Electron temperatures of intense electron-beam-produced plasmas

A method of estimating the electron temperatures in intense, relativistic, electron-beam-produced plasmas is presented. This method compares spectral line intensities obtained from visible emission spectroscopy to those expected from local thermodynamic equilibrium (LTE) plasmas. The line intensities, particularly those originating from highly excited states, are corrected for the effects of the fast-beam electrons     

Emission continua of rare gas plasmas

Photoionization cross sections of rare gases have been calculated by using the scaled Thomas-Fermi method, including polarization effects. Absorption coefficients have been derived for bound-free transitions in thermal plasmas of 6000 K to 30000 K, for a wavelength range from 300 Å to 10000 Å.     

Observation of MeV ions in long-pulse, large-scale laser-produced plasmas

A new approach for investigation of the generation of fast ions and hot electrons inside the same plasma volume in laser-produced plasmas is proposed. It is based on the spectroscopic observation of line radiation from singly and doubly excited levels with simultaneous high spectral and spatial resolution. The experimental results demonstrate the observation of fast ions from highly charged target material inside the plasma volume and suggest that the generally accepted scaling relations are seriously invalid under certain conditions. Even at rather modest intensities ions with energies of several MeV are observed. Pis’ma Zh. éksp. Teor. Fiz. 70, No. 4, 262–267 (25 August 1999) Published in English in the original Russian journal. Edited by Steve Torstveit.     

石墨阴极用于重频长脉冲高功率微波产生的初步实验

 选取两种不同成分的石墨材料（普通石墨和掺铜石墨）分别设计制作了用于电子显微镜实验的阴极样品和用于重频长脉冲高功率微波产生实验的阴极,并开展了初步实验研究。实验结果表明:掺铜石墨与普通石墨在微观结构方面存在明显不同,且掺铜石墨阴极在发射性能、微波脉冲宽度和微波脉冲后沿离散性等方面可能优于普通石墨阴极,但优势并不明显,还待在以后的实验中进一步验证。     

Vibrational investigation of 1-cyclopentylpiperazine: A combined experimental and theoretical study

FT-IR and Raman spectra of 1-cyclopentylpiperazine(1cppp)have been experimentally examined in the region of 4000–200cm-1.The optimized geometric parameters,conformational equilibria,normal mode frequencies and corresponding vibrational assignments of 1cppp(C9H18N2)are theoretically examined by means of B3LYP hybrid density functional theory(DFT)method together with 6-31++G(d,p)basis set.On the basis of potential energy distribution(PED)reliable vibrational assignments have been made and the thermodynamics functions,highest occupied and lowest unoccupied molecular orbitals(HOMO and LUMO)of 1cppp have been predicted.Calculations are employed for four different conformations in C1 and Cs point groups of 1cppp in gas phase.Comparison between the experimental and theoretical results indicates that B3LYP method is able to provide satisfactory results for predicting vibrational frequencies and the structural parameters,vibrational frequencies and assignments.Furthermore,C1(equatorial-axial)point group has been found as the most stable conformer of 1cppp.     

A theoretical and experimental investigation of an in-band pumped gain-switched thulium-doped fiber laser

In this paper,the theoretical rate equation model of an in-band pumped gain-switched thulium-doped fiber(TDF) laser is investigated.The analytical formulations of pump energy threshold,peak power extraction efficiency,and pulse extraction efficiency are derived through analyzing the interaction process between the pump pulse and the laser pulse.They are useful for understanding,designing,and optimizing the in-band pumped TDF lasers in a 1.9 μm-2.1 μm wavelength region.The experiment with an all-fiber gain-switched TDF laser pumped by a 1.558-μm pulse amplifier is conducted,and our experimental results show good agreement with theoretical analysis.     

A revised theoretical model of vacuum arc spot plasmas

The quasi-stationary hemispherical expansion of the cathodic plasma in vacuum arcs can be modeled with hydrodynamic two-fluid equations. In any case, the state of the plasma is determined by the only variable (I/r)^2/5 (with current I , distance r). In order to avoid some deficiencies of the model (as published) and to investigate more carefully the dependence of the plasma parameters on the arc current, the known analytic solution to the problem is improved by taking into consideration the variability of the Coulomb logarithm and the dependence of the boundary conditions on I. These effects are treated separately. Examples are used to illustrate the new results, with particular emphasis on ion acceleration. The influence of the above factors turns out to be rather unimportant. Quantitatively, they cause some shifts, but no qualitative change of the basic behavior of the plasma is seen     

光子加速器的理论研究

研究了光子加速器(即利用等离子体中的朗谬尔波实现光脉冲频率上转换)所涉及的基本物理问题.文中导出了在存在朗谬尔波的条件下,光脉冲频率对于等离子体本底密度及电子密度扰动的依赖关系,并就最大频率转换、光脉冲俘获、波的加速位相(accelerating phase)以及位相滑动(phase slippage)效应进行讨论.     

H, C NMR and JCH coupling constants investigation of 4-Phenylpyridine: A combined experimental and theoretical study

Proton coupled and uncoupled ¹³C, ¹H, DEPT, COSY and HETCOR NMR spectra of 4-Phenylpyridine (4-Phpy) have been reported for the first time except for its ¹H NMR spectrum. In order to provide a precise structural elucidation for carbon atoms those have very close chemical shifts to each other, the magnitude of ⁿJ_CH (n=1,2,3) coupling constants of 4-Phpy (C₁₁H₉N) have also been investigated. ¹³C, ¹H NMR chemical shifts and ^1-3J_CH coupling constants of 4-Phpy have been calculated by means of B3LYP density functional method with 6-311++G(d,p) basis set. Moreover, the optimized parameters (bond lengths, bond and torsion angles) of 4-Phpy have been calculated with B3LYP at 6-31G(d) level in methanol (ε=32.63). Comparison between the experimental and the theoretical results indicates that density functional B3LYP method is able to provide satisfactory results for predicting NMR properties.     

Combined experimental and theoretical investigation of the premartensitic transition in Ni2MnGa

Ultraviolet-photoemission (UPS) measurements and supporting specific-heat, thermal-expansion, resistivity, and magnetic-moment measurements are reported for the magnetic shape-memory alloy Ni2MnGa over the temperature range 100T(PM) is due to the Ni d minority-spin electrons. Below T(M) this peak disappears, resulting in an enhanced density of states at energies around 0.8 eV. This enhancement reflects Ni d and Mn d electronic contributions to the majority-spin density of states.     

Numerical and experimental investigation of burner device for anode gas reburning

A complex numerical and experimental investigation of burner devices for a reburning of the anode gas of aluminum production was carried out. The chosen mathematical model of the processes of aerodynamics, heat exchange, and gas burning was identified and adapted on the basis of data of real-scale measurements. Basing on computational experiments the optimization of the design of elements of the system for anode gas detoxication and transport was carried out. A new system was proposed and tested for reburning the anode gases of electrolysis production, which consists of an improved burner device and a dust-sedimenting chamber with a possibility of regulating the amount of gas suction.     

Comparison of the results of theoretical analysis and experimental investigation of dynamic volt-ampere characteristics

Dynamic volt-ampere characteristics are calculated for the case of the diffusionless approximation. The theoretical dependences obtained are compared with experimental curves for the system Si-SiO₂-Al. A method is developed allowing the mobility of the migrating ions and the magnitude of the mobile charge in the sample to be determined from the current maximum on the experimental dynamic volt-ampere characteristic and its position.Translated from Izvestiya Vysshikh Uchenbykh Zavedenii, Fizika, No. 11, pp. 47–54, November, 1984.     

Half metallic Co2TiGe—a theoretical and experimental investigation

Using first principle calculations the electronic structure and magnetic properties of the half metallic Co₂TiGe was investigated. The electronic structure calculations were performed using two different parameterization schemes. The band gap obtained in the minority spin state using LDA scheme in TB-LMTO method was smaller than that obtained using GGA scheme in FP-LAPW method. To explore the half metallic property experimentally bulk Co₂TiGe was synthesized by arc melting under argon atmosphere. The magnetic moment per formula unit determined from saturation magnetization at 2 K was 1.9 μ_B, which was close to the theoretically calculated value of 2 μ_B. A detailed analysis of the low temperature transport and magnetotransport properties exhibit characteristic features of half metals such as T^9/2 dependence of low temperature resistivity, negligible temperature dependence of resistivity below 20 K and a cross over from positive to negative MR around 100 K.     

An experimental and theoretical investigation of the valence shell photoelectron spectrum of cyanogen chloride

The valence shell photoelectron spectrum of cyanogen chloride has been studied using HeI and synchrotron radiation. In the outer valence region the molecular orbital model of ionization holds, and the main bands can be associated with single-hole states. However, in the inner valence region electron correlation effects become important, and these result in complex satellite structure being observed. Vertical ionization energies and spectral intensities have been computed using the Green's function approach, and the results have facilitated an interpretation of the experimental spectra. Photoelectron angular distributions and branching ratios have been measured and have been used to assess the bonding characteristics of the outer valence molecular orbitals. The experimental data for the 8σ orbital display an energy dependence which suggests that photoionization from this orbital may be influenced by the chlorine 3p Cooper minimum. The extent to which the 8σ orbital can be considered as a chlorine atom lone-pair is discussed. Vibrational structure has been observed in the [Xtilde] ²Π, Ã ²Σ⁺ and [Btilde] ²Π photoelectron bands recorded with HeI radiation, and has been assigned to progressions involving the ν⁺ ₁ and ν⁺ ₃ modes.     

An experimental and theoretical investigation of the frequencies and mode shapes of axisymmetric shell models

The use of doubly curved isoparametric elements in a finite element analysis enabled successful prediction to be made of the natural frequencies and mode shapes of axisymmetric shell models. The models chosen were in the form of a natural draught cooling tower, part of a large hemispherical dome and part of a smaller hemispherical dome, and all were formed from thermoplastic materials. Several natural frequencies and mode shapes were determined experimentally for all the models. The theoretical predictions compared very favourably with the experimental results. For example in the case of the cooling tower model the lowest frequency mode, with four nodal diameters and one nodal circle, was predicted to occur at 19·99 H, and experimentally it was 19·4 H. The effect of numerical results of the choice of the number of elements and hence the number of degrees of freedom was demonstrated. The use of five elements on the cooling tower model gave a difference between experimental and theoretical results of less than 3%. In representing the domes by three, five and six elements the deployment of more degrees of freedom led to a significant improvement in the results. It was also shown that some functional modelling could be misleading owing to deficiencies occurring during the incorporation of geometric and boundary conditions at the formulation stage.     

Interactions of rare gas cations with lighter rare gas atoms

High-level ab initio calculations are employed to generate potential energy curves for rare gas cations, RG⁺, interacting with neutral atoms of other rare gases, RG′, that are lighter (RG′ = Ne–Rn). The calculations employ the RCCSD(T) method, with doubly-augmented basis sets of quintuple-ζ quality. The interaction potential curves, with the full counterpoise correction applied, are calculated point-by-point. Spin-orbit coupling is applied analytically in an atom-based model. The potentials are used to calculate spectroscopic parameters, which are then compared to recent experimental work, and the very limited previous theoretical work. In addition, the potentials are used to calculate ion transport properties and the ion mobilities are compared to the few experimental data available.     

Quasi-three-level neodymium vanadate laser operation under polarized diode pumping: theoretical and experimental investigation

We propose a novel technique for pumping neodymium vanadate crystal in ⁴ F _3/2 ?? ⁴ I _9/2 transition with polarized diode light. With a theoretical model on quasi-three-level neodymium vanadate lasers including excited state absorption and energy transfer upconversion effects, the improvement on the laser performance of polarized pumping is evaluated. A maximum output power of 4.8 W in Nd:GdVO₄ 912 nm laser is achieved with the incident pump power of 21.8 W, the maximum output power increases about 85% and the slope efficiency is enhanced to 1.5 times towards the unpolarized pumping under the same condition. This technique is especially suitable for quasi-three-level systems end pumped by high-brightness fiber coupled diode sources associated with short neodymium vanadate crystals.     

Intense violet-blue photoluminescence in BaZrO3 powders: A theoretical and experimental investigation of structural order-disorder

Intense violet-blue photoluminescence (PL) emission at room temperature was verified in BaZrO₃ (BZO) powders with structural order-disorder. Ab-initio calculations, ultraviolet-visible absorption spectroscopy and PL were performed. Theoretical results showed that the local disorder in the network-formed Zr clusters present an important role in the formation of hole-electron pair. The experimental data and theoretical results are in agreement, indicating that the PL emission in BZO powders can be related to the structural order-disorder degree in the lattice.