The Payne effect in finite viscoelasticity: constitutive modelling based on fractional derivatives and intrinsic time scales

As we know from experimental testing, the stiffness behaviour of carbon black-filled elastomers under dynamic deformations is weakly dependent on the frequency of deformation but strongly dependent on the amplitude. Increasing strain amplitudes lead to a decrease in the dynamic stiffness, which is known as the Payne effect. In this essay, we develop a constitutive approach of finite viscoelasticity to represent the Payne effect in the context of continuum mechanics. The starting point for the constitutive model resulting from this development is the theory of finite linear viscoelasticity for incompressible materials, where the free energy is assumed to be a linear functional of the relative Piola strain tensor. Motivated by the weak frequency dependence of the dynamic stiffness of reinforced rubber, the memory kernel of the free energy functional is of the Mittag Leffler type. We demonstrate that the model is compatible with the Second Law of Thermodynamics and equal to a fractional differential equation between the overstress of the Second Piola Kirchhoff type and the Piola strain tensor. In order to represent the dependence of the dynamic stiffness on the amplitude of strain, we replace the physical time by an intrinsic time variable. The temporal evolution of the intrinsic time is driven by an internal variable, which is a measure for the current state of the material's microstructure. The material constants of the model are estimated using a stochastic identification algorithm of the Monte Carlo type. We demonstrate that the constitutive approach pursued here represents the combined frequency and amplitude dependence of filler-reinforced rubber. In comparison with the micromechanical Kraus model developed for sinusoidal strains, the theory set out in this essay allows the representation of the stress response under arbitrary loading histories.     

Numerical simulation of Taylor impact tests

The present paper discusses some aspects in the numerical simulation of Taylor impact tests. A phenomenological internal variable theory is presented and restricted by the second law of thermodynamics. The constitutive model consists of a thermo-hyperelastic equation for the stresses and an evolution equation for the plastic internal variable. Specific thermo-plastic constitutive functions are proposed and corresponding material parameters are identified. Taylor impact tests are numerically simulated using the explicit finite element program LS-DYNA augmented by an user-defined material subroutine and the effect of variation of selected model parameters is discussed. Numerical results allow new interpretations of experimental observations and test data and gives advice on identification of material parameters in rate-dependent inelastic constitutive models.     

Time-dependent behavior of passive skeletal muscle

An isotropic three-dimensional nonlinear viscoelastic model is developed to simulate the time-dependent behavior of passive skeletal muscle. The development of the model is stimulated by experimental data that characterize the response during simple uniaxial stress cyclic loading and unloading. Of particular interest is the rate-dependent response, the recovery of muscle properties from the preconditioned to the unconditioned state and stress relaxation at constant stretch during loading and unloading. The model considers the material to be a composite of a nonlinear hyperelastic component in parallel with a nonlinear dissipative component. The strain energy and the corresponding stress measures are separated additively into hyperelastic and dissipative parts. In contrast to standard nonlinear inelastic models, here the dissipative component is modeled using an evolution equation that combines rate-independent and rate-dependent responses smoothly with no finite elastic range. Large deformation evolution equations for the distortional deformations in the elastic and in the dissipative component are presented. A robust, strongly objective numerical integration algorithm is used to model rate-dependent and rate-independent inelastic responses. The constitutive formulation is specialized to simulate the experimental data. The nonlinear viscoelastic model accurately represents the time-dependent passive response of skeletal muscle.     

基于内变量理论的一种广义粘弹性本构方程

以Ｂｉｏｔ理论为基础，将弹性应变与非弹性尖变均取作状态为量，引入耗散势，建立了一种率相关非弹性本构关系及演变方程，进而导出一种广义的粘弹性本构方程。     

A viscoplastic constitutive model with effect of aging

It is recognized experimentally that differences in plastic flow stress due to the change in strain rate of SUS304 stainless steel are found to decrease after cyclic preloadings, but minimal change is observed in relaxation properties. Therefore, viscosity function based on tensile stress–strain properties differs from that obtained from relaxation behavior. For such case, the existing visco-plastic constitutive concept, such as the so-called overstress model where only viscosity is taken into consideration, has a poor capability in predicting the time-dependent mechanical properties systematically. A new viscoplastic constitutive concept is presented to analyze the phenomenon. In the constitutive concept, the dynamic strain aging even at room temperature, as well as viscosity, are introduced as the dominant factors of the time-dependent plastic deformation. An experimental technique is proposed and some experimental results are presented to estimate the effects of aging and viscosity separately on the time-dependency of a SCM435 low alloyed steel under tensile loading. The proposed constitutive model with aging is verified for the systematical predictions of both plastic flow properties and relaxation behavior of the SCM435 low alloyed steel.     

Experimental identification and mathematical modeling of viscoplastic material behavior

Uniaxial torsion and biaxial torsion-tension experiments on thin-walled tubes were carried out to investigate the viscoplastic behavior of stainless steel XCrNi18.9. A series of monotonic tests under strain and stress control shows nonlinear rate dependence and suggests the existence of equilibrium states, which are asymptotically approached during relaxation and creep processes. Strain controlled cyclic experiments display various hardening and softening phenomena that depend on strain amplitude and mean strain. All experiments indicate that the equilibrium states within the material depend on the history of the input process, whereas the history-dependence of the relaxation and creep behavior appears less significant. From the experiments the design of a constitutive model of viscoplasticity is motivated: The basic assumption is a decomposition of the total stress into an equilibrium stress and a non-equilibrium overstress: At constant strain, the overstress relaxes to zero, where the relaxation time depends on the overstress in order to account for the nonlinear rate-dependence. The equilibrium stress is assumed to be a rate independent functional of the total strain history. Classical plasticity is utilized with a kinematic hardening rule of the Armstrong-Frederick type. In order to incorporate the amplitude-dependent hardening and softening behavior, a generalized arc length representation is applied [14]. The introduction of an additional kinematic hardening variable facilitates consideration of additional hardening effects resulting from the non-radiality of the input process. Apart from the common yield and loading criterion of classical plasticity, the proposed constitutive model does not contain any further distinction of different cases.The experimental data are sufficient to identify the material parameters of the constitutive model. The results of the identification procedure demonstrate the ability of the model to represent the observed phenomena with satisfactory approximation.     

A constitutive model in finite viscoelasticity

A new constitutive model is suggested for the viscoelastic behavior of rubber-like materials at finite strains. The model treats a viscoelastic medium as a system with a variable number of purely elastic links, which can arise and collapse due to micro-Brownian motion of molecules.Assuming that the processes of birth and death for elastic links are independent of stresses, we obtain operator linear constitutive equations in finite viscoelasticity. According to this model, elastic and viscous effects may be distinguished and described independently of each other by a relaxation measure and a strain energy density.The potential energy of deformations is assumed to depend on the principal invariants of the relative Finger tensor of strains. Unlike the standard approach, we do not suggest any expression for the strain energy densitya priori, but suppose that this function is presented as a sum of two functions of one variable which are found by fitting experimental data.The proposed approach allows results of several experiments (uniaxial tension, biaxial tension, and torsion) for styrene butadiene rubber and butyl rubber to be predicted correctly.     

A micromechanically motivated diffusion-based transient network model and its incorporation into finite rubber viscoelasticity

This paper presents the development of a physical-based constitutive model for the representation of viscous effects in rubber-like materials. The proposed model originates from micromechanically motivated diffusion processes of the highly mobile polymer chains described within the formalism of Brownian motion. Following the basic assumption of accounting for the elastic and the viscous effects in rubber viscoelasticity by their representation through a separate elastic ground network and several viscous subnetworks, respectively, the kinetic theory of rubber elasticity is followed and extended to represent also the viscous contribution in this work. It is assumed that the stretch probability of certain chain segments within an individual viscous subnetwork evolves based on the movement of the chain endpoints described by the Smoluchowski equation extended in this work from non-interacting point particles in a viscous surrounding to flexible polymer chains. An equivalent tensorial representation for this evolution is chosen which allows for the closed form solution of the macroscopic free energy and the macroscopic viscous overstress based on a homogenization over the probability space of the introduced micro-objects. The resulting model of the viscous subnetwork is subsequently combined with the non-affine micro-sphere model and applied in homogeneous and non-homogeneous tests. Finally, the model capacity is outlined based on a comparison with in the literature available experimental data sets.     

A constitutive model for carbon black filled rubber: Experimental investigations and mathematical representation

Abspract The stress-strain behavior of carbon black filled rubber is recognized to be nonlinearly elastic in its main part (see e.g. Gent [1]). In addition, inelastic effects occur under monotonic and cyclic processes. The inelastic behavior includes nonlinear rate dependence as well as equilibrium hysteresis. Moreover, the first periods of a stress-strain curve differ significantly from the shape of subsequent cycles; a characteristic feature, which is called the Mullins effect, because it has been pointed out by Mullins [2]. All inelastic phenomena are strongly influenced by the volume fraction of the filler particles (see e.g. Payne [3], So and Chen [4], Meinecke and Taftaf [5]).The aim of the present paper is to design a constitutive model, representing this kind of material behavior as a phenomenological theory of continuum mechanics. In order to motivate the basic structure of the constitutive theory, a series of uniaxial experiments between 100% in tension and 30% in compression are presented and analyzed. First of all, monotonic strain controlled experiments show the nonlinear rate dependence of the stress response. Then, a series of inserted relaxation periods at constant strain yields the monotonic equilibrium stress-strain curve, which is strongly nonlinear and unsymmetric with respect to the origin. Finally, cyclic experiments under strain control display pronounced hysteresis behavior. The hysteresis effects are mainly rate dependent, but there exists also a weak equilibrium hysteresis (compare to similar observations of Orschall and Peeken [6]). The Mullins effect corresponds to a softening phenomenon during the first few cycles. By means of an appropriate preprocess, this effect was excluded during the above experiments. Apart from the Mullins effect, neither hardening nor significant softening phenomena were observed in the context of cyclic loadings.These results motivate the structure of a constitutive model of finite strain viscoplasticity: The total stress is decomposed into an equilibrium stress and an overstress, where the overstress is a rate dependent functional of the strain history. The overstress represents the rate dependence of the material behavior and tends asymptotically to zero during relaxation processes. The nonlinearity of the rate dependence is incorporated by means of a stress dependent relaxation time. The equilibrium stress is assumed to be a rate independent functional of the strain history. For this quantity, we make use of an arclength representation, which was originally introduced by Valanis [7]. In case of vanishing equilibrium hysteresis and vanishing rate dependence our constitutive model reduces to finite strain hyperelasticity, which is the first approximation of the constitutive properties. In more general cases the main shape of a stress-strain curve is determined by hyperelasticity, superimposed by rate dependent and equilibrium hysteresis. The representation of the Mullins effect is incorporated by a continuum damage model.Some numerical simulations at the end of the paper demonstrate that the presented theory is able to represent the observed phenomena qualitatively and quantitatively with sufficient approximation.     

填充橡胶温度依赖的非弹性力学行为实验研究

填充橡胶具有复杂的非弹性力学行为,主要包括应变率依赖的粘弹性效应和变形历史依赖的Mullins效应.当前大多数对填充橡胶的实验研究集中于室温条件,针对以上问题,本论文通过单轴压缩实验系统地研究了温度对氟橡胶粘弹性和Mullins效应这两种非弹性行为的影响.首先采用多次循环加载获得了完全消除了Mullins效应的预处理试样.通过对原试样和预处理试样的单轴加卸载实验应力响应进行对比,发现Mullins效应不受变形温度和应变率的影响.通过对消除Mullins效应橡胶材料应力松弛实验结果进行分析,发现粘弹性行为不仅与变形的温度、应变率相关,还受加载应变的影响,表现为较大的加载应变会抑制氟橡胶的应力松弛.     

Simulation of damage evolution in ductile metals undergoing dynamic loading conditions

A set of constitutive equations for large rate-dependent elastic-plastic-damage materials at elevated temperatures is presented to be able to analyze adiabatic high strain rate deformation processes for a wide range of stress triaxialities. The model is based on the concepts of continuum damage mechanics. Since the material macroscopic thermo-mechanical response under large strain and high strain rate deformation loading is governed by different physical mechanisms, a multi-dissipative approach is proposed. It incorporates thermo-mechanical coupling effects as well as internal dissipative mechanisms through rate-dependent constitutive relations with a set of internal variables. In addition, the effect of stress triaxiality on the onset and evolution of plastic flow, damage and failure is discussed.Furthermore, the algorithm for numerical integration of the coupled constitutive rate equations is presented. It relies on operator split methodology resulting in an inelastic predictor-elastic corrector technique. The explicit finite element program LS-DYNA augmented by an user-defined material subroutine is used to approximate boundary-value problems under dynamic loading conditions. Numerical simulations of dynamic experiments with different specimens are performed and good correlation of numerical results and published experimental data is achieved. Based on numerical studies modified specimens geometries are proposed to be able to detect complex damage and failure mechanisms in Hopkinson-Bar experiments.     

Integral-based constitutive equation for rubber at high strain rates

High-speed experiments were conducted to characterize the deformation and failure of Styrene Butadiene Rubber at impact rates. Dynamic tensile stress–strain curves of uniaxial strip specimens and force–extension curves of thin sheets were obtained from a Charpy tensile impact apparatus. Results from the uniaxial tension tests indicated that although the rubber became stiffer with increasing strain rates, the stress–strain curves remained virtually the same above 280 s⁻¹. Above this critical strain rate, strength, fracture strain and toughness decreased with increasing strain rates. When strain rates were below 180 s⁻¹, the initial modulus, tensile strength and breaking extension increased as the strain rate increased. Between strain rates of 180 and 280 s⁻¹, the initial modulus and tensile strength increased with increasing strain rates but the extension at break decreased with increasing strain rates. A hyper-viscoelastic constitutive relation of integral form was used to describe the rate-dependent material behavior of the rubber. Two characteristic relaxation times, 5 ms and 0.25 ms, were needed to fit the proposed constitutive equation to the data. The proposed constitutive equation was implemented in ABAQUS Explicit via a user-defined subroutine and used to predict the dynamic response of the rubber sheets in the experiments. Numerical predictions for the transient deformation and failure of the rubber sheet were within 10% of experimental results.     

Application of corotational rates of the logarithmic strain in constitutive modeling of hardening materials at finite deformations

In this paper a finite deformation constitutive model for rigid plastic hardening materials based on the logarithmic strain tensor is introduced. The flow rule of this constitutive model relates the corotational rate of the logarithmic strain tensor to the difference of the deviatoric Cauchy stress and the back stress tensors. The evolution equation for the kinematic hardening of this model relates the corotational rate of the back stress tensor to the corotational rate of the logarithmic strain tensor. Using Jaumann, Green–Naghdi, Eulerian and logarithmic corotational rates in the proposed constitutive model, stress–strain responses and subsequent yield surfaces are determined for rigid plastic kinematic and isotropic hardening materials in the simple shear problem at finite deformations.     

Application of modern time integrators to Hart's inelastic model

In this paper we consider time integration of unified inelastic models. We apply two recently proposed integration schemes. One fully implicit integrator is based on backward differentiation. The other one is a combined explicit/semi-implicit Runge–Kutta algorithm of Rosenbrock-type. As an application we consider Hart's inelastic constitutive model in its uniaxial formulation. We simulate constant strain rate tension tests and relaxation tests and draw conclusions.     

Strain-rate effects in rheological models of inelastic response

Stress–strain response under constant and variable strain-rate is studied for selected models of inelastic behavior. The derived closed-form solutions for uniaxial loading enable simple evaluation of the strain-rate effects on the material response. The effect of an abrupt change of strain-rate is also examined. Non-Newtonian viscosity which decreases with an increasing strain-rate is incorporated in the analysis. Parabolic and hyperbolic hardening are used to describe the plastic response in monotonic loading. A three-dimensional generalization of an elastic–viscoplastic model is employed to study the stress relaxation in simple shear. A combined isotropic–kinematic hardening and the concept of overstress are used in the analysis. The unloading nonlinearity of the stress–strain curve is then discussed.     

Experiments and Material Parameter Identification Using Finite Elements. Uniaxial Tests and Validation Using Instrumented Indentation Tests

In this article, we focus our attention on the relation between instrumented indentation tests and the prediction by means of finite element calculations. To this end, a finite strain viscoplasticity model of Perzyna-type with non-linear isotropic and kinematic hardening is calibrated at experimental data of steel S690QL. A particular concept for conducting uniaxial tensile and compression tests is taken up in order to represent the basic rate-dependent material behavior. In this respect, an algorithmic framework of material parameter identification using finite elements is proposed leading to a two-stage procedure in the case of the underlying rate-dependent constitutive model. On the basis of the termination points of relaxation the rate-independent equilibrium stress state can be identified and all viscous parts of the model are obtained using rate-dependent loading paths. Finally, use is made of finite elements for predicting indentation experiments, which results in a critical view on modeling and parameter identification on the basis of experimental results occurring in instrumented indentation tests.     

Relaxation behavior and modeling

Load relaxation tests deliver several orders of magnitude of inelastic strain rate data while elastic strains are converted into inelastic strains [see Lemaitre and Chaboche, 1994. (Mechanics of Solid Materials, Oxford University Press, Cambridge p. 264)]. Hart used this test for providing information on the inelastic deformation behavior for modeling purposes. Characteristic relaxation curves were obtained with ductile metals and alloys at room and high temperature showing a scaling relation derived from Hart's theory. Subsequent testing with servo-controlled testing machines and strain measurement on the gage length showed that an increase of prior strain rate also increased the average relaxation rate. For relaxation tests starting in the flow stress region, the relaxation curves can be independent of the stress and strain at the start of the relaxation tests. For the modeling of these newly found relaxation behaviors and other phenomena the viscoplasticity theory based on overstress (VBO) has been introduced. It is shown that VBO admits a long-term (asymptotic) solution that can be used with sufficient accuracy for the flow stress region of the stress–strain diagram. The long-term solution predicts the observed relaxation behaviors and that the relaxation curves coincide when shifted along the stress axis. This behavior is observed for the recently obtained data and is confirmed by two sets of the Hart-type data when they are plotted according to the new method.     

Study on the rate-dependent cyclic deformation of super-elastic NiTi shape memory alloy based on a new crystal plasticity constitutive model

In this paper, a crystal plasticity based constitutive model (Yu et al., 2013) is extended to describe the rate-dependent cyclic deformation of super-elastic NiTi shape memory alloy by considering the internal heat production. Two sources of internal heat productions are included in the proposed model, i.e., the mechanical dissipations of inelastic deformation and the transformation latent heat in the NiTi shape memory alloy. With an assumption of uniform temperature field in the alloy specimen, a simplified evolution law of temperature field is obtained by the first law of thermodynamics and the heat boundary conditions. An explicit scale-transition rule is adopted to extend the proposed single crystal model to the polycrystalline version. The capability of the extended polycrystalline model to describe the rate-dependent cyclic deformation of super-elastic NiTi shape memory alloy is verified by comparing the predictions with the corresponding experimental ones. The comparison demonstrates that the proposed constitutive model considering the internal heat production predicts the rate-dependent cyclic deformation of super-elastic NiTi shape memory alloy fairly well.