Micellization and Thermogelation of Poly(ether urethane)s Comprising Poly(ethylene glycol) and Poly(propylene glycol)

A series of multiblock poly(ether urethane)s comprising poly(ethylene glycol) (PEG), and poly(propylene glycol) (PPG) segments were synthesized. Their aqueous solutions exhibited thermogelling behavior at critical gelation concentrations (CGC) ranging from 8 to 12 wt%. The composition and structural information of the copolymers were studied by GPC and ¹H NMR. The critical micellization concentration (CMC) and thermodynamic parameters for micelle formation were determined at different temperatures. The temperature response of the copolymer solutions were studied and found to be associated with the composition of the copolymers.     

聚丁二酸丁二醇酯与氯醚弹性体协同增韧改性聚乳酸多元共混体系

以来源于可再生资源聚丁二酸丁二醇酯(PBS)和氯醚橡胶(ECO)作为聚乳酸(PLA)的增韧改性剂,通过熔融共混的方法制备了PLA/PBS/ECO三元共混体系。动态力学分析和扫描电子显微镜结果表明,ECO促进了PBS和PLA之间的相容性。力学性能测试表明,ECO与PBS可实现对聚乳酸基体的协同增韧: PLA/PBS/ECO(70/20/10)显示出最优的拉伸性能,断裂伸长率高达270%;PLA/PBS/ECO(70/10/20)的冲击强度提高至23.7 kJ/m²,是纯聚乳酸的12倍。结合形态结构和冲击断面形貌分析表明ECO的存在可起到增容/增韧双重作用, 与柔性PBS产生良好的协同效应,有效改善聚乳酸材料的韧性。我们的研究表明,构造PLA-柔性生物聚酯和生物基弹性体多元共混体系是一种获得高性能生物基材料简单高效的手段。     

聚甲基丙烯酸甲酯与聚醋酸乙烯酯共混的红外光谱研究

用红外光谱(FTIR)研究了聚甲基丙烯酸甲酯(PMMA)与聚醋酸乙烯酯(PVAc)共混体系相容性,在160℃以上共混体系发生相分离;分相体系与非分相体系的FTIR谱明显不同;共混体系的FTIR谱不能从两统组分红外光谱简单加和得到;结果表明大分子构象发生了变化,PMMA/PVAc体系相容可能是大分子构象熵变所致。     

PVB存在下PVC化学法脱氯化氢的研究

ＰＶＢ存在下ＰＶＣ化学法脱氯化氢的研究刘恒＊李大成陈朝珍（四川联合大学化工学院成都６１００６５）关键词聚氯乙烯，脱氯化氢，聚乙烯醇缩丁醛１９９６－０９－０８收稿，１９９７－０５－２６修回国家教育委员会留学归国人员资助费资助课题近年来在ＰＶＣ脱氯化氢制...     

聚丙烯酸/聚丙烯酰胺水溶液复合特性的研究

通过酸度、电导率、粘度、接触角的测定,研究了聚丙烯酸 (PAA) /聚丙烯酰胺 (PAM) 水溶液复合物及复合物膜的结构和性能。结果表明,酸度、温度、浓度和复合比影响PAA/PAM的复合水溶液中大分子链的构象和流体力学体积,适度的氢键作用可以形成均相的复合溶液。经过热处理和未经热处理的聚合物膜表现出了不同的亲水性能。     

掺杂聚丙炔醇及其酯的湿敏特性

聚醋酸丙炔酯;湿敏性;掺杂聚丙炔醇及其酯的湿敏特性     

Polymer-Based Superhydrophobic Coating Fabricated from Polyelectrolyte Multilayers of Poly(allylamine hydrochloride) and Poly(acrylic acid)

Superhydrophobic films mainly based on poly(allylamine hydrochloride) (PAH) and poly(acrylic acid) (PAA) polyelectrolyte multilayer have been deposited onto cleaned glass substrate by a layer-by-layer dip coating method. 3 bilayers of the PAH and PAA was directly coated onto the substrate as an underlying layer for subsequent coating. Desired surface roughness on the polyelectrolyte bilayers was created by etching the bilayers in hydrochloric acid solution so as to create the open pore having suitable size at the surface. Then, nanoparticles such as SiO₂ and TiO₂ of various sizes were deposited onto the etched polyelectrolyte bilayers. Finally, the surfaces were further modified with semifluorinated silane followed by cross-linking at 180 °C for 2 h to obtain desirable surface morphological features. The effect of etching time and addition of nanoparticles on surface morphology was investigated using an atomic force microscope (AFM). Wetting ability of the prepared film was determined by measuring water droplet contact angle using a goniometer. Adhesion between the superhydrophobic films and the substrate was evaluated by using a standard tape test method (D3359). The adhesion was improved by reducing the organic content in the films.     

Poly(dimethylsilylene-co-diphenylsilylene)

In this work several polyorganosilylenes were synthesized including homo-and copolymers containing SiMe₂ and SiPh₂ units. A Wurtz-type coupling reaction of the respective dichlorodiorganosilanes with sodium metal, varying the Ph₂SiCl₂/Me₂SiCl₂ ratio was the chosen synthesis method. Products with different characteristics for solubility, structure (cyclic or linear), composition, and molecular weight distribution could be obtained depending on the comonomer ratios employed. The polysilane derivatives were characterized by infrared spectroscopy (IR), proton nuclear magnetic resonance (¹H-NMR), and gel permeation chromatography (GPC). Valuable information related to the comonomers' reactivities was obtained, such as molecular weight distribution, composition, and relationships between yields of soluble, insoluble, and cyclic materials of each polycondensation reaction. © 1992 John Wiley & Sons, Inc.     

羧化聚苯醚／聚（苯乙烯—乙烯吡啶）共混相容性

用ＤＳＣ、ＤＭＡ研究了羧化聚苯醚（ＣＰＰＯ）／聚（苯乙烯－乙烯吡啶）（ＰＳＶＰ）共混体系的相容性，结果表明，与ＣＰＰＯ／ＰＳ体系相比，乙烯吡啶基的引入大大提高了共混相容性．这主要是由于ＣＰＰＯ中的羧基与ＰＳＶＰ中的吡啶基之间通过质子转移形成的正负离子间的相互作用，推动了两组分分子的均匀混合．     

聚β—羟基丁酸酯／聚醋酸乙烯酯共混体系的相容性与结晶行为

研究了制样过程聚β－羟基丁酸酯／聚醋酸乙烯酯共混体系的相容性和结晶行为的影响。ＤＳＣ、ＳＡＸＳ、ＰＯＭ等实验结果表明，ＰＨＢ／ＰＶＡｃ共混物经溶液成膜后处于分相的状态，ＰＶＡｃ对ＰＨＢ的结晶能力影响不大；而经融处理后，ＰＨＢ／ＰＶＡｃ共混物则处于相容的均相状态，随ＰＶＡｃ的含量含量的增加。     

脂肪族聚碳酸酯型聚氨酯/聚甲基丙烯酸甲酯互穿网络聚合物的研究

用同步法合成了聚碳酸亚丙酯聚氨酶／聚甲基丙烯酸甲醇互穿网络聚合物（PPCPU／PMMA，IPN），调节IPN中两组分配比制备出多种高聚物共混物。用DSC、TEM对IPN的研究结果表明．PPCPU／PMMA之IPN的两组分是互不相容的。同时对各种组成比的IPN材料进行力学性能测试，并用SEM对断面进行了观察，发现IPN的密度大于相应体系体积加和值。     

Shape Memory Properties in Poly(ethylene oxide)–Poly(ethylene terephthalate) Copolymers

Memory effects of several copolymers of poly(ethylene oxide) (PEO) and poly(ethylene terephthalate) (PET) were illustrated with photos, determined with shrinkage experiments and characterized by the recovery of samples to their original figures. Copolymers of appropriate composition could undertake an approximately full recovery which is tightly related to the annealing temperature at which shrinkage of samples occurs to some extent. Melting and recrystallization of PEO segments may be responsible for the memory effect. The memory properties of samples almost kept unchanged after many fatigue cycles (e.g. 15–20 cycles), which could make these copolymers useful in practical applications as novel shape memory materials. © 1997 John Wiley & Sons, Ltd.     

Effects of Surfactants on Phase Transition of Poly(N-isopropylacrylamide) and Poly(N-isopropylacrylamide-co-dimethylaminoethylmethacrylate)

The effect of surfactants on the phase transition of poly(N-isopropylacrylamide) (PNIPAM) and poly(N-isopropylacrylamide-co-dimethylaminoethylmethacrylate) (P(NIPAM-co-DMAEMA)) was extensively investigated by a turbidometry. When the concentration of cetyltrimethyl ammoniumchloride (CTAC) increased from 0.01 to 0.32%, the cloud point of PNIPAM increased from 32 to 38.5°C. When the concentration of sodium dodecyl sulfate (SDS) increased from 0.01 to 0.08%, the cloud point increased from 32.5 to 38°C. The cloud points with SDS were higher than the values obtained with CTAC. In addition, SDS suppressed the temperature sensitivity much more effectively than CTAC did. The adsorption of the ionic surfactants (CTAC, SDS) on the polymer chains may account for the increase in the cloud point. On the other hand, Tween 20 had little effect on the cloud point and the temperature sensitivity of the homopolymer, possible because it is nonionic. The effect of surfactants on the phase transition of P(NIPAM-co-DMAEMA) exhibited a trend similar to the effect on the phase transition of PNIPAM.     

制备聚(L-乳酸-co-乙醇酸）/聚D-乳酸共混物立构复合物的新方法

首次以高分子量的聚(L-乳酸-co-乙醇酸）(PLLGA）和D-聚乳酸（PDLA)［m(PLLGA) : m(PDLA)=3:1, c 50 mL·g^-1］为原料,氯仿为溶剂,等体积的甲醇为沉淀剂,于50 ℃蒸发4 h形成了PLLGA和PDLA的立构复合物（sc-PLA）,其结构和性能经XRD, DSC和TGA表征。结果表明：sc-PLA的结晶度达96.2%,热失重5%温度为342 ℃（PLLGA为304 ℃）。     

Phase Behaviour of Poly(styrene-co-methacrylic acid)/ Poly(styrene-co-N,N-dimethylacrylamide)/Poly(styrene-co-4-vinylpyridine) Ternary Blends by DSC and FTIR

Summary: we have investigated by DSC and FTIR the miscibility and phase behaviour of binary and ternary blends of different ratios of poly(styrene-co-methacrylic acid) containing 15 mol% of methacrylic acid (SMA15) with poly(styrene-co-N,N-dimethylacrylamide) containing 17 mol% of N,N,-dimethylacrylamide (SAD-17) and poly(styrene- co-4-vinylpyridine) containing 15 mol% of 4-vinylpyridine. SMA15 is miscible with both SAD17 and S4VP15 and interacts more strongly with S4VP15 than with SAD17 as evidenced by the positive deviations from linear average line observed with these blends and the appearance of new bands in the 1800–1550 cm⁻¹ region. This behaviour is known as ΔK effect. The FTIR study confirms that though the specific intermolecular interactions that occurred with each pair of the SMA15/S4VP15 and SMA15/SAD17 binary components are of different strength, they still exist in the ternary blend. Even though the three binary polymer pairs are individually miscible, the ternary system of SMA15/S4VP15/SAD17 exhibits only partial miscibility with small loop of immiscibility due to a significant ΔK effect. These results obtained by DSC and FTIR are in a fair agreement with theoretical prediction applying the Painter-Coleman association model.     

聚电解质PSS/PDDA分子沉积膜动力学

聚苯乙烯磺酸钠;;聚二烯丙基二甲基胺盐酸盐;聚电解质PSS/PDDA分子沉积膜动力学     

聚3-甲基噻吩及聚3-己基噻吩修饰钛酸盐纳米管的光电化学性能研究

采用水热法制备了钛酸盐纳米管, 并将钛酸盐纳米管制备成纳米结构电极进行光电化学研究. 钛酸盐纳米管产生阳极光电流, 具有n-型半导体特性. 结果表明, 聚3-甲基噻吩[poly(3-methylthiophene), PMeT]、聚3-己基噻吩[poly(3-hexylthiophene), P3HT]修饰钛酸盐纳米管后产生的光电流均较纯钛酸盐纳米管的光电流高, 且使产生光电流的波长向长波区移动. 钛酸盐纳米管/PMeT、钛酸盐纳米管/P3HT的光电转换效率分别达11.40%, 0.91%(未校正光子损失). 钛酸盐纳米管/PMeT的光电转换效率较钛酸盐纳米管/P3HT的光电转换效率高10.5%. 钛酸盐纳米管/PMeT、钛酸盐纳米管/P3HT中存在p-n异质结, 在一定条件下p-n异质结的存在有利于光生电子/空穴的分离.