共查询到20条相似文献,搜索用时 890 毫秒
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电子能量损失谱学和电子动量谱学 总被引:1,自引:0,他引:1
电子能量损失谱学和电子动量谱学经过近30年的发展已成为原子分子物理的一个重要研究领域,并在化学、聚变等离子体和凝聚态物理等方面获得重要应用.文章介绍了它们的基本原理、最新进展和应用. 相似文献
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文章简要介绍了“数字信号处理”与“数字信号处理器(DSP)”的发展历史.在数字信号处理的应用中,实时实现是非常重要的,而DSP在实时处理中,扮演了一个重要的角色.文章中还介绍了DSP在实际应用中的一些关键技术,例如DSP的种类和选型,DSP的开发工具,实时软件的开发过程等.最后,还介绍了一些DSP的应用实例,如语音编码器,视频电话和视频会议系统,用于雷达和声纳的DSP并行处理系统 相似文献
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局域化电子态集体的荧光 总被引:1,自引:0,他引:1
载流子局域化对固体材料的光电性质有着深刻的影响。长期以来,人们就发现许多固体材料的发光异常行为与固体中电子态的局域化密切相关.文章介绍了作者最近所发展的一个局域态荧光模型.借助于一个新推导出来的局域化电子态的分布函数,文章作者发展出了该模型.该模型不但定量地解释了局域态集体荧光的温度依赖的异常现象,而且清晰地揭示了异常现象背后的载流子热动力学物理.文章还介绍了该模型在一些材料的荧光数据分析中的应用。 相似文献
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调制偏振光及空间正交方位信息传递系统物理模型 总被引:3,自引:0,他引:3
受到调制的偏振光可作为方位信息的载体在空间传递,从而实现方位角度信息的传递和精密测量,这是偏振光的一个新的应用领域,在航空航天、地质测量、生物医药、军事等领域具有广泛的应用前景.文章首先介绍了调制偏振光的物理意义和空间正交方位信息传递系统的应用领域,然后介绍了利用调制偏振光进行空间正交方位信息传递系统的物理模型,并分析了一个具体实现方案. 相似文献
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国际液晶学会与活性行走的由来 总被引:2,自引:0,他引:2
国际液晶学会是作者于1990年建议成立的,活性行走的概念是作者于1992年提出的.活性行走是描述简单与复杂系统中自组织和图样形成的一个范式,已被广泛应用于自然科学和社会科学的各种系统中.文章首次给出关于国际液晶学会与活性行走创立过程的第一手资料,并介绍了活性行走的实质和意义. 相似文献
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The aim of this paper is a better comprehension of the encapsulation and interaction an anticancer drug Altretamine into BN nano ring [BNNR(9,9-5)] and AlN nano ring [AlNNR(9,9-5)]. The electronic and adsorption properties of the molecule Altretamine over the BNNR and AlNNR were theoretically studied in the solvent phase at the B3LYP/6-31G* level of theory for the first time. With the non-bonded interaction of Altretamine, the electronic properties of the BN and AlN nano-cages can be significantly changed. The electronic spectra of the Altretamine drug, complex BNNR/Altretamine and AlNNR/Altretamine in solvent water were calculated by Time Dependent Density Functional Theory (TD-DFT) for the investigation of adsorption effect. According to the natural bond orbital (NBO) results, the molecule Altretamine, BNNR and AlNNR play as both electron donor and acceptor at the complexes BNNR/Altretamine and AlNNR/Altretamine. On the other hand, the charge transfer is occurred between the bonding, antibonding or nonbonding orbitals in the molecule drug, BNNR and AlNNR. As a consequence, BNNR(9,9-5) and AlNNR(9,9-5) can be considered as a drug delivery system for the transportation of Altretamine as anticancer drug within the biological systems. 相似文献
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D. Basko G.C. La Rocca F. Bassani V.M. Agranovich 《The European Physical Journal B - Condensed Matter and Complex Systems》1999,8(3):353-362
We predict an efficient electronic energy transfer from an excited semiconductor quantum well to optically active organic
molecules of the nearby medium (substrate and/or overlayer). The energy transfer mechanism is of the F?rster type and, at
semiconductor-organic distances of about 50 ?, can easily be as fast as 10-100 ps, which is about an order of magnitude shorter
than the effective exciton lifetime in an isolated quantum well. In such conditions, the Wannier-Mott exciton luminescence
is quenched and the organic luminescence is efficiently turned on. We consider both free as well as localized quantum well
excitons discussing the dependence of the energy transfer rate on temperature and localization length. A similar mechanism
for the non-radiative energy transfer to the organic overlayer molecules from unbound electron-hole pairs excited in the 2D
continuum is shown to be much less competitive with respect to other relaxation channels inside the inorganic quantum well
(in particular, 2D exciton formation).
Received 20 July 1998 相似文献
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2-[2-(5-溴喹啉)-偶氮]-5-二乙氨基苯酚固相萃取光度法测定环境样品中镉的研究 总被引:7,自引:2,他引:5
合成了新试剂2-[2-(5-溴喹啉)-偶氮]-5-二乙氨基苯酚(5-Br-QADEAP),试剂结构通过元素分析,红外光谱和核磁共振氢谱鉴定。研究了5-Br-QADEAP与镉的显色反应,在pH 8.0的硼酸-氢氧化钠缓冲介质中,Triton X-100存在下,5-Br-QADEAP与镉反应生成2∶1稳定络合物,体系最大吸收波长λmax=595 nm,摩尔吸光系数ε=1.60×105 L·mol-1·cm-1,样品中的镉用强阴离子交换固相萃取柱固相萃取预分离和富集后用该方法测定,方法相对标准偏差在2.5%~3.2%之间,标准回收率在96%~105%,结果令人满意。 相似文献
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利用丝网印刷技术制备了基于Ru(bpy)23 (钌联吡啶)的印刷电极电致化学发光传感器,这种传感器具有制作简单、成本低、重现性好、对草酸盐的响应范围宽、检测限低等优点。详细研究了电极的制作方法以及发光试剂的固定化。在最优条件下,在pH 6.0的0.2 mol.L-1磷酸盐缓冲液中,利用所研制的ECL传感器测定C2O24-,线性响应范围为3.0×10-7~1.0×0-5mol.L-1,检测限为1.2×10-7mol.L-1(S/N=3)。根据同样的原理也可以用来测定其他的成分,如氨基酸,TprA(三丙胺),NAD(烟酰胺腺嘌呤二核苷酸)等物质。同时应该指出的是如果使用丝网印刷机器进行印刷的话,电极的重现性和稳定性还可以进一步提高。 相似文献
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Ti(SO4)2水热法制纳米SO2-4/TiO2光催化剂的光谱研究 总被引:7,自引:0,他引:7
以Ti(SO4) 2 水溶液为前驱物 ,尿素为沉淀剂 ,采用水热沉淀 加热分解 浸渍烧结法制备纳米SO2 -4/TiO2 固体超强酸光催化剂 ,并用XRD ,BET ,FTIR ,DRS和FS等对中间态粒子和产物进行表征 ,以光催化降解罗丹明B为模型反应 ,筛选制备SO2 -4/TiO2 光催化剂的优化条件。结果表明 ,用Ti(SO4) 2 为前驱物 ,水热法能在较低的温度、弱碱性介质中 ,得到纳米锐钛矿型TiO2 晶体 ;在 30 0℃下控制焙烧 4h ,基本能使水热反应副产物 (NH4) 2 SO4等分解 ,又避免H2 SO4大量的流失 ;SO2 -4负载量和烧结时间是影响SO2 -4/TiO2 光催化活性的主要因素 ,当SO2 -4负载量 11%、烧结温度 4 5 0℃时 ,制备的SO2 -4/TiO2 光催化剂活性较高 ,达P 2 5光催化剂的水平 相似文献
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R. Matzdorf 《Applied Physics A: Materials Science & Processing》1996,63(6):549-555
Lineshapes and linewidth in angle-resolved photoemission spectra from solid surfaces contain a wealth of contributions from e.g. the photohole lifetime, the lifetime of the final state electron, and from their respective interactions with phonons and lattice imperfections. In addition, finite energy and angular resolution contribute to the experimentally observed linewidths. Using photoelectron spectra from bulk and surface state transitions on copper as an example, we discuss to which extent the various contributions may be distinguished experimentally. The results indicate that relevant spectroscopic information can be directly derived from such studies at very high resolution. This will lead beyond the kinematical analysis of photoelectron data in terms of band structures and may enable us to extract quantities which refer to the dynamical properties of the many-electron system. 相似文献
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The complete structural analysis of 1-[(4-methoxyphenyl)-(3,4,5-trimethoxyphe- nyl)methyl]naphtalene 5a and 1-[(2,5-dimethoxyphenyl)-(3,4,5-trimethoxyphenyl) methyljnaphtalene 5b, prepared by alkylation of 1-[chloro-(3,4,5-trimethoxyphenyl) methyl]naphtalene without by-products such as benzofluorene 2, may be accurately determined by 1H, 13C NMR and 2D NMR analysis. 相似文献
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报道以2(3,5二氯2吡啶偶氮)5二甲氨基苯胺(简称为3,5diClPADMA)为显色剂,应用三波长叠加分光光度法测定微量钯的新方法。在002~16mol·L-1的H2SO4介质中,钯与试剂形成稳定的1∶1绿蓝色配合物,其在621和574nm有两个强弱不等的正吸收峰,在434nm处有一负吸收峰。3个峰的吸光度绝对值之和与钯浓度线性相关,钯浓度在0~12mg·L-1范围内符合比尔定律,表观摩尔吸光系数高达203×105L·mol-1·cm-1,比单波长法提高1倍。大量的有色金属及其它贵金属离子不干扰测定。所拟方法操作简便,灵敏度高,选择性好,用于钯精矿、合金及含钯分子筛中微量钯的直接测定,结果满意。 相似文献