三维荧光光谱及平行因子分析在石油类污染物检测分析中的应用

以三维荧光光谱技术结合平行因子分析算法研究了石油类污染物识别与浓度测量方法,重点分析了两种以上成品油共存时对测量的影响。以0#柴油、97#汽油与煤油的CCl4溶液为测量样本,通过两种或三种油不同配比的混合溶液来模拟多种石油类污染物共存的状态,研究平行因子分析方法在复杂混合物共存体系成分分析时的特点。实验分别针对汽柴油混合溶液、柴煤油混合溶液以及存在少量煤油干扰成分的汽柴油溶液,分解得到各溶质的激发与发射特征光谱,实现了各混合样品中主要成分含量的同时测量,计算了平均回收率。结果表明,该方法能够实现石油类污染物中共存成分的识别与浓度测量。     

A stereoscopic digital speckle photography system for 3-D displacement field measurements

Stereoscopic digital speckle photography offers a technique to measure object shapes and 3-D displacement fields in experimental mechanics. The system measures the displacement of a random white light speckle pattern, which somehow is present on the object surface, using digital correlation. This paper describes a general physical model for stereo imaging systems. A camera calibration algorithm, which takes the distortion in the lenses into account, is also presented and evaluated by real experiments. Standard deviations of small deformations as low as 1% of the pixel size for in-plane deformations and 6% of the pixel size for the out-of-plane component are reported. Using the calibration algorithm described, the main source of errors is random errors originating from the correlation algorithm.     

大耦合孔同轴输出腔的3维解析分析

 在高功率微波器件中，通常采用大耦合孔的同轴微波输出腔，该腔为3维结构。采用场等效原理将腔体、耦合孔及其输出负载(行波边界)进行分区,每个区域中的场由界面上的磁流密度决定。采用格林函数积分法可得每个区域中的3维场,再由各个区域的场匹配方程求得腔体的谐振频率、特性阻抗、有载品质因数、模式分布等参数。为腔体的计算和设计提供一种计算模型。     

3-D in vivo brain tumor geometry study by scaling analysis

A new method, based on scaling analysis, is used to calculate fractal dimension and local roughness exponents to characterize in vivo 3-D tumor growth in the brain. Image acquisition was made according to the standard protocol used for brain radiotherapy and radiosurgery, i.e., axial, coronal and sagittal magnetic resonance T₁-weighted images, and comprising the brain volume for image registration. Image segmentation was performed by the application of the k-means procedure upon contrasted images. We analyzed glioblastomas, astrocytomas, metastases and benign brain tumors. The results show significant variations of the parameters depending on the tumor stage and histological origin.     

平行因子分析法在太湖水体三维荧光峰比值分析中的应用

以太湖水样三维荧光光谱数据为例,提出在采用平行因子分析法(PARAFAC)处理后的荧光数据中提取荧光峰强度计算荧光峰比值进行水环境分析评价的方法,较直接在水样原始荧光谱图中获取的荧光峰强度更加准确客观。天然水体中各水样间由于受荧光团复杂多样性等因素的影响,某类荧光物质荧光峰的激发发射波长位置并不是固定不变的,就同一水样而言各类荧光峰之间的相互重叠干扰也将影响到荧光峰强度和位置的准确判断。而在PARAFAC模型各因子中提取相应荧光峰值可以保证各水样间同类荧光物质荧光峰在同一位置又有效减弱同一水样中各类荧光物质荧光峰之间的相互干扰,更加高效准确的利用荧光峰比值进行水环境分析。区域差异性分析时水样因子得分比值的区域变化与原始荧光峰比值变化趋势是一致的。     

FOI-PERFECT程序对电磁驱动高能量密度系统的三维弛豫磁流体力学模拟

提出一个完整的弛豫磁流体力学模型用于电磁驱动高能量密度系统的数值模拟, 它由弛豫电磁波动、弛豫热输运、P1/3近似辐射输运以及流体力学构成。电磁部分在真空区退化为电磁传播, 在等离子体物质区退化为磁扩散近似, 并且相速和群速是有上界的。这意味着弛豫磁流体力学能退化到传统的电阻性磁流体力学, 并且能用显式方法数值求解, 便于大规模高效并行化。基于此弛豫磁流体力学模型开发了三维辐射磁流体力学程序FOI-PERFECT, 指出了所采用的关键数值技术, 并给出了一些应用例子。     

Microscopic TV holography for MEMS deflection and 3-D surface profile characterization

Recent industrial demands for greater product quality in the fields of microelements and micro-electro-mechanical systems (MEMS) generate new challenges for metrology. The fast-growing MEMS industry requires a robust non-destructive quantitative measurement system for the characterization of their performance, reliability and integrity. A microscopic TV holographic system using a long working distance microscope with an extended zoom range has been developed for microelements and MEMS deformation and 3-D surface profile analysis. The system is capable of evaluating both rough and smooth surfaces. Noisy wrapped phase map is a usual problem in speckle interferometry. We have compared several phase-shifting algorithms for evaluation of speckle phase for their usefulness in generating less-noisy phase maps. The experimental results on a MEMS pressure sensor for out-of-plane deflection and 3-D surface profile analysis are presented.     

三维荧光光谱结合Zernike图像矩快速鉴别掺伪芝麻油

为了实现对掺伪芝麻油的快速鉴别,应用FS920荧光光谱仪测定样品的三维荧光光谱数据。将三维荧光光谱图视为灰度图,在没有任何预处理的前提下,直接应用Zernike图像矩提取三维光谱灰度图的特征信息,然后采用类平均法对特征信息进行聚类分析,从定性角度实现掺伪芝麻油的鉴别,并解析其组成成分。最后应用广义回归神经网络(GRNN)对掺伪样本的成分进行定量分析。聚类分析能够以很高的辨识率来识别掺伪芝麻油,并能够正确解析其组成成分。定量模型预测了2组掺伪样本中各成分的相对体积,其平均相对误差分别为2.23%,8.00%,9.70%和9.70%。分析结果表明,Zernike矩能够有效提取光谱的特征信息,光谱数据的Zernike矩特征结合聚类分析以及GRNN模型能够获得良好的定性和定量分析结果,为掺伪芝麻油的鉴别提供了一种新的方法。     

物体内部三维位移场分析的数字图像相关方法

提出了物体内部三维位移场的数字图像相关分析方法，对物体变形前后，或连续变形的两个相邻状态的内部三维结构的数字图像，通过相关运算获得三维位移场.文中给出了三维相关法的体搜索窗口、相关函数及亚像素运算的相关系数拟合函数.数字模拟结果证明了三维相关法的正确性及可靠性.位移计算精度为0.02像素. 关键词： 数字图像相关 三维相关 亚像素     

Humidity controlled crystallization of thin CH3NH3PbI3 films for high performance perovskite solar cell

Control of crystallization of a solution‐processed perovskite layer is of prime importance for high performance solar cells. In spite of the negative effect of water on perovskite solar energy conversion in several previous works, we observed that humidity plays a critical role to develop a thin uniform, dense perovskite film with preferred crystals, in particular, in a device with architecture of ITO/PEDOT:PSS/CH₃NH₃PbI₃/ PC₇₁BM/LiF/Al fabricated by two‐step sequential spin‐coating process. Humidity controlled spin‐coating of CH₃NH₃I on the pre‐formed PbI₂ layer was the most influential process and systematic structural investigation as a function of humidity revealed that grains of CH₃NH₃PbI₃ perovskite crystals increase in size with their preferred orientation while film surface becomes roughened as the humidity increases. The performance of a device was closely related to the humidity dependent film morphology and in 40% relative humidity, the device exhibited the maximum power conversion efficiency of approximately 12% more than 10 times greater than that of a device fabricated at 20% humidity. The results suggest that our process with controlled humidity can be another efficient route for high performance and reliable perovskite solar cells. (© 2016 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim)     

3-D Confocal microscopy track analysis: a promising tool for determining CR-39 response function

A new method based on the use of the confocal microscope is described in order to evaluate the CR-39 response function for Li-7 ions with an incident energy of 10.77 MeV. This method uses the formulations developed by Fromm et al. and considers two etching velocities: V_B represents the bulk etch rate and remains constant, and V_T the track etch rate, which varies along the particle's path. The confocal microscope seems to bring big improvements for track analysis. The first results of V_T versus the particle range are presented and compared with the curves obtained by the sequential etching method. The obtained V_T are plotted and compared to LET, REL₃₅₀ and the cumulative radial dose.     

三维随机粗糙面上导体目标散射的解析-数值混合算法

提出三维导体目标与导体粗糙面复合散射的解析-数值混合迭代算法,推导出三维目标与粗糙面的耦合积分方程,以及粗糙面散射的Kirchhoff近似(KA)计算式.粗糙面的KA解析计算大大降低了粗糙面求解的复杂度,与目标矩量法的混合迭代保证了计算结果的精度,使得三维体-面目标复合散射计算变得可行.由于体-面两者的高阶耦合作用明显减小,保证了该混合迭代算法的收敛性.与镜像Green函数方法的比较表明该混合算法的有效性,并讨论了粗糙面长度选择对计算结果的影响.结合Monte-Carlo方法,数值分析了理想导体Gauss 关键词： 复合散射 Kirchhoff近似 共轭梯度法 互耦迭代     

Finite-aperture effects for Fourier transform systems with convergent illumination. Part II: 3-D system analysis

One of the most important optical signal processing operations is the optical Fourier transform (OFT). Of the arrangements for implementation of the OFT, perhaps the most flexible is that for the scaled optical Fourier transform (SOFT), as it allows control over the scale of the output Fourier transform distribution. By means of an analysis in cylindrical coordinates, we examine some of the practical limits introduced by the use of a thin lens of finite aperture in the implementation of the SOFT. Using simple rules of thumb that are based on an examination of the phase and magnitude deviations from the ideal (infinite-lens) diameter case, we define a volume inside the geometric shadow, which we refer to as a sub-geometric shadow. We then show that inside this sub-geometric shadow errors introduced by diffraction can be quantified.     

Validating the performance of one-time decomposition for fMRI analysis using ICA with automatic target generation process

Independent component analysis (ICA) has been proven to be effective for functional magnetic resonance imaging (fMRI) data analysis. However, ICA decomposition requires to optimize the unmixing matrix iteratively whose initial values are generated randomly. Thus the randomness of the initialization leads to different ICA decomposition results. Therefore, just one-time decomposition for fMRI data analysis is not usually reliable. Under this circumstance, several methods about repeated decompositions with ICA (RDICA) were proposed to reveal the stability of ICA decomposition. Although utilizing RDICA has achieved satisfying results in validating the performance of ICA decomposition, RDICA cost much computing time. To mitigate the problem, in this paper, we propose a method, named ATGP-ICA, to do the fMRI data analysis. This method generates fixed initial values with automatic target generation process (ATGP) instead of being produced randomly. We performed experimental tests on both hybrid data and fMRI data to indicate the effectiveness of the new method and made a performance comparison of the traditional one-time decomposition with ICA (ODICA), RDICA and ATGP-ICA. The proposed method demonstrated that it not only could eliminate the randomness of ICA decomposition, but also could save much computing time compared to RDICA. Furthermore, the ROC (Receiver Operating Characteristic) power analysis also denoted the better signal reconstruction performance of ATGP-ICA than that of RDICA.     

Numerical analysis for verifying the performance of lens system in a scanning electron microscope

This work presents an analysis of the lens system in a thermionic scanning electron microscope (SEM) using a numerical computation and an optics-based calculation. The behaviors and characteristics of the electron beam are analyzed and the focusing capability is investigated. The beam spot size is estimated by calculation and proved by experiment. The characteristics and properties determining the SEM performance are investigated for various design parameters through a numerical analysis and an optics-based calculation. Particularly, a combination of two approaches gives more detailed information than a single approach in investigating an extremely small beam spot by demagnification through the electromagnetic lens system in a SEM column.     

热惯性对热弹性行为影响的渐近分析

当热作用时间或受热器件结构尺寸呈现微尺度特征时, 热流运动的惯性效应将对热量的传递过程产生显著地影响. 基于热质的概念, 依据牛顿力学原理引入用于描述热质运动的热波方程, 结合各向同性材料的本构关系, 构建了计及热流运动惯性效应的广义热弹性动力学模型. 利用超常传热的微尺度特征, 采用解析的方法对半无限大体外表面受热冲击作用的一维问题进行了渐近求解. 通过对热波、热弹性波的传播和各物理场分布的分析以及与已有广义热弹性理论预测结果的对比, 揭示了热流运动的惯性效应对热弹性行为的影响. 结果表明：热量的传递除了受到热流加速的时间惯性影响之外, 热流运动的空间惯性也对传热行为产生影响, 当计及空间惯性时, 热波、热弹性波的波速、波前位置, 各物理场的建立时间、阶跃峰值及阶跃间隔均受到不同程度的影响. 关键词： 热惯性 热质运动 广义热弹性动力学模型 渐近分析     

Modeling and analysis of an agent-based model for Chinese stock market

We constructed an agent-based stock market model which concisely describe investors? heterogeneity and adaptability by introducing price sensitivity and feedback time. Under different parameters, the peak and fat-tail property of return distribution is produced and the obtained statistic values coincide with empirical results: the center peak exponents range from ?0.787 to ?0.661, and the tail exponents range from ?4.29 to ?2.37. Besides, long-term correlation in volatility is examined by DFA1 method, and the obtained exponent α is 0.803, which also coincides with the exponent of 0.78 found in real market.     

2D/3D CFETR真空室电磁计算

基于ANSYS对CFETR真空室简化模型进行了2D/3D电磁分析,得到了真空室磁场强度以及电磁力的分布。分析结果显示2D/3D真空室的磁场强度及电磁力分布基本一致,这表明了可以使用2D模型替代3D模型对未来真空室简化模型进行电磁分析。     

Evaluation of the performance of high temperature conversion reactors for compound-specific oxygen stable isotope analysis

In this study conversion conditions for oxygen gas chromatography high temperature conversion (HTC) isotope ratio mass spectrometry (IRMS) are characterised using qualitative mass spectrometry (IonTrap). It is shown that physical and chemical properties of a given reactor design impact HTC and thus the ability to accurately measure oxygen isotope ratios. Commercially available and custom-built tube-in-tube reactors were used to elucidate (i) by-product formation (carbon dioxide, water, small organic molecules), (ii) 2nd sources of oxygen (leakage, metal oxides, ceramic material), and (iii) required reactor conditions (conditioning, reduction, stability). The suitability of the available HTC approach for compound-specific isotope analysis of oxygen in volatile organic molecules like methyl tert-butyl ether is assessed. Main problems impeding accurate analysis are non-quantitative HTC and significant carbon dioxide by-product formation. An evaluation strategy combining mass spectrometric analysis of HTC products and IRMS ¹⁸O/¹⁶O monitoring for future method development is proposed.     

Semi-gas kinetics model for performance modeling of flowing chemical oxygen-iodine lasers (COIL)

The gas pressure in a laser cavity of flowing chemical oxygen-iodine laser (COIL)is about 133.31333 Pa[1]. In this pressure range, effects of homogeneous and inhomo-geneous broadening competing with each other on the performances of a COIL are no-ticeable. Generally, a rate equation (RE) model is adopted to the performance modeling of a supersonic COIL, such as in refs. [1—4]. This model assumes the spectral line pro-file is homogeneously broadened. Homogeneous broadening assumption sim…