Nonlinear transport in the Boltzmann limit

Formal expressions for the irreversible fluxes of a simple fluid are obtained as functionals of the thermodynamic forces and local equilibrium time correlation functions. The Boltzmann limit of the correlation functions is shown to yield expressions for the irreversible fluxes equivalent to those obtained from the nonlinear Boltzmann kinetic equation. Specifically, for states near equilibrium, the fluxes may be formally expanded in powers of the thermodynamic gradients and the associated transport coefficients identified as integrals of time correlation functions. It is proved explicitly through nonlinear Burnett order that the time correlation function expressions for these transport coefficients agree with those of the Chapman-Enskog expansion of the nonlinear Boltzmann equation. For states far from equilibrium the local equilibrium time correlation functions are determined in the Boltzmann limit and a similar equivalence to the Boltzmann equation solution is established. Other formal representations of the fluxes are indicated; in particular, a projection operator form and its Boltzmann limit are discussed. As an example, the nonequilibrium correlation functions for steady shear flow are calculated exactly in the Boltzmann limit for Maxwell molecules.Research supported in part by NSF grant PHY 76-21453.     

Numerical method based on the lattice Boltzmann model for the Fisher equation

In this paper, a lattice Boltzmann model for the Fisher equation is proposed. First, the Chapman-Enskog expansion and the multiscale time expansion are used to describe higher-order moment of equilibrium distribution functions and a series of partial differential equations in different time scales. Second, the modified partial differential equation of the Fisher equation with the higher-order truncation error is obtained. Third, comparison between numerical results of the lattice Boltzmann models and exact solution is given. The numerical results agree well with the classical ones.     

On the Convergence of the Boltzmann Equation for Semiconductors Toward the Energy Transport Model

The diffusion limit of the Boltzmann equation of semiconductors is analyzed. The dominant collisions are the elastic collisions on one hand and the electron–electron collisions with the Pauli exclusion terms on the other hand. Under a nondegeneracy hypothesis on the distribution function, a lower bound of the entropy dissipation rate of the leading term of the Boltzmann kernel for semiconductors in terms of a distance to the space of Fermi–Dirac functions is proved. This estimate and a mean compactness lemma are used to prove the convergence of the solution of the Boltzmann equation to a solution of the energy transport model.     

A lattice Boltzmann model for the generalized Burgers-Huxley equation

In this paper we develop a lattice Boltzmann model for the generalized Burgers-Huxley equation (GBHE). By choosing the proper time and space scales and applying the Chapman-Enskog expansion, the governing equation is recovered correctly from the lattice Boltzmann equation, and the local equilibrium distribution functions are obtained. Excellent agreement with the exact solution is observed, and better numerical accuracy is obtained than the available numerical result. The results indicate the present model is satisfactory and efficient. The method can also be applied to the generalized Burgers-Fisher equation and be extended to multidimensional cases.     

Burgers-Korteweg-de Vries复合方程的格子Boltzmann方法模拟

针对Burgers-Korteweg-de Vries(cBKdV)复合方程提出一种格子Boltzmann模型.通过恰当地处理色散项u_xxx并运用Chapman-Enskog展开从格子Boltzmann方程推导出宏观方程,从而得到联系微观量与宏观量的局部平衡分布函数.对不同微分方程进行数值实验,数值解与解析解非常吻合,相比于其它数值结果,该格子Boltzmann模型的数值结果更精确,说明该数值模型的高效性.     

Integrable models through representations of the hecke algebra

We present new solutions to the Yang-Baxter equation through representations of the Hecke algebra. The generators of the Hecke algebra are considered as Boltzmann weights for face models. The heights live in a graph. These models were conjectured to be integrable by Di Francesco and Zuber. We prove integrability for some of the suggested models by building explicitly the Boltzmann weights. Some relations that the Boltzmann weights satisfy and the consequence on partition functions with various boundary conditions are also discussed.     

A new hierarchy system on the basis of a “Master” Boltzmann equation for microscopic density

It is shown that Boltzmann's equation written in terms of microscopic density (namely the unaveraged Boltzmann function) has a wider range of validity as well as finer resolvability for fluctuations than the conventional Boltzmann equation governing Boltzmann's function. In fact the new Boltzmann equation for ideal gases has implications as a microscopically exact continuity equation like Klimontovich's equation for plasmas, and can be derived without invoking any statistical concepts, e.g., distribution functions, or molecular chaos. The Boltzmann equation in the older formalism is obtained by averaging this equation only under a restricted condition of the molecular chaos. The new Boltzmann equation is seen to contain information comparable with Liouville's equation, and serves as a master kinetic equation. A new hierarchy system is formulated in a certain parallelism to the BBGKY hierarchy. They are shown to yield an identical one-particle equation. The difference between the two hierarchy systems first appears in the two-particle equation. The difference is twofold. First, the present formalism includes thermal fluctuations that are missing in the BBGKY formalism. Second, the former allows us to formulate multi-time correlations as well, whereas the latter is restricted to simultaneous correlation. These two features are favorably utilized in deriving the Landau-Lifshitz fluctuation law in a most straightforward manner. Also, equations describing the nonequilibrium interaction between thermal and fluid-dynamical fluctuations are derived.     

Selfconsistent Electron Energy Distribution Functions in Non Equilibrium oxygen: Effects on the Dissociation Rate

Electron energy distribution functions (edf) in non equilibrium oxygen have been calculated by solving the Boltzmann equation coupled to a system of vibrational master equations. The results show the importance of both superelastic vibrational collisions and of the presence of oxygen atoms in affecting edf. The coupling between the Boltzmann equation and the system of vibrational master equations brings to a temporal evolution of edf, which progressively changes from a cold molecular gas situation (all molecules in the ground vibrational level) to a vibrationally excited molecular gas and finally to a gas composed by oxygen molecules and oxygen atoms. All electronic rate coefficients follow a temporal evolution. due to the corresponding evolution of edf. Finally the present results are used for discussing the dissociation rate of molecular oxygen in electrical discharges.     

Relativistic BBGKY Theory and Collision Integral of Generalized Boltzmann Equation in a Relativistic Magnetized Plasma

Usually, only Coulomb interactions between charged particles which are independent of time are considered in BBGKY theory of a nonrelativistic plasma. In relativistic case, the induced electromagnetic forces between charged particles which are dependent on time obviously should be considered. A Lorentz-covariant generalized n-time Liouville equation for classical plasma is established. A convenient form applicable to the laboratory frame of this equation is also given. The relativistic BBGKY hierarchy is developed in which both Coulomb and electromagnetic forces between particles are included. A method for solving the relativistic pair correlation equation is given in polarization approximation. A new formula for calculating collision integral in terms of discrete particle Green functions is given. A number of generalized Boltzmann equations for relativistic plasmas are derived.     

离散速度方向模型在微尺度气体流动中的应用

离散速度方向模型是一种简化Boltzmann方程的新方法。该方法通过减少Boltzmann方程的维数来降低数值求解的计算量。在DVD模型中,分子速度的方向是离散的,而分子的速率仍然是连续的,这样就可以用一组三维的速率分布函数来代替Boltzmann方程中六维的速度分布函数。由于减少了三个动量维,同Boltzmann方程相比,DVD模型的数值计算量可以降低几个数量级。本文用数值的方法对DVD模型进行了研究。数值结果显示,在广泛的Knudsen数下,DVD方法可给出精确的计算结果。同线性化Boltzmann方程的计算结果相比,最大的误差不超过6%,在连续介质领域中,误差甚至不超过1%。     

电子束泵浦氩中高能电子分布的理论计算

 改进了文献中报导的Boltzmann基本方程。与Boltzmann基本方程相比，改进后的Boltzmann方程更全面地描述了电子与基态氩原子碰撞的物理过程，并能计算出整个能量区间的电子分布。利用Boltzmann基本方程和改进的Boltzmann方程，对电子束泵浦氩中能量大于氩原子第一激发态能量(11.56eV)的高能电子分布函数进行了理论计算。计算中，选取了电子碰撞氩的微分电离截面和激发截面的解析表达式。对计算所得的稳态电子分布函数以及达到稳态分布所需的特征时间进行了分析和讨论。     

Mode coupling from linear and nonlinear kinetic equations

The calculation of mode coupling contributions to equilibrium time correlation functions from the nonlinear Boltzmann equation is reconsidered. It is suggested that the use of a nonlinear kinetic equation is not appropriate in this context, but instead such calculations should be reinterpreted in terms of the Klimontovich equation for the microscopic phase space density. For hard spheres the Klimontovich equation is formally similar to the nonlinear Boltzmann equation, and this similarity is exploited to explain the successful calculation of mode coupling effects from the latter. The relationship of the Klimontovich formulation to the linear ring approximation is also established.     

The Phonon Boltzmann Equation, Properties and Link to Weakly Anharmonic Lattice Dynamics

For low density gases the validity of the Boltzmann transport equation is well established. The central object is the one-particle distribution function, f, which in the Boltzmann-Grad limit satisfies the Boltzmann equation. Grad and, much refined, Cercignani argue for the existence of this limit on the basis of the BBGKY hierarchy for hard spheres. At least for a short kinetic time span, the argument can be made mathematically precise following the seminal work of Lanford. In this article a corresponding program is undertaken for weakly nonlinear, both discrete and continuum, wave equations. Our working example is the harmonic lattice with a weakly nonquadratic on-site potential. We argue that the role of the Boltzmann f-function is taken over by the Wigner function, which is a very convenient device to filter the slow degrees of freedom. The Wigner function, so to speak, labels locally the covariances of dynamically almost stationary measures. One route to the phonon Boltzmann equation is a Gaussian decoupling, which is based on the fact that the purely harmonic dynamics has very good mixing properties. As a further approach the expansion in terms of Feynman diagrams is outlined. Both methods are extended to the quantized version of the weakly nonlinear wave equation.The resulting phonon Boltzmann equation has been hardly studied on a rigorous level. As one novel contribution we establish that the spatially homogeneous stationary solutions are precisely the thermal Wigner functions. For three phonon processes such a result requires extra conditions on the dispersion law. We also outline the reasoning leading to Fourier’s law for heat conduction.     

Generalized Boltzmann equation for lattice gas automata

In this paper a theory is formulated that predicts velocity and spatial correlations between occupation numbers that occur in lattice gas automata violating semi-detailed balance. Starting from a coupled BBGKY hierarchy for then-particle distribution functions, cluster expansion techniques are used to derive approximate kinetic equations. In zeroth approximation the standard nonlnear Boltzmann equation is obtained; the next approximation yields the ring kinetic equation, similar to that for hard-sphere systems, describing the time evolution of pair correlations. The ring equation is solved to determine the (nonvanishing) pair correlation functions in equilibrium for two models that violate semidetailed balance. One is a model of interacting random walkers on a line, the other one is a two-dimensional fluid-type model on a triangular lattice. The numerical predictions agree very well with computer simulations.     

Nonlinear moment method for the isotropic Boltzmann equation and invariance of the collision integral

A new approach is proposed for the development of a nonlinear moment method of solving the Boltzmann equation. This approach is based on the principle of invariance of the collision integral with respect to the choice of basis functions. Sonine polynomials with a Maxwellian weighting function are taken as these basis functions for the velocity-isotropic Boltzmann equation. It is shown that for arbitrary interaction cross sections the matrix elements corresponding to the moments of the nonlinear collision integral are not independent but are coupled by simple recurrence formulas by means of which all the nonlinear matrix elements are expressed in terms of linear ones. As a result, a highly efficient numerical scheme is constructed for calculating the nonlinear matrix elements. The proposed approach opens up prospects for calculating relaxation processes at high velocities and also for solving more complex kinetic problems. Zh. Tekh. Fiz. 69, 22–29 (June 1999)     

Master equation for the density matrix and Boltzmann equation of localized electrons in crystals

A Master equation for the density matrix and a Boltzmann equation for the occupation number of electrons in a crystal are derived. The wave function of an electron is localized within a sub crystal by a superposition of the corresponding Wannier functions. The electrons are coupled to an external electrical field, to phonons, and to a particle reservoir, describing phenomena as transport, damping, and electron sources on the surface of contact.     

On computing the Chapman-Enskog functions for viscosity and heat transfer and the Burnett functions

Hermite cubic splines and collocation are used to solve, in an efficient and accurate way, the Chapman-Enskog equations for viscosity and heat transfer and to compute the Burnett functions required for Poiseuille-flow problems based on rigid-sphere collisions and the linearized Boltzmann equation.     

Transport of charged particle pulses in interplanetary magnetic fields

The charged particle scattering in the presence of a regular magnetic field is considered starting from the Boltzmann kinetic equation in the case of an arbitrary relation between the mean free path and the distance from a particle source. It is shown that the Green function for the kinetic equation can be represented as the sum of the distribution functions of non-scattered particles which propagate with the injection pitch angle and of the scattered ones. The obtained Green function of the Boltzmann equation and also the particle density describe the space-time-pitch angle cosmic ray distribution that corresponds to an instantaneous particle injection at a particular pitch angle.This work was supported by International Science Foundation (grant N UC 8000) and by Slovak Grant Agency for Science (grant No. 1353/95).