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1.
The dynamics and stability of the high-speed fiber spinning process with spinline flow-induced crystallization and neck-like deformation have been studied using a simulation model equipped with governing equations of continuity, motion, energy, and crystallinity, along with the Phan-Thien–Tanner constitutive equation. Despite the fact that a simple one-phase model was incorporated into the governing equations to describe the spinline crystallinity, as opposed to the best-known two-phase model [Doufas et al. J Non-Newton Fluid Mech, 92:27–66, 2000a]; [Kohler et al. J Macromol Sci Phys, 44:185–202, 2005] that treats amorphous and crystalline phases separately in computing the spinline stress, the simulation has successfully portrayed the typical nonlinear characteristic of the high-speed spinning process called neck-like spinline deformation. It has been found that the criterion for the neck-like deformation to occur on the spinline is for the extensional viscosity to decrease on the spinline, so that the spinning is stabilized by the formation of the spinline neck-like deformation. The accompanying linear stability analysis explains this stabilizing effect of the spinline neck-like deformation, corroborating a recent experimental finding [Takarada et al. Int Polym Process, 19:380–387, 2004].This paper was presented at the 2nd Annual European Rheology Conference 2005 on April 21–23, 2005, in Grenoble, France.  相似文献   

2.
Two related open problems in the theory of 3D Navier-Stokes turbulence are discussed in this paper. The first is the phenomenon of intermittency in the dissipation field. Dissipation-range intermittency was first discovered experimentally by Batchelor and Townsend over fifty years ago. It is characterized by spatio-temporal binary behaviour in which long, quiescent periods in the velocity signal are interrupted by short, active ‘events’ during which there are violent fluctuations away from the average. The second and related problem is whether solutions of the 3D Navier-Stokes equations develop finite time singularities during these events. This paper shows that Leray’s weak solutions of the three-dimensional incompressible Navier-Stokes equations can have a binary character in time. The time-axis is split into ‘good’ and ‘bad’ intervals: on the ‘good’ intervals solutions are bounded and regular, whereas singularities are still possible within the ‘bad’ intervals. An estimate for the width of the latter is very small and decreases with increasing Reynolds number. It also decreases relative to the lengths of the good intervals as the Reynolds number increases. Within these ‘bad’ intervals, lower bounds on the local energy dissipation rate and other quantities, such as ||u(·, t)|| and ||∇u(·, t)||, are very large, resulting in strong dynamics at sub-Kolmogorov scales. Intersections of bad intervals for n≧1 are related to the potentially singular set in time. It is also proved that the Navier-Stokes equations are conditionally regular provided, in a given ‘bad’ interval, the energy has a lower bound that is decaying exponentially in time.Final version 17 March 05. Original version November 03.  相似文献   

3.
A filament stretching extensional rheometer with a custom-built oven was used to investigate the effect of uniaxial flow on the crystallization of polypropylene. Prior to stretching, samples were heated to a temperature well above the melt temperature to erase their thermal and mechanical histories and the Janeschitz-Kriegl protocol was applied. The samples were stretched at extension rates in the range of 0.01 s-1 £ [(e)\dot] £ 0.75 s-10.01\,\mbox{s}^{-1}\le \dot{{\varepsilon }}\le 0.75\,{\rm s}^{-1} to a final strain of ε = 3.0. After stretching, the samples were allowed to crystallize isothermally. Differential scanning calorimetry was applied to the crystallized samples to measure the degree of crystallinity. The results showed that a minimum extension rate is required for an increase in percent crystallization to occur and that there is an extension rate for which percent crystallization is maximized. No increase in crystallization was observed for extension rates below a critical extension rate corresponding to a Weissenberg number of approximately Wi = 1. Below this Weissenberg number, the flow is not strong enough to align the contour path of the polymer chains within the melt and as a result there is no change in the final percent crystallization from the quiescent state. Beyond this critical extension rate, the percent crystallization was observed to increase to a maximum, which was 18% greater than the quiescent case, before decaying again at higher extension rates. The increase in crystallinity is likely due to flow-induced orientation and alignment of contour path of the polymer chains in the flow direction. Polarized light microscopy verified an increase in number of spherulites and a decrease in spherulite size with increasing extension rate. In addition, small angle X-ray scattering showed a 7% decrease in inter-lamellar spacing at the transition to flow-induced crystallization. Although an increase in strain resulted in a slight increase in percent crystallization, no significant trends were observed. Crystallization kinetics were examined as a function of extension rate by observing the time required for molten samples to crystallize under uniaxial flow. The crystallization time was defined as the time at which a sudden increase in the transient force measurement was observed. The crystallization time was found to decrease as one over the extension rate, even for extension rates where no increase in percent crystallization was observed. As a result, the onset of extensional-flow-induced crystallization was found to occur at a constant value of strain equal to ε c  = 5.8.  相似文献   

4.
We propose an extension of the FENE-CR model for dilute polymer solutions [M.D. Chilcott, J.M. Rallison, Creeping flow of dilute polymer solutions past cylinders and spheres, J. Non-Newtonian Fluid Mech. 29 (1988) 382–432] and the Rouse-CCR tube model for linear entangled polymers [A.E. Likhtman, R.S. Graham, Simple constitutive equation for linear polymer melts derived from molecular theory: Rolie–Poly equation, J. Non-Newtonian Fluid Mech. 114 (2003) 1–12], to describe the nonequilibrium stretching dynamics of polymer chains in strong extensional flows. The resulting models, designed to capture the progressive changes in the average internal structure (kinked state) of the polymer chain, include an ‘effective’ maximum contour length that depends on local flow dynamics. The rheological behavior of the modified models is compared with various results already published in the literature for entangled polystyrene solutions, and for the Kramers chain model (dilute polymer solutions). It is shown that the FENE-CR model with an ‘effective’ maximum contour length is able to describe correctly the hysteretic behavior in stress versus birefringence in start-up of uniaxial extensional flow and subsequent relaxation also observed and computed by Doyle et al. [P.S. Doyle, E.S.G. Shaqfeh, G.H. McKinley, S.H. Spiegelberg, Relaxation of dilute polymer solutions following extensional flow, J. Non-Newtonian Fluid Mech. 76 (1998) 79–110] and Li and Larson [L. Li, R.G. Larson, Excluded volume effects on the birefringence and stress of dilute polymer solutions in extensional flow, Rheol. Acta 39 (2000) 419–427] using Brownian dynamics simulations of bead–spring model. The Rolie–Poly model with an ‘effective’ maximum contour length exhibits a less pronounced hysteretic behavior in stress versus birefringence in start-up of uniaxial extensional flow and subsequent relaxation.  相似文献   

5.
In-line measurement of rheological properties of polymer melts   总被引:1,自引:0,他引:1  
Shear viscosity (), first normal stress difference (N 1), and extensional viscosity ( E ) of polymer melts measured under processing conditions are important in process modeling, quality control, and process control. A slit rheometer that could simultaneously measure , N 1, and the planar extensional viscosity ( p ) was designed and tested by attaching it in-line to a laboratory model single-screw extruder. A tube (circular cross-section) rheometer to measure and the uniaxial extensional viscosity ( u ) simultaneously was also designed and tested. Two commercial grades of LDPE (low density polyethylene) with melt index values of 6 and 12 were used as test materials for the study. Exit and hole pressure methods were used to estimate N 1, and the entrance pressure drop method using the analyses of Cogswell, Binding, and Gibson (the last analysis used with the axisymmetric case only) was used to estimate E .The hole pressure method was considered better than the exit pressure method to estimate N 1 (due to the greater susceptibility of the latter to experimental errors). From the hole pressure method N 1 was obtained from 100 kPa to 500 kPa over a range of shear rates from 40 s–1 to 700 s–1. Among the analyses used to estimate the extensional viscosity, Cogswell's is recommended due to its simpler equations without loss of much information compared to the other analyses. The range of extension rates achieved was 1 to 30 s–1. The combination of the hole pressure and entrance pressure drop methods in a slit rheometer is a feasible design for a process rheometer, allowing the simultaneous measurement of the shear viscosity, first normal stress difference and planar extensional viscosity under processing conditions. Similarly, combining the entrance pressure drop measurements with a tube rheometer is also feasible and convenient.  相似文献   

6.
The rheological behavior and morphology of carbon nanofiber/polystyrene (CNF/PS) composites in their melt phase have been characterized both through experimental measurements and modeling. Composites prepared in the two different processes of solvent casting and melt blending are contrasted; melt-blended and solvent-cast composites were each prepared with CNF loadings of 2, 5, and 10 wt%. A morphological study revealed that the melt blending process results in composites with shorter CNFs than in the solvent-cast composites, due to damage caused by the higher stresses the CNFs encounter in melt blending, and that both processes retain the diameter of the as-received CNFs. The addition of carbon nanofiber to the polystyrene through either melt blending or solvent casting increases the linear viscoelastic moduli, G′ and G″, and steady-state viscosity, η, in the melt phase monotonically with CNF concentration, more so in solvent cast composites with their longer CNFs. The melt phase of solvent-cast composites with higher CNF concentrations exhibit a plateau of the elastic modulus, G′, at low frequencies, an apparent yield stress, and large first normal stress difference, N 1, at low strain rates, which can be attributed to contact-based network nanostructure formed by the long CNFs. A nanostructurally-based model for CNF/PS composites in their melt phase is presented which considers the composite system as rigid rods in a viscoelastic fluid matrix. Except for two coupling parameters, all material constants in the model for the composite systems are deduced from morphological and shear flow measurements of its separate nanofiber and polymer melt constituents of the composite. These two coupling parameters are polymer–fiber interaction parameter, σ, and interfiber interaction parameter, C I. Through comparison with our experimental measurements of the composite systems, we deduce that σ is effectively 1 (corresponding to no polymer–fiber interaction) for all CNF/PS nanocomposites studied. The dependence of CNF orientation on strain rate which we observe in our experiments is captured in the model by considering the interfiber interaction parameter, C I, as a function of strain rate. Applied to shear flows, the model predicts the melt-phase, steady-state viscosities, and normal stress differences of the CNF/PS composites as functions of shear rate, polymer matrix properties, fiber length, and mass concentration consistent with our experimental measurements.  相似文献   

7.
Filled polymeric liquids often exhibit apparent yielding and shear thinning in steady shear flow. Yielding results from non-hydrodynamic particle—particle interactions, while shear thinning results from the non-Newtonian behavior of the polymer melt. A simple equation, based on the linear superposition of two relaxation mechanisms, is proposed to describe the viscosity of filled polymer melts over a wide range of shear rates and filler volume fraction.The viscosity is written as the sum of two generalized Newtonian liquid models. The resulting equation can describe a wide range of shear-thinning viscosity curves, and a hierarchy of equations is obtained by simplifying the general case. Some of the parameters in the equation can be related to the properties of the unfilled liquid and the solid volume fraction. One adjustable parameter, a yield stress, is necessary to describe the viscosity at low rates where non-hydrodynamic particle—particle interaction dominate. At high shear rates, where particle—particle interactions are dominated by interparticle hydrodynamics, no adjustable parameters are necessary. A single equation describes both the high and low shear rate regimes. Predictions of the equation closely fit published viscosity data of filled polymer melts. n power-law index - n 1,n 2 power-law index of first (second) term - shear rate - steady shear viscosity - 0 zero-shear rate viscosity - 0, 1, 0, 2 zero-shear rate viscosity of first (second) term - time constant - 1, 2 time constant of first (second) term - µ r relative viscosity of filled Newtonian liquid - 0 yield stress - ø solid volume fraction - ø m maximum solid volume fraction  相似文献   

8.
9.
A model and simulation method are developed for two-dimensional non-isothermal melt spinning of a visco elastic melt. The visco elastic stress is evaluated from a non-isothermal Giesekus constitutive equation developed by application of the pseudo-time method to the isothermal form of the model [J. Non-Newt. Fluid Mech. (2001)]. The crystallization kinetics is described with the model proposed by Nakamura et al. [J. Appl. Polym. Sci. 17 (1973) 1031], whereas the crystallization rate, which is a function of both temperature and molecular orientation, is evaluated according to the equation proposed by Ziabicki [Fundamentals of Fiber Formation, Wiley, New York, 1976]. The set of non-linear governing equations is solved by using the DEVSS-G/SUPG finite element method. Melt spinning is simulated for two different polymers: amorphous polystyrene and fast-crystallizing Nylon-6,6. The analysis demonstrates that although the kinematics in the thread-line are approximately one-dimensional, the radially non-uniform thermal history, caused by the leading order variation of the temperature gradient ∂T/∂r, gives rise to radially non-uniform visco elastic stresses. This stress gradient results in radially non-uniform molecular orientation and a strong radial variation in crystallinity for Nylon-6,6. The radially non-uniform stress profiles obtained from the simulations are in good agreement with experimental results for melt spinning of polystyrene. Simulations of Nylon-6,6 show that the thermally-induced crystallization depends strongly on the choice of the Avrami index n, and a sharp increase in crystallinity due to stress-induced crystallization is predicted only when the molecules are highly oriented in the drawing direction at high drawing speeds. The significant influences of visco elasticity, air drag, and operating conditions on non-isothermal melt spinning dynamics also are predicted.  相似文献   

10.
The basic problem of order reduction of nonlinear systems with time periodic coefficients is considered in state space and in direct second order (structural) form. In state space order reduction methods, the equations of motion are expressed as a set of first order equations and transformed using the Lyapunov–Floquet (L–F) transformation such that the linear parts of new set of equations are time invariant. At this stage, four order reduction methodologies, namely linear, nonlinear projection via singular perturbation, post-processing approach and invariant manifold technique, are suggested. The invariant manifold technique yields a unique ‘reducibility condition’ that provides the conditions under which an accurate nonlinear order reduction is possible. Unlike perturbation or averaging type approaches, the parametric excitation term is not assumed to be small. An alternate approach of deriving reduced order models in direct second order form is also presented. Here the system is converted into an equivalent second order nonlinear system with time invariant linear system matrices and periodically modulated nonlinearities via the L–F and other canonical transformations. Then a master-slave separation of degrees of freedom is used and a nonlinear relation between the slave coordinates and the master coordinates is constructed. This method yields the same ‘reducibility conditions’ obtained by invariant manifold approach in state space. Some examples are given to show potential applications to real problems using above mentioned methodologies. Order reduction possibilities and results for various cases including ‘parametric’, ‘internal’, ‘true internal’ and ‘true combination resonances’ are discussed. A generalization of these ideas to periodic-quasiperiodic systems is included and demonstrated by means of an example.  相似文献   

11.
Data from iPP film casting experiments served as a basis to model the effect of flow on polymer crystallization kinetics. These data describe the temperature, width, velocity and crystallinity distributions along the drawing direction under conditions permitting crystallization along the draw length.In order to model the effect of flow on crystallization kinetics, a modification of a previously defined quiescent kinetic model was adopted. This modification consisted in using a higher melting temperature than in the original quiescent model. The reason for the modification was to account for an increase of crystallization temperature due to entropy decrease of the flowing melt. This entropy decrease was calculated from the molecular orientation on the basis of rubber elasticity theory applied to the entangled and elongated melt. The evolution of molecular orientation (elongation) during the film casting experiments was calculated using a non-linear dumbbell model which considers the relaxation time, obtained from normal stress difference and viscosity functions, to be a function of the deformation rate.The comparison between experimental distributions and model based crystallinity distributions was satisfactory.  相似文献   

12.
Very different materials are named ‘Glass’, with Young's modulus E and Poisson's ratio ν extending from 5 to 180 GPa and from 0.1 to 0.4, respectively, in the case of bulk inorganic glasses. Glasses have in common the lack of long range order in the atomic organization. Beside the essential role of elastic properties for materials selection in mechanical design, we show in this analysis that macroscopical elastic characteristics (E,ν) provide an interesting way to get insight into the short- and medium-range orders existing in glasses. In particular, ν, the packing density (Cg) and the glass network dimensionality appear to be strongly correlated. Networks consisting primarily of chains and layers units (chalcogenides, low Si-content silicate glasses) correspond to ν>0.25 and Cg>0.56, with maximum values observed for metallic glasses (ν0.4 and Cg>0.7). On the contrary, ν<0.25 is associated to a highly cross-linked network with a tri-dimensional organization resulting in a low packing density. Moreover, the temperature dependence of the elastic moduli brings a new light on the ‘fragility’ of glasses (as introduced by Angell) and on the level of cooperativity of atomic movements at the source of the deformation process. To cite this article: T. Rouxel, C. R. Mecanique 334 (2006).  相似文献   

13.
Experimental data of two low-density polyethylene (LDPE) melts at 200°C for both shear flow (transient and steady shear viscosity as well as transient and steady first normal stress coefficient) and elongational flow (transient and steady-state elongational viscosity) as published by Pivokonsky et al. (J Non-Newtonian Fluid Mech 135:58–67, 2006) were analysed using the molecular stress function model for broadly distributed, randomly branched molecular structures. For quantitative modelling of melt rheology in both types of flow and in a very wide range of deformation rates, only three nonlinear viscoelastic material parameters are needed: Whilst the rotational parameter, a 2, and the structural parameter, β, are found to be equal for the two melts considered, the melts differ in the parameter describing maximum stretch of the polymer chains.  相似文献   

14.
Fatigue life of ‘bead-on-plate’ on commercially pure aluminum and Al---Zn---Mg alloy have been investigated. In both cases, the fatigue life of ‘Bead-on-Plate’ specimen was drastically reduced. But when the same weld-bead was flushed off, a marginal improvement in fatigue life was observed. For Al---Zn---Mg alloy, the post weld heat treatment was less effective than flushing of weld-bead for improving the fatigue life of welded specimens. Results are analyzed with the help of S-N diagrams and microphotographs.  相似文献   

15.
Summary Based on Maron-Pierce's equation, an empirical equation was suggested, which relates the relative viscosity ( r ) of the polymer melt filled with various inorganic filler, such as glass fiber, carbon fiber, talc, precipitated- and natural-calcium carbonate powder, and glassy small sphere, to the volume fraction () of the filler. The equation is r = (1 –/A)–2, whereA is a parameter relating to the packing geometry of the filler, which is similar to the parameter 0 in Maron-Pierce's equation. In the equation r is defined as the ratio of the viscosity of the filledsystem to that of the medium at the same shear stress not the shear rate. The applicability of the equation is above the shear stress about 104 dyne/cm2. The equation has a simple form and is considered to have a practical utility for filled-polymer melt systems.With 2 figures and 1 table  相似文献   

16.
We investigated the dynamic viscoelasticity and elongational viscosity of polypropylene (PP) containing 0.5 wt% of 1,3:2,4-bis-O-(p-methylbenzylidene)-d-sorbitol (PDTS). The PP/PDTS system exhibited a sol–gel transition (T gel) at 193 °C. The critical exponent n was nearly equal to 2/3, in agreement with the value predicted by a percolation theory. This critical gel is due to a three-dimensional network structure of PDTS crystals. The elongational viscosity behavior of neat PP followed the linear viscosity growth function + (t), where η + (t) is the shear stress growth function in the linear viscoelastic region. The elongational viscosity of the PP/PDTS system also followed the + (t) above T gel but did not follow the + (t) and exhibited strong strain-softening behavior below T gel. This strain softening can be attributed to breakage of the network structure of PDTS with a critical stress (σ c) of about 104 Pa.  相似文献   

17.
The macromolecular alignment and texture orientation in sheared thermotropic copolyester were investigated using in situ wide-angle X-ray scattering (WAXS) and polarizing optical microscopy (POM). The molecular behavior was correlated with viscoelastic properties. The polymer is a random copolyester based on 60 mol% 1,4-hydroxybenzoic acid (B) and 40 mol% ethylene terephthalate (ET) units. X-ray scattering showed that the molecular chains were aligned along the flow direction. The degree of molecular orientation, , is an increasing function of the applied shear rate. However, rheo-optics showed that shear flow could not orient the polydomain texture, i.e., neither defect stretching nor elimination of defects was observed. Instead, shear compressed the microdomains and gave rise to long-range orientation correlations. Rheology showed that the nematic melt is viscoelastic, the loss modulus G″ dominates the elastic modulus G′, and the dynamic viscosity η* is shear thinning. Moreover, the steady shear viscosity, η, also behaved shear thinning, while the first normal stress difference N 1 remained positive. The empirical Cox–Merz rule did not hold, , within the shear rate range studied. The microscopic and rheological properties suggest that B–ET is a flow-aligning nematic polymer.  相似文献   

18.
A comparison between two quantities concerning quiescent crystallization of polymer melts, namely the quiescent crystallization onset time (t on,q) and gel time (t gel), is performed using rheological methods. It was found that t gel as measured from the evolution of loss angle (tan δ) occurs slightly earlier than t on,q, defined as the time required for the viscosity to reach twice its steady-state value. The change of viscosity with time was measured with Small Amplitude Oscillatory Shear (SAOS) method. Two alternative methods to measure t on,q are studied: by continuous shear at a very small shear rate and by creep method. A very good agreement from all the three methods was achieved, indicating the robust nature of this quantity. Finally, the gel times for different PB-1 samples are considered. When the difference in crossover angular frequencies (ω x ) of the samples is taken into account in performing t gel experiments, it can be shown that the temperature dependence of t gel for the samples are the same. However, for samples having high molecular weight t gel measurements are problematic. In this case, t on,q serves as an easier tool to compare the crystallization behaviour of different samples.  相似文献   

19.
 Various grades of polypropylene were melt blended with a thermotropic liquid crystalline polymer, a block copolymer of p-hydroxy benzoic acid and ethylene terephthalate (60/40 mole ratio). The blends were extruded as cast films at different values of draw ratio (slit width/film thickness). Fibrillation of TLCP dispersed phase with high fiber aspect ratio (length/width) was obtained with the matrix of low melt flow rate, i.e., high viscosity and with increasing film drawing. Melt viscosities of pure components and blends measured using capillary rheometer were found to decrease with increasing shear rate and temperature. Viscosity ratios (dispersed phase to matrix phase) of the systems being investigated at 255 °C at the shear rate ranged from 102 to 104 s−1, were found to lie between 0.04 and 0.15. The addition of a few percent of elastomeric compatibilizers; a tri-block copolymer SEBS, EPDM rubber and maleated-EPDM, was found to affect the melt viscosity of the blend and hence the morphology. Among these three compatibilizers, SEBS was found to provide the best fibrillation. Received: 10 January 2000/Accepted: 24 January 2000  相似文献   

20.
Zonal fracturing mechanism in deep crack-weakened rock masses   总被引:1,自引:0,他引:1  
The mechanical behaviors of deep crack-weakened rock masses are different from those of shallow crack-weakened rock masses. The surrounding rock in shallow crack-weakened rock mass engineering is classified into loose zone, plastic zone and elastic zone, while the surrounding rock in deep crack-weakened rock mass engineering is classified into fractured zone and non-fractured zone, which occur alternatively. It is assumed that the deep rock masses contain one joint set, in which the probability density function describing the distribution of sizes is assumed to follow the Rayleigh distribution, and the probability density function describing the distribution of spacing is assumed to follow the Weibull distribution. On the basis of strength criterion of deep rock mass, the near-field stress redistribution around circular opening induced by excavation is determined. The strong interaction among cracks is investigated by using the dislocation model. The nucleation, growth, interaction and coalescence of cracks were analyzed based on the strain energy density factor theory. When cracks coalesce, failure of deep crack-weakened rock masses occurs, fractured zone is formed. Then, size and quantity of fractured zone and non-fractured zone are given out. The size and quantity of fractured zone increase with decreasing strength of rock mass. The size and quantity of fractured zone increase with increasing in situ stress. Zonal fracturing phenomenon occurs once value of in situ stress is larger than the unaxial compressive strength of rock masses. The size and quantity of fractured zone decrease with increasing λ when p2 > p1. The size and quantity of fractured zone increase with increasing λ when p2 < p1.  相似文献   

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