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N-Substituted 1,6-dihydro-3(2H)-pyridinones have been synthesised from N-substituted piperidine-3,5-diones via the methyl enol ethers. Reduction of the latter with sodium borohydride (NaBH4) is described. 相似文献
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IntroductionDuetothespecificpropertiesimpartedbyfluorine ,theintroductionofafluorineatomorafluoroalkylgroupintoleadmoleculeshasbeenwidelyusedasoneofthemethodsforthedevelopmentofnovelbiologicallyactivecompounds.1Indolesareattractivecompoundsfromtheviewp… 相似文献
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Methods published over the last 10 years for the production of substituted 1(2H)-isoquinolones, including those involving the use of organometallic compounds, are discussed. 相似文献
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A convenient and efficient four step synthesis of 2-methyl-5-(methylthio)benzothiazole is presented. 相似文献
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A new one-pot convenient preparation of 3,4-dihydro-4-imino-2(1H)-quinazolinones (4) is described by the reaction of 2-aminobenzonitriles (1) with chlorosulfonyl isocyanate (2), while the reaction of 1 with chlorocarbonyl isocyanate (6) affords ureidobenzonitriles (7), which on thermal cyclization gives 4. 相似文献
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以邻甲基苯酚为原料,与1-氯-2-甲基-2-丁烯反应生成2-甲基-6-(3-甲基-2-丁烯基)苯酚,然后催化氧化得到目标产物2-甲基-6-(3-甲基-2-丁烯基)对苯二醌。该合成路线简单,易于操作,最终收率51%。 相似文献
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Danilyuk I. Yu. Vas’kevich R. I. Vovk M. V. 《Russian Journal of Organic Chemistry》2018,54(6):954-956
Russian Journal of Organic Chemistry - Heating of 4-aryl-N-(1H-pyrazol-4-yl)but-3-enamides in polyphosphoric acid selectively afforded 5-aryl-1-(1H-pyrazol-4-yl)pyrrolidin-2-ones. 相似文献
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N-Ethoxycarbonyl-4-pyridone is reduced to N-ethoxycarbonyl-4-oxo-1, 2, 3, 4-tetrahydropyridine by sodium borohydride in t-butyl alcohol containing ethyl chloroformate. Saponification of the product leads to 4-Oxo-1, 2, 3, 4-tetrahydropyridine. 相似文献
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A series of 3-aryl-3-(5,5-dimethyl-3-hydroxy-2-cyclohexene-1-one-2-yl) propanic esters were synthesized by reaction of aromatic aldehydes, 5,5-dimethyl-1,3-cyclohexanedione and isopropylidene malonate in alcohols catalyzed by KF-Al2O3. The structure of 4a was determined by X-ray analysis. 相似文献
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The synthesis of the title compounds starting with the chemoselective dehydrogenation of 3-[2-(3,4-dihydro-1-naphthalenyl)ethyl]imidazolidine-2,4-diones has been described. 相似文献
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水合茚三酮与芳甲基酮、水合肼缩合环化制得2-芳基-3,4-二氮杂芴酮(2); 2经还原得2-芳基-3,4-二氮杂芴(3).2与2-溴联苯格氏试剂反应得到中间体叔醇(4); 4在酸性条件下关环合成了2-芳基-3,4-二氮杂螺二芴,其结构经1H NMR,13C NMR和元素分析表征. 相似文献
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Applicationsofsamariumdiiodideasamild,neutral,selectiveandversatilesingleelectrontransferreducingandcouplingreagentinorganicsynthesishavesignificantlygrowninthelastdecade'.PreviousworkonsomedeoxygenationandsomereductivecleavageofS-S,Se-Se,Te-TebondswithSml,wasreported'.ItiswellknownthatnitrocompoundscanbereducedeasilybySml2.However,theyarejustreducedtothecorrespondingammes',lit'tleattentionhasbeenconcernedontheintermediatederivedfromanitrogroupbySml,treatment,whichmaybeinducesomereactionsd… 相似文献
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Ren-Lin Zheng Xiu-Xiu Zeng Hai-Yun He Jun He Sheng-Yong Yang Luo-Ting Yu 《合成通讯》2013,43(10):1521-1531
An improved synthesis of 6-aryl-3-cyanopyridine-2-(1H)-thiones utilizing enaminones as starting materials catalyzed by 1,4-diazabicyclo[2.2.2]octane (DABCO) was described. Moreover, a convenient one-pot conversion of aryl ketones to 6-aryl-3-cyanopyridine-2-(1H)-thiones was also developed in moderate to good yields (up to 80%). 相似文献
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An efficient procedure for the preparation of furanone 3 from commercially available starting material lactone 1, is reported. 相似文献