采用不同透明电极的非晶铟镓锌氧化物薄膜晶体管

采用透明材料ITO和AZO为源漏电极,在室温下利用射频磁控溅射方法制作了底栅结构的非晶铟镓锌氧化物薄膜晶体管。实验发现,制备的薄膜晶体管均表现出了良好的开关特性。其中采用AZO为电极的薄膜晶体管的场效应迁移率为1.95cm2/V.s,开关比为4.53×105,在正向偏压应力测试下,阈值电压的漂移量为4.49V。     

氧化锌基薄膜晶体管最新研究进展

ZnO基TFT被认为是最有可能取代当前大规模产业化的a-Si:H TFT的下一代MOSFET,在最近几年受到广泛的关注.简单介绍了ZnO基TFT的结构、原理、各层材料的作用、要求和制造方法以及可靠性研究,包括时间、温度和可见光或紫外光辐照以及偏压作用对器件特性的影响方面的最新进展,分析了实现产业化尚需克服的问题.     

底栅和顶栅结构全透明氧化锌薄膜晶体管的制备

报道了制备在50mm石英玻璃衬底上的透明氧化锌薄膜晶体管(ZnO-TFT),采用了底栅和顶栅两种结构进行比较.ZnO沟道层由射频磁控溅射方法制备,SiO2薄膜作为栅绝缘层.结果发现底栅结构的ZnO-TFT具有较好的电学性质,该器件工作在n沟道增强模式,具有较好的夹断效应和饱和特性,其场效应迁移率、阈值电压和电流开关比分别为18.4cm2/(V·s),-0.5V和104.顶栅结构的ZnO-TFT则工作在n沟道耗尽模式,没有明显的饱和特征.不同结构ZnO-TFT电学性质的差别可能是由于不同的ZnO/SiO2界面特性所致.两种结构的ZnO-TFT在可见光波段都有很高的光学透过率.     

底栅和顶栅结构全透明氧化锌薄膜晶体管的制备

报道了制备在50mm石英玻璃衬底上的透明氧化锌薄膜晶体管(ZnO-TFT),采用了底栅和顶栅两种结构进行比较.ZnO沟道层由射频磁控溅射方法制备,SiO2薄膜作为栅绝缘层.结果发现底栅结构的ZnO-TFT具有较好的电学性质,该器件工作在n沟道增强模式,具有较好的夹断效应和饱和特性,其场效应迁移率、阈值电压和电流开关比分别为18.4cm2/(V·s),-0.5V和104.顶栅结构的ZnO-TFT则工作在n沟道耗尽模式,没有明显的饱和特征.不同结构ZnO-TFT电学性质的差别可能是由于不同的ZnO/SiO2界面特性所致.两种结构的ZnO-TFT在可见光波段都有很高的光学透过率.     

Load‐Controlled Roll Transfer of Oxide Transistors for Stretchable Electronics

A stretchable and transparent In‐Ga‐Zn‐O (IGZO) thin film transistors with high electrical performance and scalability is demonstrated. A load‐controlled roll transfer method is realized for fully automated and scalable transfer of the IGZO TFTs from a rigid substrate to a nonconventional elastomeric substrate. The IGZO TFTs exhibit high electrical performance under stretching and cyclic tests, demonstrating the potentiality of the load‐controlled roll transfer in stretchable electronics. The mechanics of the load‐controlled roll transfer is investigated and simulated, and it is shown that the strain level experienced by the active layers of the device can be controlled to well below their maximum fracture level during transfer.     

金属氧化物IGZO薄膜晶体管的最新研究进展

最近几年,金属氧化物IGZO薄膜晶体管成为研究热点,具有高迁移率、稳定性好、制作工艺简单等优点,备受人们关注。文章综述了制作金属氧化物IGZO晶体管的结构及其优缺点,总结了影响金属氧化物IGZO薄膜晶体管性能的因素,并提出了制作高性能金属氧化物IGZO薄膜晶体管的方法。     

High‐Mobility ZnO Thin Film Transistors Based on Solution‐processed Hafnium Oxide Gate Dielectrics

The properties of metal oxides with high dielectric constant (k) are being extensively studied for use as gate dielectric alternatives to silicon dioxide (SiO₂). Despite their attractive properties, these high‐k dielectrics are usually manufactured using costly vacuum‐based techniques. In that respect, recent research has been focused on the development of alternative deposition methods based on solution‐processable metal oxides. Here, the application of the spray pyrolysis (SP) technique for processing high‐quality hafnium oxide (HfO₂) gate dielectrics and their implementation in thin film transistors employing spray‐coated zinc oxide (ZnO) semiconducting channels are reported. The films are studied by means of admittance spectroscopy, atomic force microscopy, X‐ray diffraction, UV–Visible absorption spectroscopy, FTIR, spectroscopic ellipsometry, and field‐effect measurements. Analyses reveal polycrystalline HfO₂ layers of monoclinic structure that exhibit wide band gap (≈5.7 eV), low roughness (≈0.8 nm), high dielectric constant (k ≈ 18.8), and high breakdown voltage (≈2.7 MV/cm). Thin film transistors based on HfO₂/ZnO stacks exhibit excellent electron transport characteristics with low operating voltages (≈6 V), high on/off current modulation ratio (～10⁷) and electron mobility in excess of 40 cm² V^?1 s^?1.     

Light Effects on the Bias Stability of Transparent ZnO Thin Film Transistors

We report on the bias stability characteristics of transparent ZnO thin film transistors (TFTs) under visible light illumination. The transfer curve shows virtually no change under positive gate bias stress with light illumination, while it shows dramatic negative shifts under negative gate bias stress. The major mechanism of the bias stability under visible illumination of our ZnO TFTs is thought to be the charge trapping of photo‐generated holes at the gate insulator and/or insulator/channel interface.     

双栅酞菁铜有机薄膜晶体管

有机薄膜晶体管以其成本低、柔性好、易加工等优点越来越受到人们的青睐,目前已广泛应用于低端器件。为了获得更实际的应用,OTFTs的性能还需进一步的提高和改善。文章中以酞菁铜(CuPc)为有机半导体材料,制备了双栅结构的有机薄膜晶体管,其阈值电压为-4.5V,场效应迁移率0.025cm2/V.s,开关电流比Ion/Ioff达到9.8×103,与单栅有机薄膜晶体管相比,双栅器件在更低的操作电压下获得了更大的输出电流,场效应迁移率更高,而且通过对两个栅压的调节,对导电沟道实现了更好的控制,器件性能有了较大的提高。     

Skin‐Like Oxide Thin‐Film Transistors for Transparent Displays

Flexible transparent display is a promising candidate to visually communicate with each other in the future Internet of Things era. The flexible oxide thin‐film transistors (TFTs) have attracted attention as a component for transparent display by its high performance and high transparency. The critical issue of flexible oxide TFTs for practical display applications, however, is the realization on transparent and flexible substrate without any damage and characteristic degradation. Here, the ultrathin, flexible, and transparent oxide TFTs for skin‐like displays are demonstrated on an ultrathin flexible substrate using an inorganic‐based laser liftoff process. In this way, skin‐like ultrathin oxide TFTs are conformally attached onto various fabrics and human skin surface without any structural damage. Ultrathin flexible transparent oxide TFTs show high optical transparency of 83% and mobility of 40 cm² V^?1 s^?1. The skin‐like oxide TFTs show reliable performance under the electrical/optical stress tests and mechanical bending tests due to advanced device materials and systematic mechanical designs. Moreover, skin‐like oxide logic inverter circuits composed of n‐channel metal oxide semiconductor TFTs on ultrathin, transparent polyethylene terephthalate film have been realized.     

Fully Patterned Low‐Voltage Transparent Metal Oxide Transistors Deposited Solely by Chemical Spray Pyrolysis

All‐inorganic transparent thin‐film transistors deposited solely by the solution processing method of spray pyrolysis are reported. Different precursor materials are employed to create conducting and semiconducting species of ZnO acting as electrodes and active channel material, respectively, as well as zirconium oxide as gate dielectric layer. Additionally, a simple stencil mask system provides sufficient resolution to realize the necessary geometric patterns. As a result, fully functional low‐voltage n‐type transistors with a mobility of 0.18 cm² V^?1 s^?1 can be demonstrated via a technique that bears the potential for upscaling. A detailed microscopic evaluation of the channel region by electron diffraction, high‐resolution and analytical TEM confirms the layer stacking and provides detailed information on the chemical composition and nanocrystalline nature of the individual layers.     

离子辅助沉积掺铝氧化锌透明导电膜的研究

报道了采用离子辅助电子枪蒸发技术制备优质氧化锌透明导电膜的工艺和结果,分析了源掺杂,镀膜气氛,衬底温度等参数与膜的电导率及透光特性的关系,作出了电阻率低达2×10     

全透明低回滞s-SWCNT/AgNW薄膜晶体管的可控制备

利用高纯度、高均一性的半导体型单壁碳纳米管(s-SWCNT)网络薄膜作为薄膜晶体管的沟道材料,以高透明度、低薄膜电阻的银纳米线(Ag NW)网络薄膜作为源、漏电极,在玻璃基底上制备了大面积、高透明度的碳纳米管薄膜晶体管阵列,并使用聚甲基丙烯酸甲酯(PMMA)薄膜在器件表面通过干法封装获得了较低回滞的电子器件,得到了整体透明度达到82%以上的器件。提出的器件制备方法不仅制备材料易得,不需要高温过程,而且能够实现器件的大面积制备,对碳纳米管薄膜晶体管的全透明柔性化进程具有推进作用。     

High Performance Indium‐Gallium‐Zinc Oxide Thin Film Transistor via Interface Engineering

Solution‐processed indium‐gallium‐zinc oxide (IGZO) thin film transistors (TFTs) have become well known in recent decades for their promising commercial potential. However, the unsatisfactory performance of small‐sized IGZO TFTs is limiting their applicability. To address this issue, this work introduces an interface engineering method of bi‐functional acid modification to regulate the interfaces between electrodes and the channels of IGZO TFTs. This method increases the interface oxygen vacancy concentration and reduces the surface roughness, resulting in higher mobility and enhanced contact at the interfaces. The TFT devices thus treated display contact resistance reduction from 9.1 to 2.3 kΩmm, as measured by the gated four‐probe method, as well as field‐effect mobility increase from 1.5 to 4.5 cm² (V s)^?1. Additionally, a 12 × 12 organic light emitting diode display constructed using the acid modified IGZO TFTs as switching and driving elements demonstrate the applicability of these devices.     

A Review of Low‐Temperature Solution‐Processed Metal Oxide Thin‐Film Transistors for Flexible Electronics

Solution processing, including printing technology, is a promising technique for oxide thin‐film transistor (TFTs) fabrication because it tends to be a cost‐effective process with high composition controllability and high throughput. However, solution‐processed oxide TFTs are limited by low‐performance and stability issues, which require high‐temperature annealing. This high thermal budget in the fabrication process inhibits oxide TFTs from being applied to flexible electronics. There have been numerous attempts to promote the desired electrical characteristics of solution‐processed oxide TFTs at lower fabrication temperatures. Recent techniques for achieving low‐temperature (<350 °C) solution‐processed and printed oxide TFTs, in terms of the materials, processes, and structural engineering methods currently in use are reviewed. Moreover, the core techniques for both n‐type and p‐type oxide‐based channel layers, gate dielectric layers, and electrode layers in oxide TFTs are addressed. Finally, various multifunctional and emerging applications based on low‐temperature solution‐processed oxide TFTs are introduced and future outlooks for this highly promising research are suggested.     

非晶铟镓锌氧化物薄膜晶体管的制备及其光敏特性研究

基于射频磁控溅射法制备了以非晶铟镓锌氧化物(a-IGZO)作为有源层的底栅顶接触式薄膜场效应晶体管(Thin Film Transistor,TFT),其长/宽比为300μm/100μm。研究了该器件在无激光和在三种不同波长激光照射下的光敏特性。实验表明,器件在波长分别为660、450和405nm三种激光照射下的阈值电压V_th分别为4.2、2.5和0V,均低于无激光时的4.3V,且器件的阈值电压随激光波长减小单调降低,此外,随着激光波长的下降,“明/暗”电流比K由0.54上升到8.06(在VGS=6V且VDS=5V条件下),光敏响应度R由0.33μA/mW上升到4.88μA/mW,可见激光波长越短,可获得更强的光电效应,光灵敏度也更高,该效应表明该器件在光电探测等领域具有广阔的应用前景。     

掺Al ZnO柔性透明导电薄膜研究进展

柔性透明导电薄膜ZAO具有优异的光电性能且资源丰富、成本低、对环境无污染,成为当前的研究热点.总结了近年来对柔性衬底材料处理的方法,分析了柔性透明导电薄膜的研究历史和现状.介绍了柔性透明导电薄膜ZAO的结构、光电特性、典型制备方法和应用前景.评述了柔性ZAO薄膜的研究现状,并对其近期研究和应用工作进行了展望.     

氧化物半导体薄膜晶体管的研究进展

简要说明了非晶硅、多晶硅和有机半导体用作薄膜晶体管沟道层的不足,从电学性质、光学性质和制备温度等几方面介绍了氧化物薄膜晶体管在有源阵列驱动显示技术中的优势,并介绍了氧化物沟道层制备工艺的优化和掺杂方法.最后,展望了氧化物半导体薄膜晶体管应用前景.