Systematic remarks on objectivity and frame-indifference,liquid crystal theory as an example

In this paper objectivity and material frame-indifference are systematically discussed, because changing the observer and changing the motion of a material with respect to an observer independent standard frame of reference have to be distinguished carefully. Objectivity and observer invariance of the physical laws and of the constitutive mappings are introduced. Semi-objectivity and objectivity of different time derivative operators are investigated. As examples, changing the observer in liquid crystal theory and changing the motion in linear heat conducting materials is considered.     

Original Article On the frame dependence and form invariance of the transport equations for the Reynolds stress tensor and the turbulent heat flux vector: its consequences on closure models in turbulence modelling

The present paper shows that the transport equations governing second order turbulent closures are form invariant, but remain frame dependent through the emergence of the body force; thus they do not fulfil the principle of material frame indifference as formulated by Truesdell & Noll (1965). However, this frame dependence corresponds to that first discussed by Müller (1972) and today developed in the framework of the new concept of extended thermodynamics. Following this new concept, these relations are consequently incorporated as additional basic balance laws. The results are: 1) in the case of the Reynolds-stress-transport equation, this eliminates the so-called constraints imposed in [15–17, 19] on turbulence models; 2) to ensure the closure of the new set of basic balance laws, closure assumptions can then be considered as proper constitutive equations which must be restricted by the well known constitutive theory principles in extended thermodynamics. Received: April 4, 1996     

Extended thermodynamics of molecular ideal gases

The objective of extended thermodynamics of molecular ideal gases is the determination of the 17 fields ofmass density, velocity, energy density, pressure deviator, heat flux, intrinsic energy density and intrinsic heat flux. The intrinsic energy represents the rotational or the vibrational energy of the molecules. The necessary field equations are based upon balance laws and the system of equations is closed by constitutive relations which are characteristic for the gas under consideration. The generality of the constitutive relations is restricted by theprinciple of material frame indifference, and by the entropy principle. These principles reduce the constitutive coefficients of all fluxes to the thermal and caloric equation of state of the gas and provide inequalities for the transport coefficients. The transport coefficients can be related to the shear viscosity, the heat conductivity, and the coefficients of self-diffusion and attenuation of sound waves, so that the field equations become quite specific. The theory is in perfect agreement with the kinetic theory of molecular gases. It is shown that in non-equilibrium the temperature is discontinuous at thermometric walls. The dynamic pressure and the volume viscosity, are discussed and it is shown how extended thermodynamics and ordinary thermodynamics are related.     

Some theoretical considerations and experimental investigations on a constitutive law in thermoplasticity

Based on classical thermodynamics and restricted to classical continua, a general frame for the formulation of constitutive laws in thermoplasticity is sketched. Within this frame a more particular constitutive law is formulated taking into account large nonisothermal deformations with isotropic and anisotropic (kinematic) hardening, and allowing for certain deviations from the so-called normality rule. The material parameters and functions entering this law are determined for a mild carbon steel by isothermal tension-torsion tests on thin-walled tubes at different temperature levels. The separate knowledge of the influence of deformation rate is investigated since processes with large deformations at higher rates usually are nonisothermal. With respect to cyclic deformations, the given constitutive law has to be generalized.     

Scission induced by circular shear and heat conduction in an elastomeric cylinder

Constitutive equations for the thermo-mechanics of elastomeric materials generally assume that they do not undergo microstructural change. A constitutive theory is discussed here which accounts for such changes arising from continuous scission of macromolecular junctions of elastomeric networks due to deformation and high temperatures and the subsequent cross-linking of molecules into new networks with new reference states. The total stress is the superposition of the stresses in the remainder of the original network and in each subsequently formed network. Each network acts as a temperature-dependent non-linear elastic material. The interaction of this material response with inhomogeneous deformation and temperature fields is studied for finite circular shear of a cylinder. Numerical results illustrate how the mechanical response of the cylinder depends on the temperature dependence of both the scission–cross-linking process and the properties of the elastic networks.     

Continuous symmetries and constitutive laws of dissipative materials within a thermodynamic framework of relaxation: Part I: Formal aspects

An analysis of the continuous symmetries of the constitutive laws of inelastic materials written within a thermodynamical framework of relaxation is performed. This framework relies on the generalization of Gibb’s relationship outside the equilibrium of a uniform system, and the use of the fluctuation theory to model the material dissipation due to its internal microstructure change [Cunat, C., 2001. The DNLR approach and relaxation phenomena. Part I – Historical account and DNLR formalism. Mech. Time-depend. Mater. 5, 39–65]. The approach leads to a viscoelastic like formulation for small deformations, and changes gradually for finite strains towards elastoviscoplasticity (with or without damage) via a dependence of characteristic times with the loading path, in a way similar to the endochronic approach developed by Valanis [Valanis, K.C., 1975. On the fundations of the endochronic theory of viscoplasticity. Arch. Mech. 27, 857–868]. The present thermodynamic framework has been previously applied to elastoviscoplastic materials under cyclic and non-proportional loadings [Dieng, L., Abdul-Latif, A., Haboussi, M., Cunat, C., 2005b. Cyclic plasticity modeling with the distribution of non-linear relaxations approach. Int. J. Plasticity 21, 353–379]. The constitutive laws split into the state laws relating intensive variables (thermodynamics forces) to extensive-like variables, and the complementary evolution laws of the internal variables associated to the dissipative mechanisms. An interpretation of a non-equilibrium thermodynamic approach of irreversible processes in terms of an extremum principle is proposed, associated to a Lagrangian functional. It is shown that one possible choice for the Lagrangian kernel is the material derivative of the internal energy density, augmented by a complementary term that accounts for the evolution laws of the internal variables. Interpreting the material behavior during the non-equilibrium evolution as the Euler–Lagrange equations of the resulting action integral, a differential condition expressing both the local and variational symmetries encapsulated into the Lagrangian formulation is formulated. It is further shown that both symmetry conditions are fully equivalent along the optimal path corresponding to the satisfaction of the constitutive laws. In terms of both practical and methodological aspects, the predictive nature of the symmetry analysis is highlighted, as a systematic tool for the exploitation of the constitutive response. Its performance and utility are exemplified by the construction of a time–temperature equivalence principle for a dry viscous polymer (PA66); the calculated shift factor is shown to well agree with the empirical shift factor given by Williams–Landel–Ferry (WLF) expression. A systematic interpretation of the calculated symmetry groups of the constitutive laws in terms of master curves for various plastic and viscoplastic materials shall be presented in a forthcoming contribution.     

Statistical Foundations of Liquid-Crystal Theory. I: Discrete Systems of Rod-Like Molecules

We develop a mechanical theory for systems of rod-like particles. Central to our approach is the assumption that the external power expenditure for any subsystem of rods is independent of the underlying frame of reference. This assumption is used to derive the basic balance laws for forces and torques. By considering inertial forces on par with other forces, these laws hold relative to any frame of reference, inertial or noninertial. Finally, we introduce a simple set of constitutive relations to govern the interactions between rods and find restrictions necessary and sufficient for these laws to be consistent with thermodynamics. Our framework provides a foundation for a statistical mechanical derivation of the macroscopic balance laws governing liquid crystals.     

Development of constitutive laws for thermomechanical behaviors of composites containing multi-type ellipsoidal reinforcements

Composite materials are widely used in industrial applications because of their excellent properties and behaviors. While a composite material is defined as a mixture of two or more different materials, many research works in the literature dealt with composites of only two constituents, which are matrix and one type of particles. On the other hand, the theoretical research works that dealt with more than two constituents are rare. Using some additives affects the sintering behavior, the tribological behavior and the fracture mechanics behavior of composites. For example, a suitable amount of additives as sintering aids, in the sintering process, could lower the sintering temperature, enhance phase wettability and bonding strength and improve the interlaminar fracture resistance of a composite. Therefore, it is worthwhile to develop the constitutive laws that describe the behavior of such composite materials. Accordingly, the aim of this paper is to modify the previous paper, Shabana (2003) [Shabana, Y.M., 2003. Incremental constitutive equation for discontinuously reinforced composites considering reinforcement damage and thermoelastoplasticity. Computational Materials Science 28, 31–40], in order to propose constitutive laws that predict the thermomechanical behavior of composites containing multi-type ellipsoidal reinforcements. This includes reinforcements with different materials and/or different shapes that are represented by aspect ratios. These constitutive laws not only predict the macroscopic and microscopic thermoelastoplastic behaviors of composites containing multi-type ellipsoidal reinforcements, but also characterize their different overall effective properties such as modulus of elasticity, Poison’s ratio and thermal expansion coefficient in different directions. Beside this, they are applicable for porous materials and composites with multiple reinforcements and porosities of different shapes and distributions. In the present numerical analyses, composites with two, three and four constituents considering different materials and aspect ratios as well as reinforcement damage are discussed.     

Thermomechanical Multiscale Constitutive Modeling: Accounting for Microstructural Thermal Effects

In this work we present a thermomechanical multiscale constitutive model for materials with microstructure. In these materials thermal effects at microscale have an impact on the effective macroscopic stress. As a result, it turns out that the homogenized stress depends upon the macroscopic temperature and its gradient. In order to allow this interplay to be thermodynamically valid, we resort to a macroscopic extended thermodynamics whose elements are derived from the microscopic behavior using homogenization concepts. Hence, the thermodynamics implications of this new class of multiscale models are discussed. A variational approach based on the Hill–Mandel Principle of Macro-homogeneity, and which makes use of the volume averaging concept over a local representative volume element (RVE), is employed to derive the thermal and mechanical equilibrium problems at the RVE level and the corresponding homogenization expressions for the effective heat flux and stress. The material behavior at the RVE level is described through standard phenomenological constitutive models. To sum up, the novel contribution of the model presented here is that it allows to include the microscopic temperature fluctuation field, obtained from the multiscale thermal analysis, in the micro-mechanical problem at the RVE level while keeping thermodynamic consistency.     

On phase transformations in shape memory alloy materials and large deformation generalized plasticity

A new version of rate-independent generalized plasticity, suitable for the derivation of general thermomechanical constitutive laws for materials undergoing phase transformations, is proposed within a finite deformation framework. More specifically, by assuming an additive decomposition of the finite strain tensor into elastic and inelastic (transformation induced) parts and by considering the fractions of the various material phases as internal variables, a multi-phase formulation of the theory is developed. The concepts presented are applied for the derivation of a three-dimensional thermomechanical model for shape memory alloy materials. The ability of the model in simulating several patterns of the extremely complex behavior of these materials, under both monotonic and cyclic loadings, is assessed by representative numerical examples.     

材料的弹粘塑性本构关系和应力波的演化

试验表明，大多数工程材料在冲击载荷作用之下的变形一般都同时包含有可恢复的瞬态性弹性变形和不可恢复的粘滞性塑性变形，即其本构关系可以用弹粘塑性模型来描述。本文从内变量理论出发，探讨了时率相关材料的弹粘塑性本构关系的一般特性，建立了增量型的弹粘塑性本构关系的一般理论框架和普适的表达式，并且对两种最常用的本构模型——Bodner-Partom模型和Johnson-Cook模型给出了在一维应变条件下的具体形式。通过计算和讨论一维应变粘塑性靶板中冲击波的衰减机制和应力波的演化规律，特别是考察各种粘塑性本构模型中的材料参数对冲击波的衰减和应力波的演化的影响，得出了一些可以直接应用或具有一定借鉴价值的结果，为研究应力波的其他衰减机制以及在人防工程中智能防护层设计时新材料的选取奠定了基础。     

A principle of virtual work for combined electrostatic and mechanical loading of materials

The equations governing mechanics and electrostatics are formulated for a system in which the material deformations and electrostatic polarizations are arbitrary. A mechanical/electrostatic energy balance is formulated for this situation in terms of the electric enthalpy, in which the electric potential and the electric field are the independent variables, and charge and electric displacement, respectively, are the conjugate thermodynamic forces. This energy statement is presented in the form of a principle of virtual work (PVW), in which external virtual work is equated to internal virtual work. The resulting expression involves an internal material virtual work in which (1) material polarization is work-conjugate to increments of electric field, and (2) a combination of Cauchy stress, Maxwell stress and a product of polarization and electric field is work-conjugate to increments of strain. This PVW is valid for all material types, including those that are conservative and those that are dissipative. Such a virtual work expression is the basis for a rigorous formulation of a finite element method for problems involving the deformation and electrostatic charging of materials, including electroactive polymers and switchable ferroelectrics. The internal virtual work expression is used to develop the structure of conservative constitutive laws governing, for example, electroactive elastomers and piezoelectric materials, thereby determining the form of the Maxwell or electrostatic stress. It is shown that the Maxwell or electrostatic stress has a form fully constrained by the constitutive law and cannot be chosen independently of it. The structure of constitutive laws for dissipative materials, such as viscoelastic electroactive polymers and switchable ferroelectrics, is similarly determined, and it is shown that the Maxwell or electrostatic stress for these materials is identical to that for a material having the same conservative response when the dissipative processes in the material are shut off. The form of the internal virtual work is used further to develop the structure of dissipative constitutive laws controlled by rearrangement of material internal variables.     

On mechanics of saturated granular materials

A continuum theory of saturated granular materials is formulated. The basic balance laws for the solid phase as well as for the fluid phase are presented. The constitutive equations are derived and the basic equations of motion of the solid and fluid continua are obtained. Several cases of interest, such as incompressible granules saturated with liquids are discussed. It is shown that the theory contains, as its special cases, the Mohr-Coulomb criterion for a granular material as well as Darcy's law of flow through porous media.     

NEW POINTS OF VIEW ON THE NONLOCAL FIELD THEORY AND THEIR APPLICATIONS TO THE FRACTURE MECHANICS(Ⅱ)--RE-DISCUSS NONLINEAR CONSTITUTIVE EQUATIONS OF NON-LOCAL THERMOELASTIC BODIES

In this paper, nonlinear constitutive equations are deduced strictly according to the constitutive axioms of rational continuum mechanics. The existing judgments are modified and improved. The results show that the constitutive responses of nonlocal thermoelastic body are related to the curvature and higher order gradient of its material space, and there exists an antisymmetric stress whose average value in the domain occupied by thermoelastic body is equal to zero. The expressions of the antisymmetric stress and the nonlocal residuals are given. The conclusion that the directions of thermal conduction and temperature gradient are consistent is reached. In addition, the objectivity about the nonlocal residuals and the energy conservation law of nonlocal field is discussed briefly, and a formula for calculating the nonlocal residuals of energy changing with rigid motion of the spatial frame of reference is derived. Foundation item: the Natural Science Foundation of Province Jiangshu (BK97063)     

Large-strain constitutive laws for the cylindrical deformation of shells

Expressions are developed for the strain energy and stress resultants in the case of large strain-large bending cylindrical deformations of shells of non-linear materials. The deformation variables are the extension and curvature of the material reference surface. The Mooney material is used as an example where appropriate.The influence of the large deformations on the constitutive laws is evaluated. Of special interest is the effect of cross terms and of the ability to express the stress resultants as partial derivatives of the strain energy with respect to appropriate deformation variables.     

NEW POINTS OF VIEW ON THE NONLOCAL FIELD THEORY AND THEIR APPLICATIONS TO THE FRACTURE MECHANICS(Ⅱ)——RE-DISCUSS NONLINEAR CONSTITUTIVE EQUATIONS OF NONLOCAL THERMOELASTIC BODIES

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Modelling of stress softening in elastomeric materials: foundations of simple theories

This work is concerned with formulation of constitutive relations for materials exhibiting the stress softening phenomenon (known as the Mullins effect) typical observed in elastomeric and other amorphous materials during loading–reloading cycles. It is assumed that microstructural changes in such materials during the deformation process can be represented by a single scalar-valued softening variable whose evolution is accompanied by microforces satisfying their own law of balance, besides the classical laws of mechanics underlying macroscopic deformation of a material. The constitutive equations are then derived in consistency with thermodynamics of irreversible processes with the restriction to purely mechanical theory. The general form of the derived constitutive equations is subsequently simplified through introduction of additional assumptions leading to various models of the stress softening phenomenon. As an illustration of the general theory, it is shown that the so-called pseudo-elastic model proposed in the literature may be derived without an ad hoc postulate of the variational principle.     

Theory of multiphase mixtures—A thermomechanical formulation

The paper presents a theory of mixtures with the nonzero interfacial area between the constituents of the mixture. The conservation laws are physically motivated by utilizing a volume averaging procedure and by the definition of a mapping transformation. It is shown that the theory constructed in this manner is consistent with the theory of mixtures with a vanishingly small interfacial area and that a second law of thermodynamics can be assigned for each phase of the mixture. The conservation laws are examined for invariance properties with the principle of the material frame indifference, and a particular constitutive assumption is discussed. Also presented in the paper are the conservation laws in the integral form and the jump conditions for the singular surfaces in the multiphase mixture.     

An admissible form of an inelastic constitutive equation—I. General theory

From the viewpoint of irreversible thermodynamics an admissible form of rate-type constitutive equation of inelastic materials is given. The displacement gradient tensor F referred to the temporarily fixed reference frame which coincides with the Euler frame at the instant of the reference time is decomposed linearly into elastic and inelastic parts so that the procedure of formulation is simplified and clarified. The inelastic deformation rate is directly related to the internal production rate of entropy. The existence of an inelastic potential of the usual sense is not assumed, though the result can be understood to include the conventional flow theory based on an inelastic potential. An example of an elastoviscoplastic constitutive equation is given and some properties of yield surfaces are discussed.