Optical absorption spectrum of Ni2+ doped in ammonium zinc sulphate

The optical absorption spectrum of Ni²⁺ ion doped in ammonium zinc sulphate has been studied at room and liquid air temperatures. From the nature and the positions of the bands a successful interpretation of all the bands could be made assumingO _h symmetry for the Ni²⁺ ion in the crystal. The fine splitting of the³ T ₁ ¹ band at liquid air temperature has been successfully interpreted to be due to spin-orbit interaction. The crystal field and spin-orbit parameters derived areDq=1000 cm⁻¹;B=750 cm⁻¹;C=3.45B andξ=600 cm⁻¹.     

Optical absorption spectrum of Ni2+ ions doped in sodium potassium sulphate single crystal

Single crystals of nickel-doped sodium potassium sulphate were grown by slow evaporation method at room temperature. From the nature and position of the bands observed, a successful interpretation of all the observed bands could be made assuming the octahedral symmetry for the Ni^{2 +} ion in the crystal. The bands have been ascribed to transitions from the ground³A_2g(F) state to the excited³T_2g(F),¹E_g(D),³T_1g(F),¹T_2g(D) and³T_1g(P) states. The experimental and calculated energies are in good agreement. The crystal field parameters derived areDq= =880 cm^–1,B= 900cm^–1 andC=3600 cm^–1.One of the authors, Sujatha John expresses her thanks to the Secretary and the Principal, R. B. V. R. Reddy College, Hyderabad for according her permission to pursue the M. Phil. course.     

Optical absorption spectrum of Cr3+ ion doped in zinc cesium sulphate hexahydrate

Optical absorption spectrum of Cr³⁺ ion doped in zinc cesium sulphate hexahydrate single crystal has been studied both at room and liquid nitrogen temperatures. From the nature and position of the bands a successful interpretation of all the bands could be made assuming octahedral symmetry for the Cr³⁺ ion in the crystal. The observed bands are assigned to the transitions from the ground ⁴A_2g(F) state to the excited ²E_g(G), ²T_1g(G), ⁴T_2g(F) and ⁴T_1g(F) states.The crystal field parameters Dq = 1735 cm^?1, B = 635 cm^?1 and C = 4.75 B are found to give a good fit to the observed band positions.     

Optical absorption spectrum of chromium doped rubidium aluminium sulphate dodecahydrate

Optical absorption spectrum of chromium doped rubidium aluminium sulphate dodecahydrate single crystal is investigated. The electronic spectrum in the UV-VIS region is characteristic of Cr ³⁺ in trigonal symmetry and vibrational spectrum in the i.r. region is ascribed to the SO ₄²⁻ and H ₂O groups. The following crystal field parameters are evaluated for Cr ³⁺ in trigonal symmetry.Dq = 1840cm ⁻¹, Dσ = 140cm ⁻¹, Dτ = 140cm ⁻¹, B = 700cm ⁻¹ C = 3100cm ⁻¹.     

Optical absorption spectrum of Co2+ in ammonium perchlorate single crystal

Single crystals of cobalt — doped ammonium perchlorate were grown at room temperature. The electronic absorption bands observed at room and liquid air temperatures have been assigned transitions from the ground⁴T₁(F) state to the excited⁴T₂(F),⁴A₂(F),²T₁(G) and⁴T₁(P) states. The crystal parameters derived areDq=880 cm^–1,B=865 cm^–1 andC= 4·63B.The authors wish to express their thanks to the authorities of the Indian Institute of Science, Bangalore for kind permission to use their spectrophotometer. Two of the authors (B. C. V.Reddy and J. L.Rao) express their greatful thanks to the council of scientific and Industrial Research (New Delhi) for financial assistance.     

Electronic absorption spectrum of Ni2+ in lithium potassium sulphate single crystal

Single crystals of nickel-doped lithium potassium sulphate were grown by slow evaporation method at room temperature. From the nature and position of the bands observed, a successful interpretation of all the bands could be made assumingO _h symmetry for the Ni²⁺ ion in the crystal. The bands have been assigned transitions from the ground³A_2g(F) state to the excited³T_2g(F),¹E_g(D),³T_1g(F),¹T_2g(D) and³T_1g(P) states. The crystal field parameters derived areDq=910cm^–1,B=890cm^–1 andC=3560cm^–1.The authors wish to express their thanks to Prof. K. Sreerama Murthy for his constant encouragement throughout this investigation. The authors are also thankful to Prof. Mihir Chowdhury, Indian Association for the cultivation of Science, Calcutta for giving permission to take the spectra.     

Electronic absorption spectrum of CO+ in an ion beam

The He+He⁺¹ interactions have been studied, as a function of the internuclear separation R, in terms of the electronic forces acting on the nuclei and the change in the charge distribution. The analysis reveals that at large R the atomic densities are polarized inwards, causing an attractive force on each nucleus, while at small R the difference in the nature of the interactions in the ²Σ_u and ²Σ_g systems is noted. It is seen that the He+He⁺¹ (²Σ_u) interaction is less attractive than the He⁺¹+He⁺¹ interaction at lower values of R.     

Optical absorption spectrum of Cr3+ in natural ruby

Two sharp line-like bands calledN andR lines on the red side, a close doublet (B lines) on the violet side and two broad bands are observed for natural ruby. At liquid air temperature the splitting ofR line was found and also three sharp-bands calledR, R′ andB lines are identified with spin-forbidden transitions of² E,² T ₁ and² T ₂. The two broad bands calledU band andY band are assigned accordingly to the spin-allowed transitions⁴ T ₂ and⁴ T ₁ respectively. The observed bands of natural ruby have been attributed to Cr³⁺ ion in an octahedral environment with trigonal distortion. The crystal field parameters which gave a good fit to the observed band positions areB=732 cm⁻¹,C=4.25B,Dq=1830 cm⁻¹,V=−1996 cm⁻¹ andλ=34 cm⁻¹.     

Nd3+离子掺杂氧化物玻璃的光谱性质

高温熔融法制备了69.5B2O3-20Li2O-(10-χ)CaO-χPbO-0.5Nd2O3(χ=1,3,5,7,mol%)和68.5Li2O-(29-φ)CaO-φAl2O3-2La2O3-0.5Nd2O3(φ=3,7,10,15,mol%)玻璃,测量了玻璃样品的吸收和发射光谱(800nm激光二极管激发),从吸收光谱出发,应用Judd-Ofelt理论获得了Nd3+光学跃起的强度参数。根据强度参数和发射光谱,计算了Nd3+离子4F3/2→4I11/2跃迁的荧光发射截面σe。结果显示,在B2O3-Li2O-CaO-PbO-Nd2O3系统中随着CaO的减少和PbO的增加,Nd3+离子的强度参数Ω2增大,表明样品的对称性降低;强度参数Ω6也增大,说明玻璃样品中Nd-O键的共价性和键强降低;同时,Nd3+离子4F3/2→4I11/2跃迁的荧光发射截面σe的大小和荧光强度都减小。在Li2O-CaO-Al2O3-La2O3-Nd2O3系统中,随着CaO的减少和Al2O3的增加,Nd3+离子的强度参数Ω2减小,说明样品的对称性增加;强度参数Ω6减小,说明玻璃样品中Nd-O键的共价性和键强增强;同时,Nd3+离子4F3/2→4I11/2跃迁的荧光发射截面的大小和荧光强度也都减小。     

Optical absorption spectrum of VO2+ in calcium tartrate tetrahydrate

Single srystals of calcium tartrate doped with VO²⁺ are grown from silica gel. Its optical absorption spectrum is studied at laboratory and liquid air temperatures. The spectrum is analysed and ascribed to VO²⁺ ion in C_4v symmetry. The following crystal field parameters are evaluated.

$\text{Dq = 1835}\text{cm}{}^{\mathrm{?1}}\text{, Ds = ?1980}\text{cm}{}^{\mathrm{?1}}\text{, Dt = 1280}\text{cm}{}^{\mathrm{?1}}$

     

Optical spectroscopy of MgNb2O6 and ZnNb2O6 doped with Ni2+

Published in Zhurnal Prikladnoi Spektroskopii, Vol. 62, No. 4, pp. 30–37, July–August, 1995.     

Electronic absorption spectrum of Mn2+ ions doped in diglycine barium chloride monohydrate

The absorption spectrum of Mn²⁺ doped in diglycine barium chloride monohydrate has been studied at room temperature. The observed bands are assigned as transitions from the ${}^6\text{A}{}_{\mathrm{1g}}\text{(S)}$ ground state to various excited quartet levels of a Mn²⁺ ion in a cubic crystalline field. A new method has been suggested to evaluate the Racah parameters (B and C) accurately. The observed band positions are fitted with four parameters B, C, Dq and α, and the values obtained for the parameters are B= 810 cm^-1, C = 2990 cm^-1, Dq = 750 cm^-1 and α = 76 cm^-1.     

Co2+ and Mn2+ ion locations in doped CsCdCl3

Summary Substitutional Co²⁺ and Mn²⁺ ions at the two different Cd sites in the compound CsCdCl₃ have been studied by using electron paramagnetic resonance. The preferential occupation, Co²⁺ in the Cd_II site, Mn²⁺ in the Cd_I site, is discussed in terms of crystallochemical symmetry arguments. Paper presented at the ?V International Conference on Ternary and Multinary Compounds?, held in Cagliari, September 14–16, 1982.     

Absorption spectrum of VO2+ ion doped in caesium cadmium sulphate hexahydrate single crystal

Results of the optical absorption spectrum of VO²⁺ ion doped in caesium cadmium sulphate hexahydrate studied at room (300 K) and liquid nitrogen (77 K) temperatures are reported. The site symmetry of the ion is found to be C_4ν. Correlating the optical and ESR spectral data, the molecular orbital coefficients are evaluated.     

Excited state absorption in Mn2+ doped phosphate glass

The possibility of obtaining laser action from Mn²⁺ doped glass has been investigated. The excited state absorption at the expected laser wavelength was measured and explains the unsuccessful attempts to obtain laser action.     

Optical spectra of Cu2+ ions in synthetic beryl

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 53, No. 5, pp. 767–770, November, 1990.     

Far ultraviolet absorption spectrum of the K+ ion in KCl

The reflectivity of KCl has been measured up to 45 eV with synchrotron radiation extending the range of previous measurements. The absorption coefficient is compared with an ab initio calculation using an orthogonalized-plane-wave expansion for the final states of the excited electron and including excitonic and crystalline effects. The distribution of the oscillator strength and its modulations are well reproduced by the theory.     

Optical absorption studies on cobalt doped struvite

Abstract

Optical absorption spectrum of cobalt doped MgNH₄PO₄ · 6H₂O (struvite) is investigated in UV-VIS-NIR regions. The spectrum in UV-VIS-NIR region is attributed to Co²⁺ in octahedral symmetry whereas the IR spectrum is attributed to vibrations due to PO₄ ^3-, NH₄ ⁺ and H₂O. The following crystal field (Dq) and interelectronic repulsion (B, C) parameters are evaluated: Dq = 940cm^?1, B = 870cm^?1 and C = 3970cm^?1.     

Optical emission spectrum of the NO2+ dication

We recorded and rotationally analyzed a new emission band at 2563 Å obtained from a low-pressure, hot cathode and magnetically confined electric discharge through pure NO vapor. The available experimental data from photoion-fluorescence photon coincidence and translational energy loss spectroscopy, in conjunction with ab initio calculation, allowed assignment of the new band to the B²Σ⁺-X²Σ⁺ (0, 0) transition of the NO²⁺ ion.