共查询到20条相似文献,搜索用时 15 毫秒
1.
Jang-Hoon Park Jong-Su Kim Eun-Gi Shim Kyung-Won Park Young Taik Hong Yun-Sung Lee Sang-Young Lee 《Electrochemistry communications》2010,12(8):1099-1102
We demonstrate a novel and facile approach to surface modification of high-voltage charged LiCoO2, which is based on encapsulating LiCoO2 by a polyimide (PI) gel polymer electrolyte layer. The PI is introduced onto the LiCoO2 by thermally curing 4-component (pyromellitic dianhydride/biphenyl dianhydride/phenylenediamine/oxydianiline) polyamic acid. The PI nanoencapsulating layer features the high surface coverage, nanometer thickness, and facile ion transport. These unique characteristics are expected to enable the PI coating layer to effectively suppress the undesirable interfacial reaction of the LiCoO2 with liquid electrolyte, which plays a key role in noticeably improving the 4.4 V cycle performance and mitigating the vigorous exothermic reaction between the charged LiCoO2 and liquid electrolyte. 相似文献
2.
Singh Laxman Kumar Atendra Lee Hansol Lee Jiwon Ji Minsoo Lee Youngil 《Journal of Solid State Electrochemistry》2018,22(8):2561-2568
Journal of Solid State Electrochemistry - This article reports for the first time ultrafast automatic flame synthesis of high-quality LiCoO2 in open-air conditions as a cathode material for Li-ion... 相似文献
3.
Li Bingyan Liu Wenhua Zhu Juxia Zhou Qinghua Lv Lu Li Huili Hu Wei 《Journal of Solid State Electrochemistry》2022,26(12):2743-2748
Journal of Solid State Electrochemistry - In this work, anion (F, Cl, and S)-doped LiCoO2 cathode materials were systematically investigated by using first-principles calculations. The results show... 相似文献
4.
Zelang Jian Wentao Wang Maoyu Wang Yan Wang Nick AuYeung Miao Liu Zhenxing Feng 《中国化学快报》2018,29(12):1768-1772
In this study, we fabricated a Al2O3 layer coated on the surface of LiCoO2 by a facile and scale-up sol-gel method. The proper thickness coating can improve the cycling life with the cut-off potential (4.5 V), which capacity retention is~73% after 500 cycles, and enhance the capacity, which shows~180 mAh/g. 相似文献
5.
《Electrochemistry communications》2007,9(7):1486-1490
The further enhancement of high-rate capabilities for all solid-state lithium secondary batteries is reported. A LiNbO3 layer of nanometer thickness was interposed between LiCoO2 and sulfide solid electrolyte as buffer layer. This greatly reduced the interfacial resistance in the cathode and enhanced the high-rate capabilities of solid-state lithium batteries, providing good prospects for practical application of lithium secondary batteries free from safety issues. 相似文献
6.
《Electrochemistry communications》2007,9(1):149-154
Olivine LiCoPO4 phase grown LiCoO2 cathode material was prepared by mixing precipitated Co3(PO4)2 nanoparticles and LiCoO2 powders in distilled water, followed by drying and annealing at 120 °C and 700 °C, respectively, for 5 h. As opposed to ZrO2 or AlPO4 coatings that showed a clearly distinguishable coating layer from the bulk materials, Co3(PO4)2 nanoparticles were completely diffused into the surface of the LiCoO2 and reacted with lithium of LiCoO2. An olivine LiCoPO4 phase was grown on the surface of the bulk LiCoO2, with a thickness of ∼7 nm. The electrochemical properties of the LiCoPO4 phase, grown in LiCoO2, had excellent cycle life performance and higher working voltages at a 1C rate than the bare sample. More importantly, Li-ion cells, containing olivine LiCoPO4, grown in LiCoO2, showed only 10% swelling at 4.4 V, whereas those containing bare sample showed a 200% increase during storage at 90 °C for 5 h. In addition, nail penetration test results of the cell containing olivine LiCoPO4, grown in LiCoO2 at 4.4 V, did not exhibit thermal runaway with a cell surface temperature of ∼80 °C. However, the cell containing bare LiCoO2 showed a burnt-off cell pouch with a temperature above 500 °C. 相似文献
7.
合成了一种新型的一维(1D)羰基配位聚合物[Cu (BGPD)(DMA)(H2O)]·DMA (记为Cu-BD,H2BGPD=N,N′-双(甘氨酰)均苯四甲酸二酰亚胺,DMA=二甲基乙酰胺),并考察了其用作锂离子电池正极材料的电化学性能。电化学测试结果表明,Cu-BD正极在50 mA·g-1的电流密度下循环100圈后仍然保留50 mAh·g-1的比容量,具有较好的循环稳定性。Cu-BD电极反应机理研究表明,BGPD2-配体和Cu (Ⅱ)离子在充放电过程中都可能参与了电子转移过程。 相似文献
8.
合成了一种新型的一维(1D)羰基配位聚合物[Cu(BGPD)(DMA)(H2O)]·DMA(记为Cu-BD,H2BGPD=N,N''-双(甘氨酰)均苯四甲酸二酰亚胺,DMA=二甲基乙酰胺),并考察了其用作锂离子电池正极材料的电化学性能。电化学测试结果表明,Cu-BD正极在50 mA·g-1的电流密度下循环100圈后仍然保留50 mAh·g-1的比容量,具有较好的循环稳定性。Cu-BD电极反应机理研究表明,BGPD配体和Cu(II)离子在充放电过程中都可能参与了电子转移过程。 相似文献
9.
Yongheng Si Kun Bai Yaxin Wang Han Lu Litong Liu Ziyan Long Yujuan Zhao 《Journal of Energy Chemistry》2023,(7):537-546
Defective layered Mn-based materials were synthesized by Li/Na ion exchange to improve their electrochemical activity and Coulombic efficiency. The annealing temperature of the Na precursors was important to control the P3-P2 phase transition, which directly affected the structure and electrochemical characteristics of the final products obtained by ion exchange. The O3-Li0.78[Li0.25Fe0.075Mn0.675]Oδcathode made from a P3-type precursor calcined at 700... 相似文献
10.
Hydrothermally prepared 100 nm-sized LiCoO2 with a plate morphology packed in a crucible resulted in 40 μm-sized particles that consisted of aggregated < 1 micron-sized particles after annealing at 900 °C for 3 h. In the condition where the optimized electrode pore volume was 20%, 4.1 g/cc of electrode density was obtained, which corresponded to 3 Wh/cc, which is the highest value among the cathode materials. Furthermore, the LiCoO2 showed excellent capacity retention of 78% after 290 cycles in a Li-ion cell under 7 C rate cycling. 相似文献
11.
Shumei Dou 《Journal of Solid State Electrochemistry》2013,17(4):911-926
Layered structural lithium metal oxides with rhombohedral α-NaFeO2 crystal structure have been proven to be particularly suitable for application as cathode materials in lithium-ion batteries. Compared with LiCoO2, lithium nickel manganese oxides are promising, inexpensive, nontoxic, and have high thermal stability; thus, they are extensively studied as alternative cathode electrode materials to the commercial LiCoO2 electrode. However, a lot of work needs to be done to reduce cost and extend the effective lifetime. In this paper, the development of the layered lithium nickel manganese oxide cathode materials is reviewed from synthesis method, coating, doping to modification, lithium-rich materials, nanostructured materials, and so on, which can make electrochemical performance better. The prospects of lithium nickel manganese oxides as cathode materials for lithium-ion batteries are also looked forward to. 相似文献
12.
13.
P. Sivakumar Prasant Kumar Nayak Judith Grinblat Nina Perkas Boris Markovsky Doron Aurbach Aharon Gedanken 《Journal of Solid State Electrochemistry》2016,20(6):1683-1695
Li- and Mn-rich layered Li1.2Ni0.13Co0.13Mn0.54O2 cathode material was synthesized using sonochemical method followed by annealing at 700, 800, and 900 °C for 10 h. The material was characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscopy (TEM), Raman spectroscopy, and electrochemical techniques. Its performance as a cathode material for Li-ion batteries was examined. With the sample annealed at 900 °C, an initial specific capacity of 240 mAh g?1 was obtained, which decreased to 215 mAh g?1 after 80 cycles, thus retaining about 90 % of its initial capacity. In contrast, samples annealed at lower temperatures exhibited lower capacity retention upon cycling. Thus, the final annealing temperature was found to have a significant effect on the electrochemical stability of this material in terms of capacity, average voltage, and rate capability. The advantage of this synthesis, which includes a sonochemical stage, compared with a conventional co-precipitation synthesis, was also confirmed. 相似文献
14.
Makhonina Е. V. Pechen L. S. Volkov V. V. Rumyantsev А. М. Koshtyal Yu. М. Dmitrienko А. О. Politov Yu. А. Pervov V. S. Eremenko I. L. 《Russian Chemical Bulletin》2019,68(2):301-312
Russian Chemical Bulletin - Li-rich layered oxides Li1.2Mn0.54Ni0.13Co0.13O2 were synthesized by modified Pechini method using various compositions of the reaction mixture. Difference in the... 相似文献
15.
《Electrochemistry communications》2007,9(5):1228-1232
Using a commercially available LiCoO2 as starting material, a surface-modified cathode material was obtained by coating it with a nano layer of amorphous carbon. The carbon-coated LiCoO2 was characterized by X-ray diffraction analysis, scanning electronic microscopy, transmission electronic microscopy, electrochemical impedance spectroscopy and measurement of charge/discharge behavior. Results show that the carbon-coated LiCoO2 displays marked lower charge transfer resistance, higher lithium ion diffusion coefficient and much better rate capability than the original LiCoO2. It also indicates promising application of lithium ion batteries in the areas requiring charge and discharge at high rate. 相似文献
16.
Nanostructured LiCoO2 fibers were prepared by the sol-gel related electrospinning technique using metal acetate and citric acid as starting materials. The transformation from the xerogel fibers to the LiCoO2 fibers and the nanostructure of LiCoO2 fibers have been investigated in detail. The LiCoO2 fibers with 500 nm to 2 mum in diameter were composed of polycrystalline nanoparticles in sizes of 20-35 nm. Cyclic voltammetry and charge-discharge experiments were applied to characterize the electrochemical properties of the fibers as cathode materials for lithium-ion batteries. The cyclic voltammogram curves indicated faster diffusion and migration of Li+ cations in the nanostructured LiCoO2 fiber electrode. In the first charge-discharge process, the LiCoO2 fibers showed the initial charge and discharge capacities of 216 and 182 (mA.h)/g, respectively. After the 20th cycle, the discharge capacity decreased to 123 (mA.h)/g. The X-ray diffraction and high-resolution transmission electron microscopy analyses indicated that the large loss of capacity of fiber electrode during the charge-discharge process might mainly result from the dissolution of cobalt and lithium cations escaping from LiCoO2 to form the crystalline Li2CO3 and CoF2 impurities. 相似文献
17.
Shen Yu Liu Shuhong Liu Hongwen Zhao Hong 《Journal of Solid State Electrochemistry》2023,27(4):1055-1060
Journal of Solid State Electrochemistry - LiMnPO4 is of great interest as the promising cathode material in lithium-ion batteries for its low cost and good stability, but still suffers from limited... 相似文献
18.
《Journal of Energy Chemistry》2018,(6)
To design the high-energy-density Li-ion batteries, the anode materials with high specific capacity have attracted much attention. In this work, we adopt the first principles calculations to investigate the possibility of a new two dimensional boron material, named BG, as anode material for Li-ion batteries. The calculated results show that the maximum theoretical specific capacity of B_G is 1653 m Ah g~(-1)(LiB1.5).Additionally, the energy barriers of Li ion and Li vacancy diffusion are 330 meV and 110 meV, respectively, which imply fast charge and discharge ability for BGas an anode material. The theoretical findings reported in this work suggest that BGis a potential candidate as anode material of high-energy-density Li-ion batteries. 相似文献
19.
20.
Dongmin Li Bao Zhang Xing Ou Jiafeng Zhang Kui Meng Guanjun Ji Pengfei Li Jianhui Xu 《中国化学快报》2021,32(7):2333-2337
In this paper, the ammonia leaching process and high-energy ball milling method were adapted to recover spent LiCoO2 material. The ammonia reduction leaching mechanism of LiCoO2 material in the ammonia-sodium sulfite-ammonium chloride system was elucidated. Compared with untreated LiCoO2 material, the leaching equilibrium time of LiCoO2 after ball-milled for 5 h was reduced from 48 h to 4 h, and the leaching efficiency of lithium and cobalt was improved from 69.86% and 70.80% to 89.86% and 98.22%, respectively. Importantly, the apparent activation energy and leaching kinetic equation of the reaction was calculated by the shrinking core reaction model, indicating that the reaction was controlled by the chemical reaction. 相似文献