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Helmut Behrens Günter Landgraf Peter Merbach Matthias Moll Karl-Heinz Trummer 《Journal of organometallic chemistry》1983,253(2):217-229
The nitrosylcarbonylisonitrile complexes η5-C5H5M(NO)(CO)CNR (R = Me for Cr, Mo, W; R = Et, SiMe3, GeMe3, SnMe3 for Mo) are formed by treatment of the nitrosylcarbonylcyanometalates Na[η5-C5H5M(NO)(CO)CN] with [R3O]BF4 (R = Me, Et), Me3SiCl, Me3GeCl or Me3SnCl. The isoelectronic dicarbonylisonitrile compounds η5-C5H5Mn(CO)2CNR (R = SiMe3, GeMe3, SnMe3, PPh2, AsMe2) and η5-C5H5Re(CO)2CNAsMe2 are obtained by analogous reactions of Na[η5-C5H5M(CO)2CN] (M = Mn, Re) with Me3ECl (E = Si, Ge, Sn), Ph2PCl and Me2AsBr.With phosgene the anionic complexes Na[η5-C5H5M(CO)2CN] (M = Mn, Re) can be transformed into the new carbonyldiisocyanide-bridged dinuclear complexes η5-C5H5M(CO)2CN-C(O)-NC(OC)2M-η5-C5H5. Finally, the reactions of η5-C5H5M(NO)(CO)CNMe (M = Cr, Mo, W) with NOPF6, leading to the cationic dinitrosylisonitrile complexes [η5-C5H5M(NO)2CNMe]+, are described. 相似文献
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N. B. Chumaevskii V. A. Zakharov G. D. Bukatov G. I. Kuznetzova und Y. I. Yermakov 《Colloid and polymer science》1978,256(2):205
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C. Auer v. Welsbach 《Monatshefte für Chemie / Chemical Monthly》1910,31(10):1159-1202
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