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采用激光光热透射技术测量材料的热扩散率 总被引:2,自引:0,他引:2
介绍利用激光光热透射技术测量材料热扩散率的方法,用该方法测量黄铜,纯铁、铝、纯铜及锗的热扩散率,其结果与能常采用的检测手段一致。 相似文献
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光声(光热)效应是由于物质吸收一强度随时间变化的光束而被时变加热时所引起的一系列热效应和声效应,研究了这些热效应和声效应,可以获得物质的热学和学学性质,光声技术正是探测由于吸收光辐射后样品的微小温度变化所引起的周围气体压力变化,具有灵敏度高、操作方便、应用广泛等独特的优点,已成为研究物质光谱特性、热学性质等的独特有力手段,文章主要介绍了光声技术在固体热扩散率测量中的原理及常规应用方法。 相似文献
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用共线光热偏转技术测量光学薄膜的微弱吸收 总被引:2,自引:0,他引:2
用具有高灵敏的共线光热偏转技术研究SiO_2、ZrO_2、MgF_2、ZnS等单层光学薄膜的吸收特性,测得它们的吸收率.实验结果与激光量热法及横向光热偏转技术符合良好,表明共线光热偏转技术是测量光学薄膜弱吸收的较理想方法. 相似文献
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Jing Wang Ningning Zu Xianfeng Hao Yuanhui Xu Zhiping Li Zhijian Wu Faming Gao 《固体物理学:研究快报》2014,8(9):776-780
Structural, electronic and magnetic properties of Sr2FeOsO6 have been revisited by using the first‐principle calculations. Semiconducting behavior is reproduced. The band gap is 0.09 eV from generalized gradient approximation (GGA) and 0.30 eV by considering both SOC and U, a bit larger than the experimental observed 0.125 eV. In the C‐type antiferromagnetic configuration, spin frustration is found by analysing the magnetic exchange parameters, explaining the experimental observed magnetic complexity.
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Recently, Sr2FeMoO6 has been established as a new colossal magnetoresistance material with substantial low-field magnetoresistance at room temperature and has attracted much attention in the double perovskite family. This material always appears with a certain degree of miss-site disorder where Fe and Mo interchange their positions. Using renormalized perturbation expansion, we calculate the density of states and determine the variation of the critical temperature in the low disorder regime. 相似文献
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在成功制备具有双钙钛矿结构Sr2Fe1-xCoxMoO6系列样品的基础上,对其结构、输运性质和磁性质进行了系统研究.结果发现,随着Co替代浓度x值的增加,样品的电阻率-温度关系由半金属行为转变为半导体行为,其室温电阻率从3.9×10-5Ω·cm增大到6.0×10-1Ω·cm;样品由亚铁磁体转变成反铁磁体,其磁相变温度TN值也随之下降;Co对Fe的部分替代使其磁电阻效应受到抑制.基于对其电子结构的分析,其磁电阻效应的起源以及Co的元素替代效应也在文中进行了讨论. 相似文献
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研究了Sr2Fe1-xAlxMoO6(0≤x≤0.30)系列多晶样品的磁学和输运性质.室温X射线衍射谱图的精修结果显示Al3+掺杂没有改变样品的晶格结构,但提高了Sr2FeMoO6晶格的阳离子有序度.5K时样品的磁化曲线说明平均单位分子饱和磁矩随着Al含量的增加而下降,但平均单位Fe离子磁矩却逐渐提高.磁化曲线的拟合结果显示样品内反铁磁相互作用对饱和磁矩的贡献随着Al含量的增加而下降,说明一定量的Fe离子被Al替代后,抑制了样品内Fe-O-Fe反相边界的形成,从而提高了Sr2FeMoO6晶格的阳离子有序度和平均单位Fe离子磁矩.对饱和磁矩的分析表明非磁性Al3+离子掺杂会形成无磁相互作用的Mo-O-Al-O-Mo区,可以将原来较大的Mo-O-Fe亚铁磁区分割成许多小的区域,并且使这些亚铁磁区间的磁耦合作用变弱,从而提高了低场磁电阻效应.阳离子有序度的提高使来源于自旋相关电子在反相边界处散射的高场磁电阻明显降低,导致了样品的磁电阻在x=0.15时达到了最大值. 相似文献
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采用溶胶凝胶法制备了Sr3Al2O6:Eu2+,Dy3+红色长余辉发光材料,利用X射线衍射仪对材料的物相进行了分析,结果表明,1200℃下制备的样品的物相为Sr3Al2O6,少量的Eu和Dy掺杂没有影响样品的相组成.采用荧光分光光度计、照度计测定了样品的发光特性.结果表明Sr3Al2O6:Eu2+和Sr3Al2O6:Eu2+,Dy3+的激发光谱均为激发峰位于473 nm的宽带谱.Sr3Al2O6:Dy3+的发射峰位于530.1 nm,对应于Dy3+代替Sr2+位置后基质中形成的施主-受主对Dy·Sr-V″Sr的重新组合.Sr3-0.02-yAl2O6:0.02Eu2+,yDy3+(0相似文献
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在成功制备具有双钙钛矿结构Sr2Fe1-xCoxMoO6系列样品的基础上,对其结构、输运性质和磁性质进行了系统研究.结果发现,随着Co替代浓度x值的增加,样品的电阻率-温度关系由半金属行为转变为半导体行为,其室温电阻率从3.9×10-5Ω·cm增大到6.0×10-1Ω·cm;样品由亚铁磁体转变成反铁磁体,其磁相变温度TN值也随之下降; Co对Fe的部分替代使其磁电阻效应受到抑制.基于对其电子结构的分析,其磁电阻效应的起源以及Co的元素替代效应也在文中进行了讨论.
关键词:
双钙钛矿结构
2FeMoO6')" href="#">Sr2FeMoO6
磁电阻 相似文献
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Douvalis A. P. Venkatesan M. Coey J. M. D. Alamelu T. Varadaraju U. V. 《Hyperfine Interactions》2002,144(1-4):267-272
Hyperfine Interactions - We present a 57Fe Mössbauer study of the Sr2?x Ca x FeReO6 double perovskite series, with x=0, 0.1, 0.2, 0.5, 1.0, 1.5 and 2.0. The analysis at 300 and 16 K... 相似文献
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Anderson Dias Ganesanpotti Subodh Mailadil T. Sebastian Roberto L. Moreira 《Journal of Raman spectroscopy : JRS》2010,41(6):702-706
Sr2ZnTeO6 ceramics were prepared by the solid‐state route and their vibrational phonon modes were investigated using optical spectroscopic techniques, for the first time. X‐ray diffraction (XRD) and Raman and infrared spectroscopies were employed to investigate the structures of these perovskite materials and the results analysed together with group‐theoretical predictions. The number and behaviour of the first‐order modes observed in both spectroscopic techniques are in agreement with the calculations for a tetragonal I4/m space group. The complete set of the optical phonon modes was determined, and the intrinsic dielectric properties of the materials were evaluated, allowing us to discuss their potential application in microwave (MW) circuitry. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献