Impact of reinforcing filler on the dynamic moduli of elastomer compounds under shear deformation in relation to wet sliding friction

In pursuit of a better understanding of the relationship between wet sliding friction and bulk viscoelastic properties of elastomer compounds, especially the contribution from different reinforcing fillers, the linear thermorheological behavior, the nonlinear dynamic moduli under shear deformation (for strain up to about 140%), and the wet sliding friction have been characterized in detail for crosslinked compounds of low-cis polybutadiene filled with different reinforcing fillers including carbon black, graphitized carbon black, and precipitated silica. We examine the scenario of possible extra energy dissipation via higher harmonic excitation in rubber compounds coupled with dynamic deformation consisting of components at many frequencies during sliding of rubber on a rough surface. While no straightforward explanation is identified relating the observed difference in wet sliding friction arising from different fillers to the bulk viscoelastic properties, some unexpected viscoelastic features arising from the compounds are observed.     

A rheological study of shear induced crystallization

The isothermal crystallization of three isotactic polypropylene (iPP) types, with different molar mass (distributions), was studied after a well defined shear treatment of the melt at an elevated temperature and a subsequent quench to the crystallization temperature. For these experiments a standard rheometer of the cone and plate configuration was used. The development of the crystallization was monitored by dynamic oscillatory measurements. Shearing in the melt was shown to enhance subsequent crystallization at lower temperatures. Not only the total shear at constant rate is of importance, but also the chosen combination of rate and shearing time. Moreover, a pronounced influence of molar mass was detected. The exploration of the melting temperatures and times which are necessary for an erasion of the memory effects showed that the effect of shearing could not completely be erased, possibly as a consequence of mechanical degradation.     

Shear band analysis and shear moduli calibration

Strain localization is a well known phenomenon, generally associated with plastic deformation and rupture in solids, especially in geomaterials. In this process, deformation is observed to concentrate in narrow zones called shear bands. This phenomenon has been studied extensively in the last 20 years by different researchers, experimentally, theoretically and numerically. A criterion for the onset of localization can be predicted solely on the basis of the constitutive law of the material, using the so-called shear band analysis. This criterion gives the critical orientation, and the critical stress state and strain for a given loading history. An important point, already stressed by Vardoulakis in 1980, is that in particular, out-of-axes shear moduli play a central role in the criterion. These are the moduli involved in the response to a deviatoric stress increment with principal axes oriented at 45° from total stress principal axes. Out-of-axes shear moduli are difficult parameters to calibrate; common tests, with fixed principal stress and strain directions, do not provide any information on these moduli, as long as they remain homogeneous. Still, real civil engineering and environmental problems are definitely not simple axisymmetric triaxial tests; practical modeling involves complex stress paths, and need complex parameters to be calibrated. Only special tests, like compression–torsion on hollow cylinder tests, or even more complex tests can be used for shear moduli calibration. However, shear band initiation in homogeneous, fixed-axes tests does activate out-of-axes shear. Hence, it is natural that shear band analysis makes shear moduli enter into the analysis.Then, a typical inverse analysis approach can be used here: experimental observation of strain localization in triaxial tests can be used together with a proper shear band analysis for the model considered, in order to determine out-of-axes shear moduli.This approach has been used for a stiff marl in the framework of a calibration study on a set of triaxial tests. The steps of the method are presented, and the bifurcation surface in the stress space is exhibited.     

Relation between steady shear flow and dynamic rheology

Summary The relationships between steady shear flow and dynamic rheology are investigated at relatively high shear rates and frequencies. A useful empirical relationship in this region predicts that the magnitude of the complex dynamic viscosity | ^*| should be compared with the shear viscosity at equal values of frequency and shear rate (Cox-Merz-rule). Polystyrenes (PS) and Polyacrylamides (PAAm) have been investigated over a wide range of concentration and molecular weight. Only in case of PAAm/H₂O solutions we have found that the results do not coincide with Cox-Merz-rule. As far as we know this is the first time that deviations from Cox-Merz-rule were observed in a homogeneous system. A molecular interpretation is given.

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Zusammenfassung Die Beziehung zwischen der Scherviskosität und der komplexen (dynamischen) Viskosität bei relativ hohen Schergeschwindigkeiten und Frequenzen wurde untersucht. Eine geeignete empirische Beziehung in diesem Bereich sagt aus, daß der Betrag der komplexen Viskosität | ^*| mit der Scherviskosität bei gleichen Werten von Frequenz und Schergeschwindigkeit vergleichbar ist (Cox-Merz-Regel). Polystyrole (PS) and Polyacrylamide (PAAm) wurden über einen weiten Bereich der Konzentration und des Molekulargewichts untersucht. Nur im Fall der PAAm/H₂O-Lösungen wurden Abweichungen von der Cox-Merz-Regel gefunden. Soweit uns bekannt, ist es das erste Mal, daß Abweichungen von der Cox-Merz-Regel in einem homogenen System gefunden wurden. Eine molekulare Erklärung wird gegeben.

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Presented at the IUPAC 26^th International Symposium on Macromolecules, Mainz, September 17–21, 1979.

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With 4 figures and 1 table     

Comparison between the dynamic moduli of fully non-linear and quasilinear viscoelastic materials

This paper deals with the non-linear viscoelastic model with multiple hereditary integrals (MHI) in the frequency domain and the conditions that it reduces to single hereditary integral or the quasilinear viscoelastic (QLV) model. It is shown that when the higher order complex moduli are related to the first-order modulus as the MHI model reduces to the QLV model. The coefficients of quasilinearity should be real and independent of amplitude and frequency.     

A relation between shear flow material functions for a single-integral constitutive equation

This contribution suggests some relations between normal-stress differences and shear stress, both in the steady state and in the transient regimes. It shows that the general form of the BKZ-type equation can be used for the discussion of the relations between several material functions. In addition, a geometric interpretation is offered and some examples are discussed.     

A method of determining complex moduli of viscoelastic materials

A method is introduced whereby the complex moduli of viscoelastic materials may be determined in a relatively simple and accurate manner by means of calibration of the measuring system using a specimen of known properties. The appropriate data-reduction equations are presented and use of the method is demonstrated for determination of complex moduli for bovine bones over a four-octave frequency range.     

Stability of unstably stratified shear flow between parallel plates *

The linear stability of unstably stratified shear flows between two horizontal parallel plates has been investigated. The eigenvalue problem was solved numerically by making use of the expansion method in Chebyshev polynomials, and critical Rayleigh numbers were obtained accurately in the Reynolds number range of [0.01,100]. It was found that the critical Rayleigh number for two-dimensional disturbances increases with an increase of the Reynolds number. The result strongly supports previous stability analyses except for the analysis by Makino and Ishikawa (1985) in which a decrease of the critical Rayleigh number was obtained. For some cases, a discontinuity in the critical wavenumber occurs, due to the development of two extrema in the neutral stability boundary.     

Experimental validation of steady shear and dynamic viscosity relation for yield stress fluids

A common problem when studying yield stress fluids under steady shear in rotating rheometry is that of sample fracture. It is therefore preferable to work with oscillating shear, where fracture is limited. Doraiswamy et al. (1991) proposed a model for yield stress fluids that predicts the relation: ^*( _m ) = (y) between the viscosity in steady shear and the complex viscosity in dynamic shear. The present study validates this relation experimentally with both controlled stress and controlled strain, and demonstrates its limitations. Three yield stress fluids were used: a lubricating grease with lithium based soap, a thixotropic dispersion of colloidal silica in a polymer solution and a non-thixotropic aqueous gel.     

Small-diameter parallel plate rheometry: a simple technique for measuring rheological properties of glass-forming liquids in shear

The rheological characterization of glass-forming liquids is challenging due to their extreme temperature dependence and high stiffness at low temperatures. This study focuses on the special precautions that need to be taken to accommodate high sample stiffness and torsional instrument compliance in shear rheological experiments. The measurement errors due to the instrument compliance can be avoided by employing small-diameter parallel plate (SDPP) rheometry in combination of numerical instrument compliance corrections. Measurements of that type demonstrate that accurate and reliable rheological data can be obtained by SDPP rheometry despite unusually small diameter-to-gap (d/h) ratios. Specimen preparation for SDPP requires special attention, but then experiments show excellent repeatability. Advantages and some current applications of SDPP rheometry are briefly reviewed. SDPP rheometry is seen as a simple and versatile way to measure rheological properties of glass-forming liquids especially near their glass transition temperature.     

A rheological model for materials which support coexistent shear rates

In this work we study a version of the three constant differential-type Oldroyd constitutive relation which allows distinct objective time derivatives for the extra stress and the stretching. We integrate the constitutive equation and determine an equivalent history integral representation for this model for the general class of viscometric motions. For certain choices of the material parameters and initial conditions, we find that this model allows for the development of shear rate discontinuities in the flow domain as a steady viscometric flow is achieved. Correspondingly, we also give evidence that intense shear rate oscillations may occur during the transient period as an impulsively started viscometric flow in a channel tends to a steady state under a constant critical shear stress. This critical shear stress lies in an interval of values for which the material experiences the phenomenon of “flow yielding”. A qualitative comparison with experimental data is made for certain creams and greases. The material instabilities inherent in this constitutive theory for viscometric motions are suggestive of the instabilities that occur in many viscoelastic fluids such as sharkskin patterns, wavy fracture, and spurt flow.     

A three-parameter model describing the experimental relation between shear stress and shear rate for laminar flow of aqueous polymer solutions

Summary A three-parameter model is introduced to describe the shear rate — shear stress relation for dilute aqueous solutions of polyacrylamide (Separan AP-30) or polyethylenoxide (Polyox WSR-301) in the concentration range 50 wppm – 10,000 wppm. Solutions of both polymers show for a similar rheological behaviour. This behaviour can be described by an equation having three parameters i.e. zero-shear viscosity ₀, infinite-shear viscosity , and yield stress ₀, each depending on the polymer concentration. A good agreement is found between the values calculated with this three-parameter model and the experimental results obtained with a cone-and-plate rheogoniometer and those determined with a capillary-tube rheometer.

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Zusammenfassung Der Zusammenhang zwischen Schubspannung und Schergeschwindigkeit von strukturviskosen Flüssigkeiten wird durch ein Modell mit drei Parametern beschrieben. Mit verdünnten wäßrigen Polyacrylamid-(Separan AP-30) sowie Polyäthylenoxidlösungen (Polyox WSR-301) wird das Modell experimentell geprüft. Beide Polymerlösungen zeigen im untersuchten Schergeschwindigkeitsbereich von ein ähnliches rheologisches Verhalten. Dieses Verhalten kann mit drei konzentrationsabhängigen Größen, nämlich einer Null-Viskosität ₀, einer Grenz-Viskosität und einer Fließgrenze ₀ beschrieben werden. Die Ergebnisse von Experimenten mit einem Kegel-Platte-Rheogoniometer sowie einem Kapillarviskosimeter sind in guter Übereinstimmung mit den Werten, die mit dem Drei-Parameter-Modell berechnet worden sind.

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a Pa^–1 physical quantity defined by:a = {1 – ( / ₀)}/ ₀ - c l concentration (wppm) - D m capillary diameter - L m length of capillary tube - P Pa pressure drop - R m radius of capillary tube - u m s^–1 average velocity - v _r m s^–1 local axial velocity at a distancer from the axis of the tube - shear rate (–dv _r /dr) - local shear rate in capillary flow - s^–1 wall shear rate in capillary flow - Pa s dynamic viscosity - _a Pa s apparent viscosity defined by eq. [2] - ( _a ) Pa s apparent viscosity in capillary tube at a distanceR from the axis - ₀ Pa s zero-shear viscosity defined by eq. [4] - Pa s infinite-shear viscosity defined by eq. [5] - l ratior/R - kg m^– density - Pa shear stress - ₀ Pa yield stress - _r Pa local shear stress in capillary flow - _R Pa wall shear stress in capillary flow _R = (PR/2L) - _v m³ s^–1 volume rate of flow With 8 figures and 1 table     

Rarefied gas shear flow between two movable segments of parallel plates

A study is made of the two-dimensional steady-state rarefied gas flow observed between two parallel plane surfaces of finite and different length when one of the surfaces is fixed and the other moves parallel to itself at a constant velocity, while remaining within the bounds of a given segment with fixed ends (the motion is similar to that of a conveyer belt). This flow can be regarded as a twodimensional counterpart of the classical one-dimensional Couette flow. The corresponding problem is formulated in a rectangular domain for the nonlinear kinetic equation with a model collision operator and is solved by a finite-difference method for various boundary conditions. For simplicity's sake, the flow was studied under conditions such that it can be considered near-isothermal. The gas pressures on each side of the gap formed by the plates may be the same or different. If the pressures on both sides of the gap are equal, then a near-zero-gradient flow develops between the plates. In this case, the greater the plate length, the nearer the flow in the middle of the gap to one-dimensional Couette flow. The end effects are examined, together with the conditions in which the flow in the middle of the domain can be assumed to be practically one-dimensional. In the zero-gradient regime, the system operates, in general, as a pump transferring gas from one side of the gap the other. The ability to pump gas also remains if a small counterpressure exists.Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No. 3, pp. 150–155, May–June, 1995.The work was financially supported by the Russian Foundation for Fundamental Research (project No. 93-013-17928).     

Lattice Boltzmann simulations of turbulent shear flow between parallel porous walls

The effects of two parallel porous walls are investigated, consisting of the Darcy number and the porosity of a porous medium, on the behavior of turbulent shear flows as well as skin-friction drag. The turbulent channel flow with a porous surface is directly simulated by the lattice Boltzmann method （LBM）. The Darcy-Brinkman- Forcheimer （DBF） acting force term is added in the lattice Boltzmann equation to simu- late the turbulent flow bounded by porous walls. It is found that there are two opposite trends （enhancement or reduction） for the porous medium to modify the intensities of the velocity fluctuations and the Reynolds stresses in the near wall region. The parametric study shows that flow modification depends on the Darcy number and the porosity of the porous medium. The results show that, with respect to the conventional impermeable wall, the degree of turbulence modification does not depend on any simple set of param- eters obviously. Moreover, the drag in porous wall-bounded turbulent flow decreases if the Darcy number is smaller than the order of O（10-4） and the porosity of porous walls is up to 0.4.     

Determination of in-plane and out-of-plane shear moduli of composite materials

A general closed-form relationship was derived between torque and angle of twist for a prismatic composite specimen in terms of the geometric parameters and shear properties of the laminae. In the case of unidirectional laminates, relations are expressed in terms of three principal shear moduli, G₁₂, G₂₃ and G₁₃. An experimental method was developed for determining these moduli by measuring surface and edge strains with strain gages. Unidirectional coupons of graphite/epoxy and silicon carbide/glass ceramic were tested in torsion and the three shear moduli were determined in each case.     

A BEM solution to transverse shear loading of composite beams

In this paper a boundary element method is developed for the solution of the general transverse shear loading problem of composite beams of arbitrary constant cross-section. The composite beam consists of materials in contact, each of which can surround a finite number of inclusions. The materials have different elasticity and shear moduli with same Poisson’s ratio and are firmly bonded together. The analysis of the beam is accomplished with respect to a coordinate system that has its origin at the centroid of the cross-section, while its axes are not necessarily the principal ones. The transverse shear loading is applied at the shear centre of the cross-section, avoiding in this way the induction of a twisting moment. Two boundary value problems that take into account the effect of Poisson’s ratio are formulated with respect to stress functions and solved employing a pure BEM approach, that is only boundary discretization is used. The evaluation of the transverse shear stresses is accomplished by direct differentiation of these stress functions, while both the coordinates of the shear center and the shear deformation coefficients are obtained from these functions using only boundary integration. Numerical examples with great practical interest are worked out to illustrate the efficiency, the accuracy and the range of applications of the developed method. The accuracy of the proposed shear deformation coefficients compared with those obtained from a 3-D FEM solution of the ‘exact’ elastic beam theory is remarkable.     

一种考虑横向剪切变形的三角形板弯曲单元

本文从部分协调的三角形薄板弯曲单元出发,并假设横向剪切应变在单元内线性变化,提出了一种考虑横向剪切变形的具有15个自由度的三角平板弯曲单元。该单元应用于薄板和中等厚度板分析均有较高的精度,计算效率高,可用于工程中具有复杂形状的薄板和中等厚度板结构的分析。     

The relation between CDM instability and Deborah number in differential type rheological equations

Previous studies have argued that rheological equations of the differential type, such as second-order fluid models, are inadequate because they result in unstable solution after cessation of steady shear. If the sign of the viscoelastic coefficient is selected so that the storage modulus is positive, the fluid velocity increases indefinitely and the flow does not decay by viscous dissipation, in contradiction to thermodynamic laws. This study mitigates this problem by demonstrating that the solution of such equations is actually stable at low values of Deborah number De, where these equations are only valid for other reasons. In fact, second order and higher order differential type equations are applicable only if the relaxation time of the fluid is low relative to a characteristic time of the flow. The study shows how to determine the characteristic time and thus clarifies, in practical terms, the limits of the region where differential type equations can be applied.Presented at the Third European Rheology Conference and Golden Jubilee Meeting of the British Society of Rheology, Edinburgh, Sept. 3–7, 1990.     

Effect of damping on dynamic behavior of a piezothermoelastic laminate considering the effects of transverse shear

In this paper, we analyze dynamic behavior of a piezothermoelastic laminate considering the effect of damping due to interlaminar shear and the effect of transverse shear. The analytical model is a rectangular laminate composed of fiber-reinforced laminae and piezoelectric layers. The model is assumed to be a symmetric cross-ply laminate with all egdes simply supported and to be subjected to mechanical, thermal and electrical loads varying arbitrarily with time. Behavior of the laminate is analyzed based on the first-order shear deformation theory. The effect of damping due to interlaminar shear is incorporated into our analysis by introducing the interlaminar shear stresses which satisfy the Newton’s law of viscosity. Solutions of the following quantities are obtained: (1) natural frequencies of the laminate, (2) weight functions for the deflection and rotations and (3) unsteady deflection due to loads varying arbitrarily with time. Moreover, numerical examples of the solutions are shown to examine the effects of damping and transverse shear on dynamic behavior of the laminate and how the voltage applied to the laminate decreases the deflection due to mechanical or thermal loads.