Internal rotation and 14N quadrupole coupling of 3- and 5-methylisoxazole

In the following we present a ¹⁴N quadrupole hyperfine structure, a fourth-order centrifugal distortion, and an IAM methyl internal rotation analysis of 3- and 5-methylisoxazole. The measurements were done in the frequency range of 8 to 26 GHz employing a microwave Fourier transform spectrometer.     

Methyl barrier to internal rotation and quadrupole coupling constants in S-methylchlorothioformate

Internal rotation A-E splittings have been observed in the ground state for both ³⁵Cl and ³⁷Cl isotopic species of S-methylchlorothioformate. The values $\text{V}{}_3\text{(}{}^{35}\text{Cl}\text{) = 893 ± 20}$ and $\text{V}{}_3\text{(}{}^{37}\text{Cl) = 890 ± 20 cal/mole}$ have been obtained. The anaalysis of the hyperfine structure gave $\text{χ}{}_{\mathrm{aa}}\text{(}{}^{35}\text{Cl}\text{) = ?49.2}$, $\text{χ}{}_{\mathrm{bb}}\text{(}{}^{35}\text{Cl}\text{) = 22.4}$ and $\text{χ}{}_{\mathrm{aa}}\text{(}{}^{37}\text{Cl}\text{) = ?39.0}$, $\text{χ}{}_{\mathrm{bb}}\text{(}{}^{37}\text{Cl) = 18.3 MHz}$. Only the syn-conformation of the methyl group with respect to the carbonyl group has been observed. A partial r₀ structure is given.     

Microwave spectrum,quadrupole coupling constants,and barrier to internal rotation of 2-iodopropene

The microwave spectrum of 2-iodopropene has been investigated between 7.7 and 18 GHz. The measured transition frequencies of the ground and two vibrationally excited states have been analyzed using direct diagonalization of the rotational and quadrupole Hamiltonian. The following rotational and quadrupole coupling constants have been determined in a leastsquares fit for the ground state: A = 9285.153(20) MHz; B = 2337.2198(14) MHz; C = 1887.5871(14) MHz; and χ_cc = ?1820.783(33) MHz; χ_ab = 147.5(10) MHz; χ_bb = 957.018(41) MHz; and χ_cc = 863.765(40) MHz. The quadrupole coupling constants have been transformed to their principal axis system. From the splittings of some transitions of the first torsionally excited state a value of V₃ = 905(3) cm^?1 has been found for the threefold barrier hindering the internal rotation of the methyl group.     

Microwave spectrum,conformation, quadrupole coupling constants,and barrier to internal rotation of methoxyamine

The microwave spectra of three isotopic species of methoxyamine (CH₃ONH₂) have been studied. For the normal species the ground-state rotational constants are A = 42488 ± 150 MHz, B = 10049.59 ± 0.03 MHz, and C = 8962.85 ± 0.03 MHz. From these data and those from the -NHD and -ND₂ species, the amino protons have been shown to occupy a symmetrical trans position relative to the methyl group. The barrier to internal rotation of the methyl group has been found to be 873 ± 15 cm^?1 by analysis of ground-state splittings. Analysis of hyperfine splittings has yielded the ¹⁴N quadrupole coupling constants, which have the following values for the normal isotopic species: χ_aa = 3.63 ± 0.03 MHz, χ_bb = ?3.69 ± 0.07 MHz, and χ_cc = 0.06 ± 0.07 MHz.     

Proton stripping to 14N

The ¹³C(³He, d) reaction at a beam energy of 43.6 MeV was used to examine levels of ¹⁴N up to 11.7 MeV over an angular region including the main stripping peaks. Many spectroscopic factors were determined reliably for known states and found to be mostly in good agreement with calculations for the stronger levels. Several new spin or parity assignments are made at high excitation.     

Microwave spectrum,structure, quadrupole coupling constants,dipole moment,and barrier to internal rotation of N-methylhydroxylamine

The microwave spectrum has been observed and analyzed for five isotopic species of N-methylhydroxylamine. For the normal species the rotational constants (in Megahertz) are A = 38 930.771 ± 0.005, B = 3939.607 ± 0.002, and C = 8690.716 ± 0.001. These data show that the molecule exists in the trans conformation, with structural parameters that include the following: CN = 1.460, NO = 1.461, NH = 1.007, and OH = 0.962. Hyperfine structure analyses have yielded the complete inertial axis ¹⁴N quadrupole coupling constant tensor, and thus the tensor values in the electric field-gradient principal axis system as follows: χ_xx = 4.41 ± 0.30, χ_yy = 1.93 ± 0.45, and χ_zz = ?6.34 ± 0.30 MHz. The total electric dipole moment has been found to have the value μ_T = 0.71 D, and the barrier to internal rotation of the methyl group is 3.55 kcal/mole.     

The microwave spectrum,barrier to internal rotation of the methyl group,and N nuclear quadrupole coupling constants in methacrylonitrile

The microwave spectrum of methacrylonitrile has been assigned and frequencies are listed in the 8–40 GHz frequency region for the assigned transitions. The rotational constants are A = 9297.48 ± 0.30, B = 4166.33 ± 0.01, and C = 2924.68 ± 0.01 all in units of MHz. The barrier to internal rotation of the methyl group is V₃ = 2030 ± 60 cal/mole. The ¹⁴N nuclear quadrupole coupling constants are χ_aa = −4.18 ± 0.04 and χ_bb = 2.03 ± 0.15 in units of MHz.     

A study of 14N using the 13C(d,n)14N reaction

Absolute differential cross sections for the ¹³C(d, n)¹⁴N reaction were measured at deuteron bombarding energies of 4.5, 5.0 and 5.5 MeV. Spectroscopic factors and statistical compound-nucleus contributions are obtained by treating the observed cross sections as an incoherent sum of distorted-wave Born approximation and compound-nucleus contributions. Energy-averaged spectroscopic factors are derived. An anomaly is observed in the yield for the 2.313 MeV T= 1 state.     

Unexpected interference patterns observed in the 12C(14N, 13N)13C reaction at energies close to the Coulomb barrier

The reaction ¹²C(¹⁴N, ¹³N)¹³C has been measured at 28, 32, 34 and 36 MeV beam energies. The energy dependence of the measured interference pattern cannot be reproduced by DWBA calculations which take account of the interference between proton and neutron transfer. A rather strong asymmetry of the angular distributions about θ_c.m. = 90° has been observed.     

The 26Mg(14N, 10B)30Si and 26Mg(14N, 11B)29Si reactions

Reactions induced by ¹⁴N on ²⁶Mg at bombarding energies of 60–95 MeV have been studied. Angular distributions for states populated in ²⁹Si by the (¹⁴N, ¹¹B) reaction and in ³⁰Si by the (¹⁴N, ¹⁰B) reaction have been compared with Hauser-Feshbach and DWBA calculations to determine the reaction mechanism and to deduce spectroscopic information. The cross sections for the states populated in ²⁹Si and ³⁰Si are in poor agreement with statistical model calculations, indicating a non-compound nucleus mechanism.     

Sequential calculations for heavy-ion induced two-nucleon transfer on 14N, 15N and 16O

¹¹B and ¹³C induced two-nucleon transfer data on ¹⁴N, ¹⁵N and ¹⁶O are compared with exact finite-range sequential transfer calculations. The data appear to be consistent with this reaction model and the assumed shell-model structure of the states populated. Single-nucleon transfer data on these targets is also analyzed using the DWBA. Modifications to the exit channel optical potential are required to obtain agreement with shell-model spectroscopic factors.     

Charge exchange reaction 14C(6Li, 6He)14N

Angular distributions of the charge exchange reaction ¹⁴C(⁶Li, ⁶He)¹⁴N leading to the 1⁺ ground state and 3.95 MeV 1⁺, and 5.20 MeV 2^? excited states at the 34 MeV incident beam energy were analyzed and measured. The 62 MeV data of Goodman et al. were also reanalyzed. The direct one-step charge exchange caused by the spin-isospin dependent term in the two-body interaction can account well for the observed data. The strength of spin-isospin dependent effective interaction (gaussian form with a range parameter of 1.8 fm) was extracted to be 18.5 MeV.     

Microwave and Raman spectra,dipole moment,barrier to internal rotation,and vibrational assignment of silylphosphine-d2

The microwave spectra of SiH₃PD₂ have been recorded in the range 26.5–40.0 GHz. Both a- and c-type transitions were observed and assigned. The rigid rotor rotational constants were determined to be A = 37589.06 ± 0.11, B = 5315.70 ± 0.02, and C = 5258.70 ± 0.02 MHz. The barrier to internal rotation has been calculated from the A-E splittings to be 1512 ± 26 cal/mole. The dipole moment components of |μ_a| = 0.22 ± 0.01, |μ_c| = 0.56 ± 0.01, and |μ_t| = 0.60 ± 0.01 D were determined from the Stark effect. By using previously determined microwave data for SiH₃PH₂, several structural parameters have been calculated and their values are compared to similar ones in other compounds. The Raman (0–2500 cm^?1) spectra of gaseous, liquid, and solid SiH₃PH₂ and gaseous SiH₃PD₂ have been recorded and interpreted in detail on the basis of C_s molecular symmetry.     

The reaction 14C(6Li, 6He)14N and the distribution of Gamow-Teller strength

We find that the correlation between the L=0 component of the (⁶Li, ⁶He) reaction and the GT matrix element holds down to a very low level of GT strength, and that essentially all (90%) of the GT strength lies in the 3.95 MeV state of ¹⁴N.     

Investigation of low-lying states of 15N via 14N(d,p)15N reactions with vector polarized deuterons

Angular distributions of cross section and vector analyzing power have been measured for the ¹⁴N(d, p)¹⁵N reaction at E_d = 10 MeV for transitions to levels up to 8.6 MeV excitation in ¹⁵N. Distorted wave Born approximation calculations and calibration curves were used to determine total and orbital angular momenta and spectroscopic factors of the transferred neutrons. The results were compared with different theoretical approaches.     

On the decay of the photo resonance in 14N and 14C nuclei

The decay of the photo resonances in ¹⁴N and ¹⁴C nuclei is analyzed in terms of the shell model with intermediate coupling. Cross sections and branching ratios of nucleon channels are compared with experimental data. Successive decay branches are estimated.     

Time-dependent Hartree-Fock calculations for 14N + 12C reactions

We present Time-Dependent Hartree-Fock calculations for the massasymmetric system ¹⁴N + ¹²C in the range 20 ? E_cm ? 114. A simplified effective interaction of the Skyrme form has been used and the orbital angular motion of the ions has been treated in the rotating frame approximation. The overall magnitude of the calculated fusion cross-section is in agreement with experiment. The calculated differential cross section for direct inelastic reaction products is proportional to ${}^1\text{sin θ}$. This is in contrast to the exponential decrease observed experimentally.     

Angular distributions of neutron polarization from the 14C(p,n)14N and 11B(α, n)14N reactions and R-matrix analysis oF 15N in the excitation-energy range between 11.5 and 12.5 MeV

Angular distributions of neutron polarization from the ¹⁴C(p, n)¹⁴N and ¹¹B(α, n)¹⁴N reactions have been studied for the particle energies E_p = 1.788, 2.025, 2.272 and 2.450 MeV, and E_α = 2.049 MeV. The polarization was derived from the left-right asymmetry induced by elastic scattering from ⁴He. Together with existing measurements of angular distributions and total cross sections for several reaction channels leading to ¹⁵N with an excitation energy between 11.5 and 12.5 MeV, these data were used to deduce from R-matrix analysis a set of resonance parameters for the ¹⁵N levels in this energy range.     

15N excitation contribution to 48Ca(16O, 15N)49Sc reaction

The effect of ¹⁵N excitation process is studied in the reaction ⁴⁸Ca(¹⁶O, ¹⁵N)⁴⁹Sc. The excitation process is included into a generalized non-local optical potential for a scattersing ¹⁵N-⁴⁹Sc and is found to be responsible for a shift of a grazing peak in the exact finite-range DWBA calculation.