiNbO3 was greatly improved when the Hf-doping concentration was above 4 mol%. 相似文献
19.
A series of Mg:Ce:Cu:LiNbO3 crystals has been grown by Czochralski method. Their infrared transmittance spectra and ultraviolet-visible absorption spectra were measured and discussed to investigate their defect structure. The nonvolatile holographic recording of Mg:Ce:Cu:LiNbO3 crystals was characterized by the two-photon fixed method. We found that the recording time of Mg:Ce:Cu:LiNbO3 crystals became shorter and nonvolatile diffraction efficiency decreases with the increase of Mg doping concentration, especially doping with Mg approaches and exceeds the so-called threshold. And the nonvolatility vanishes when the concentration of MgO exceeds 4 mol%. The intrinsic and extrinsic defects were discussed to explain the nonvolatile holographic properties in the Mg:Ce:Cu:LiNbO3 crystals. 相似文献