共查询到14条相似文献,搜索用时 15 毫秒
1.
Birefringence in polycarbonate: Molecular orientation induced by cooling stresses. I. Free quenching
The residual birefringence distributions in polycarbonate disks quenched in a liquid bath under various conditions are determined. Unbalanced distributions of approximately parabolic shape are obtained in the cross-sections in general. A systematic influence of the initial quench temperature on the imblance of the birefringence distributions is observed, with higher initial temperatures leading to a strong shift of birefringence in the positive direction. The systematic variation of the birefringence distribution with quenching conditions is interpreted in terms of a stress and an orientation contribution. The distributions are predicted correctly by a numerical program making use of the linear stress-optical rule with a different stress-optical coefficient above and below the glass-transition temperature. The contribution of molecular orientation is distinguished experimentally from the stress contribution by annealing experiments. © 1993 John Wiley & Sons, Inc. 相似文献
2.
Birefringence distributions in cross-sections of quenched polycarbonate disks are investigated. The effects of the introduction of new surfaces by sectioning are studied by using different cross-section widths, by quenching rod-shaped specimens, and by measuring the birefringence with oblique incident light. The experimental results are confirmed by numerical calculations of stress distributions in rods with varying aspect ratios. Stress release by appropriate sectioning is used to distinguish between stress and orientation contribution to birefringence. It is found that cutting cross-sections leads to a major stress redistribution in the width direction. This does not affect the birefringence measurement, but the decrease of the stress level in the long direction needs to be taken into account. The molecular orientation in the quenched samples cannot be explained only by the effect of transient thermal stresses above the glass transition. There is another orientation contribution, most likely related to stress relaxation below Tg. © 1993 John Wiley & Sons, Inc. 相似文献
3.
A physical modeling and a two‐dimensional numerical simulation of the injection‐molding of a disk cavity by using a hybrid finite element method (FEM) and finite difference method (FDM) are presented. Three stages of the injection‐molding cycle––filling, packing, and cooling––are included. The total residual stresses are taken to be a sum of the flow stresses calculated using a compressible nonlinear viscoelastic constitutive equation and the thermal stresses calculated using a linear viscoelastic constitutive equation. The total residual birefringence is taken to be the sum of the flow birefringence related to the flow stresses through the stress–optical rule, and the thermal birefringence related to the thermal stresses through the photoviscoelastic constitutive equation. The Tait equation is used to describe the P‐V‐T relationship. The simulation shows that without packing the birefringence in the surface layer of moldings, with its maximum near the surface, is caused by the frozen‐in flow birefringence (flow stresses) and in the core region by the frozen‐in thermal birefringence (thermal stresses). With packing, a second birefringence maximum appears between the center and the position of the first maximum due to flow in the packing stage. The predicted birefringence profiles and extinction angle profiles are found to be in fair agreement with corresponding measurements in literature for disk moldings. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 622–639, 2006 相似文献
4.
The fiber orientation distribution is one of the important microstructure variables for thermoplastic composites reinforced with discontinuous fibers. In this paper, the long fibers in the injection molded part are measured in detail by micro X-ray CT. A three dimensional (3D) structure of the sample is built and two dimensional images are generated for image analysis. The orientation tensor of fibers is calculated in the flow plane. It shows a symmetric distribution of fibers through the thickness direction, which consists of outer skin, transition zone and the core. The skin layer is so thin that it has only one layer of highly oriented fibers. The core layer also has highly oriented fibers but the direction of fibers is different from that in the skin layer. Nevertheless, the clustering of the fibers is characterized quantitatively in the core. The transition zone can be divided into two subzones by the principal directions of the tensor. 相似文献
5.
In contrast to solid parts fabricated through conventional injection molding (CIM), foamed parts manufactured via foam injection molding (FIM) exhibit substantial variations in mechanical properties, which are attributed to differences in the cellular structure. In this study, parts with different cellular structures are fabricated via FIM, during which the gas dissolution and desorption processes are controlled by subjecting the gas‐laden melt to reciprocating compression and expansion operations. The results suggest that the cell density can be drastically improved by rapidly decreasing the pressure caused by the mold opening and that the cell orientation obviously occurs in the direction perpendicular to the mold‐opening direction. Moreover, the cell density and cellular orientation can be adjusted by utilizing appropriate mold opening and closing operations, leading to improvements in the resultant ultimate mechanical properties. In particular, the foamed samples fabricated with controlled mold opening‐closing operations exhibit excellent tensile strength and strain‐at‐break, indicating that samples containing a high density of cells oriented along the tensile test direction facilitate the formation of superductility and an increase in tensile strength. Hence, a method that combines FIM with batch foaming has been proposed for improving the cellular structure and controlling the cellular orientation. 相似文献
6.
Marcia Cristina Branciforti Carlos Amauri Oliveira Jose Alexandrino de Sousa 《先进技术聚合物》2010,21(5):322-330
In order to promote better understanding of the structure‐mechanical properties relationships of filled thermoplastic compounds, the molecular orientation and the degree of crystallinity of injection molded talc‐filled isotactic polypropylene (PP) composites were investigated by X‐ray pole figures and wide‐angle X‐ray diffraction (WAXD). The usual orientation of the filler particles, where the plate planes of talc particles are oriented parallel to the surface of injection molding and influence the orientation of the α‐PP crystallites was observed. The PP crystallites show bimodal orientation in which the c‐ and a*‐axes are mixed oriented to the longitudinal direction (LD) and the b‐axis is oriented to the normal direction (ND). It was found that the preferential b‐axis orientation of PP crystallites increases significantly in the presence of talc particles up to 20 wt% in the composites and then levels‐off at higher filler content. WAXD measurements of the degree of crystallinity through the thickness of injection molded PP/talc composites indicated an increasing gradient of PP matrix crystallinity content from the core to the skin layers of the molded plaques. Also, the bulk PP crystallinity content of the composites, as determined by DSC measurements, increased with talc filler concentration. The bulk crystallinity content of PP matrix and the orientation behavior of the matrix PP crystallites and that of the talc particles in composites are influenced by the presence of the filler content and these three composite's microstructure modification factors influence significantly the flexural moduli and the mechanical stiffness anisotropy data (ELD/ETD) of the analyzed PP/talc composites. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
7.
The structural evolution during uniaxial stretching of poly(vinyl chloride) films was studied using our real time spectral birefringence stretching machine. The effect of clay loading and the amount of plasticizer as well as the rate effects on the birefringence development and true mechanical response are presented with a final model summarizing the molecular phenomena during stretching. Mechano‐optical studies revealed that birefringence correlated with mechanical response (stress, strain, work) nonlinearly. This was primarily attributed to the preexisting strong network of largely amorphous chains connected via small crystallites that act as physical crosslinking points. These crystallites are not easily destroyed during the high‐speed stretching process as evidenced from the birefringence–true strain curves along with the X‐ray crystallinity measurements. At high speeds, the amorphous chains do not have enough time to relax and hence attain higher orientation levels. The crystallites, however, orient more efficiently when stretched at slow speeds. Apparently, some relaxation of the surrounding amorphous chains helps rotate the crystallites in the stretching direction. Overall birefringence is higher at high stretching speeds for a given true strain value. When the nanoparticles are incorporated, the orientation levels are increased significantly for both the crystalline and amorphous phases. Nanoplatelets increase the continuity of the network because they have strong interaction with the amorphous chains and/or crystallites. This in turn helps transfer the local stresses to the attached chains and increase the orientation levels of the chains. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 724–742, 2005 相似文献
8.
准确测定钛合金粉末微注射成形脱脂坯中氧氮氢含量对钛合金的粉末微注射工艺改进有很大指导作用。采用工业镍板经过表面打磨、酸洗、加工成固定质量的镍粒来代替市售的镍助熔剂,通过自制镍粒预先加入设备预脱气减少空白影响的方式建立了脉冲熔融-红外/热导法测定钛合金粉末微注射成形的脱脂坯中氧氮氢含量的方法。实验表明,镍粒助熔剂与石墨坩埚经二次脱气,可确保镍粒助熔剂的空白降至极低值以代替市售的镍篮、镍屑等助熔剂。钛合金粉末微注射成形脱脂坯采用振动磨形式加工至0.178 mm以下,镍粒的加入量为1.5 g,分析功率为5 300 W时,可以获得稳定准确的结果。采用实验方法对脱脂坯实际样品进行测定,其相对标准偏差(RSD,n=6)分别为0.080%~0.47%、0.28%~1.3%和1.6%~2.0%;采用加入钛合金标准样品进行加标回收实验,氧氮氢加标回收率分别在95.7%~104%、97.8%~100%及96.6%~103%。方法满足脱脂坯中的氧氮氢快速检测要求的同时,极大地降低了分析成本。 相似文献
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10.
M. Ree T. J. Shin Y.-H. Park S. I. Kim S. H. Woo C. K. Cho C. E. Park 《Journal of Polymer Science.Polymer Physics》1998,36(8):1261-1273
A soluble poly(amic acid) precursor solution of fully rod-like poly(p-phenylene pyromellitimide) (PMDA-PDA) was spin cast on silicon substrates, followed by soft bake at 80–185°C and subsequent thermal imidization at various conditions over 185–400°C in nitrogen atmosphere to be converted to the polyimide in films. Residual stress generated at the interface was measured in situ during imidization. In addition, the imidized films were characterized in the aspect of polymer chain orientation and ordering by prism coupling and X-ray diffraction. The soft-baked precursor film revealed a residual stress of 16–28 MPa at room temperature, depending on the soft bake condition: higher temperature and longer time in the soft bake gave higher residual stress. The stress variation in the soft-baked precursor film was not significantly reflected in the final stress in the resultant polyimide film. However, the residual stress in the polyimide film varied sensitively with variations in imidization process parameters, such as imidization temperature, imidization steps, heating rate, and film thickness. The polyimide film exhibited a wide range of residual stress, −7 MPa to 8 MPa at room temperature, depending on the imidization condition. Both rapid imidization and low-temperature imidization generated high stress in the tension mode in the polyimide film, whereas slow imidization as well as high temperature imidization gave high stress in the compression mode. Thus, a moderate imidization condition, a single- or two-step imidization at 300°C for 2 h with a heating rate of < 10 K/min was proposed to give a relatively low stress in the polyimide film of < 10 μm thickness. However, once a precursor film was thermally imidized at a chosen process condition, the residual stress–temperature profile was insensitive to variations in the cooling process. All the films imidized were optically anisotropic, regardless of the imidization history, indicating that rod-like PMDA-PDA polyimide chains were preferentially aligned in the film plane. However, its degree of in-plane chain orientation varied on the imidization history. It is directly correlated to the residual stress in the film, which is an in-plane characteristic. For films with residual stress in the tension mode, higher stress films exhibited lower out-of-plane birefringence, that is, lower in-plane chain orienta-tion. In contrast, in the compression mode, higher stress films showed higher in-plane chain orientation. © 1998 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 36: 1261–1273, 1998 相似文献
11.
Cristina M. Quintella Yuji N. Watanabe Mauro Korn Marcelo Embiruçu 《Analytica chimica acta》2004,523(2):293-300
A fully mechanized set-up was built for the experimental determination of bi-dimensional dispersion with high spatial resolution (2400 μm2). Gravitational and wall effects in a single stream were evaluated by using time-based sampling and a micro-flow cell. Vertical upward and downward flows as well as horizontal flows were investigated. Ethylene glycol (MEG) and Rhodamine B in MEG were used as carrier and sample solutions, respectively. Longitudinal profiles were obtained by laser induced total fluorescence (LIF) at up to 19 transversal sites and combined to generate high-resolution bi-dimensional profiles. A two frontal maxima pattern was observed for all flows. The volumetric fraction of RB shape was highly stretched for downward flow and there was high asymmetry for horizontal flow. The sensitivity of three dispersion parameters was evaluated: maximum peak value, peak half-width at half-height, and peak area.Data modeling showed that the tanks-in-series was more sensitive to wall effects, had good adjustment with only one tank for upward and horizontal flow and needed two tanks for downward flow which was attributed to the latter having higher dispersion. A black box empirical modeling described better the gravitational effect and allowed to identify a parameter sensitive to upward and downward flow as well as hinting to two inner streams within the horizontal flow. It also pointed to a wall dispersion contribution of twice that of the liquid-liquid dispersion. 相似文献
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Pablo E Carrero Julian F Tyson 《Spectrochimica Acta Part B: Atomic Spectroscopy》1998,53(14):1931-1943
A sample solution was passed at 20 ml min−1 through a column (150×4 mm2) of Amberlite IRA-410Stron anion-exchange resin for 60 s. After washing, a solution of 0.1% sodium borohydride was passed through the column for 60 s at 5.1 ml min−1. Following a second wash, a solution of 8 mol l−1 hydrochloric acid was passed at 5.1 ml min−1 for 45 s. The hydrogen selenide was stripped from the eluent solution by the addition of an argon flow at 150 ml min−1 and the bulk phases were separated by a glass gas–liquid separator containing glass beads. The gas stream was dried by passing through a Nafion® dryer and fed, via a quartz capillary tube, into the dosing hole of a transversely heated graphite cuvette containing an integrated L’vov platform which had been pretreated with 120 μg of iridium as trapping agent. The furnace was held at a temperature of 250°C during this trapping stage and then stepped to 2000°C for atomization. The calibration was performed with aqueous standards solution of selenium (selenite, SeO32−) with quantification by peak area. A number of experimental parameters, including reagent flow rates and composition., nature of the gas–liquid separator, nature of the anion-exchange resin, column dimensions, argon flow rate and sample pH, were optimized. The effects of a number of possible interferents, both anionic and cationic were studies for a solution of 500 ng 1−1 of selenium. The most severe depressions were caused by iron (III) and mercury (II) for which concentrations of 20 and 10 mg 1−1 caused a 5% depression on the selenium signal. For the other cations (cadmium, cobalt, copper, lead,. magnesium, and nickel) concentrations of 50–70 mg 1−1 could be tolerated. Arsenate interfered at a concentration of 3 mg−1, whereas concentrations of chloride, bromide, iodide, perchlorate, and sulfate of 500–900 mg l−1 could be tolerated. A linear response was obtained between the detection limit of 4 ng 1−1, with a characteristic mass of 130 pg. The RSDs for solutions containing 100 and 200 ng 1−1 selenium were 2.3% and 1.5%, respectively. 相似文献
14.
Inside Back Cover: Molecular Imaging of Growth,Metabolism, and Antibiotic Inhibition in Bacterial Colonies by Laser Ablation Electrospray Ionization Mass Spectrometry (Angew. Chem. Int. Ed. 48/2016)
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Dr. Hang Li Pranav Balan Prof. Akos Vertes 《Angewandte Chemie (International ed. in English)》2016,55(48):15181-15181