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Belli Dell' Amico D Calderazzo F Curiardi M Labella L Marchetti F 《Inorganic chemistry》2004,43(17):5459-5465
Reactions of perchlorates of iron(II), nickel(II), and zinc(II) with 2,2':6',2':6',2'"-quaterpyridine (qtpy) gave the first crystallographically established bis-qtpy metal complexes of formula [M(qtpy)(2)][ClO(4)](2) (M = Fe, Ni, Zn). Coordination of two terdentate quaterpyridines to the same center produces a distorted octahedron of six nitrogen atoms around the metal, leaving two pendant pyridyl groups, one for each quaterpyridine. For the diamagnetic zinc system, an NMR investigation has been carried out in order to establish the conditions to obtain the intermediate mono-qtpy complex, of formula [Zn(qtpy)(H(2)O)(2)][ClO(4)](2), which has also been crystallographically established. The corresponding hexafluorophosphate derivatives [M(qtpy)(2)][PF(6)](2) (M = Ni and Zn) were prepared in DMF at room temperature. 相似文献
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The metallothermic reduction of praseodymium tribromide, PrBr3, with lithium metal (molar ratio 1:1) in sealed tantalum containers at 850°C yields bronze lustrous rods of Pr2Br5. The crystal structure (monoclinic, P21/m, Z = 2, a = 774.38(4), b = 415.33(3), c = 1327.06(9) pm, β = 90.816(6)°, Vm = 128.52(2) cm3 mol?1) contains seven- and eight-coordinate trivalent praseodymium in mono- and bicapped trigonal prisms. Pr2Br5 should therefore be formulated as (Pr3+)2(Br?)5(e?). It is isostructural with Pr2I5 and is believed to be identical with PrBr2,38 reported for the Pr/PrBr3 system. 相似文献
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Susan Swansburg Yoon-Ki Choi Sam-Rok Keum Erwin Buncel Robert P. Lemieux 《Liquid crystals》1998,24(3):341-346
Two series of mesogens derived from the non-activated spiropyran dyes 6-hydroxy-1 ,3 ,3- trimethylspiro\[2H -1-benzopyran-2,2-indoline] (series trimethylspiro\[2 H -1-benzopyran-2,2-indoline] (series 2 ) have been synthesized. Analysis by differential scanning calorimetry, polarizing microscopy and X-ray diffraction showed compounds in series 1 form monotropic nematic and SmA phases, while compounds in series 2 form only a monotropic nematic phase. 相似文献
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Some new substituted dihydrothieno[2',3':4,5]thieno[2,3-c]quinolin-6-ones 9- 12 and tetrahydrodithieno[2,3-b: 2',3'-d]thieno[2',3'-c:2',3'-c']diquinolin-6,14-dione (17) were prepared from the corresponding new anilides 5-8 and from the corresponding dianilide 15, respectively, by a multistep combination of chemical and photochemical reactions. All the prepared compounds are of particular interest because they might serve as DNA intercalators in anticancer therapy. 相似文献
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Ouellette W Koo BK Burkholder E Golub V O'Connor CJ Zubieta J 《Dalton transactions (Cambridge, England : 2003)》2004,(10):1527-1538
Hydrothermal reactions of Na3VO4, an appropriate Cu(II) source, bisterpy and an organodiphosphonate, H2O3P(CH2)nPO3H2 (n = 1-6) yielded a family of materials of the type [Cu2(bisterpy)]4+/VxOy(n-)/[O3P(CH2)nPO3]4-. This family of bimetallic oxides is characterized by an unusual structural diversity. The oxides [[Cu2(bisterpy)]V2O4[O3PCH2PO3H]2] (1), [[Cu2(bisterpy)(H2O)]VO2[O3P(CH2)3PO3][HO3P(CH2)3PO3H2]] (4) and [[Cu2(bisterpy)]V2O4[O3P(CH2)6PO3H]2].2H2O (7.2H2O) are one-dimensional, while [[Cu2(bisterpy)(H2O)2]V2O4[O3P(CH2)2PO3][HO3P(CH2)2PO3H]2] (2), [[Cu2(bisterpy)]V4O8[O3P(CH23PO3]2].4H2O (3.4H2O) and [[Cu2(bisterpy)]V2O4(OH)2[O3P(CH2)4PO3]].4H2O (5.4H2O) are two-dimensional. The V(IV) oxide [[Cu2(bisterpy)]V4O4[O3P(CH2)5PO3H]4].7.3H2O (6.7.3H2O) provides a relatively unusual example of a three-dimensional bimetallic oxide phosphonate. The structures reveal a variety of V/P/O substructures as building blocks. 相似文献
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The titled compound exists as two polymorphic solid phases (denoted form-I and form-II). Form-I obtained by as-synthesized material is a more stable phase. Form-II is a less stable phase. Spontaneous solid-solid transformation from form-II to form-I is observed in the temperature range between room temperature and the melting point of form-I (Tm = 156.5 degrees C), and its activation energy is estimated to be 96 kJ mol-1 by Arrhenius plot. The solid-solute-solid transformation (recrystallization from solution) from form-II to form-I is also observed. In contrast, form-II is obtained only by a solid-melt-solid transformation from form-I. Therefore, the system of two polymorphs is monotropic. The solid-state NMR measurement shows that form-I has the molecular conformation of complete S-syn-anti-syn in the oligothiophene backbone, whereas form-II has that of S-all-anti. With the solution NMR data, the polymorphism could not be observed. Therefore, the polymorphs originate from the different molecular packing involving the conformational change of the molecule. This unique property is attributed to the extra bulky terminal groups of the compounds. However, despite the extra bulky terminal groups, the mentioned polymorphism is not observed in the titled compound analogue which has S-all-anti conformation (like form-II). 相似文献
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1INTR0DUCTIONa-Thiocarbonylthioformamideshavebeensynthesizedsince1980[l-23,however,thereisn0reP0rtofthesecomP0undsrelatedtheirpropertiesandreactivities(3).Ac-cordingtothepublishedpapers('-",adithioketone,adithioesterandadithioth-ioesteraresnitablefort4 2JcycloadditionwithalkenicandacetylenicdienophileS.Wewanttoknowwhethera-thiocarbonylthioformamideshavethesamecharacters,thereforethereactionofathiobenzoylthioformmorpholine(1)withdiethylacetylenedicarboxylate(2)wasexplored.Theredultsshowth… 相似文献
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G. Q. Zhong S. R. Luan P. Wang Y. C. Guo Y. R. Chen Y. Q. Jia 《Journal of Thermal Analysis and Calorimetry》2006,86(3):775-781
The
thiourea complexes of antimony and bismuth triiodide were synthesized by a
direct reaction of antimony and bismuth triiodide with thiourea powder at
room temperature. The formula of the complex is MI3[SC(NH2)2]3(M=Sb, Bi). The crystal structure of the
complexes belongs to monoclinic system and the lattice parameters are a=1.4772 nm, b=1.6582
nm, c=2.0674 nm and β=90.81° for
SbI3(SC(NH2)2)3
and a=1.4009 nm, b=2.0170
nm, c=2.0397 nm and β=90.84° for
BiI3[SC(NH2)2]3.
The infrared spectra reveal that the trivalent antimony or bismuth ion is
coordinated by the nitrogen atom, not the sulfur atom of the thiourea. Thermal
analysis shows that there are two times structure rearrangements or phase
transformation in the complexes from 100 to 170°C. 相似文献