SiO2和HfO2薄膜光学性能的椭偏光谱测量

结合XRD和原子力显微镜等方法,利用椭圆偏振光谱仪测试了单层SiO2薄膜（K9基片）和单层HfO2薄膜（K9基片）的椭偏参数,并用Sellmeier模型和Cauchy模型对两种薄膜进行拟合,获得了SiO2薄膜和HfO2薄膜在300-800nm波段内的色散关系。用X射线衍射仪确定薄膜结构,并用原子力显微镜观察薄膜的微观形貌,分析表明：SiO2薄膜晶相结构呈现无定型结构,HfO2薄膜的晶相结构呈现单斜相结构;薄膜光学常数的大小和薄膜的表面形貌有关;Sellmeier和Cauchy模型较好地描述了该波段内薄膜的光学性能,并得到薄膜的折射率和消光系数等光学常数随波长的变化规律。     

High frequency impedance spectroscopy study on Gd-doped CeO<Subscript>2</Subscript> thin films

The gadolinia-doped ceria (GDC) thin films were deposited by pulsed laser deposition. Samples with special geometry were prepared which allowed us to characterize GDC film in across-plane direction. The electrical properties of the films were investigated by means of impedance spectroscopy in the frequency range of 10 Hz to 10 GHz and 380–600 K temperature interval. The data analysis was performed by using appropriate equivalent circuit. The equivalent circuit modeled thin GDC film itself, platinum metal connections (traces) in the dielectric medium of sapphire substrate and interfaces between the film and platinum electrodes. Hence, several factors influenced the impedance spectra, namely the properties of substrate, the oxygen-ion transport in the film, ion blocking at the interface between the film and the electrode, and metal traces. The electrical properties of GDC thin films were compared with these of bulk ceramics and showed similar conductivity and dielectric permittivity values. The study also revealed that measurement data at electrical field frequencies of up to 10 GHz were particularly important to correctly estimate electrical properties of GDC thin films, because at high temperatures the electric response of GDC film shifts to high frequencies (higher than 1 MHz at 600 K). The thin film sample preparation for high frequency measurements and fitting of impedance data by using relatively simple equivalent circuit model is presented.     

Dielectric properties of ultrathin films of molecular crystals

Dielectric properties of thin films (TF) of molecular crystals, including the effect of size and the boundary surfaces were analysed using Green's function method. Polarisability of molecules in various film layers and dielectric susceptibility of TF were calculated. A comparison with crystal bulk has shown that dielectric properties of TF are strongly influenced both by the sample dimensions and by the boundary conditions.The frequency dependence of the dielectric susceptibility has also been derived. One obtains the monotonous variation for the frequencies above and below exciton band. However, for the frequencies within the exciton band there appears to be complicated, non-monotonous dependence. The relationship between the dielectric susceptibility and the film width for the same frequency shows a complex, oscillatory behaviour. Furthermore, the amplitude of these oscillations increases with increasing film width, demanding the introduction of a damping factor. Finally, the thickness dependence of dielectric susceptibility was analysed in the Cole-Cole plot.     

Barriola-Vilenkin黑洞Dirac场的广义Stefan-Boltzmann定律

利用薄膜模型研究Barriola-Vilenkin黑洞的热辐射,得到了黑洞的热辐射满足广义Stefan-Boltzmann定律的结论,导出的广义Stefan-Boltzmann系数不再是一个恒量,当截断距离以及薄膜厚度取定后,它是一个与黑洞视界附近的时空度规以及辐射粒子的径向平均泻流速率有关的比例系数.得到的Barriola-Vilenkin黑洞视界附近Dirac场的辐射能通量与薄层膜内辐射粒子的径向平均泻流速率成正比,与黑洞的质量平方成反比。     

一般加速带电带磁的动态黑洞中标量场的熵

在一般加速带电带磁的动态黑洞中,化简Klein-Gordon场方程,利用乌龟坐标变换,得到在视界面附近的辐射温度.用薄膜brick-wall模型,选择适当的截断因子和薄膜厚度,得到在视界面附近薄膜上的熵,结果表明黑洞熵与视界面积成正比. 关键词： 黑洞 Hawking温度 薄膜brick-wall模型 熵     

Characterization of heat-treated tungsten thin films using picosecond duration thermoelastic transients

Picosecond duration thermoelastic transients generated with femtosecond lasers have seen considerable use as a means to characterize sub-surface properties of thin metal films and interfaces. Frequently only the acoustic information is analyzed, because valuable information is readily available by quantifying relative changes in the observed signal, such as film thickness as determined from acoustic time-of-flight measurements. The simulations presented here model material transients in metals with a two-temperature parabolic model of thermoelasticity, which shows good agreement with experimental measurements. Simulations are conducted such that direct comparisons with experimental measurements allow determination of the relevant physical properties of the sample. Using these comparisons, the variations of the thermal conductivity of tungsten thin films that occur as a result of heat treatment are reported and the accompanying variation in the electrical conductivity is calculated.     

Electrochromic and photoluminescence properties of cobalt oxide thin films prepared by spray pyrolysis

Cobalt oxide thin films were prepared by a facile spray pyrolysis technique, using a perfume atomizer with an aqueous solution of hydrated cobalt chloride salt with a molar concentration of 0.025?M as a source of cobalt. The films were deposited onto glass substrates at temperature of 350?°C. The structural, morphological, and electrochromic properties of the obtained films were studied. It was found from X-ray diffraction analysis that the films were polycrystalline in nature with spinel-type cubic structure and preferred orientation along [111] direction. The Scanning Electron Microscopy images revealed a porous structure with the average grain size around 200?nm. The cyclic voltammetry measurements revealed that Cobalt oxide thin film is an anodically coloring electrochromic material with a transmittance variation in the visible range of 31%, and a fast response time (about 2?seconds) and a good cycling stability. These electrochromic performances make cobalt oxide thin film an attractive material for using as an anodic electrochromic material in smart windows devices. The photoluminescence spectra exhibited a strong emission in the visible region confirming the good crystallinity properties of Co₃O₄ thin films.     

Mathematical model of the dynamics of micropolar elastic thin beams. Free and forced vibrations

A method of hypotheses has been developed to construct a mathematical model of micropolar elastic thin beams. The method is based on the asymptotic properties of the solution ofan initial boundary value problem in a thin rectangle within the micropolar theory of elasticity with independent displacement and rotation fields. An applied model of the dynamics of micropolar elastic thin beams was constructed in which transverse shear strains and related strains are taken into account. The constructed dynamics model was used to solve problems of free and forced vibrations of a micropolar beam. Free vibration frequencies and modes, forced vibration amplitudes, and resonance conditions were determined. The obtained numerical calculation results show the specific features of free vibrations of thin beams. Micropolar thin beams have a free vibration frequency which is almost independent of the thin beam size, but depends only on the physical and inertial properties of the micropolar material. It is shown for the micropolar material that the free vibration frequency values of beams can be readily adjusted and hence a large vibration frequency separation can be achieved, which is important for studying resonance.     

电子束蒸发和离子束溅射HfO_2紫外光学薄膜

HfO2薄膜在紫外光学中具有十分重要的地位,不同方法制备的HfO2薄膜特性不同,可以满足不同的实际应用需求。本文分别利用电子束蒸发和离子束溅射方法制备了用于紫外光区域的HfO2薄膜,并对薄膜的材料和光学特性进行了表征与比较。通过对单层HfO2薄膜的实测透射和反射光谱进行数值反演,得到了HfO2薄膜在230～800 nm波段的折射率和消光系数色散曲线,结果表明两种方法制备的HfO2薄膜在250nm的消光系数均小于2×10-3。在此基础上,制备了两种典型的紫外光学薄膜元件(紫外低通滤波器和240nm高反射镜),其光谱性能测试结果表明,两种不同方法制备的器件均具有较好的光学特性。     

Investigation of material properties of thin copper films through finite element modelling of microindentation test

Technology processes of thin metal films deposition are entailed with changes in material’s microstructure. As a result, deposited films often are characterized with material properties, which are different from these of the original bulk material. Determination of these material characteristics is of big importance for practice. In the present work the material properties of thin bright copper film with known depth were investigated. The film was deposited electrochemically over substratum composed of metallurgic brass alloy (CuZn36). Based on the results from microindentation test the load-displacement curve is obtained after the indenter is unloaded and the imprint diameter is measured. Consequently the process of indentation was modelled numerically. The numerical simulation is based on the finite element model of the indentation process. As a result of the simulation the load-displacement curve was obtained numerically for a certain set of material parameters. The trial-error approach is applied to find most appropriate set which fit the experimental load-displacement curve. At the end results, which were obtained through numerical simulation give good coincidence with the experiment. Therefore the proposed method can be successfully applied for identification of material parameters of the accepted model. The proposed trial-error approach is appropriate for investigation of thin films with known thickness, deposited on a substrate with known material characteristics.     

Physical properties of high performance fluoride ion conductor BaSnF4 thin films by pulsed laser deposition

This article presents the results on the growth and characterization of BaSnF₄ thin films on glass substrates prepared by pulsed laser deposition technique. The structural results of BaSnF₄ thin film carried out by glancing angle X-ray diffraction technique indicates the formation of the film with similar structure (tetragonal, P₄/nmm) to the bulk target material. The absorption coefficient and band gap of the film is determined by suitable analysis of the transmittance spectra. The transport properties of the thin films are studied using impedance spectroscopy in the temperature range of 323–573 K. The frequency-dependent imaginary part of impedance plot shows that the conductivity relaxation is non-Debye in nature. The scaling behavior of the imaginary part of impedance at various frequencies indicates temperature-independent relaxation behavior.     

球对称动态黑洞Dirac场的熵的再讨论

采用新的广义乌龟坐标变换，利用薄膜brick-wall模型.讨论了球对称动态黑洞Driac场的Hawking温度和熵，由于k因子的变化，使Hawking温度有一定影响，而截断因子不再因时空结构不同而异，变得与稳态情况相同. 关键词： 广义乌龟坐标变换 薄膜brick-wall模型 Driac场 熵     

Grain boundary potential and charge density at grain boundaries of chemically prepared thin silver sulfide films

The grain boundary potential and interface state charge density at the grain boundaries of silver sulfide (Ag₂S) thin films prepared by chemical conversion of cadmium sulfide (CdS) films have been determined from the dc resistance of the material and are found to be sensitive to annealing. A reduction in the grain boundary potential and the grain boundary charge density of the film has been noticed when the source CdS film is annealed at different temperatures prior to chemical conversion. The variation in the grain boundary charge density of the grown Ag₂S film with source annealing temperature has been found to be similar to that of thin cadmium sulfide film, reported earlier. An additional low temperature heat treatment of the sample results in an enhancement in the charge density at the grain boundaries. The change in the silver vacancy and/or oxygen and sulfur content of the films as revealed from the energy dispersive spectra of the films suggests possible role of film composition on the grain boundary charge density.     

Influence of Surface Transition Layers on Phase Transformation and Pyroelectric Properties of Ferroelectric Thin Film

Taking into account surface transition layers （STLs）, we study the phase transformation and pyroelectric properties of ferroelectric thin films by employing the transverse Ising model （TIM） in the framework of the mean field approximation. The distribution functions representing the intra-layer and inter-layer couplings between the two nearest neighbour pseudo-spins are introduced to characterize STLs. Compared with the results obtained by the traditional treatments for the thin films using only the single surface transition layer （SSL）, it is shown that the STL model reflects a more realistic and comprehensive situation of films. The effects of various parameters on the phase transformation properties have shown that STL can make the Curie temperature of the film higher or lower than that of the corresponding Sulk material, and the thickness of STL is a key factor influencing the film properties. For a film with definite thickness, there exists a critical STL thickness at which ferroelectricity will disappear when the intra-layer and inter-layer interactions are weak.     

Rheological properties of a highly confined film of a lyotropic lamellar phase

We investigated the rheological properties of a thin film of a lyotropic lamellar phase with a Dynamic Surface Forces Apparatus. The minimum thickness of the film is varied between one to several tens of layers by confining the materials between solid surfaces. The rheometric properties are measured with the application of a small harmonic compression. These properties depend clearly on the smectic order of the material. Whole mechanical properties may be easily described by taking into account interactions between membranes and motion of the dislocation line loops. In particular, it is shown that at the dynamical frequencies investigated in this study, the solvent flows between membranes which remain undeformed. Consequences and perspectives of this study will be discussed.Received: 22 April 2004, Published online: 11 August 2004PACS: 61.30.St Lyotropic phases - 61.30.Jf Defects in liquid crystals - 83.80.Qr Surfactant and micellar systems, associated polymers     

栅控电子枪中轮辐栅网截止放大系数的研究

本文首先建立轮辐栅网结构模型, 分区计算其屏蔽系数和单个栅格内栅丝半径与该栅格面积之比, 结合 Spangenberg书中的结论给出了轮辐栅网截止放大系数的新表达式, 然后详细地研究了栅丝半径、各环区所对球心角以及径向栅丝数目对截止放大系数的影响, 并计算了温度升高之后截止放大系数的变化, 最后给出了设计轮辐栅网的步骤和具体实例. 结果显示, 根据新表达式设计的栅网具有更好的稳定性和可靠性, 能够很好地解决平板正方形栅格近似中存在的问题.     

Radiation Energy Flux and Radiation Power of Schwarzschild Black Hole

Applying the entropy density near the event horizon, we obtained the result that the radiation energy flux of the black hole is always proportional to the quartic of the temperature of its event horizon. That is to say, the thermal radiation of the black hole always satisfies the generalized Stefan–Boltzmann law. The derived generalized Stefan–Boltzmann coefficient is no longer a constant. When the cut-off distance and the thin film thickness are both fixed, it is a proportional coefficient which is related to the black hole mass, the kinds of radiation particles and space–time metric near the event horizon. In this paper, we have put forward a thermal particle model in curved space–time. By this model, the result has been obtained that when the thin film thickness and the cut-off distance are both fixed, the radiation energy flux received by observer far away from the Schwarzschild black hole is proportional to the average radial effusion velocity of the radiation particles in the thin film, and inversely proportional to the square of the distance between the observer and the black hole.     

Raman scattering of polycrystalline GaSb thin films grownby co-evapouration process

<正>This paper reports that GaSb thin films have been co-deposited on soda-lime glass substrates.The GaSb thin film structural properties are characterized by Raman spectroscopy.The Sb-A_1g/GaSb-TO ratio decreases rapidly with the increase of substrate temperature,which suggests a small amount of crystalline Sb in the GaSb thin film and suggests that Sb atoms in the thin film decrease.In Raman spectra,the transverse optical（TO） mode intensity is stronger than that of the longitudinal optical（LO） mode,which indicates that all the samples are disordered.The LO/TO intensity ratio increases with increasing substrate temperature which suggests the improved polycrystalline quality of the GaSb thin film.A downshift of the TO and LO frequencies of the polycrystalline GaSb thin film to single crystalline bulk GaSb Raman spectra is also observed.The uniaxial stress in GaSb thin film is calculated and the value is around 1.0 GPa.The uniaxial stress decreases with increasing substrate temperature.These results suggest that a higher substrate temperature is beneficial in relaxing the stress in GaSb thin film.     

Finite element modeling of the deformation of magnetoelastic film

Recently a new class of biocompatible elastic polymers loaded with small ferrous particles, a magnetoelastic polymer, has been developed. This engineered material is formed into a thin film using spin casting. An applied magnetic field will deform the film. The magnetic deformation of this film has many possible applications, particularly in microfluidic pumps and pressure regulators. In this paper a finite element method suitable for the transient simulation of arbitrarily shaped three-dimensional magnetoelastic polymers subjected to time-varying magnetic fields is developed. The approach is similar to that employed in finite elment magnetohydrodynamic simulations, the key difference is a more complex hyperelastic material model. In order to confirm the validity of the approach, finite element solutions for an axially symmetric thin film are compared to an analytical solution based on the membrane (infinitely thin) approximation. For this particular problem the two approaches give qualitatively similar results and converge as the film thickness approaches zero.     

CdSe量子点滤光片尺寸、温度依赖的光学特性

为了缩小光谱仪体积使之适用于军事卫星等领域,本文将胶体量子点作为滤光材料,研究了CdSe胶体量子点滤光片的光学特性.本文采用热注入法合成出了高质量的CdSe胶体量子点,经过对苯二胺消光处理制备成CdSe胶体量子点滤光片.利用透射电子显微镜(TEM)进行样品形貌结构的表征及粒径尺寸的测量,并分别在不同温度下进行了紫外.可...