A general approach for defining the macroscopic free energy density of saturated porous media at finite strains under non-isothermal conditions

A general approach is proposed for defining the macroscopic free energy density function (and its complement, the free enthalpy) of a saturated porous medium submitted to finite deformations under non-isothermal conditions, in the case of compressible fluid and solid constituents. Reference is made to an elementary volume treated as an ‘open system’, moving with the solid skeleton. The proposed free energy depends on the generalised strains (namely an appropriate measure of the strain of the solid skeleton and the variation in fluid mass content) and the absolute temperatures of the solid and fluid phases (which are assumed to differ from each other for the sake of generality). This macroscopic energy proves to be a potential for the generalised stresses (namely the associated measure of the total stress and the free enthalpy of the pore fluid per unit mass) and the entropies of the solid and fluid phases. In contrast with mixture theories, the resulting free energy is not the simple sum of the free energies of the single constituents. Two simplified cases are examined in detail, i.e. the semilinear theory (originally proposed for isothermal conditions and extended here to non-isothermal problems) and the linear theory. The proposed approach paves the way to the consistent non-isothermal-hyperelastic-plastic modelling of saturated porous media with a compressible fluid and solid constituents.     

Derivation of a new free energy for biological membranes

A new free energy for thin biomembranes depending on chemical composition, degree of order and membranal-bending deformations is derived in this paper. This is a result of constitutive and geometric assumptions at the three-dimensional level. The enforcement of a new symmetry group introduced in (Deseri et al., in preparation) and a 3D--2D dimension reduction procedure are among the ingredients of our methodology. Finally, the identification of the lower order term of the energy (i.e. the membranal contribution) on the basis of a bottom-up approach is performed; this relies upon standard statistical mechanics calculations. The main result is an expression of the biomembrane free energy density, whose local and non-local counterparts are weighted by different powers of the bilayer thickness. The resulting energy exhibits three striking aspects:

On consistent micromechanical estimation of macroscopic elastic energy,coherence energy and phase transformation strains for SMA materials

An apparatus of micromechanics is used to isolate the key ingredients entering macroscopic Gibbs free energy function of a shape memory alloy (SMA) material. A new self-equilibrated eigenstrains influence moduli (SEIM) method is developed for consistent estimation of effective (macroscopic) thermostatic properties of solid materials, which in microscale can be regarded as amalgams of n-phase linear thermoelastic component materials with eigenstrains. The SEIM satisfy the self-consistency conditions, following from elastic reciprocity (Betti) theorem. The method allowed expressing macroscopic coherency energy and elastic complementary energy terms present in the general form of macroscopic Gibbs free energy of SMA materials in the form of semilinear and semiquadratic functions of the phase composition. Consistent SEIM estimates of elastic complementary energy, coherency energy and phase transformation strains corresponding to classical Reuss and Voigt conjectures are explicitly specified. The Voigt explicit relations served as inspiration for working out an original engineering practice-oriented semiexperimental SEIM estimates. They are especially conveniently applicable for an isotropic aggregate (composite) composed of a mixture of n isotropic phases. Using experimental data for NiTi alloy and adopting conjecture that it can be treated as an isotropic aggregate of two isotropic phases, it is shown that the NiTi coherency energy and macroscopic phase strain are practically not influenced by the difference in values of austenite and martensite elastic constants. It is shown that existence of nonzero fluctuating part of phase microeigenstrains field is responsible for building up of so-called stored energy of coherency, which is accumulated in pure martensitic phase after full completion of phase transition. Experimental data for NiTi alloy show that the stored coherency energy cannot be neglected as it considerably influences the characteristic phase transition temperatures of SMA material.     

双面理想完整约束系统的机械能守恒律

研究双面理想完整约束系统在约束不是定常且主动力不是有势时的机械能守恒律. 建立系统的能量变化方程,给出存在机械能守恒律的充分必要条件. 分析有机械能守恒律的12种情况. 最后给出说明性算例.     

The relation between a microscopic threshold-force model and macroscopic models of adhesion

This paper continues our recent work on the relationship between discrete contact interactions at the microscopic scale and continuum contact interactions at the macroscopic scale(Hulikal et al., J. Mech. Phys. Solids 76,144–161, 2015). The focus of this work is on adhesion. We show that a collection of a large number of discrete elements governed by a threshold-force based model at the microscopic scale collectively gives rise to continuum fracture mechanics at the macroscopic scale. A key step is the introduction of an efficient numerical method that enables the computation of a large number of discrete contacts. Finally,while this work focuses on scaling laws, the methodology introduced in this paper can also be used to study roughsurface adhesion.     

Thermodynamic potential of free energy for thermo-elastic-plastic body

The procedure of derivation of thermodynamic potential of free energy (Helmholtz free energy) for a thermo-elastic-plastic body is presented. This procedure concerns a special thermodynamic model of a thermo-elastic-plastic body with isotropic hardening characteristics. The classical thermodynamics of irreversible processes for material characterized by macroscopic internal parameters is used in the derivation. Thermodynamic potential of free energy may be used for practical determination of the level of stored energy accumulated in material during plastic processing applied, e.g., for industry components and other machinery parts received by plastic deformation processing. In this paper the stored energy for the simple stretching of austenitic steel will be presented.     

The behaviour of the internal potential energy of a system of particles in a non-inertial frame

Summary The existence and behaviour of the internal potential energy of a system of particles in a noninertial frame is investigated and some useful results are obtained. A consequence of the above results which concerns the internal energy of a many-particle system is also drawn.

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Die Bedeutung der inneren potentiellen Energie yon Partikel-Systemen in einem Nicht-Inertialsystem

Übersicht Die Bedeutung der inneren potentiellen Energie von Partikel-Systemen in einem Nicht-Inertialsystem wird für ein Partikel-System untersucht. Dabei werden einige nützliche Ergebnisse erzielt und Folgerungen über die innere Energie von Mehrpartikel-Systemen abgeleitet.

     

A new free energy for plastic damage analysis

This work presents a new free energy for the ductile plastic damage analysis. The derivation here is based on the ductile plastic damage model proposed by Lemaitre and the examination of the plastic strain of a damaged material. The result given here can be used for the damage evolution law derived from the potential of dissipation.     

Inspection of free energy functions in gradient crystal plasticity

The dislocation density tensor computed as the cud of plastic distortion is regarded as a new constitutive variable in crystal plasticity. The dependence of the free energy function on the dislocation density tensor is explored starting from a quadratic ansatz. Rank one and logarithmic dependencies are then envisaged based on considerations from the statistical theory of dislocations. The rele- vance of the presented free energy potentials is evaluated from the corresponding analytical solutions of the periodic two-phase laminate problem under shear where one layer is a single crystal material undergoing single slip and the second one remains purely elastic.     

The relaxation of a double-well energy

This paper studies coherent, energy-minimizing mixtures of two linearly elastic phases with identical elastic moduli. We derive a formula for the relaxed or macroscopic energy of the system, by identifying microstructures that minimize the total energy when the volume fractions and the average strain are fixed. If the stress-free strains of the two phases are incompatible then the relaxed energy is nonconvex, with double-well structure. An optimal microstructure always exists within the class of layered mixtures. The optimal microstructure is generally not unique, however; we show how to construct a large family of optimal, sequentially laminated microstructures in many circumstances. Our analysis provides a link between the work of Khachaturyan and Roitburd in the metallurgical literature and that of Ball, James, Pipkin, Lurie, and Cherkaev in the recent mathematical literature. We close by explaining why the corresponding problem for three or more phases is fundamentally more difficult.Supported in part by ARO contract DAAL03-89-K-0039, DARPA contract F49620-87-C-0065, ONR grant N00014-88-K-0279, NSF grant DMS-8701895 and AFOSR grant 90-0090     

The free energy of mixing for n-variant martensitic phase transformations using quasi-convex analysis

The construction of effective models for materials that undergo martensitic phase transformations requires usable and accurate functional representations for the free energy density. The general representation of this energy is known to be highly non-convex; it even lacks the property of quasi-convexity. A quasi-convex relaxation, however, does permit one to make certain estimates and powerful conclusions regarding phase transformation. The general expression for the relaxed free energy is however not known in the n-variant case. Analytic solutions are known only for up to 3 variants, whereas cases of practical interests involve 7-13 variants. In this study we examine the n-variant case utilizing relaxation theory and produce a seemingly obvious but very powerful observation regarding a lower bound to the quasi-convex relaxation that makes practical evolutionary computations possible. We also examine in detail the 4-variant case where we explicitly show the relation between three different forms of the free energy of mixing: upper bound by lamination, the Reuß lower bound, and a lower estimate of the -measure bound. A discussion of the bounds and their utility is provided; sample computations are presented for illustrative purposes.     

On a framework for small-deformation viscoplasticity: free energy,microforces, strain gradients

This study develops a general theory for small-deformation viscoplasticity based on a system of microforces consistent with its own balance; a mechanical version of the second law that includes, via the microforces, work performed during viscoplastic flow; a constitutive theory that allows for dependences on plastic strain-gradients. The microforce balance and the constitutive equations—suitably restricted by the second law—are shown to be together equivalent to a flow rule that accounts for variations in free energy due to flow. When this energy is the sum of an elastic strain energy and a defect energy quadratic, isotropic, and positive definite in the plastic-strain gradients, the flow rule takes the form of a second-order parabolic PDE for the plastic strain coupled to the usual PDE arising from the standard macroscopic force balance and the elastic stress-strain relation. The classical macroscopic boundary conditions are supplemented by nonstandard boundary conditions associated with viscoplastic flow. As an aid to solution, a weak (virtual power) formulation of the nonlocal flow rule is derived.     

Characterization of a system generating a homogeneous isotropic turbulence field by free synthetic jets

A facility inspired by Hwang and Eaton (2004a, b) for generating a homogeneous isotropic turbulence was built, the objective being to study evaporating droplets in the presence of turbulence. Turbulence was produced by the mixing of six synthetic jets, in ambient atmosphere. Combined PIV and LDA techniques were used to measure the statistical turbulence properties. The turbulence produced was found to be homogeneous isotropic with a small mean flow within a domain having an average size of 50 mm × 50 mm × 50 mm. The rms fluctuations were of the order of 0.9 m/s, corresponding to a Taylor Reynolds number of 240 and an integral length scale of about 40 mm. This apparatus proved to be well suited to the study of the evaporation of droplets in a controlled turbulence field.