共查询到19条相似文献,搜索用时 93 毫秒
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酯基硫醇锡PVC热稳定剂的合成 总被引:5,自引:1,他引:4
酯基硫醇锡PVC热稳定剂的合成魏荣宝*梁娅韩宝成卢世荣高铁男(天津理工学院化工系天津300191)关键词酯基硫醇锡,制备,PVC热稳定剂1996-08-20收稿,1996-12-12修回天津市自然科学基金资助项目酯基硫醇锡是70年代末开发的一类PVC... 相似文献
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稀土PVC热稳定剂作用模式及协同效应研究 总被引:3,自引:0,他引:3
稀土化合物对PVC良好的稳定作用,并存在广泛的协同效应。探索了一种计算机辅助研究稀土PVC热稳定剂作用模式及效应的方法,可以预测稳定剂的稳定效能。结果表明,在稀土硬脂酸盐及同类稳定剂中,曲线回归方程参数有效地反映了热稳定剂类型的差别;引入协同效应函数,不仅提高了回归方程的可信度,而且能反映协同效应的形成规律。 相似文献
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PVC有机锡热稳定剂的研究 总被引:8,自引:1,他引:8
双(β-烷氧羰烷基)二氯化锡与二酸、二酚、二醇、二醇通过界面缩聚反应,合成了一系列新的有机锡聚酯、聚醚、聚硫醚。新合成的聚合物可作为PVC制品的热稳定剂使用。 相似文献
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为了进一步研发性价比高且"无铅化"的稀土复合热稳定剂,研究了系列硬脂酸轻稀土盐(镧/铈/镨/钕/钐/铕/混合)与其他常用PVC热稳定(助)剂的复配效果。通过刚果红试纸法、红外光谱分析(FT-IR)、转矩流变仪等探究了复合热稳定剂对PVC性能的影响。结果表明:复合热稳定剂配方为硬脂酸轻稀土盐0.7~1.0份、硬脂酸锌0.8~0.9份、β-二酮0.3~0.6份和季戊四醇0.8~0.9份。将3份复合热稳定剂添加到100份PVC树脂中,静态及动态热稳定时间延长至100和35 min左右;动态热稳定性能和力学性能优于市售钙锌热稳定剂,与市售铅盐较接近。红外光谱分析表明复合热稳定剂可在加热初期减缓PVC氧化降解,较好地抑制初期着色,对PVC性能影响顺序为:镧组钕组混合组铈组镨组钐组铕组。 相似文献
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聚氯乙烯(PVC)的有机辅助稳定剂包括含N有机稳定剂、含P有机稳定剂、含O有机稳定剂、含S有机稳定剂等四种类型。其中含O有机稳定剂和含S有机稳定剂对改善PVC初期着色和长期稳定性效果显著,是PVC的有机辅助稳定剂发展的重要方向。文章介绍了PVC的有机辅助稳定剂的作用机理及应用进展。 相似文献
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The stability and migration product of medical PVC tubes plasticized with polyadipates were investigated by ageing in phosphate buffer at pH 1.679 and water at different temperatures. Changes in the PVC tubes were studied by water absorption, weight loss, Fourier infrared spectroscopy (FTIR), differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). The low molecular weight migration product that was released was extracted and silylanized before gas chromatography/mass spectroscopy (GC/MS) identification and quantification. After 70 days, the weight loss was less than 0.5% and only a small amount of adipic acid migrated when a tube was aged at 37°C in water and phosphate buffer (pH 1.679), and at 70°C in water after 56 days. However, when aged at 70 and 110°C, gradual deactivation of heat stabilizer after 21 days of ageing in buffer solution and separation of plasticizer from PVC matrix occurred. When the tube was aged at 110°C, significant degradation of both polyadipates and PVC were observed. Adipic acid and 1,4-butanediol monomers and oligomers of polyadipate were the major migration products from polyadipates in the water ageing solution, while only a relatively high amount of adipic acid was identified as the main product in the buffer ageing solution. 相似文献
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Ahmed M. Khalil Samira T. Rabie Ludmila Kapralkova Mahmoud A. Abd El Ghaffar 《高分子科学杂志,A辑:纯化学与应用化学》2016,53(2):96-103
Itaconamide derivatives have been prepared and investigated as photo-stabilizers for rigid PVC. We investigated their stabilizing efficiencies by testing the weight loss (%) with the amount of formed gel. The results indicated a reasonable stabilizing efficiency of these derivatives compared with commercial UV absorber; phenyl salicylate. The extent of discoloration of the photodegraded polymer was also improved in the presence of the prepared compounds. Rheological properties were studied to investigate the flow behavior with providing a vision into the mechanical behavior for the tested materials. Employing the evaluated photostabilizers reflects the reduction in the extent of cross-linking of the polymer. This implies preserving the mechanical properties of PVC. A radical mechanism is proposed to account for the stabilizing action of the investigated materials. The prepared itaconamide derivatives provide appropriate photostability and mechanical properties for a durable poly(vinyl chloride). 相似文献
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Dorel Feldman 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(8):659-667
Poly(vinyl chloride) is one of the major thermoplastics beside other commodities polymers like polyethylene and polystyrene. However, some of its main characteristics such as plasticity, thermal and photo stability are inferior to other commodity polymers. Adding nano scale inorganic fillers to poly(vinyl chloride) or other polymers in view to obtain polymer nanocomposites with superior properties has drawn the attention of many researchers in the last decades. Poly(vinyl chloride) nanocomposites are obtained mainly by in situ polymerization, solution based or mixing techniques. The resulting products show improvement of most important properties of poly(vinyl chloride) such as thermal, mechanical, rheological, flammability, antibacterial, etc. This paper presents preparation ways of poly(vinyl chloride) nanocomposites using different nano fillers and the improved properties compared with those of virgin poly(vinyl chloride). 相似文献
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The authors developed a nitrate ion-selective electrode(ISE) based on poly(vinyl chloride)(PVC) membrane with methyltrioctylammonium nitrate as a carrier and 1-decanol as a plasticizer. The performance of the nitrate-sensitive membranes was optimized by tuning the composition of components. The electrode exhibits a linear response with a Nernstian slope of (52±1.0) mV per decade for the nitrate ion concentration ranging from 5.8×10-5 mol/L to 1.0 mol/L. The electrode can be used to detect a low concentration of nitrate ions down to 3×10-5 mol/L in a pH range of 2.1-11.5 without any compensation. The advantage of the electrode includes simple preparation, short response time and good repeatability. The detection performance of the novel electrode on nitrate ions has been tested for water samples. 相似文献
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PVB存在下PVC化学法脱氯化氢的研究刘恒*李大成陈朝珍(四川联合大学化工学院成都610065)关键词聚氯乙烯,脱氯化氢,聚乙烯醇缩丁醛1996-09-08收稿,1997-05-26修回国家教育委员会留学归国人员资助费资助课题近年来在PVC脱氯化氢制... 相似文献
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T. Lewe D. Naumann G. Nowicki H. Schneider W. Tyrra Th. Gilles K.-F. Tebbe 《无机化学与普通化学杂志》1996,622(12):2009-2015
Syntheses and Properties of Some New Tris(fluorophenyl)antimony and -bismuth Compounds. Crystal Structure of Tris(2,6-difluorophenyl)bismuth (2,6-F2C6H3)3Bi, (2,4,6-F3C6H2)3Bi, and (2,6-F2C6H3)3Sb are prepared via Grignard reactions with BiBr3 and SbBr3, respectively. The syntheses and properties of the new compounds and the crystal structure of (2,6-F2C6H3)3Bi are described. From the reaction of BiBr3 with Ag(OCOC6H3F2) the bismuth benzoate Bi(OCOC6H3F2)3 is formed in 83% yield. Attempts to prepare (2,6-F2C6H3)3Bi by decarboxylation of the bismuth benzoate failed. 相似文献
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A. Marongiu T. Faravelli G. Bozzano M. Dente E. Ranzi 《Journal of Analytical and Applied Pyrolysis》2003,70(2):519-553
This paper presents an initial attempt at describing poly(vinyl chloride) (PVC) thermal degradation through a semi-detailed and lumped kinetic model. A mechanism of 40 species and pseudocomponents (molecules and radicals) involved in about 250 reactions permits quite a good reproduction of the main characteristics of PVC degradation and volatilization. The presence of the two step mechanism—the first step of which corresponds to dehydrochlorination and the second to the tar release and residue char formation—are correctly predicted both in quantitative terms and in the temperature ranges. The model was validated by comparison with several thermo gravimetric analyses, both dynamic at different heating rates, and isothermal. When compared with the typical one step global apparent degradation models, the approach proposed here spans quite large operative ranges, especially when it comes to predicting product distributions. The initial results of these product predictions, even though quite preliminary, are encouraging and confirm the validity of the model. 相似文献