Mass-spectrometric investigation of solid lubricating coatings subjected to friction in a deep vacuum

The life of solid lubricating coatings of the VNII NP type, based on molybdenum disulfides and various binders, has been experimentally investigated under deep vacuum conditions (10^–8–5 · 10^–9 torr) together with the composition of the gas released in the friction process. It is shown that both under atmospheric conditions and in a deep vacuum the life of the coatings depends on the chemical nature of the film-former. The depth of the vacuum also has an important influence on the life of the coatings, both the mechanism and the end result of this effect depending to a large extent on the physicochemical properties of the bind. On the interval 10^–1–10^–2 torr there is a sudden change in the life of the coating.Physicotechnical Institute of Low Temperatures, Academy of Sciences of the Ukrainian SSR, Khar'kov. Translated from Mekhanika Polimerov, No. 6, pp. 1070–1075, November–December, 1970.     

Maximum force of friction in rubber-metal friction pairs under conditions of constant compressive deformation of the rubber

The maximum force of friction at the initial moment of slip has been investigated on rubber-metal friction pairs under conditions of constant compressive deformation of the rubber during transition from the high-elastic to the glassy state. Filled butadiene-nitrile rubber compounds were studied in the temperature range from +20 to –50°C. The temperature dependence of the maximum force of friction has a sharply expressed maximum near the glass transition temperature. As the temperature falls, the force of friction at first increases, in accordance with the molecular-kinetic theory. As the temperature continues to fall, in the transition region the maximum force of friction begins to rise more sharply owing to a sharp increase in the volume-mechanical friction component. The fall in the maximum force of friction below the glass transition point associated with a decrease in the deformed volume of rubber due to shrinkage and with the reduced mechanical loss factor.Mekhanika Polimerov, Vol. 3, No. 3, pp. 533–538, 1967     

Behavior of antifrictional self-lubricating plastics at elevated temperatures in the friction process

Conclusions 1. The process of friction of antifrictional self-lubricating plastics based on F-1 polyarylate and various fillers has been studied. It has been shown that a distinctive feature of this process is the formation of a film of the same composition as that of the antifrictional plastic on the steel surface.2. It has been shown that during the process of friction of antifrictional self-lubricating plastics both structural changes in the mobybdenum disulfide and also tribochemical transformations of molybdenum disulfide and copper, plus reaction of these with the counterbody material, take place in the surface films.3. It has been found that the nature of the tribochemical transformations depends on the chemical composition of the antifrictional self-lubricating plastic and affects the temperature limits of the friction zones.Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow. Translated from Mekhanika Polimerov, No. 4, pp. 649–657, July–August, 1976.     

Investigation of the friction of rubber under constant compressive strain conditions at low pressure

A vacuum tribometer was developed which was used to investigate the maximum friction force occurring at the initial instant of slipping in rubber-metal friction pairs under conditions of a given (from 5 to 40%) compressive strain at a low pressure in the temperature range from +100 to –100°C. Filled rubbers on a base of nitrile-butadiene rubbers were studied. Up to the glass transition temperature T_g the vacuum had practically no effect on the maximum friction frocef _m; at temperatures T_g and lower the values off _m obtained in a vacuum were 10–15% higher than those obtained in the atmosphere. It is shown that with a decrease of temperature from 20°C to the glass transition temperature T_g the slope of the dependence of the maximum friction force on the degree of deformation increases, and below T_g decreases. The effect of the slipping speed v on the maximum friction forcef _m was also studied.Laboratory of Polymer Physics, V. I. Lenin Moscow State Pedagogical Institute. Leningrad Branch, Scientific Research Institute of the Rubber Industry. Translated from Mekhanika Polimerov, No. 3, pp. 486–492, May–June, 1970.     

Mechanical properties of carbon fibers coated with refractory carbides

The internal friction method has been used to investigate the protective function of barrier coatings of silicon and zirconium carbide. The effect of the thickness of the coating on the mechanical characteristics of carbon fibers and their oxidation resistance is examined. The optimal coating thickness is established. A surface hardening effect of the coatings has been detected.Voronezh Polytechnic Institute, Moscow. Translated from Mekhanika Polimerov, No. 3, pp. 536–538, May–June, 1976.     

Effect of normal load on the temperature and velocity dependence of the force of friction for high-elastic materials

The problem of the effect of normal load on the temperature and velocity dependence of the force of friction is examined for rubbers based on SKN-18, SKN-26, and SKN-40. In the temperature range from 18°–100°C the force of friction for these rubbers falls linearly with increase in temperature. The effect of loads up to 10⁷N/cm² on the temperature dependence of the force of friction for SKN-18, SKN-26, and SKN-40 rubbers reduces to a change in the real contact area or an increase in the temperature dependence with increase in load.The velocity dependence of the force of friction for SKN-18 rubber reveals a weak dependence of the activation energy and the average "jump distance" of the molecular chains on specific load. In the low-velocity region the force of friction depends linearly on the logarithm of velocity, at velocities above 0.44 cm/min and pressures of 30×10⁵ N/cm² the force of friction increases sharply due to an increase in uncontrolled heating of the friction surfaces.Mekhanika Polimerov, Vol. 1, No. 4, pp. 123–129, 1965     

The transfer mechanism in polymer friction

The process of material transfer in polymer friction has been investigated. The effect of the molecular and supermolecular structure of the polymer on the kinetics of the process is examined.Institute of Mechanics of Metal-Polymer Systems, Academy of Sciences of the Belorussian SSR, Gomel'. Translated from Mekhanika Polimerov, No. 4, pp. 668–672, July–August, 1973.     

Static friction of metal - polymer pairs under vacuum conditions

The static friction of a series of polymer — steel friction pairs has been investigated as a function of the stationary contact time at temperatures from –150°C to +200°C. The experimental technique is described and the results of the experiments are evaluated.Novocherkassk Sergo Ordzhonikidze Polytechnic Institute. Translated from Mekhanika Polimerov, No. 6, pp. 1065–1069, November–December, 1970.     

Friction properties of highly elastic materials at high contact pressures

A newly designed high-pressure tribometer has been employed to investigate the pressure dependence of the friction force of SKN-40 crosslinked butadiene-nitrile rubber in contact with a steel surface on the pressure range to 1200 kgf/cm² (20°C). Over the entire range of contact pressures the friction process is molecular-kinetic in nature and characterized by a linear dependence of the friction force on the logarithm of the sliding velocity. In the region of normal pressures up to 200 kgf/cm², where the effect of pressure on the friction force reduces to the formation of the actual contact area, the friction constant (proportionality factor relating the friction force and the actual contact area) is practically independent of the pressure. At pressures above 200–300 kgf/cm² the increase in the friction force at fixed actual contact area is attributable to the effect of pressure on the friction constant. The nature of this effect is related not with an increase in the chain-surface interaction energy (the activation energy does not increase), but with an increase in the forces of adhesion owing to the greater number of polymer chain-steel surface contacts on the actual contact area (increase in contact density).Lenin Moscow State Pedagogical Institute, Laboratory for Problems of Polymer Physics. Translated from Mekhanika Polimerov, No. 1, pp. 140–146, January–February, 1971.     

Wear of glass-reinforced plastics in aggressive media

The effect of certain aggressive media on the wear of glass-reinforced plastics has been investigated. It is shown that as the angle of inclination of the glass reinforcing fibers relative to the friction surface increases, the wear of the material is sharply reduced.Ukrainian Agricultural Academy, Kiev. Translated from Mekhanika Polimerov, No. 2, pp. 364–366, March–April, 1974.     

Investigation of the physicochemical processes associated with the friction of antifriction materials

Certain physicochemical processes associated with the friction of model antifriction materials based on stiff-chain polymers are examined. The effect of the ambient medium, temperature and the composition of the model antifriction material on the nature of these processes is demonstrated.Institute of Electro-Organic Compounds, Academy of Sciences of the USSR, Moscow. Translated from Mekhanika Polimerov, No. 4, pp. 634–640, July–August, 1974.     

Effect of loading on the roughness set in run-in metal - rubber surfaces

A study has been made on the effect of loading on the roughness set of a metal surface run-in with rubber containing an SKN-18 + SKN-26 nitrile rubber blend in conditions of friction without lubrication. The experimental results are compared with those calculated.State Scientific-Research Institute of Mechanical Engineering, Moscow. Scientific-Research Institute of the Rubber Industry, Moscow. Translated from Mekhanika Polimerov, No. 4, pp. 737–740, July–August, 1972.     

Study of the strength and coefficients of friction of metal-containing polymers based on heteropolyacids

The strength and coefficients of friction of new heat-resistant composite materials consisting of metallopolymers of iron and cobalt based on molybdosilicic and tungstosilicic heteropolyacids have been studied. It has been established that the use of a lubricant in the frication of metallopolymers over steel brings about a sharper deerease in the coefficients of friction than in the case of the friction of the compact material; this is due to the ability of the metallopolymers to absorb the lubricant material.Kiev Automobile-Road Institute. Translated from Mekhanika Polimerov, No. 5, pp. 931–933, September–October, 1973.     

Experimental study of the effect of friction and bending on the strain distribution around the perimeter of a glass-reinforced plastic ring with unidirectional structure

The effect of friction and bending on the circumferential strain distribution in glass-reinforced plastic rings with unidirectional structure, stretched by two rigid half-disks, has been experimentally investigated. Strain distribution curves for rings of various thicknesses are given. The strain distribution at different levels over the thickness of the ring and the change in compressive strain along the radius have been studied.Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow. Translated from Mekhanika Polimerov, No. 5, pp. 947–949, September–October, 1971.     

Effect of liquid media on the deformation of the surface layers of a polymer-metal pair in sliding friction

The relation between the high-elastic component of polyurethane deformation and the deformation of the surface layers of metals has been investigated for sliding friction in various media. The surface layers of polymer and metal are plastically deformed. There is a certain correlation between the coefficient of friction and the amount of deformation.Kiev Institute of Civil Aviation Engineers. Translated from Mekhanika Polimerov, No. 1, pp. 147–149, January–February, 1970.     

Friction of polymeric materials

The case of contact of polymer and metallic surface has been examined. A formula is proposed for calculating the contact area as a function of time of holding the compression surface under load and for calculating the coefficient of friction, the dependence of Young's modulus and shear strength on temperature, deformation rate, and average force on the contact surface being taken into account. The nature of deformation of irregularities on the surfaces of polymeric materials under the action of normal and tangential loading has been examined.See [1] for Communication 1.Institute for Polymer Mechanics, Academy of Sciences of the Latvian SSSR, Riga. Translated from Mekhanika Polimerov, No. 5, pp. 809–815, September–October, 1972.     

Temperature dependence of the coefficient of friction of Ftorlon-graphite fiber

The reduced friction of Ftorlon (fluoroplastic) — graphite fiber against steel on the temperature interval 120–190°C is examined.Khmel'nitskii Technological Institute of Maintenance and Repairs. Translated from Mekhanika Polimerov, No. 6, pp. 1120–1121, November–December, 1973.     

Effect of surface-active agents on the friction properties of polymers

The effect of surface-active agents on the friction properties of plastics has been investigated in relation to the example of an aqueous solution of alkyl phenol polyethylene glycol ether (OP-10) and polymethyl methacrylate. In the presence of a surface-active agent, as a result of adsorption plasticization, the deformation is localized in a thin plasticized layer without affecting the underlying layers of plastic.Moscow Lenin State Pedagogical Institute, Problem Laboratory of Polymer Physics. Translated from Mekhanika Polimerov, No. 5, pp. 927–929, September–October, 1970.     

Some laws of plastics friction

The dependence of the actual contact area S of plastics on temperature, specific load, and sliding speed has been investigated. The value of S increases exponentially with the specific load, the maximum value at large specific loads being less than the nominal contact area. The temperature dependence of S under static conditions between 20 and 130° C is attributable to the decrease in the static modulus of elasticity of the plastic near the glass transition point and to the development of high-elastic and plastic deformations at elevated temperatures. There is practically no change in S as the sliding speed varies from 10^–3 to 10 cm/min; at the same time the force of friction increases slightly.Mekhanika Polimerov, Vol. 3, No. 6, pp. 1078–1081, 1967     

Deformation of polymers under friction loading

A study has been made of the laws of distribution of elastic and residual deformations in the surface layers of polymers subjected to friction. The dependence of these deformations on normal pressure, sliding velocity, and duration of loading has been determined. A relation between deformation and antifriction characteristics has been established, and the relative effect of normal and tangential loads on surface-layer deformation determined.Mekhanika Polimerov, Vol. 3, No. 3, pp. 539–543, 1967