Effect of mineral fillers on properties of composite matrix material

The influence of mineral fillers on thermomechanical properties of matrix material of composites is investigated. Different methods to determine elastic properties and thermal expansion coefficients of composite materials have been considered and compared. Injection moulded polyester samples containing varying concentrations of talc filler are tested and properties such as Young 's modulus, thermal expansion coefficients, and volumetric shrinkage during cure are measured. Results obtained by theoretical models and from experiments are compared and discussed.To be presented at the Ninth International Conference on the Mechanics of Composite Materials (Riga, October 1995).Published in Mekhanika Kompozitnykh Materialov, Vol. 31, No. 4, pp. 435–445, July–August, 1995.     

Effect of aging creep of polyestermalein resin/mineral filler composites

Long-term (More than 20 years) creep under compression of two polymer concretes, polyestermalein resin/mineral filler composites, was studied. The concretes differ with diabase filler size (d=5–10 mm and d=10–20 mm). It was shown that nonlinearity of viscoelastic properties of concrete increases as the size of filler particle decreases. Aging of the polymer concretes reduces their viscoelastic compliance and shortens the time interval necessary to reach equilibrium conditions under stable loading state.Presented at the Ninth International Conference on the Mechanics of Composite Materials, Riga, October, 1995.Institute of Theoretical and Applied Mechanics of the AS CR, Prague 9, Prosecká 74, Czech Republic. Central Laboratory of Physical-Chemical Mechanics of the BAS, Sofia 1113 Acad. Bontchev Street, IV km, Bl. 1. Published in Mekhanika Kompozitnykh Materialov, Vol. 32, No. 2, pp. 190–194, March–April, 1995.     

Structure and properties of magnetic fibrous polymeric materials

Characteristic features of the filtration of liquids by magnetic fibrous polymeric materials (MFPM) are addressed; these materials are a set of fibers of a polymeric material containing a ferritic filler; they are adhesively bound at points of their intersection. It is demonstrated that variations in structural parameters (fiber thickness, distribution of fiber throughout the material, and its concentration), as well as the degree and direction of magnetization of the MFPM exert an influence on the efficiency of the liquid filtration. Optimum parameters for MFPM designed to purify liquids of ferromagnetic and nonmagnetic contaminants are given.A paper to be presented at the Ninth International Conference on the Mechanics of Composite Materials, Riga, October, 1995.Translated from Mekhanika Kompozitnykh Materialov, Vol. 31, No. 3, pp. 291–297, May–June, 1995.     

Scale factor in an experimental model of a highly reinforced composite

Formation of shrinkage defects during isothermal curing of network polymers is considered. The cure was carried out under conditions of adhesive interaction of the polymer matrix with the rigid filler present in the composite. The dependence of the relative mean distance between cohesive defects on the tube diameter in the tube model developed earlier was investigated over more than two orders of magnitude of tube diameters. This distance was found to be constant in the range considered. A similar process of shrinkage defect formation was observed for a plate model.Presented at the Ninth International Conference on the Mechanics of Composite Materials (Riga, October 1995).Translated from Mekhanika Kompozitnykh Materialov, Vol. 31, No. 2, pp. 163–168, March–April, 1995.The work was financed by the Russian Fund for Basic Research (Project 94-03-09253).     

Dynamic compressive strength of epoxy composites

The strength of laminated and unidirectionally reinforced composite materials was investigated in conditions of dynamic uniaxial compression with a strain rate of 50–1000 sec^–1 using the split Hopkinson pressure bar method. It was shown that in conditions of dynamic compression, glass/epoxy, aramid/epoxy, and carbon/epoxy composites exhibit elastic-brittle behavior with anisotropy of the strength and elastic properties. The effect of the strain rate on the strength characteristics of fiberglass-reinforced plastics was demonstrated.Translated from Mekhanika Kompozitnykh Materialov, Vol. 31, No. 6, pp. 776–782, November–December, 1995.Presented at the Ninth International Conference on the Mechanics of Composite Materials (Riga, October, 1995).     

Mechanical characteristics of autopericardium and indications for its application in surgery

We compare the mechanical characteristics under uniaxial tension of human pericardium in native form and stabilized by glutaraldehyde solution. We assess the effect of the media (water, hypertonic and physiological solutions) on the change in the mechanical properties of the stabilized autopericardium. We determine the optimal concentration of the stabilizing solution and the treatment time ensuring the required properties of the autopericardium. We present data from analysis of the morphological changes occurring in the transplant and the results of the operations.Report presented at the Ninth International Conference on the Mechanics of Composite Materials, Riga, October, 1995.Translated from Mekhanika Kompozitnikh Materialov, Vol. 32, No. 2, pp. 219–225, March–April 1996.     

New mathematical model for nonuniform deformation of composites

A new mathematical model is suggested for nonuniform deformation of composite materials valid for arbitrary external load gradients. As a basis stochastic equations are suggested for the statics of an elastic microinhomogeneous two-component material with volumetric forces differing from zero. Expressions are obtained for all coefficients in terms of elastic constants of the components and geometric parameters of the structure.Presented at the Ninth International Conference on the Mechanics of Composite Materials (Riga, October, 1995).Translated from Mekhanika Kompozitnykh Materialov, Vol. 31, No. 3, pp. 310–318, May–June, 1995.     

High strength and high conductivity composite wires for high pulsed magnet

Magnets for high pulsed magnetic fields require a winding with high electrical conductivity, high strength, high heat capacity, and a softening temperature greater than 300 °C. Different conductors, developed on DRET contracts, are presented. The ultimate tensile stress at room temperature of macrocomposites, where the reinforcement is either a jacket or fibres, checks the rule of mixtures, whereas _uts of Cu/Nb nanocomposites with continuous Nb nanofibres exhibit a very interesting deviation from the rule of mixtures leading to _uts(77K) = 1206 MPa for 30% Nb.To be presented at the Ninth International Conference on the Mechanics of Composite Materials, 17–20 October 1995, Riga.Published in Mekhanika Kompozitnykh Materialov, Vol. 31, No. 4, pp. 518–525, July–August, 1995.     

Prediction of the deformation properties of a polymeric composite with a granular-fibrous filler

Conclusion A variant of calculation of the characteristics of the deformation properties of a hybrid composite containing a complex disperse filler in the form of granular particles and short fibers was proposed. The effect of aggregation of the granular filler, the statistical distributions of the fibers by lengths and orientation in the material, and the anisotropy of the fibers are taken into consideration in the calculation. The statistical distribution of the orientation of the fibers is given by a function proportional to the distance from the center to the surface of a triaxial ellipsoid in the corresponding direction. The uniform random distribution of the fibers in bulk and in the plane is a special case of this distribution. The results of the analysis of the effect of the parameters of the statistical distributions of the length and orientation of short fibers on the elasticity characteristics of a composite are reported. The dependence of the creep of the composite on the ratio of the concentration of the components of the complex filler was determined, and the efficiency of partial replacement of a granular filler by a short-fiber filler to inhibit creep of the composite was demonstrated. The possibilities of predicting the long-term creep were experimentally confirmed on the example of LDPE filled with ground limestone and short glass fibers.Presented at the Sixth All-Union Conference on the Mechanics of Polymer and Composite Materials (Riga, November, 1986).Translated from Mekhanika Kompozitnykh Materialov, No. 5, pp. 898–909, September–October, 1987.     

Active polymeric materials

The ranges of potential use of active polymeric composite materials that interact physically, chemically, or biochemically with other materials or the environment are discussed. The high effectiveness of these materials in anti-corrosion filtering and sealing components of engineering systems, as well as in medicine, the food industry, etc., is demonstrated on the basis of our own experimental studies and results published by other authors.A paper to be presented at the Ninth International Conference on the Mechanics of Composite Materials (Riga, October, 1995).Translated from Mekhanika Kompozitnykh Materialov, Vol. 31, No. 3, pp. 298–304, May–June, 1995.     

Production and characterization of UHMWPE fibers/LDPE composites

The production of unidirectionally fiber-reinforced composites (tapes) consisting of high-strength/high-modulus UHMWPE fibers and LDPE matrix is described. Two production techniques are applied: impregnation by aqueous powder dispersion and dry powder impregnation. The produced composites exhibit excellent mechanical properties. Depending on the fiber volume content which can be obtained: tensile strength (in fiber direction) 460–1100 MPa, elastic modulus 11–22 GPa, and elongation at break 4.9–8.3%.Presented at the Ninth International Conference on the Mechanics of Composite Materials, Riga, October, 1995.Technical University of Berlin. Institute of Nonmetallic Materials. Polymer Physics Group.-Englishe Str. 20, D-10587 Berlin. Germany. Published in Mekhanik Kompozitnykh Materialov, Vol. 32, No. 6. pp. 719–728, November–December, 1996.     

Thermal dependence of electric conductivity in thermoplastic composites

Thermal dependence of the electric conductivity of thermoplastic composites based on both amorphous (hiPS) and crystallized (PP) polymers is investigated in this study. Two types of carbon black fillers with different values of BET surface area were used as charge conductors. Composites based on crystallized polymer matrices indicate the sharp growth of electric resistivity just before the melting range. This maximum is followed by substantial decrease of resistance at T > T_melt. With the decrease of carbon black concentration both relative growth of resistance at the T T_melt and further dropping resistance at T > T_melt increase. Composites filled with particles of higher surface area are characterized by less pronounced matrix influence on thermal dependence of electric conductivity than composites filled with particles of lower surface area; this can be caused by more pronounced matrix/filler interaction in the first case. The range of temperatures at which the resistance increase occurs does not depend on the type of carbon filler and its concentration. Composites with amorphous matrices are characterized by distinct increase of resistance above glass transition. Thermal treatment of the sample significantly affects the initial values and intensity of the temperature dependence of the resistance.To be presented at the Ninth International Conference on the Mechanics of Composite Materials, Riga, October, 1995.Published in Mekhanika Kompozitnykh Materialov, Vol. 31, No. 4, pp. 526–532, July–August, 1995.     

Analysis of the anisotropic properties of honeycomb sandwich plates

A mathematical model has been described and an approach proposed to the diagnostics of the anisotropic properties of the relative elasticity constants of three-layer (sandwich) plates with a honeycomb filler. Compact analytical relationships between the anisotropy coefficients and the geometrical dimensions of the cells have been obtained. A practical approach has been proposed for the selection of rational parameters of the honeycomb structure, at which its anisotropic properties would be in the chosen region of the functional space. The conditions have been formulated at which the constructive anisotropy, inherent to honeycomb structures, degenerates to isotropy for some relative elastic constants.Paper to be presented at the Ninth International Conference on the Mechanics of Composite Materials (Riga, October 1995).Translated from Mekhanika Kompozitnykh Materialov, Vol. 31, No. 4, pp. 482–487, July–August, 1995.     

Scale effect of Young's modulus of highly oriented polymers

The scale effect of the acoustic Young's modulus E of oriented polymer fibers has been experimentally revealed. If the fiber length L is smaller than its critical value L₀, the modulus decreases proportionally to the logarithm of the fiber length. An increasing temperature causes a proportional increase in the slope dE/d(In L). The scale effect is explained by the influence of the specimen volume on the probability of initiation of intense thermal fluctuations, which cause a decline in the Young's modulus.Presented at the 10th International Conference on the Mechanics of Composite Materials (Riga, April 20–23, 1998).Translated from Mekhanika Kompozitnykh Materialov, Vol. 34, No. 6, pp. 839–846, November–December, 1998.     

Theory of spherofibrous composites. 2. Fundamental equations

Fundamental equations of the theory of spatially reinforced media with a matrix reinforced by spherical particles are proposed on the basis of a linearly reinforced layer and tl.e hypothesis of a longitudinal state. For an arbitrary orientation of the fibers, the generalized elasticity equation for composites was found to contain 21 elastic constants and approximate formulas were derived for their determination.Presented at the Ninth International Conference on the Mechanics of Composite Materials, Riga. Latvia (October, 1995).Communication 1. see preceding article.A. A. Blagonravov Institute of Mechanical Engineering. Russian Academy of Sciences, Moscow. Russian. Translated from Mekhanika Kompozitnykh Materialov, Vol. 32, No. 3, pp. 306–316, May–June, 1996.     

Effect of side branches on the properties of cross-linked polyurethanes

Two series of samples of cross-linked polyurethanes: based on diethylene glycol and polypropylene glycol having calculated M_c 1000, were investigated. In synthesis by partial substitution of glycols by fatty acid ester and triethanolamine, long side branches were created in the structure of the polymer. The effect of the mass concentration of these branches on the physicomechanical properties of polyurethanes was evaluated. The different character of the effect of these branches on the properties of two types of polyurethane was demonstrated.Submitted to the Xth International Conference on Mechanics of Composite Materials (Riga, April 20–23, 1998).Latvian State Institute of Wood Chemistry. Riga, LV-1006 Latvia. Translated from Mekhanika Kompozitnykh Materialov, No. 6, pp. 840–844. November–December. 1997.     

An estimation of reliability of unidirectional composites by catastrophe theory

In the present work, interest is centered on the theory of fracture and practical approaches to reliability estimation of unidirectional composite materials which are based on it. Fracture mechanics is considered not as a theory of macrocracks but as mechanics of fracture mechanisms of the composites with allowance made for probability estimation. A model of composite material with fibers eliminated from the carrying scheme and parameters specific to the stress-strain-damage state (SSDS) was considered. According to the model, during loading, self-accelerated energy rise is accounted for by structural damages growth — the catastrophe takes place. The model allows us to calculate the critical stress. The composites redistribute forces from overloading zones to neighboring ones by microstructural deformations and damages. It is the effect of reservation of carrying ability. Due to this effect, low-value probability of fracture is sufficiently less for the composite than for homogeneous materials. The approach allows us to evaluate the reliability function for both static loading and fatigue.Presented at the Ninth International Conference on the Mechanics of Composite Materials, Riga, October, 1995.Computing Center of the Russian Academy of Sciences, Krasnoyarsk, Russia. Published in Mekhanika Kompozitnykh Materialov, Vol. 32, No. 4, pp. 539–548, July–August, 1996.     

Electromechanical properties of laminated piezoelectric composites

The general expressions for the effective elastic, piezoelectric, and dielectric coefficients of a laminated piezocomposite composed of laminates in parallel connection are shown. By means of the asymptotic averaging method [12] these effective coefficients are calculated. The effective coefficients as well as physical properties such as electromechanical piezoelectric coupling coefficients, acoustic impedance, and wave velocity for a two-phase composite, where one phase is ceramic and the other one is polymer, are analyzed. A comparison with another results is shown.Presented at the Ninth International Conference on the Mechanics of Composite Materials, Riga, October, 1995.Published in Mekhanika Kompozitnykh Materialov, Vol. 32, No. 3, pp. 410–417, May–June, 1996.     

A new benchmark for transient analysis of laminated plate elements

Conclusions In this paper, a new benchmark was presented to verify the finite element method programs for analysis of composite element impact problems. The benchmark presented possesses a double contact between the impactor and the laminated plate. The results of the analytical solution were presented, and compared with the results obtained by a commercially available FEM-program. This work was an example of a numerical solution method verification, and the test was found suitable as a benchmark due to its simplicity in modeling and its versatility in assessing programs.Published in Mekhanika Kompozitnykh Materialov, Vol. 31, No. 2, pp. 209–215, March–April, 1995.Presented at the Ninth International Conference on the Mechanics of Composite Materials (Riga, October, 1995).     

Optimum stacking sequence of composite laminates for maximum strength

A method is presented for maximum strength optimum design of symmetric composite laminates subjected to in-plane and transverse loadings. The finite element method based on shear deformation theory is used for the analysis of composite laminates. Ply orientation angles are chosen as design variables. The quadratic failure criterion which is meant to predict fracture, is used as an object function for optimum stacking sequence design of a laminated plate. The Broydon-Fletcher-Goldfarb-Shanno optimization technique is employed to solve the optimization problem effectively. Numerical results are given for various loading conditions, boundary conditions, and aspect ratios. The results show that the quadratic failure criterion such as Tsai-Hill theory is effective for the optimum structural design of composite laminates.Presented at the Ninth International Conference on the Mechanics of Composite Materials (Riga, October 1995).Published in Mekhanika Kompozitnykh Materialov, Vol. 31, No. 3, pp. 393–404, May–June, 1995.