Derived thermodynamic design data for rankine power cycle systems operating on R142b

Theoretical Rankine power cycle efficiencies ν_R and the (PR) have been presented for Rankine power cycles operating on R142b. These values are listed in tabular form for temperature drops of 5–75°C and for boiler temperatures 25–125°C in 5°C increments. A composite graph showing the relationship between ν_R, T_BO, (PR) and temperature drop (T_BO − T_CO) illustrates the feasible operating range for R142b power cycle systems. The derived thermodynamic data can be used for the rapid preliminary design of the Rankine power cycle systems operating on R142b.     

Derived thermodynamic design data for rankine power cycle systems operating on R502

Theoretical Rankine power cycle efficiencies ν_R and the pressure (PR) have been presented for Rankine power cycles operating on R502. These values are listed in tabular form for temperature drops of 5–75°C and for boiler temperatures 35–80°C in 5°C increments. A composite graph showing the relationship between ν_R, T_BO, (PR) and temperature drop (T_BO - T_CO illustrates the feasible operating range for R502 power cycle systems. The derived thermodynamic data can be used for the rapid preliminary design of Rankine power cycle systems operating on R502.     

Evolution of the spectral characteristics upon annealing of lithium borate glasses containing europium and aluminum

The spectral and structural characteristics of lithium borate glasses containing europium and aluminum have been investigated upon annealing at different temperatures. It has been found that the spectral characteristics of the studied system change nonmonotonically with an increase in the annealing temperature. After annealing at a temperature of 600°C, the luminescence spectra of the glasses exhibit broad structureless bands that are specific for the amorphous phase containing Eu³⁺ ions. Then, after annealing at T = 700°C, narrow lines appear in the wavelength ranges 585–595 and 610–620 nm, which correspond to the luminescence of the Eu(BO₂)₃ and EuAl₃(BO₃)₄ borates. A further increase in the annealing temperature (T = 800–900°C) leads to the disappearance of europium aluminum borate. In the luminescence spectra of these samples, there are narrow bands in the wavelength range λ = 585–595 nm, which are typical of europium metaborate. Finally, at a temperature of 1050°C, these bands disappear and narrow lines appear again in the wavelength range 610–620 nm, which are characteristic of the EuAl₃(BO₃)₄ borate. Thus, the temperature annealing makes it possible to purposely change the spectral characteristics of the studied system in the wavelength range 590–615 nm.     

Calibration of berlinite (AlPO4) as Raman spectroscopic pressure sensor for diamond‐anvil cell experiments at elevated temperatures

Changes in the band position of the 462 and the 1111 cm^–1 A₁ modes of berlinite (AlPO₄) with temperature and pressure were determined in situ to 500°C and to 10 GPa using Raman spectroscopy and diamond‐anvil cells. These bands shift in opposite directions with pressure and, likewise, with temperature. At a known temperature, the relative difference of both band positions (Δν)_P,T can therefore be used as a pressure gauge that does not require calibration of the spectrometer. At ambient pressure, the observed temperature dependence of this relative difference of the line positions is very close to linear and can be described by (Δν)_{T, 0.1 MPa} (cm^–1) = 0.0181 T – 0.46 where 23 ≤ T (°C) ≤ 500. Along the 23°C isotherm to 10 GPa, pressure and relative wavenumber difference (Δν)_{P, 23°C} are related by the equation P (GPa) = 0.00083 [(Δν)_{P, 23°C}]² – 0.062 (Δν)_{P, 23°C}. Both equations can be combined to determine pressures at higher temperatures under the assumption that the change in (Δν)_P,T with pressure is insensitive to temperature. Copyright © 2011 John Wiley & Sons, Ltd.     

Derived thermodynamic design data for heat pump systems operating on R152a

Theoretical Rankine coefficients of performance and the compression ratios have been presented for heat pump systems operating on R152a. These values are listed in tabular form for temperature lifts of 10–75°C and condensing temperatures of 20–85°C in 5°C increments. A composite plot has been drawn to illustrate the feasible operating range of R152a heat pump systems.     

Derived thermodynamic design data for heat pump systems operating on R503

Theoretical Rankine coefficients of performance and the compression ratios have been presented for heat pump systems operating on R503. These values are listed in tabular form for temperature lifts of 5–75°C and condensing temperatures of 5–18°C in one degree increments. A composite plot has been drawn to illustrate the feasible operating range of R503 heat pump systems.     

Derived thermodynamic design data for heat pump systems operating on R13

Theoretical Rankine coefficients of performance and the compression ratios have been presented for heat pump systems operating on R13. These values are listed in tabular form for temperature lifts of 5–75°C and condensing temperatures of 6–26°C in one degree increments. A composite plot has been drawn to illustrate the feasible operating range of R13 heat pump systems.     

Derived thermodynamic design data for heat pump systems operating on R744

Theoretical Rankine coefficients of performance and the compression ratios have been presented for heat pump systems operating on R503. These values are listed in tabular form for temperature lifts of 10–55°C and condensing temperatures of 7–30°C in one degree increments. A composite plot has been drawn to illustrate the feasible operating range of R744 heat pump systems.     

Derived thermodynamic design data for heat pump systems operating on R170

Theoretical Rankine coefficients of performance and the compression ratios have been presented for heat pump systems operating on R170. These values are listed in tabular form for temperature lifts of 5–75°C and condensing temperatures of 6–31°C in one degree increments. A composite plot has been drawn to illustrate the feasible operating range of R170 heat pump systems.     

Derived thermodynamic design data for heat pump systems operating on R23

Theoretical Rankine coefficients of performance and the compression ratios have been presented for heat pump systems operating on R23. These values are listed in tabular form for temperature lifts of 5–75°C and condensing temperatures of 5–24°C in one degree increments. A composite plot has been drawn to illustrate the feasible operating range of R23 heat pump systems.     

Derived thermodynamic design data for heat pump systems operating on R1270

Theoretical Rankine coefficients of performance and the compression ratios have been presented for heat pump systems operating on R1270. These values are listed in tabular form for temperature lifts of 5–75°C and condensing temperatures of 12–90°C in one degree increments. A composite plot has been drawn to illustrate the feasible operating range of R1270 heat pump systems.     

Investigation of the temperature dependence for the spectra of supercooled water in the middle infrared

The temperature dependence of the bending ν₂, combination ν₂ + ν _L , and stretching (ν₁, ν₃, 2ν₂) absorption bands in the infrared spectra of supercooled water with a temperature-change step Δt from 2 to 2.5°C was studied using an advanced infrared Fourier spectrometer. It was found that the frequency of the maximum of the stretching absorption band (2700–3700 cm^?1) decreases with the reduction of the water temperature from ?0.5 to ?5.0°C. The frequency of the maximum of the combination absorption band (2130 cm^?1) increases with the reduction of the water temperature in a range from ?3.0 to ?5.0°C. The frequency of the maximum of the absorption band of bending oscillation (1640 cm^?1) is invariable with a reduction of the water temperature from ?0.5 to ?5.0°C.     

The adsorption of PH3 on the Si(111)-(7 × 7) surface: an example of autocatalytic dissociative chemisorption

The dissociative chemisorption of phosphine, PH₃, on the Si(111)-(7 × 7) surface has been examined employing supersonic molecular beam techniques. The initial probability of reaction, S_R,0, has been found to be sensitive to substrate temperature, T_s, where S_R,0 increases sharply by approximately a factor of 4–5 as T_s is increased above 800°C, which corresponds well with the (7 × 7) ↔ “(1 × 1)” phase transition. The reaction probability, S_R, measured as a function of dose for PH₃ reacting on Si(111)-(7 × 7) at T_s < 800°C, exhibits a dramatic increase as the surface is exposed to the PH₃ molecular beam. This unique autocatalytic behavior is consistent with a mechanism in which submonolayer coverages of P(a) are capable of lifting the (7 × 7) reconstruction thus giving rise to a more reactive “(1 × 1)-like” phase. The reaction probability of Si₂H₆ on Si(111)-(7 × 7) is also observed to pass through a maximum with increasing P(a) coverages, and can be explained by considering similar changes in surface structure and reactivity.     

Development in geothermal energy in mexico—part twenty seven: The potential for geothermal organic rankine cycle power plants in Mexico

Mexico possesses large amounts of geothermal energy. Samples from over 800 geothermal surface phenomena indicate that only 1.1% have an estimated reservoir temperature greater than 200°C. Current practice in Mexico is to produce power from such reservoirs using an open flash steam cycle. It is estimated that 4.8% of geothermal resources are in the temperature rangefrom 140 to 200°C which is a suitable range in which to operate Organic Rankine cycle power plants. Organic Rankine cycle power plants have been built in a range of sizes from 10kW_e to 45 MW_e. They have considerable potential for increasing the production of electricity from Mexico's geothermal resources. Organic Rankine cycle plants are discussed together with the conditions for their economic operation.     

Kinetic study of isothermal crystallization process of Gd2Ti2O7 precursor's powder prepared through the Pechini synthetic approach

Crystallization process of Gd₂Ti₂O₇ precursor's powder prepared by Pechini-type polymerized complex route has been studied under isothermal experimental conditions in an air atmosphere. It was found that the crystallization proceeds through two-parameter Šesták–Berggren (SB) autocatalytic model, in the operating temperature range of 550 °C≤T≤750 °C. Based on the behavior of SB parameters (M, N), it was found that in the lower operating temperature range, the crystallites with relatively low compactness exist, which probably disclosed low dimensionality of crystal growth from numerous nucleation sites, where the amorphous solid is produced. In the higher operating temperature region (above 750 °C), it was established that a morphological well-defined and high-dimensional particles of the formed pyrochlore phase can be expected. It was found that at T=850 °C, there is a change in the rate-determining reaction step, from autocatalytic into the contracting volume mechanism.     

Measurement of the tensor analyzing power components in the coherent photoproduction of a π 0 meson on a deuteron

The components of the tensor analyzing powers, T ₂₀, T ₂₁, and T ₂₂, of the coherent photoproduction of a π₀ meson on a deuteron have been measured for photon energies of 250–450 MeV and pion emission angles of 90°–145°. The results are compared with the theoretical predictions.     

Ternary LiBH4–MgH2–NaAlH4 hydride confined into nanoporous carbon host for reversible hydrogen storage

Ternary hydride of LiBH₄–MgH₂–NaAlH₄ confined into carbo n aerogel scaffold (CAS) via melt infiltration for reversible hydrogen storage is proposed. Nanoconfinement of hydrides into CAS is obtained together with surface occupation of some phases, such as Al and/or LiH. Regarding nanoconfinement, not only multiple-step decomposition of LiBH₄–MgH₂–NaAlH₄ hydride reduces to about single step, but also reduction of dehydrogenation temperature is significantly observed, for example, ∆T up to 70 °C regarding last dehydrogenation step. Moreover, decomposition of NaBH₄ in nanoconfined sample can be done at 360 °C (dehydrogenation temperature in this study), which is 115 and 180 °C lower than that of NaBH₄ in milled LiBH₄–MgH₂–NaAlH₄ and bulk NaBH₄, respectively. The reaction of LiBH₄+NaAlH₄→LiAlH₄+NaBH₄ takes place during nanoconfinement and the decomposition of LiAlH₄ is observed, resulting deficient hydrogen content liberated. However, hydrogen content released (1st cycle) and reproduced (2nd–4th cycles) from this ternary hydride enhances up to 11% and 22% of full hydrogen storage capacity due to nanoconfinement. After rehydrogenation (T=360 °C and P(H₂)=50 bar H₂ for 12 h), NaBH₄, MgH₂, and Li₃AlH₆ are reversible, whereas Li₃AlH₆ and NaBH₄ in milled sample cannot be recovered due to deficient hydrogen pressure (T=360 °C and P(H₂)=80 bar) and probably evaporation of molten sodium during dehydrogenation, respectively. The latter results in inferior hydrogen content reproduced from milled sample to nanoconfined sample.     

Measurement of intensities of multiplets in the 2ν3-band of methane at low temperatures

The integrated intensities of the multiplets P(1)–P(10), R(0)–R(9), and of the Q-branch in the 2ν₃-band of ¹²CH₄ have been measured at 102°K, 152°K, 202°K, 251°K, and 300°K. Comparison of our data with theoretical line strengths confirms, at all of the temperatures mentioned, the intensity anomalies observed by Margolis⁽⁵⁾ for lines in this band. The integrated intensity of the 2ν₃-band is found to be S_v = (1·76±-0·04)(300/T (°K)) cm^?2 atm^?1.     

Intensity and transmission measurements in the ν3-fundamental of N2O at low temperatures

Spectral transmission of i.r. radiation through the nitrogen-broadened lines of the υ₃-fundamental of N₂O has been measured at 154°, 202° and 300°K. A value of S⁰_v = 1411±54 cm^-2atm^-1 at S.T.P. has been obtained for the combined strength of the ν₃ and ν₂¹+ν₃?ν₂¹ bands using the Wilson-Wells-Penner-Weber method. This value for S_v, the relative intensity calculations of Gray Young, the room-temperature data of Toth for nitrogen-broadened half-widths in the ν₁+ν₃ and 2ν₂⁰+ν₃ bands and the T^-0.75 variation of line width with temperature proposed by Varanasi and Sarangi are shown to yield excellent agreement between the measured and computed spectral transmittance throughout the band.     

Levelcrossing Experimente im Tm I-Spektrum

A semi phenomenological dynamical theory for the rotations of the BO₆ octahedra in ABO₃ perovskites is proposed, which accounts for the soft mode and the central peak forT≧T _c observed by neutron scattering in SrTiO₃. The neutron scattering cross section is discussed. The EPR line width is predicted to diverge as ?^?ν(1–2η) and as ?^?ν(2–2η) for three- and two dimensional correlations with ?=(T-T _c )/T _c . The theory is generalized to other structural transitions.