自受激拉曼晶体Nd3+:SrMoO4的光谱性质研究

通过拉曼散射光谱，吸收光谱，荧光发射寿命和808 nm LD激发下的红外荧光光谱的实验测量，系统研究了Nd³⁺:SrMoO₄晶体的自受激拉曼光谱性质.分析指认了拉曼散射光谱中各拉曼峰所对应的晶格振动模式，得出了其SRS活性最强的声子频率约为898 cm^-1，对应于(MoO^2-₄)离子团的完全对称光学伸缩振动A_g模；通过J-O理论对晶体的吸收谱进行了全面的光谱参数计算，得出⁴F_3/2→⁴I_11/2跃迁的积分发射截面达0.57×10^-18 cm²，自发辐射概率为141.06 s^-1；同时，实验测得该跃迁的荧光发射寿命约为0.2 ms.最后，结合808 nm LD激发下的红外波段荧光光谱，论证了SrMoO₄晶体中Nd³⁺离子1068 nm发射通过拉曼频移获得1180 nm一级斯托克斯激光发射的可能性，为Nd³⁺:SrMoO₄晶体的自受激拉曼激光器研究提供了理论依据. 关键词： 3+离子')" href="#">d³⁺离子 4 晶体')" href="#">SrMoO₄ 晶体 自受激拉曼散射     

MgB2超导薄膜的变温拉曼光谱研究

MgB₂作为迄今为止超导转变温度最高的合金超导体,由于其具有结构简单、相干长度长、晶界间不存在弱连接、上临界场很高、电-声散射时间短等特点,MgB₂超导薄膜在电子学领域有着广阔的的应用前景。拉曼光谱是研究电-声子相互作用和超导能带的一种有效方法,且已广泛用于分析MgB₂材料的电子、声子特征以及超导体能带结构,研究表明,样品质量、晶粒尺寸以及测试条件对MgB₂拉曼峰的峰位和峰形影响很大,其中拉曼光谱随温度的变化也是一个研究重点,但目前关于MgB₂变温拉曼光谱的研究,测试的温度范围相对较小,局限在83 K到室温区域或是转变温度附近。研究了大范围温度区间内MgB₂薄膜的拉曼光谱变化,采用混合物理化学沉积法在(0001)SiC衬底上制备了MgB₂多晶薄膜,薄膜的晶粒尺寸约为300 nm,超导转变温度为39.3 K,对其在10～293 K之间的拉曼光谱进行了测试,测量的波数范围为20～1 200 cm-1。变温拉曼光谱的测试结果显示,在高频620 cm-1附近以及低频80和110 cm-1附近存在MgB₂的拉曼峰。经分析,低频区域出现的两个拉曼峰的频率与超导能隙宽度相对应,表明MgB₂的双能隙特性。考虑到MgB₂中四种声子模式的拉曼活性,高频620 cm-1附近的拉曼峰应是由E_2g振动模所贡献的,且随着测试温度的降低,该拉曼峰的峰位未发生明显的偏移,但半高宽显著变小,从293 K时的380.7 cm-1减小到10 K时的155 .7 cm-1,分析表明E_2g声子与电子系统的非线性耦合所引起的非简谐效应可能是拉曼峰半高宽线性变小的主要原因。     

不同波长激光激发下C6H12受激拉曼散射模式竞争

发现不同波长激光激发下C₆H₁₂的受激拉曼散射模式竞争现象. 在不同波长的激光激发下，不同拉曼模式的Stokes光占优势. 短波长(404，532nm)激光激发时小频移模式ω₁(802cm^-1)为弱增益模式，大频移模式ω₂(2852—3038cm^-1)为强增益模， 主要产生ω₂模式的Stokes光. 长波长(80 关键词： 模式竞争 6H₁₂')" href="#">C₆H₁₂ 受激拉曼散射     

Bi4Ge3O12晶体及其熔体结构的高温拉曼光谱研究

研究了BGO晶体在不同温度下(在300—1323 K的温度范围)的拉曼光谱及其熔体的高温拉曼光谱，分析了BGO晶体结构随温度变化的规律及BGO熔体的结构特征.随着温度的升高，BGO晶体的拉曼光谱谱峰都不同程度地向低波数方向移动，也存在不同程度的展宽，同时强度减弱.另外，在BGO熔体中存在［GeO₄］和［BiO₆］的结构基团；但两种结构之间的联键消失，即在熔体中二者是相互独立的生长基元. 关键词： 高温拉曼光谱 熔体 BGO晶体     

n-SiC拉曼散射光谱的温度特性

测量了采用离子注入法得到掺N的n-SiC晶体从100—450 K的拉曼光谱. 研究了SiC一级拉曼谱、电子拉曼散射谱及二级拉曼谱的温度效应. 实验结果表明,大部分SiC一级拉曼峰会随温度升高向低波数方向移动,但声学模红移(峰值位置向低频方向移动)的幅度较光学模小. 重掺杂4H-SiC的纵光学声子等离子体激元耦合(LOPC)模频率随温度升高表现出先蓝移(峰值位置向高频方向移动)后红移的变化趋势,表明LOPC模的温度特性不仅会受到非简谐效应的影响,还与实际已离化杂质浓度有关. 电子拉曼散射峰线宽随温度升高而增 关键词： 碳化硅 温度 纵光学声子等离子体激元耦合模 电子拉曼散射     

不同晶粒尺寸SnO2纳米粒子的拉曼光谱研究

对晶粒尺寸在4—80nm范围的纯SnO₂纳米颗粒进行了拉曼散射研究.除了SnO₂本征拉曼振动峰外，还有几个新的拉曼振动峰和波长在700nm左右的一个发光很强而且峰宽很大的荧光峰被观察到.结果所示，当纳米颗粒尺寸减小时，纳米SnO₂颗粒的体相 特征拉曼峰变弱，而由缺陷，表面和颗粒尺寸引起的相关效应呈强势.晶粒尺寸在20nm左右是引起体相拉曼光谱变化的临界尺寸.晶粒尺寸在20nm以下，其体相拉曼峰的发生宽化和峰位移动，以及分别出现在位于571cm^-1 的表面振动峰，位于351cm-1 处的界面峰和与表面吸附水分子及氢氧基团的N系列拉曼峰是纳米SnO颗粒的主要特征.这些结果反映了纳米颗粒的微结构变化与颗粒尺寸和表面效应以及它们之间相互作用的信息. 关键词： ２')" href="#">纳米SnO_２ 拉曼光谱 荧光光谱 水分子的吸附     

六方晶型MgTiO3温致微结构变化及其原位拉曼光谱研究

采用固相烧结法制备了六方晶型结构的MgTiO₃粉体. 经高温原位X射线衍射分析(293-1473 K)进行了表征与确认,获得了晶胞参数及其随温度的变化,测量了高温原位拉曼光谱(273-1623 K),并运用第一性原理理论计算方法对应核实了拉曼谱峰的归属. 结果表明,随着温度升高,MgTiO₃晶面间距和晶格常数增大,从而反映对于拉曼光谱较为敏感的键长和键角的变化;温致拉曼位移可以反映Ti-O,Mg-O等键长以及Ti-O-Ti,Ti-O-Mg与Mg-O-Mg等键角随温度的细微变化,相关关系则独立于温度,有效提升了原位拉曼光谱微探针诊断技术的分析能力;拉曼谱峰随温度升高而展宽,表明原子瞬间运动振幅加剧,弥散性增加,稳定性有所下降,但仍维持六方晶型. 关键词： 3')" href="#">MgTiO₃ 微结构 拉曼光谱 高温     

LiB3O5晶体高温拉曼光谱研究

研究了LiB₃O₅晶体在不同温度下(在300—1173K的温度范围)的拉曼光谱,分析了LBO晶体结构随温度变化的规律.随着温度的升高,LBO晶体的拉曼光谱谱峰都不同程度地向低波数方向移动,也存在不同程度的展宽,同时强度减弱.发现晶体在1100K存在明显相变,与LBO晶体的相图给出的1107K的相变温度基本相符. 关键词： 3O₅晶体')" href="#">LiB₃O₅晶体 高温拉曼光谱 相变     

液芯光纤中溶液吸收和荧光的性质对CS2受激拉曼散射阈值的影响

利用液芯光纤技术研究了不同浓度的β-Carotene的CS₂溶液的吸收与荧光的特性对CS₂的一、二阶Stokes谱线阈值的影响.实验发现随溶液浓度(10^-8—10^-6 mol/L)增加，CS₂的一阶Stokes谱线的激发阈值相对变高；并且与纯CS₂芯液的受激拉曼散射相比较，在低抽运能量激发下，就观察到CS₂的二阶Stokes谱线.这主要是由于在CS₂的受激拉曼谱线产生的过程中，β-Carotene的CS₂溶液的吸收和荧光共同影响了CS₂的一、二阶Stokes谱线的阈值.我们进行了理论上的拟合与分析，其结果与实验符合很好. 关键词： 2受激拉曼散射阈值')" href="#">CS₂受激拉曼散射阈值 液芯光纤 吸收与荧光     

YbVO4晶体的受激拉曼散射

采用腔外单次通过方式,研究了一种新型晶体YbVO₄的受激拉曼散射.当抽运激光为532 nm皮秒脉冲时获得了3级斯托克斯线(558.47 nm, 587.92 nm, 620.67 nm)和1级反斯托克斯线(507.58 nm),测得YbVO₄晶体1级斯托克斯受激拉曼散射的稳态增益系数为17.8±0.2 cm/GW,受激拉曼散射的整体转换效率达到37%.实现了YbVO₄晶体对355 nm皮秒激光的受激拉曼散射,观察到1级斯托克斯线(366.1 关键词： 受激拉曼散射 稳态增益系数 转换效率 4晶体')" href="#">YbVO₄晶体     

Photoacoustic Raman Spectroscopy of Gases

Abstract

Photoacoustic Raman spectroscopy (PARS) [1] is a nonlinear spectroscopic technique based upon the selective population of a given energy state of a system by the process of coherent Raman amplification (stimulated Raman scattering). The necessary conditions for this process are: (1) the transition involving the initial and final energy levels must be Raman-active, i.e., the transitions must involve a change in the molecular polarizability; and (2) the frequency difference of the two incident laser beams must be adjusted to equal the frequency of this Raman-active transition. Since the occurrence of a Raman spectrum depends on a change in polarizability of the molecule and not on the presence of a transition dipole moment, Raman-active transitions can occur for molecules that have no infrared spectrum. This fact makes PARS a particularly attractive analytical technique for studying molecules which have no infrared spectrum The PARS technique was first demonstrated experimentally using     

Raman-scattering spectrum of GaN straight nanowires

The Raman spectrum of GaN straight nanowires deposited on a LaAlO₃ crystal substrate was studied. The E₂ (high) phonon frequency at 560 cm^-1 shows a 9 cm^-1 shift compared with the calculated value. The low-energy shift and band broadening of the Raman modes result from the nanosize effect. The unique property of the low intensity ratio of I_E2/I_A1(LO) on the Raman spectrum from the GaN straight nanowires was observed. Received: 5 June 2000 / Accepted: 7 June 2000 / Published online: 2 August 2000     

Two-phonon Raman scattering in GaAs

The second-order Raman Spectrum of GaAs has been measured at room temperature by using an argon ion laser with Brewster's angle configuration. A number of critical points have been interpreted by considering neutron inelastic scattering work and detailed critical-point analysis in Ge. The Γ₁ component is the strongest in the spectrum where overtone scattering is dominant. Combination scattering has been observed in the energy region between 300 and 350 cm^?1for both Γ₁ and Γ₁₅ components. The second-order Raman spectrum is compared with the two-phonon overtone Raman intensity, calculated from neutron diffraction data. In the low frequency region, the Raman spectrum shows directly the one-phonon density of states of the TA phonon.     

液体的脉冲差分光声喇曼光谱

采用脉冲光声方法测量了各种有机和无机液体的受激喇曼光谱,探讨了影响这种光谱技术灵敏度的主要原因,即来自线性吸收信号的干扰,并进一步采用一种改进的方法——差分方法,消除了线性光声信号的影响,可以测量到比较弱的喇曼谱线以及浓度比较低的物质的喇曼光谱,并探讨了这种技术在痕量物质测量以及探测环境污染物质等领域中的应用前景.     

Minerals from Macedonia. XXII. Laser‐induced fluorescence bands in the FT‐Raman spectrum of almandine mineral

Two strong bands centered at 446 and 607 cm⁻¹ have been observed in the FT‐Raman spectrum of almandine [Fe₃Al₂(SiO₄)₃] excited with 1064 nm, which were completely absent in the corresponding dispersive Raman spectra obtained using 488, 514.5 and 532 nm excitation. Furthermore, the mentioned strong bands have not been registered in the anti‐Stokes side of the FT‐Raman spectrum, and were therefore assigned to laser‐induced fluorescence bands. Their appearance is related to the presence of rare‐earth element traces as impurities in the almandine sample. Additionally, the FT‐Raman (and dispersive Raman) spectrum of the isomorphous spessartine [Mn₃Al₂(SiO₄)₃] mineral has been introduced, which did not show the presence of these fluorescence emission bands. The purity of the minerals was confirmed by study of their powder X‐ray diffraction (PXRD) patterns. Copyright © 2008 John Wiley & Sons, Ltd.     

Theoretical investigation on Raman induced kerr effect spectroscopy in nonlinear confocal microscopy

The imaging theory of Raman induced Kerr effect spectroscopy (RIKES) in nonlinear confocal microscopy is presented in this paper. Three-dimensional point spread function (3D-PSF) of RIKES nonlinear confocal microscopy in isotropic media is derived with Fourier imaging theory and RIKES theory. The impact of nonlinear property of RIKES on the spatial resolution and imaging properties of confocal microscopy have been analyzed in detail. It is proved that RIKES nonlinear confocal microscopy can simultaneously provide more information than two-photon confocal microscopy concerning molecular vibration mode, vibration orientation and optically induced molecular reorientation, etc. It is shown that RIKES nonlinear confocal microscopy significantly enhances the spatial resolution and imaging quality of confocal microscopy and achieves much higher resolution than that of two-photon confocal microscopy.     

超声空化对丙酮激光喇曼光谱的影响

本研究设计了一种可吸入超声的喇曼光谱样品池,对丙酮的激光喇光曼谱的检测表明,超声空化降低了喇曼光谱的强度,我们认为,超声空化减少了激光光路上参与散射的丙酮分子数是光谱强度降低的主要原因。     

Raman‐induced Kerr effect spectroscopy of single‐wall carbon nanotubes aqueous suspensions in the range 0.1–10 and 100–250 cm−1

Here, we study a low (less than 0.1 µg/ml) concentration aqueous suspension of single‐wall carbon nanotubes (SWNTs) by Raman‐induced Kerr effect spectroscopy (RIKES) in the spectral bands 0.1–10 and 100–250 cm⁻¹. This method is capable of carrying out direct investigation of SWNT hydration layers. A comparison of RIKES spectra of SWNT aqueous suspension and that of milli‐Q water shows a considerable growth in the intensity of low wavenumber Raman modes. These modes in the 0.1–10 cm⁻¹ range are attributed to the rotational transitions of H₂O₂ and H₂O molecules. We explain the observed intensity increase as due to the production of hydrogen peroxide and the formation of a low‐density depletion layer on the water–nanotube interface. A few SWNT radial breathing modes (RBM)are observed (ω_RBM = 118.5, 164.7 and 233.5 cm⁻¹) in aqueous suspension, which allows us to estimate the SWNT diameters (∼2.0, 1.5, and 1 nm, respectively). Copyright © 2011 John Wiley & Sons, Ltd.     

Raman spectrum of metallic layered compound NbSe2

Raman spectrum of layer-type compound NbSe₂ has been obtained at liquid nitrogen temperature. The frequencies of the Raman active modes E²_2g, A_1g and E¹_2g are measured to be 29.6 cm^?1, 230.9 cm^?1 and 238.3 cm^?1 respectively. The observed second order Raman spectrum of NbSe₂ is very different from the corresponding spectrum of MoS₂. These results show that the force constants of NbSe₂ are less anisotropic than those of MoS₂.     

Variation of Raman spectrum after optical excitation in amorphous As2Se3 at 1.6°K

Several experiments, involving electronic states have shown that amorphous As₂Se₃ is modified at low temperature by the action of not very strongly absorbed light (α～10²cm^?1). This paper presents Raman scattering results before and after illumination. The shape of the Raman spectrum is changed by illumination: its high energy side has grown near 260 cm^?1. This light induced modification of the vibrational states is discussed within the framework of a previous qualitative model involving changes in local atomic configuration.