Dynamical enhanced electron emission and discharges at contaminated surfaces

Broad-area electrodes show electron emission already at electric field strengthsF≈10⁷ V/m. This enhanced field emission (EFE) occurs only for contaminated surfaces. EFE is accompanied by photon emission and gas desorption yielding finally discharges. EFE is caused by dust and contaminants initiating the following effects:

an electron is stochastically emitted in a trigger zone

the electron gains energyΔE?eΔxF ^*

which excites electronic states

which relax by the emission of electrons, photons, and atoms

where the positive charges left behind enhanceF ^*=βF (β?1) initiating so an electron avalanche, i.e., a high conductivity channel. Because of charge migration and neutralization, this avalanche has a life time. This pulsating EFE is accompanied by light emission and gas desorption yielding finally a gas cloud and a discharge.

The pulsating, self-sustained EFE has the same root as:

the enhanced secondary emission found first by Malter

the conductivity switching exhibited by thin (≈ 1 μm) layers of semiconductors or insulators

the normal cathode fall and

the firing-wave instability in neurodynamics.

     

The moment of inertia at the saddle point of low energy fission of even-even nuclei

We use the molecular model of low energy fission, which describes the nucleus by two interacting fragments, to calculate the moment of inertia for U²³⁶ in the cranking approximation including BCS theory. We show that the moment of inertia at the saddle point:

1. depends almost linearly on the fragment distance.
2. is influenced only very weakly by the pairing constant and by the fragment deformations.
3. shows, as a function of the distribution of mass between the two fragments (A ₁ ,A ₂ ), a minimum near the magic configurationA ₁=132,Z ₁=50 and depends in this mass region strongly on the term structure near the Fermi energy.
4. is approximately that of a rigid body.

     

Continuous measures in one dimension

Families of unimodal maps satisfying

1. T _λ: [?1,1]?[?1,1] withT(±1)=?1 and |T _λ ^′ (1)|>1.
2. T _λ(x) isC ² inx ² and λ, and symmetric inx.
3. T ₀(0)=0,T ₁(0)=1 with \(\frac{d}{{d\lambda }}\) T _λ(0)>0

are considered. The results of Guckenheimer (1982) are extended to show that there is a positive measure of λ for whichT _λ has a finite absolutely continuous invariant measure. The appendix contains general theorems for the existence of such measures for some markov maps of the interval.     

The process e + e − → bb̅W + W − at the next linear collider in the Minimal Supersymmetric Standard Model

The complete matrix element for e ⁺ e^? → bb?W⁺ W^? is computed at tree-level within the Minimal Supersymmetric Standard Model. Rates of interest to phenomenological analyses at the Next Linear Collider are given. In particular, we study:

• ? tt? production and decay tt? →(bW ⁺)(b?W ^?)
• ? ZH production followed by Z → bb? and H → W ⁺ W^?
• ? AH production followed by A→ bb? and H → W ⁺ W^?
• ? hW ⁺ W^? production followed by h→ bb?.

Top and Higgs finite width effects are included, as well as all those of the irreducible backgrounds.     

Small-angle X-ray scattering on spinodal,nucleotic or coarsening processes in two-phase systems containing spherical,fibrillar or lamellar inhomogeneities

We study the effects of some of the most important and typical structural changes in two-phase systems on selected structural parameters obtained from small-angle x-ray scattering (SAXS) measurements. To limit the present study, it was assumed that the Phase, 1, embedded in the matrix

1. is monodispersed and homogeneous,
2. possesses one of the three most extreme shapes (spherical, fibrillar or lamellar) and
3. changes its behaviour

1. through type change (spinodal or nucleotic or coarsening), without changing the shape,
2. through a change of the shape only, or
3. through a) (type change) and b) (shape change) simultaneously.

To find the type of change for three basically different shapes of Phase 1 and to calculate its intensity (amount of the change) the following three SAXS parameters must be compared before and after the treatment of the system:

1. chord lengthl ₁ (and/or radius of gyrationR),
2. volume partw ₁ of the Phase 1, and
3. relative inner surfaceS _v of the system.

It is shown by this comparison that by the pure type change in the case of

1. spinodal change, all three SAXRS parameters are increasing or decreasing simultaneously and proportional to a power of the intensity of the change,
2. nucleotic change,l ₁ (and/orR) is unchanged, the other two (w ₁ andS _v ) are increasing or decreasing simultaneously and directly proportional to the intensity,
3. coarsening change,w ₁ is unchanged and anincreasing ofl ₁ is always accompanied by adecreasing ofS _v and vice versa.

In addition to this type change, the cases of mere changes of the shape (“shape change”) and finally of simultaneous type and/or shape change are studied. For the case of pure shape change the alteration of the dimensions (chord lengthl ₁ and/or radius of gyrationR) must be followed. The limitations of the analyses of the simultaneous type and/or shape change are discussed in detail.     

Polarization effects of picosecond CARS in liquids

Coherent Raman scattering of delayed probing pulses after ultrafast excitation is investigated under generalized polarization conditions. Three factors are shown to contribute to the scattering signal:

1. scattering off the isotropic part of the resonant material excitation via the isotropic component of the Raman polarizability
2. scattering via the anisotropic part of the Raman polarizability from a second, oriented component of the resonant material excitation
3. four-wave mixing via the non-resonant part χ_NR of the third-order susceptibility. We demonstrate theoretically and experimentally that different polarization conditions lead to drastic changes of the signal transients in liquids. For the ring breathing mode of C₆H₅Br the ratio of non-resonant to resonant contributions is measured to be χ_NR/χ_res=0.037±0.015.

     

Unbounded derivations ofC*-algebras II

It is demonstrated that a closed symmetric derivation δ of aC?-algebra \(\mathfrak{A}\) generates a strongly continuous one-parameter group of automorphisms of aC?-algebra \(\mathfrak{A}\) if and only if, it satisfies one of the following three conditions

1. (αδ+1)(D(δ))= \(\mathfrak{A}\) , α∈?\{0}.
2. δ possesses a dense set of analytic elements.
3. δ possesses a dense set of geometric elements.

Together with one of the following two conditions

1. ∥(αδ+1)(A)∥≧∥A∥, α∈IR,A∈D(δ).
2. If α∈IR andA∈D(δ) then (αδ+1)(A)≧0 impliesA≧0.

Other characterizations are given in terms of invariant states and the invariance ofD(δ) under the square root operation of positive elements.     

Jump discontinuities of semilinear,strictly hyperbolic systems in two variables: Creation and propagation

The creation and propagation of jump discontinuities in the solutions of semilinear strictly hyperbolic systems is studied in the case where the initial data has a discrete set, {x _i } _i ⁼¹ⁿ , of jump discontinuities. LetS be the smallest closed set which satisfies:

1. S is a union of forward characteristics.
2. S contains all the forward characteristics from the points {x _i } _i ⁼¹ⁿ .
3. if two forward characteristics inS intersect, then all forward characteristics from the point of intersection lie inS.

We prove that the singular support of the solution lies inS. We derive a sum law which gives a lower bound on the smoothness of the solution across forward characteristics from an intersection point. We prove a sufficient condition which guarantees that in many cases the lower bound is also an upper bound.     

Optically-pumped stimulated recombination radiation inp-type InSb in high magnetic fields

In this paper measurements of the frequency, linewidth and polarization of stimulated recombination radiation (SRR) fromp-type InSb are reported. The samples had low excess-carrier concentrations between 10¹⁴ and 10¹⁵ per cm³ and different lengths between 0.4 and 9 mm. They were held in magnetic fields up to 6T at temperatures of pumped liquid helium. The excitation was done optically by the radiation of a Q-switched CO-laser. We could observe a number of different stimulated processes:

1. band-to-band recombination (tuning between 1875 and 1980 cm^?1),
2. band-to-acceptor recombination (tuning between 1840 and 1930 cm^?1),
3. stimulated spin-flip Raman scattering (SFR) of the SRR by excited electrons,
4. SFR of the laser by excited electrons and its interaction with the SRR.

From the observed shift of the band gap by exchange and correlation energy the number of created electron-hole pairs can be calculated to be up to 10¹⁶ per cm³. The observed acceptor binding energy varies from 66 cm^?1 atB=0 to 71 cm^?1 at 4.5T.     

A proof of the unitarity ofS-matrix in a nonlocal quantum field theory

Using the formfactors which are entire analytic functions in a momentum space, nonlocality is introduced for a wide class of interaction Lagrangians in the quantum theory of one-component scalar field φ(x). We point out a regularization procedure which possesses the following features:

1. The regularizedS ^δ matrix is defined and there exists the limit $$\mathop {\lim }\limits_{\delta \to 0} S^\delta = S.$$
2. The Green positive-frequency functions which determine the operation of multiplication in \(S \cdot S^ + \mathop = \limits_{Df} S \circledast S^ + \) can be also regularized ?^δ and there exists the limit $$\mathop {\lim }\limits_{\delta \to 0} \circledast ^\delta = \circledast \equiv .$$
3. The operator \(J(\delta _1 ,\delta _2 ,\delta _3 ) = S^{\delta _1 } \circledast ^{\delta _2 } S^{\delta _3 + } \) is continuous at the point δ₁=δ₂=δ₃=0.
4. $$S^\delta \circledast ^\delta S^{\delta + } \equiv 1at\delta > 0.$$ Consequently, theS-matrix is unitary, i.e. $$S \circledast S^ + = S \cdot S^ + = 1.$$

     

Photoemission on the highT c superconductors Y−Ba−Cu−O

XPS and UPS photoemission experiments on the highT _c superconductors (T _c ≈90 K) with nominal composition YBa₂Cu₃O_9-y (y≈2) show the following:

1. The density of electronic states at the Fermi energy is very small, much smaller than in pure Cu.
2. The Cu 2p spectra show only a Cu²⁺ contribution.
3. The Ba core levels show a structure with two components of nearly equal magnitude, which leads to the suggestion that these compounds have large O^2? vacancies coordinated to Ba²⁺ sites.
4. Annealing at 400°C under UHV conditions leads possibly to a partial reduction of Cu²⁺ to lower Cu valence states and to a small increase of the O^2? vacancy component of the Ba²⁺ line.

     

Berechnung der Signalform bei Doppelresonanzexperimenten an2 P 3/2-Zuständen im starken Magnetfeld

A computer program has been set up, which permits to calculate the signal shape for optical double resonance experiments in² P _3/2-states of alkali atoms in a strong magnetic field. The application to the 5² P _3/2-state of³⁹K, where recently large discrepancies have been reported between early double resonance measurements and new level crossing experiments, has the following results:

1. The measured strong field spectra can be reproduced satisfactorily, if the level crossing data for the hyperfine structure coupling constants are used.
2. The computed line shifts are in good agreement with a formula recently deduced by means of a new approximation methode.

     

On continuity of Bowen-Ruelle-Sinai measures in families of one dimensional maps

Let us consider a family of mapsQ _a (x)=ax(1?x) from the unit interval [0,1] to itself, wherea∈[0,4] is the parameter. We show that, for any β<2, there exists a subsetE?4 in [0,4] with the properties

1. Leb([4??,4]?E) < ?^β for sufficiently small ?>0,
2. Q _a admits an absolutely continuous BRS measure µ_a whena∈E, and
3. µ_a converges to the measure µ₄ asa tends to 4 on the setE. Also we give some generalization of this results.

     

Ambiguities in theη-nucleon scattering length determination

The positive sign of theη-nucleon scattering lengthb _ηN was predicted in [1] assuming the resonance mechanism for theπ ^?p → ηn reaction. We demonstrate that

1. the assumption about thet-channel mechanism of the reaction leads tob _ηN < 0 and
2. the experimental data on theη production cross section are equally compatible with both resonance andt-channel mechanisms.

     

Bounds on the number of eigenvalues of the Schrödinger operator

Inequalities on eigenvalues of the Schrödinger operator are re-examined in the case of spherically symmetric potentials. In particular, we obtain:

1. A connection between the moments of order (n ? 1)/2 of the eigenvalues of a one-dimensional problem and the total number of bound statesN _n, inn space dimensions;
2. optimal bounds on the total number of bound states below a given energy in one dimension;
3. alower bound onN ₂;
4. a self-contained proof of the inequality for α ≧ 0,n ≧ 3, leading to the optimalC ₀₄,C ₃;
5. solutions of non-linear variation equations which lead, forn ≧ 7, to counter examples to the conjecture thatC _0n is given either by the one-bound state case or by the classic limit; at the same time a conjecture on the nodal structure of the wave functions is disproved.

     

Lattice dynamics and transport equations for quantum crystals including singular interactions

The influence of frequency modulation of the rf field and modulation of the static magnetic field on NMR-response is investigated. The mathematical treatment using density operator formalism results in a different dynamical behaviour of the nuclei whether frequency—or field modulation is applied. Therefore a general equivalence of the two kinds of modulation does not exist. Explicite solutions for the nuclear magnetization with simultaneous frequency—and field modulation are evaluated for systems obeying Bloch equations. Resonance experiments have been performed using different detection methods:

1. rf spectrum analysis of the nuclear induction emf from a decoupled (zero leakage) crossed coil setup.
2. conventional lock-in detection of the signal information from an NMR-detector with single resonant circuit.

     

The use of unitarity bounds for a stable extrapolation of low energy data

The properties of the scattering amplitude allow to define a functionf(z) satisfying the following conditions:

1. f(z) is holomorphic in a simply connected domain , which can be mapped conformally onto the unit disk;
2. |Imf(z)| is bounded by some constantM in ;
3. |Ref(z)| is known not to exceed some constantm on a certain part Γ₁ of the boundary Γ of ;f(z) is continuously extensible onto Γ.

Using these properties, constraints are derived on the real part off(z) valid at any point . The result is used for performing a stable extrapolation of low energy pion-pion scattering data to any finite energy. We derive a bound on energy averaged values of the real part of the scattering amplitude. The bound depends onm, M, on the energy variabless and on the energy average intervals ₂?s ₁. Generalizations of the method are discussed.     

Correlation inequalities and uniqueness of the equilibrium state for the plane rotator ferromagnetic model

We derive new inequalities for the plane rotator ferromagnetic model and use them to obtain the following results:

1. If the model is isotropic, the derivability of the free energy as function of the magnetic fieldh implies the existence of a unique translation invariant Gibbs state and if furthermoreh=0 all Gibbs states are invariant by rotation of the spins.
2. If the model is anisotropic the above assertion holds forh non-zero.
3. If the model is anisotropic then there are at most two extremal translation invariant Gibbs states for almost all values of the anisotropy parameter.

     

SIMS and flash desorption studies of nickel oxygen interaction

O₂ exposure of polycrystalline nickel at 300 K results in characteristics changes of secondary ion emission. These can be described by a model which is in good agreement with corresponding LEED, AES, XPS, and ΔΦ results of other authors. According to this model, oxygen can be bonded on Ni in at least five different phases:

1. chemisorption, indicated by a rapid increase of Ni⁺, Ni ₂ ⁺ , and Ni₂O⁺ (≦5 L);
2. a rearranged chemisorption layer, characterized by a drastic decrease of Ni⁺, Ni ₂ ⁺ , and Ni₂O⁺ (5–15 L);
3. nickel oxide (NiO) responsible for a strong NiO^?- and NiO ₂ ^? -emission (≦40 L);
4. oxygen on top of this NiO layer, producing a final increase of Ni⁺ and NiO⁺ and a O₂-flash signal at 400 K (>40 L);
5. bulk dissolved oxygen in thermal equilibrium with a chemisorption layer (after several exposure/heating cycles).

During ion bombardment of a 100 L O₂ exposed Ni surface these different binding states occur in a reversed order of succession. O₂-flash signals at 400 and 1100 K, related to drastic changes in secondary ion emission at 400, 700, and 1100 K, reflect the disappearance of various oxygen binding states. The exchange between different oxygen phases was studied by¹⁶O₂/¹⁸O₂ isotope experiments.