高气压非平衡等离子体化学及应用基础研究

文章概述了气体放电、非平衡等离子体化学研究现状与发展趋势,提出了高气压非平衡等离子体新概念,应用特种新工艺实施高气压强电场（〉４００Ｔｄ）放电获得高能（〉１０ｅＶ）电子的方法,激励气体分子分解、电离成离子、原子、激发态原子（及分子）和自由基等,按预定模型合成新物质、新分子,使常规难以进行的化学反应得以进行或加速进行,高气压非平衡等离子体化学具有极其广阔的应用前景。     

(GaAs)n(n=1-4)原子链电子输运性质的理论计算

本文利用密度泛函理论结合非平衡格林函数的方法, 对 (GaAs)_n(n=1-4)直线原子链与Au(100)-3×3两半无限电极耦合构成Au-(GaAs)_n-Au纳米结点的电子输运性质进行了第一性原理计算. 在各结点拉伸过程中, 对其结构进行了优化, 得到各结点稳定平衡结构时Ga-As的平均键长分别为0.220, 0.224, 0.223, 0.223 nm, 平衡电导分别为2.328G₀, 1.167G₀, 0.639G₀, 1.237G₀; 通过对结点投影态密度的计算, 发现电子传输主要是通过Ga, As原子中p_x与p_y电子轨道相互作用形成的π键进行的. 在0-2 V的电压范围内, 对于(GaAs)_n(n=1-3)的原子链的电流随电压增大而增大, I-V曲线呈线性关系, 表现出类似金属导电行为; 对于(GaAs)₄原子链在0.6-0.7 V, 0.8-0.9 V的电压范围内却存在负微分电阻现象.     

空间多能电子辐照聚合物充电过程的稳态特性

空间同步轨道上多能电子辐照聚合物的充电过程及其稳态特性是研究和抑制通信卫星静电放电的基础.在同步电子散射-输运微观模型的基础上,采用具有10—400 keV积分能谱分布的多能电子辐照聚酰亚胺样品,进行了多能电子辐照聚酰亚胺充电过程的数值模拟,获得了空间电荷密度、空间电位、空间电场分布和聚合物样品参数条件下的表面电位和最大场强.结果表明,多能电子与样品发生散射作用并沉积在样品内形成具有高密度的电荷区域分布,同时在迁移和扩散的作用下输运至样品底部形成样品电流;充电达到稳态、电子迁移率较小时(小于10-10cm2·V-1·s-1),表面电位绝对值和充电强度随电子迁移率的降低明显加强,捕获密度较大时(大于1014cm-3),表面电位绝对值和充电强度随捕获密度的增大明显加强;聚合物样品厚度对表面电位和充电强度的影响大于电子迁移率、捕获密度和相对介电常数的影响.研究结果对于揭示空间多能电子辐照聚合物的充电现象及微观机理、提高航天器故障机理研究水平具有重要科学意义和价值.     

Quantum beating patterns observed in the energetics of Pb film nanostructures

We have studied the nanoscale structural evolution of Pb films grown at 110 K on a Si(111) substrate as they are annealed to increasingly higher temperatures. Surface x-ray diffraction from a synchrotron source is used to observe the morphology evolve from an initial smooth film through various metastable states before reaching a state of local equilibrium, at which point the coverage of different height Pb structures is analyzed and related to the thickness-dependent surface energy. Rich patterns are seen in the resulting energy landscape similar to the beating patterns heard from the interference of two musical notes of similar pitch. The explanation is, however, very simple, as demonstrated by a model calculation based on the confinement of free electrons to a quantum well.     

Coefficient of detector collection

An analytical model for the coefficient of collection for an SEM detector field is proposed. The Dirichlet problem for calculating the detector’s electrostatic field is solved. The trajectories of secondary electrons are calculated numerically. Collection efficiency diagrams for different ratios of work length to pole piece diameter are constructed. The results could be useful for linear measurements of nanoscale structures and modeling the reference signal in electron beam lithography.     

Quantum wires and quantum dots for neutral atoms

By placing changeable nanofabricated structures (wires, dots, etc.) on an atom mirror one can design guiding and trapping potentials for atoms. These potentials are similar to the electrostatic potentials which trap and guide electrons in semiconductor quantum devices like quantum wires and quantum dots. This technique will allow the fabrication of nanoscale atom optical devices. Received: 28 October 1997 / Revised: 17 February 1998 / Accepted: 17 July 1998     

Nonlinear soliton-like excitations in two-dimensional lattices and charge transport

We study soliton-like excitations and their time and space evolution in several two-dimensional anharmonic lattices with Morse interactions: square lattices including ones with externally fixed square lattice frame (cuprate model), and triangular lattices. We analyze the dispersion equations and lump solutions of the Kadomtsev-Petviashvili equation. Adding electrons to the lattice we find solectron bound states and offer computational evidence of how electrons can be controlled and transported by such acoustic waves and how electron-surfing occurs at the nanoscale. We also offer computational evidence of the possibility of long lasting, fast lattice soliton and corresponding supersonic, almost loss-free transfer or transport of electrons bound to such lattice solitons along crystallographic axes.     

Maximal Heat Generation in Nanoscale Systems

We investigate the heat generation in a nanoscale system coupled to normal leads and find that it is maximal when the average occupation of the electrons in the nanoscale system is 0.5, no matter what mechanism induces the heat generation.     

Efficient photovoltaic current generation at ferroelectric domain walls

We elucidate the mechanism of a newly observed photovoltaic effect which occurs in ferroelectrics with periodic domain structures. Under sufficiently strong illumination, domain walls function as nanoscale generators of the photovoltaic current. The steps in the electrostatic potential function to accumulate electrons and holes on opposite sides of the walls while locally reducing the concentration of the oppositely charged carriers. As a result, the recombination rate adjacent to the walls is reduced, leading to a net diffusion current. In open circuit, photovoltages for periodically ordered domain walls are additive and voltages much larger than the band gap can be generated. The internal quantum efficiency for individual domain walls can be surprisingly high, approaching 10% for above band-gap photons. Although we have found the effect in BiFeO(3) films, it should occur in any system with a similar periodic potential.     

Particle simulation of an ultrarelativistic two-stream instability

A two-stream instability in an unmagnetized plasma is examined by a particle-in-cell simulation. Each beam initially consists of cold electrons and protons that stream at a relative Lorentz factor 100. This is representative for plasma close to the external shocks of gamma-ray bursts. An electrostatic wave develops which saturates by trapping electrons. This wave collapses and the resulting electrostatic turbulence gives an electron momentum distribution that resembles a power law with a spectral break. Some electrons reach Lorentz factors over 1000.     

短脉冲激光刻蚀加工铜材料的机制

 利用数值模拟方法,研究波长1 064 nm、脉冲宽度介于1~20 ps的激光在刻蚀铜靶时,单次脉冲作用下非平衡场刻蚀和热平衡刻蚀两种机制的竞争过程。结果表明：随着脉冲宽度的增加,刻蚀过程由非平衡电荷分离场刻蚀占主导地位转变为热平衡刻蚀起主要作用,且脉冲宽度和激光峰值功率密度增大到一定程度后,各种电子加速机制在不同时刻开始突显,电子能量分布出现多峰结构。在能量密度为15 J/cm2的激光作用下,1和5 ps脉宽对应的非平衡场刻蚀深度分别为110和101 nm,10和20 ps脉宽分别为25和18 nm。     

Silicon clathrate with an f-electron system

A novel crystal of Ba6Ce2Au4Si42 with Ba and Ce encapsulated into silicon-polyhedral clusters is self-assembled from the state of elemental mixture. Each atom in the crystal is arranged in its well-defined position with a nanoscale period, causing unique interactions between the conduction and the magnetic electrons originating from the independent sources of Ba and Ce, respectively. In this system, the long-distant magnetic f electrons can interact with each other through nanoscale spacing with isotropic three dimensionality, leading to the occurrence of a unique spontaneous spin ordering at 6.5 K.     

Nanoscale hydrophobic interaction and nanobubble nucleation

We report large-scale atomistic simulation of midrange nanoscale hydrophobic interaction, manifested by the nucleation of nanobubble between nanometer-sized hydrophobes at constrained equilibrium. When the length scale of the hydrophobes is greater than 2 nm, the nanobubble formation shows hysteresis behavior resembling the first-order transition. Calculation of the potential of mean force versus interhydrophobe distance provides a quantitative measure of the strength of the nanoscale hydrophobic interaction.     

激光等离子体相互作用的局域振荡电子加热机制

 用2.5维粒子模拟程序模拟了超强激光与等离子体的相互作用过程，发现超强激光可以通过J×B加热机制加速电子并引起电荷分离，从而产生很强的静电场并形成电场势阱，电子在静电场势阱中振荡，被多次加速，使得高速电子被甩出势阱，进而增强电荷分离，然后静电场结构被破坏，静电势能传给电子。在此过程中，电子在此阱中作局域振荡，并且被J×B机制多次加速，激光的能量会有效地传给电子，使电子能量高达10MeV。这是一种新的电子加热机制，称之为局域振荡电子加热机制。     

Nonlinear Evolution of Lower-Hybrid Drift Instability in Harris Current Sheet

We perform 2.5-dimensional particle-in-cell simulations to investigate the nonlinear evolution of the lower hybrid drift instability (LHDI) in Harris current sheet. Due to the drift motion of electrons in the electric field of the excited low hybrid drift (LHD) waves, the electrons accumulate at the outer layer, and therefore there is net positive charge at the inner edge of the current sheet. This redistribution of charge can create an electrostatic field along the z direction, which then modifies the motions of the electrons along the y direction by E×B drift. This effect strongly changes the structure of the current sheet.     

Coherent nonlinear transport in quantum rings

While equilibrium properties of mesoscopic systems are well understood, many questions are still debated concerning the non-equilibrium properties, which govern nonlinear transport. Nonlinear transport measurements have been performed on two-terminal semiconductor quantum rings in the open regime, where the rings are used as electron interferometers and show the Aharonov–Bohm effect. We observe a magnetic field asymmetry of the nonlinear conductance, compatible with the non-validity of the Onsager–Casimir relations out-of-equilibrium. In particular, the voltage-antisymmetric part of the nonlinear conductance of these two-terminal devices is not phase rigid, as it is the case for the linear conductance. We show that this asymmetry is directly related to the electronic phase accumulated by the electrons along the arms of the ring and can be tuned using an electrostatic gate.     

Observation of charge density wave solitons in overlapping tunnel junctions

We report on direct observation of microscopic solitons in single electronic processes of the coherent interlayer tunneling in charge density waves. Special nanoscale devices were fabricated from the chain compound using focused ion beams. The spectra were drastically refined by working at high (up to 27 T) magnetic fields. Internal quantum tunneling of electrons can go through solitons that are energetically more favorable quantum particles than electrons. In addition to the interband tunneling across the gap 2Delta, we observe a clear peak at the intermediate voltage approximately 2Delta/3, which we associate with the creation of microscopic solitons, the energy of which must be 2Delta/pi. These solitons might correspond to the long sought special quasiparticle--the spinon.     

Ultraintense laser-produced fast-electron propagation in gas jets

We study the propagation of fast electrons in a gas at different densities. A large relativistic electron current is produced by focusing a short-pulse ultrahigh-intensity laser on a metallic target. It then propagates in a gas jet placed behind the foil. Shadowgraphy in the gas shows an electron cloud moving at sub-relativistic average velocities. The experiment shows (i) the essential role of the density of background material for allowing propagation of fast electrons, (ii) the importance of the ionization phase which produces free electrons available for the return current, and (iii) the effect of electrostatic fields on fast-electron propagation.     

Large tunable Rashba spin splitting of a two-dimensional electron gas in Bi2Se3

We report a Rashba spin splitting of a two-dimensional electron gas in the topological insulator Bi(2)Se(3) from angle-resolved photoemission spectroscopy. We further demonstrate its electrostatic control, and show that spin splittings can be achieved which are at least an order-of-magnitude larger than in other semiconductors. Together these results show promise for the miniaturization of spintronic devices to the nanoscale and their operation at room temperature.     

Resistive Electrostatic Ion Cyclotron Instability in Plasmas

The stability of electrostatic ion cyclotron waves propagating obliquely with respect to the background magnetic field is studied for collisional, fully-ionized plasmas in which there is a relative field-aligned streaming between electrons and ions. It is found that electron-ion collisions, in conjunction with electron streaming, provides a mechanism for instability. The role of electron streaming is to supply a source of free energy and the role of electron-ion collisions is to restrict the field-aligned mobility of the electrons, thus preventing them from establishing a Boltzmann equilibrium. Ion-ion collisions and finite ion Larmor radius are found to exert a stabilizing influence. The instability is analyzed for both current-carrying plasmas and counterstreaming-beam-plasma systems.