冷凝器滴状冷凝的动态描述及接触角的选择

从化学势变化的角度对液滴的冷凝过程进行了动态描述;给出了实现持续的Brown凝并的条件;结合冷凝器壁面液滴的脱落半径与接触角的关系,求出了滴状冷凝时液滴接触角的最优选择范围. 关键词： 化学势 临界体积 Brown凝并 接触角脱落半径     

冷凝器滴状冷凝的超临界系数和BrOWn凝并

在文献[１］的基础上引入了超临界系数以描述液滴冷凝过程；证明了当液滴凝聚相同数量的气相分子时，接触角大于９０°的冷凝器壁面球冠形液滴的化学势减少量将大于冷凝器内部球形液滴的化学势减少量，并且这种化学势减少量均与液滴的曲率半经的４次方成反比，从而将导致冷凝器内部发生Ｂｒｏｗｎ 凝并过程； 探讨了提高冷凝速率的有效途径．     

冷凝器壁面滴状冷凝的热力学机理及最佳接触角

应用自由能判据证明了冷凝器壁面液滴的力学平衡条件与接触角有关,进而证明了当壁面液滴与壁面的接触大于90°时,冷凝器壁面液滴的化学势将小于同曲率的球形液滴的化学势;另外,在相同饱和比下,壁面液滴的临界半径也小于球形液滴的临界半径.而在接触角小于90°时,情况则恰好相反.正是由于这双重原因,使得滴状冷凝的传热性能大大优于膜状冷凝的传热性能,并由此求出了冷凝器壁面液滴的最佳接触角. 关键词：     

液滴碰撞不同接触角线缆表面的模拟

针对常见的液滴输电线缆搭建对应的计算模型,通过Fluent内置的VOF对不同疏水性表面进行计算,讨论液滴与线缆的接触时间、铺展半径与接触角度之间的关系,并分析不同接触角下液滴的压力云图和速度矢量图。模拟计算结果显示：液滴与壁面接触的运动状态受壁面接触角的影响,液滴铺展面积和接触时间与壁面接触角呈反比关系;提高壁面接触角会降低铺展面积、减少接触时间,加快液滴的回缩、回弹,运动液滴最终滑落离开壁面;小接触角壁面铺展面积增大、接触时间增加,液滴最终完全铺展停留于壁面上。研究结果对探究不同疏水性下液滴在线缆壁面结冰的原理及特性具有一定的指导和参考意义。     

滴状冷凝中液滴的内外压差及临界半径

用热力学方法证明了壁面上球冠形液滴的内外压差同样遵循经典的Laplace方程,并用力学方法给予了验证.液滴的内外压差与固液接触角无关,只取决于液体的表面张力和液滴半径;液滴的临界半径也与接触角无关,其值可用经典的Kalvin公式计算 关键词： 滴状冷凝 液滴 压差 临界半径     

超亲水-超疏水组合壁面冷凝性能研究

本文通过水热法,结合气相沉积法和掩膜紫外光刻法,在玻璃基底上成功地制备了一种具有多尺度结构的超亲水-超疏水组合壁面,并对制备的具有不同润湿差异的组合壁面的冷凝效率进行了测试。结果表明壁面的冷凝效率取决于亲疏水区域的宽度和润湿性差异,其中当亲水区域宽度为0.80 mm,接触角约为0°,疏水区域宽度为0.95 mm,接触角为158°时,其冷凝效率相比光滑铜片的冷凝效率可以提高39%。进一步分析表明,液滴在极端润湿模式的组合表面的润湿分界线处具有较高的体积传输速率,且在超亲水区形成的连续微流通道加快了冷凝液滴快速排放,提高了整体表面的自更新能力。本文的研究,将为复杂润湿界面滴状冷凝的优化提供方向。     

蒸气凝结相关问题探讨

讨论了几个与蒸气凝结相关的问题,指出壁面上球冠形液滴的内外压差和临界半径同样遵循经典的Laplace公式和Kalvin公式;蒸气在冷壁上的冷凝形态主要由后退接触角决定;空气中的水蒸气在换热器表面呈膜状冷凝时换热器的性能优于呈滴状冷凝时换热器的性能。     

蒸汽滴状冷凝液滴表面温度分布及演化

利用红外热成像技术研究了蒸汽滴状冷凝中液滴合并过程表面温度分布及演化机制,并基于此分析了不同尺寸液滴表面温度随传热通量变化的分布规律。实验结果表明:与蒸汽在微小液滴表面发生连续冷凝不同,液滴合并过程中蒸汽通过四个阶段实现在大液滴表面的周期性冷凝传热;其中,在液滴吸收蒸汽冷凝放热阶段和向壁面传热阶段之间存在一个平衡,高热通量时,蒸汽向液滴表面传热过程占主导,液滴表面温度随尺寸增加而升高;低热通量时,液滴向冷凝壁面传热过程占主导,液滴表面温度随尺寸增加而降低。液滴运动引起的蒸汽在大液滴表面直接冷凝过程为强化低压蒸汽冷凝传热提供了新思路。     

剪切变稀液滴撞击不同浸润性壁面的数值模拟研究

基于有限元法,采用水平集方法捕捉相界面的移动,构建了液滴撞击固体壁面的数值模型.通过修正的幂律模型描述流体的非牛顿剪切变稀特性,探讨了剪切变稀特性对液滴撞击固体壁面后铺展行为的影响,分析了撞击不同浸润性壁面时剪切变稀特性对液滴撞击壁面行为的影响差异.研究结果表明:随着幂律指数m的减小,液滴撞击过程中的黏性耗散减小,液滴的形貌变化及无量纲参数变化更为显著.接触角为55°的情况下:当m降低至0.85时,液滴铺展过程中开始出现显著区别于牛顿流体液滴的振荡现象;当m降低至0.80时,液滴在回缩过程中会出现中心液膜断裂的情况.接触角为100°时,剪切变稀液滴均会出现振荡行为,振荡幅度随着m的减小而增大.接触角为160°时,牛顿流体液滴与剪切变稀液滴均会在回缩过程中弹起,但剪切变稀液滴的弹起速度更快.此外,基于数值计算结果,本文提出了接触角为55°情况下剪切变稀液滴撞击壁面后的最大无量纲铺展直径预测模型.     

蒸汽剪切驱动液滴行为的格子Boltzmann模拟

滴状冷凝过程中,存在蒸汽流动对液滴的吹扫作用,液滴在蒸汽剪切作用下克服壁面黏附变形和运动,液滴运动速度越大,冷凝传热性能越高。但是液滴在蒸汽作用下变形和运动的细节还不清晰,蒸汽速度对液滴变形和运动的影响机理还不明确。本文采用自由能格子Boltzmann方法研究了在不同蒸汽速度剪切作用下,液滴在具有不同润湿性固体表面上的变形和运动过程,分析了蒸汽速度和接触角对液滴变形和运动的影响机制,结果显示随着蒸汽速度的增加,液滴变形越大,液滴在固体表面的运动速度越大,停留时间越短,有利于液滴的移除和表面更新,相同蒸汽速度的作用下,液滴在接触角大的固体表面上变形和运动速度越大,也有利于液滴的移除和表面更新。从而定性或半定量地揭示了蒸汽速度影响蒸汽滴状冷凝传热的物理机制。     

Water condensation kinetics on a hydrophobic surface

Employing thermal desorption spectroscopy, we show that the effective probability of water condensation at low water vapor pressure on an octane film is much below unity at 100-120 K. This unusual finding is related to a small binding energy of H2O monomers on octane (approximately equal to 0.08 eV), requiring the formation of critical water clusters for condensation to occur. This results in strong temperature and impingement-rate dependencies of the water condensation rate and a nonlinear uptake as a function of dose time. All these features are rationalized quantitatively by a kinetic model of water condensation.     

纤维膜在膜蒸馏过程中的膜内毛细冷凝现象

膜蒸馏过程中的膜内冷凝现象是该技术在实际应用中不可忽视的一个重要问题。本文以疏水化改性处理的纤维膜作为研究对象,采用实验现象观察和理论分析并用的方法,研究了纤维膜在膜蒸馏过程发生膜内毛细管冷凝的影响因素包括膜蒸馏模块结构、蒸馏膜参数、热力学参数,探讨了毛细冷凝对膜蒸馏的影响。实验表明毛细冷凝可以在膜蒸馏过程中发生,但并不终止膜蒸馏过程,而是减小了传质系数。毛细冷凝容易发生在蒸馏膜厚度小、热料液温度高、冷却液温度低或气隙小的情况下。实验结果和理论分析表明,传质系数实验值的降低可作为膜孔内发生毛细冷凝的判定依据。通过简化蒸气在疏水多孔介质的传递过程,建立了膜蒸馏过程发生毛细冷凝时的传质平衡模型。     

Zur Supraleitung von Doppelschichten aus Ag/Sn

Superimposed films of Ag and Sn are produced on suitable conditions of condensation, so that diffusion between the layers is prevented (the condensation temperatures of Ag and Sn are 320 ?K and 150 ?K, respectively). Immediately after condensation the films are cooled to liquid helium temperature, and the transition temperatures of superconductivity are measured. These values are in agreement with a phenomenological theory of P. and R.Hilsch for sufficient thick films. Resistance measurements indicate that an alloy of Ag and Sn is formed above 280 ?K. There is only a small shift of transition temperature caused by the alloying process.     

Structural evidence of charge renormalization in semi-dilute solutions of highly charged polyelectrolytes

We show experimentally that Manning counterion condensation also leads to a renormalization of the charge density at high concentrations of highly charged, flexible, hydrophilic polyelectrolytes. Investigations by small angle neutron and X-ray scattering of semi-dilute solutions of poly(acrylamide-co-sodium-2-acrylamido-2-methylpropane sulfonate) at different charge densities above the condensation threshold, show that the scattering function is invariant with the charge density. Received 16 June 1998     

蒸气在倾斜细小直径圆管内的流动凝结换热特性

细小管内的流动凝结换热具有许多超常换热特性,经典的Ｎｕｓｓｅｌｔ分析方法已不能满足需要。在以往研究的基础上,本文进一步通过实验探析换热温差和蒸气流量对不同直径的细小管内流动凝结换热的影响。研究表明,管径越小,换热温差对凝结换热系数的影响程度越低;通过流量和倾角对凝结换热数的影响,分析了重力引发的流动分层和剪切力对凝结液的排除两种因素对细管传热强化的作用机制。本文的实验结果和用于常规尺度下的通用关联式对比表明,采用细管,管内的流动凝结换热得到无可置疑的强化     

Wetting property of smooth and textured hydrophobic surfaces under condensation condition

Static and dynamic wetting behaviors of sessile droplet on smooth, microstructured and micro/nanostructured surface under condensation condition are systematically studied. In contrast to the conventional droplet wetting on such natural materials by dropping, we demonstrate here that when dropwise condensation occurs, the sessile droplet will transit from the Cassie-Baxter wetting state to the Wenzel wetting state or partial Cassie-Baxter wetting state on the microstructured surface or the micro/nanostructured surface, which leads to a strong adhesion between the droplet and the substrate. In contrast, the apparent contact angle and the sliding angle on the smooth surface changes a little before and after the condensation because of small roughness. Theoretical analysis shows that the roughness factor controls the adhesion force of the droplet during condensation, and a theoretical model is constructed which will be helpful for us to understand the relationship between the adhesion force and the geometry of the surface.     

Experimental signatures of cosmological neutrino condensation

Superfluid condensation of neutrinos of cosmological origin at a low enough temperature can provide simple and elegant solution to the problems of neutrino oscillations and the accelerated expansion of the universe. It would give rise to a late time cosmological constant of small magnitude and also generate tiny masses for the neutrinos as observed from their flavor oscillations. We show that carefully prepared beta decay experiments in the laboratory would carry signatures of such a condensation, and thus, it would be possible to either establish or rule out neutrino condensation of cosmological scale in laboratory experiments.     

水平和竖直细圆管内流动凝结换热特性的对比研究

本文采用基于相平衡理论的最小能量原理,根据当地气液两相流动条件确定气液界面形状,以此为基础,从理论上探讨水平细圆管内流动凝结的特点。通过与竖直条件下管内凝结换热特性的对比,分析重力、气液界面剪切力、表面张力对流动凝结的影响。研究发现,细圆管由竖直变为水平放置时,管径的减小同样导致重力的影响削弱,并且凝结换热得到进一步强化;但由于流型的变化,随管径的减小强化的程度减弱。     

Features of molecular-beam mass spectrometry registration of clusters in underexpanded supersonic jets

The structure of clustered supersonic underexpanded jets of molecular nitrogen and argon was measured by the method of molecular beam mass-spectrometry. Peculiarities of application of the molecular beam methods for recording the supersonic rarefied gas jets under the conditions of weak and developed condensation (i.e., in the presence of small and large clusters in jets) have been discovered, identified, and studied. An unusual shape of longitudinal and transverse cross sections of the clustered supersonic jets was revealed and explained when scanning with a molecular-beam system. It has been determined that small clusters and monomers are the sources of double-ionized monomers available near the flow axis, and dimer ions at the early stages of condensation, whereas another mechanism of such ion formation dominates, when large clusters area available in the flow. A marker for fixing the stage of formation of small clusters in a supersonic flow is proposed.     

Pion condensation and the Meisner effect in superdense neutron stars

The pion condensation in superdense neutron stars is at the origin of a Meisner effect with a very small London penetration depth.