Global Compensated Compactness Theorem for General Differential Operators of First Order

Let A ₁(x, D) and A ₂(x, D) be differential operators of the first order acting on l-vector functions ${u= (u_1, \ldots, u_l)}$ in a bounded domain ${\Omega \subset \mathbb{R}^{n}}$ with the smooth boundary ${\partial\Omega}$ . We assume that the H ¹-norm ${\|u\|_{H^{1}(\Omega)}}$ is equivalent to ${\sum_{i=1}^2\|A_iu\|_{L^2(\Omega)} + \|B_1u\|_{H^{\frac{1}{2}}(\partial\Omega)}}$ and ${\sum_{i=1}^2\|A_iu\|_{L^2(\Omega)} + \|B_2u\|_{H^{\frac{1}{2}}(\partial\Omega)}}$ , where B _i  = B _i (x, ν) is the trace operator onto ${\partial\Omega}$ associated with A _i (x, D) for i = 1, 2 which is determined by the Stokes integral formula (ν: unit outer normal to ${\partial\Omega}$ ). Furthermore, we impose on A ₁ and A ₂ a cancellation property such as ${A_1A_2^{\prime}=0}$ and ${A_2A_1^{\prime}=0}$ , where ${A^{\prime}_i}$ is the formal adjoint differential operator of A _i (i = 1, 2). Suppose that ${\{u_m\}_{m=1}^{\infty}}$ and ${\{v_m\}_{m=1}^{\infty}}$ converge to u and v weakly in ${L^2(\Omega)}$ , respectively. Assume also that ${\{A_{1}u_m\}_{m=1}^{\infty}}$ and ${\{A_{2}v_{m}\}_{m=1}^{\infty}}$ are bounded in ${L^{2}(\Omega)}$ . If either ${\{B_{1}u_m\}_{m=1}^{\infty}}$ or ${\{B_{2}v_m\}_{m=1}^{\infty}}$ is bounded in ${H^{\frac{1}{2}}(\partial\Omega)}$ , then it holds that ${\int_{\Omega}u_m\cdot v_m \,{\rm d}x \to \int_{\Omega}u\cdot v \,{\rm d}x}$ . We also discuss a corresponding result on compact Riemannian manifolds with boundary.     

Besov Space Regularity Conditions for Weak Solutions of the Navier–Stokes Equations

Consider a bounded domain ${{\Omega \subseteq \mathbb{R}^3}}$ with smooth boundary, some initial value ${{u_0 \in L^2_{\sigma}(\Omega )}}$ , and a weak solution u of the Navier–Stokes system in ${{[0,T) \times\Omega,\,0 < T \le \infty}}$ . Our aim is to develop regularity and uniqueness conditions for u which are based on the Besov space $$B^{q,s}(\Omega ):=\left\{v\in L^2_{\sigma}(\Omega ); \|v\|_{B^{q,s}(\Omega )} := \left(\int\limits^{\infty}_0 \left\|e^{-\tau A}v\right\|^s_q {\rm d} \tau\right)^{1/s}<\infty \right\}$$ with ${{2 < s < \infty,\,3 < q <\infty,\,\frac2{s}+\frac{3}{q} = 1}}$ ; here A denotes the Stokes operator. This space, introduced by Farwig et al. (Ann. Univ. Ferrara 55:89–110, 2009 and J. Math. Fluid Mech. 14: 529–540, 2012), is a subspace of the well known Besov space ${{{\mathbb{B}}^{-2/s}_{q,s}(\Omega )}}$ , see Amann (Nonhomogeneous Navier–Stokes Equations with Integrable Low-Regularity Data. Int. Math. Ser. pp. 1–28. Kluwer/Plenum, New York, 2002). Our main results on the regularity of u exploits a variant of the space ${{B^{q,s}(\Omega )}}$ in which the integral in time has to be considered only on finite intervals (0, δ ) with ${{\delta \to 0}}$ . Further we discuss several criteria for uniqueness and local right-hand regularity, in particular, if u satisfies Serrin’s limit condition ${{u\in L^{\infty}_{\text{loc}}([0,T);L^3_{\sigma}(\Omega ))}}$ . Finally, we obtain a large class of regular weak solutions u defined by a smallness condition ${{\|u_0\|_{B^{q,s}(\Omega )} \le K}}$ with some constant ${{K=K(\Omega, q)>0}}$ .     

Nondispersive solutions to the L 2-critical Half-Wave Equation

We consider the focusing L ²-critical half-wave equation in one space dimension, $$i \partial_t u = D u - |u|^2 u$$ , where D denotes the first-order fractional derivative. Standard arguments show that there is a critical threshold ${M_{*} > 0}$ such that all H ^1/2 solutions with ${\|u\|_{L^2} < M_*}$ extend globally in time, while solutions with ${\|u\|_{L^2} \geq M_*}$ may develop singularities in finite time. In this paper, we first prove the existence of a family of traveling waves with subcritical arbitrarily small mass. We then give a second example of nondispersive dynamics and show the existence of finite-time blowup solutions with minimal mass ${\|u_0\|_{L^2} = M_*}$ . More precisely, we construct a family of minimal mass blowup solutions that are parametrized by the energy E ₀ > 0 and the linear momentum ${P_0 \in \mathbb{R}}$ . In particular, our main result (and its proof) can be seen as a model scenario of minimal mass blowup for L ²-critical nonlinear PDEs with nonlocal dispersion.     

Stochastic Variational Inequalities and Applications to the Total Variation Flow Perturbed by Linear Multiplicative Noise

In this work, we introduce a new method to prove the existence and uniqueness of a variational solution to the stochastic nonlinear diffusion equation ${{\rm d}X(t) = {\rm div} \left[\frac{\nabla X(t)}{|\nabla X(t)|}\right]{\rm d}t + X(t){\rm d}W(t) {\rm in} (0, \infty) \times \mathcal{O},}$ where ${\mathcal{O}}$ is a bounded and open domain in ${\mathbb{R}^N, N \geqq 1}$ and W(t) is a Wiener process of the form ${W(t) = \sum^{\infty}_{k = 1}\mu_{k}e_{k}\beta_{k}(t), e_{k} \in C^{2}(\overline{\mathcal{O}}) \cap H^{1}_{0}(\mathcal{O}),}$ and ${\beta_{k}, k \in \mathbb{N}}$ are independent Brownian motions. This is a stochastic diffusion equation with a highly singular diffusivity term. One main result established here is that for all initial conditions in ${L^2(\mathcal{O})}$ , it is well posed in a class of continuous solutions to the corresponding stochastic variational inequality. Thus, one obtains a stochastic version of the (minimal) total variation flow. The new approach developed here also allows us to prove the finite time extinction of solutions in dimensions ${1\leqq N \leqq3}$ , which is another main result of this work.     

Incompressible 3D Navier–Stokes Equations as a Limit of a Nonlinear Parabolic System

In this paper, we consider the Cauchy problem for a nonlinear parabolic system ${u^\epsilon_t - \Delta u^\epsilon + u^\epsilon \cdot \nabla u^\epsilon + \frac{1}{2}u^\epsilon\, {\rm div}\, u^\epsilon - \frac{1}{\epsilon}\nabla\, {\rm div}\, u^\epsilon = 0}$ in ${\mathbb {R}^3 \times (0,\infty)}$ with initial data in Lebesgue spaces ${L^2(\mathbb {R}^3)}$ or ${L^3(\mathbb {R}^3)}$ . We analyze the convergence of its solutions to a solution of the incompressible Navier?CStokes system as ${\epsilon \to 0}$ .     

Generalized Resolvent Estimates of the Stokes Equations with First Order Boundary Condition in a General Domain

In this paper, we prove unique existence of solutions to the generalized resolvent problem of the Stokes operator with first order boundary condition in a general domain ${\Omega}$ of the N-dimensional Eulidean space ${\mathbb{R}^N, N \geq 2}$ . This type of problem arises in the mathematical study of the flow of a viscous incompressible one-phase fluid with free surface. Moreover, we prove uniform estimates of solutions with respect to resolvent parameter ${\lambda}$ varying in a sector ${\Sigma_{\sigma, \lambda_0} = \{\lambda \in \mathbb{C} \mid |\arg \lambda| < \pi-\sigma, \enskip |\lambda| \geq \lambda_0\}}$ , where ${0 < \sigma < \pi/2}$ and ${\lambda_0 \geq 1}$ . The essential assumption of this paper is the existence of a unique solution to a suitable weak Dirichlet problem, namely it is assumed the unique existence of solution ${p \in \hat{W}^1_{q, \Gamma}(\Omega)}$ to the variational problem: ${(\nabla p, \nabla \varphi) = (f, \nabla \varphi)}$ for any ${\varphi \in \hat W^1_{q', \Gamma}(\Omega)}$ . Here, ${1 < q < \infty, q' = q/(q-1), \hat W^1_{q, \Gamma}(\Omega)}$ is the closure of ${W^1_{q, \Gamma}(\Omega) = \{ p \in W^1_q(\Omega) \mid p|_\Gamma = 0\}}$ by the semi-norm ${\|\nabla \cdot \|_{L_q(\Omega)}}$ , and ${\Gamma}$ is the boundary of ${\Omega}$ . In fact, we show that the unique solvability of such a Dirichlet problem is necessary for the unique existence of a solution to the resolvent problem with uniform estimate with respect to resolvent parameter varying in ${(\lambda_0, \infty)}$ . Our assumption is satisfied for any ${q \in (1, \infty)}$ by the following domains: whole space, half space, layer, bounded domains, exterior domains, perturbed half space, perturbed layer, but for a general domain, we do not know any result about the unique existence of solutions to the weak Dirichlet problem except for q =  2.     

Well-Posedness of Nematic Liquid Crystal Flow in {L^{3}_{\rm uloc}(\mathbb{R}^3)}

In this paper, we establish the local well-posedness for the Cauchy problem of a simplified version of hydrodynamic flow of nematic liquid crystals in ${\mathbb{R}^3}$ for any initial data (u ₀, d ₀) having small ${L^{3}_{\rm uloc}}$ -norm of ${(u_{0}, \nabla d_{0})}$ . Here ${L^{3}_{\rm uloc}(\mathbb{R}^3)}$ is the space of uniformly locally L ³-integrable functions. For any initial data (u ₀, d ₀) with small ${\|(u_0, \nabla d_0)\|_{L^{3}(\mathbb{R}^3)}}$ , we show that there exists a unique, global solution to the problem under consideration which is smooth for t > 0 and has monotone deceasing L ³-energy for ${t \geqq 0}$ .     

Multistage γ-level \mathcal{H}_{\infty} control for input-saturated systems with disturbances

For input-saturated systems with disturbances, states in the domain of attraction cannot converge to the origin, but only to neighborhood around it. In order to design the smallest possible target invariant set and the largest possible domain of attraction, in this paper, we introduce a multistage γ-level $\mathcal{H}_{\infty}$ control for achieving a smaller target invariant set within a given $\mathcal{H}_{\infty}$ performance level and a larger domain of attraction than results obtained in previous studies. In particular, for the case in which the disturbances satisfy a matched condition, this paper introduces an $\mathcal{H}_{\infty}$ control with an extra control part to perfectly reject these disturbances despite the uncertainties; the introduction of the $\mathcal{H}_{\infty}$ control with an extra control part causes the target invariant set to shrink to the origin and the $\mathcal{H}_{\infty}$ performance level to become zero.     

Elongational rheology of NIPAM-based hydrogels

Hydrogels of different composition based on the copolymerization of N-isopropyl acrylamide and surfmers of different chemical structure were tested in elongation using Hencky/real definitions for stress, strain, and strain rate, offering a more scientific insight into the effect of deformation on the properties. In a range between $\dot {\varepsilon }=10$ and 0.01 s $^{-1}$ , the material properties are independent of strain rate and show a very clear strain hardening with a “brittle” sudden fracture. The addition of surfmer increases the strain at break $\varepsilon _{\mathrm {H}}^{\max }$ and at the same time leads to a failure of hyperelastic models. The samples can be stretched up to Hencky strains $\varepsilon _{\mathrm {H}}^{\max }$ between 0.6 and 2.5, depending on the molecular structure, yielding linear Young’s moduli E $_{0}$ between 2,700 and 39,000 Pa. The strain-rate independence indicates an ideal rubberlike behavior and fracture in a brittle-like fashion. The resulting stress at break $\sigma _{\textrm max}$ can be correlated with $\varepsilon _{\mathrm {H}}^{\max } $ and $E_{0}$ as well as with the solid molar mass between the cross-linking points $M_{\mathrm {c}}^{\textrm {solids}} $ , derived from $E_{0}$ .     

Semianalytical Solution for \text{ CO}_{2} Plume Shape and Pressure Evolution During \text{ CO}_{2} Injection in Deep Saline Formations

The injection of supercritical carbon dioxide ( $\text{ CO}_{2})$ in deep saline aquifers leads to the formation of a $\text{ CO}_{2}$ rich phase plume that tends to float over the resident brine. As pressure builds up, $\text{ CO}_{2}$ density will increase because of its high compressibility. Current analytical solutions do not account for $\text{ CO}_{2}$ compressibility and consider a volumetric injection rate that is uniformly distributed along the whole thickness of the aquifer, which is unrealistic. Furthermore, the slope of the $\text{ CO}_{2}$ pressure with respect to the logarithm of distance obtained from these solutions differs from that of numerical solutions. We develop a semianalytical solution for the $\text{ CO}_{2}$ plume geometry and fluid pressure evolution, accounting for $\text{ CO}_{2}$ compressibility and buoyancy effects in the injection well, so $\text{ CO}_{2}$ is not uniformly injected along the aquifer thickness. We formulate the problem in terms of a $\text{ CO}_{2}$ potential that facilitates solution in horizontal layers, with which we discretize the aquifer. Capillary pressure is considered at the interface between the $\text{ CO}_{2}$ rich phase and the aqueous phase. When a prescribed $\text{ CO}_{2}$ mass flow rate is injected, $\text{ CO}_{2}$ advances initially through the top portion of the aquifer. As $\text{ CO}_{2}$ is being injected, the $\text{ CO}_{2}$ plume advances not only laterally, but also vertically downwards. However, the $\text{ CO}_{2}$ plume does not necessarily occupy the whole thickness of the aquifer. We found that even in the cases in which the $\text{ CO}_{2}$ plume reaches the bottom of the aquifer, most of the injected $\text{ CO}_{2}$ enters the aquifer through the layers at the top. Both $\text{ CO}_{2}$ plume position and fluid pressure compare well with numerical simulations. This solution permits quick evaluations of the $\text{ CO}_{2}$ plume position and fluid pressure distribution when injecting supercritical $\text{ CO}_{2}$ in a deep saline aquifer.     

A Unified Approach to Regularity Problems for the 3D Navier-Stokes and Euler Equations: the Use of Kolmogorov’s Dissipation Range

Motivated by Kolmogorov’s theory of turbulence we present a unified approach to the regularity problems for the 3D Navier-Stokes and Euler equations. We introduce a dissipation wavenumber ${\Lambda(t)}$ that separates low modes where the Euler dynamics is predominant from the high modes where the viscous forces take over. Then using an indifferent to the viscosity technique we obtain a new regularity criterion which is weaker than every Ladyzhenskaya-Prodi-Serrin condition in the viscous case, and reduces to the Beale-Kato-Majda criterion in the inviscid case. In the viscous case we prove that Leray-Hopf solutions are regular provided ${\Lambda \in L^{5/2}}$ , which improves our previous ${\Lambda \in L^\infty}$ condition. We also show that ${\Lambda \in L^1}$ for all Leray-Hopf solutions. Finally, we prove that Leray-Hopf solutions are regular when the time-averaged spatial intermittency is small, i.e., close to Kolmogorov’s regime.     

Optimal Assumptions for Discreteness

There exists, in every dimension ${n \geq 3}$ , a Lipschitz mapping of finite distortion such that the (outer) distortion satisfies ${K\in L^{n-1}}$ but it maps a line segment to a point.     

Extensions of Serrin’s Uniqueness and Regularity Conditions for the Navier–Stokes Equations

Consider a smooth bounded domain ${\Omega \subseteq {\mathbb{R}}^3}$ , a time interval [0, T), 0?<?T?≤?∞, and a weak solution u of the Navier–Stokes system. Our aim is to develop several new sufficient conditions on u yielding uniqueness and/or regularity. Based on semigroup properties of the Stokes operator we obtain that the local left-hand Serrin condition for each ${t\in (0,T)}$ is sufficient for the regularity of u. Somehow optimal conditions are obtained in terms of Besov spaces. In particular we obtain such properties under the limiting Serrin condition ${u \in L_{\rm loc}^\infty([0,T);L^3(\Omega))}$ . The complete regularity under this condition has been shown recently for bounded domains using some additional assumptions in particular on the pressure. Our result avoids such assumptions but yields global uniqueness and the right-hand regularity at each time when ${u \in L_{\rm loc}^\infty([0,T);L^3(\Omega))}$ or when ${u(t)\in L^3(\Omega)}$ pointwise and u satisfies the energy equality. In the last section we obtain uniqueness and right-hand regularity for completely general domains.     

Regularity and Asymptotic Behavior of Nonlinear Stefan Problems

We study the following nonlinear Stefan problem $$\left\{\begin{aligned}\!\!&u_t\,-\,d\Delta u = g(u) & &\quad{\rm for}\,x\,\in\,\Omega(t), t > 0, \\ & u = 0 \, {\rm and} u_t = \mu|\nabla_{x} u|^{2} &&\quad {\rm for}\,x\,\in\,\Gamma(t), t > 0, \\ &u(0, x) = u_{0}(x) &&\quad {\rm for}\,x\,\in\,\Omega_0,\end{aligned} \right.$$ where ${\Omega(t) \subset \mathbb{R}^{n}}$ ( ${n \geqq 2}$ ) is bounded by the free boundary ${\Gamma(t)}$ , with ${\Omega(0) = \Omega_0}$ , μ and d are given positive constants. The initial function u ₀ is positive in ${\Omega_0}$ and vanishes on ${\partial \Omega_0}$ . The class of nonlinear functions g(u) includes the standard monostable, bistable and combustion type nonlinearities. We show that the free boundary ${\Gamma(t)}$ is smooth outside the closed convex hull of ${\Omega_0}$ , and as ${t \to \infty}$ , either ${\Omega(t)}$ expands to the entire ${\mathbb{R}^n}$ , or it stays bounded. Moreover, in the former case, ${\Gamma(t)}$ converges to the unit sphere when normalized, and in the latter case, ${u \to 0}$ uniformly. When ${g(u) = au - bu^2}$ , we further prove that in the case ${\Omega(t)}$ expands to ${{\mathbb R}^n}$ , ${u \to a/b}$ as ${t \to \infty}$ , and the spreading speed of the free boundary converges to a positive constant; moreover, there exists ${\mu^* \geqq 0}$ such that ${\Omega(t)}$ expands to ${{\mathbb{R}}^n}$ exactly when ${\mu > \mu^*}$ .     

Global Well-posedness of Incompressible Inhomogeneous Fluid Systems with Bounded Density or Non-Lipschitz Velocity

In this paper, we first prove the global existence of weak solutions to the d-dimensional incompressible inhomogeneous Navier–Stokes equations with initial data ${a_0 \in L^\infty (\mathbb{R}^d), u_0 = (u_0^h, u_0^d) \in \dot{B}^{-1+\frac{d}{p}}_{p, r} (\mathbb{R}^d)}$ , which satisfy ${(\mu \| a_0 \|_{L^\infty} + \|u_0^h\|_{\dot{B}^{-1+\frac{d}{p}}_{p, r}}) {\rm exp}(C_r{\mu^{-2r}}\|u_0^d\|_{\dot{B}^{-1+\frac{d}{p}}_{p,r}}^{2r}) \leqq c_0\mu}$ for some positive constants c ₀, C _r and 1 < p < d, 1 < r < ∞. The regularity of the initial velocity is critical to the scaling of this system and is general enough to generate non-Lipschitz velocity fields. Furthermore, with additional regularity assumptions on the initial velocity or on the initial density, we can also prove the uniqueness of such a solution. We should mention that the classical maximal L ^p (L ^q ) regularity theorem for the heat kernel plays an essential role in this context.     

Resistance Coefficients of Polymer Membrane with Concentration Polarization

The Kedem-Katchalsky equations, modified by means of symmetric transformations of Peusner thermodynamic networks, were applied to interpret the membrane transport in concentration polarization conditions. The results from the study demonstrate that the resistance coefficients counted for membrane transport of aqueous solutions of glucose through Nephrophan membrane in horizontal plane are nonlinearly dependent on mean concentration of glucose in the membrane ${(\bar{C})}$ . It was also shown that the threshold value of concentration ${(\bar{C}_{cr})}$ existed, and for ${\bar{C} > \bar{C}_{cr}}$ , the resistance coefficients depend, while for ${\bar{C} < \bar{C}_{cr}}$ , they do not depend on the membrane system configuration. Increase of mean glucose concentration in the membrane (in the range ${\bar{C} > \bar{C}_{cr})}$ causes decrease of difference between resistance coefficients of the membrane system in homogeneous conditions (solutions mechanically stirred) and in conditions with hydrodynamic instabilities (configuration B). Besides increase of mean glucose concentration in the membrane (in the range ${\bar{C} > \bar{C}_{cr})}$ causes increase of the difference between resistance coefficients for membrane system with concentration polarization without hydrodynamic instabilities (configuration A) and membrane system in homogeneous conditions.     

Regularization of Point Vortices Pairs for the Euler Equation in Dimension Two

In this paper, we construct stationary classical solutions of the incompressible Euler equation approximating singular stationary solutions of this equation. This procedure is carried out by constructing solutions to the following elliptic problem $$\left\{\begin{array}{l@{\quad}l} -\varepsilon^2 \Delta u = \sum\limits_{i=1}^m \chi_{\Omega_i^{+}} \left(u - q - \frac{\kappa_i^{+}}{2\pi} {\rm ln} \frac{1}{\varepsilon}\right)_+^p\\ \quad - \sum_{j=1}^n \chi_{\Omega_j^{-}} \left(q - \frac{\kappa_j^{-}}{2\pi} {\rm \ln} \frac{1}{\varepsilon} - u\right)_+^p , \quad \quad x \in \Omega,\\ u = 0, \quad \quad \quad \quad \quad \quad \quad \quad \quad \quad \quad \quad \quad \quad x \in \partial \Omega,\end{array}\right.$$ where p > 1, ${\Omega \subset \mathbb{R}^2}$ is a bounded domain, ${\Omega_i^{+}}$ and ${\Omega_j^{-}}$ are mutually disjoint subdomains of Ω and ${\chi_{\Omega_i^{+}} ({\rm resp}.\; \chi_{\Omega_j^{-}})}$ are characteristic functions of ${\Omega_i^{+}({\rm resp}. \;\Omega_j^{-}})$ , q is a harmonic function. We show that if Ω is a simply-connected smooth domain, then for any given C ¹-stable critical point of Kirchhoff–Routh function ${\mathcal{W}\;(x_1^{+},\ldots, x_m^{+}, x_1^{-}, \ldots, x_n^{-})}$ with ${\kappa^{+}_i > 0\,(i = 1,\ldots, m)}$ and ${\kappa^{-}_j > 0\,(j = 1,\ldots,n)}$ , there is a stationary classical solution approximating stationary m + n points vortex solution of incompressible Euler equations with total vorticity ${\sum_{i=1}^m \kappa^{+}_i -\sum_{j=1}^n \kappa_j^{-}}$ . The case that n = 0 can be dealt with in the same way as well by taking each ${\Omega_j^{-}}$ as an empty set and set ${\chi_{\Omega_j^{-}} \equiv 0,\,\kappa^{-}_j=0}$ .     

Drainage of Capillary-Trapped Oil by an Immiscible Gas: Impact of Transient and Steady-State Water Displacement on Three-Phase Oil Permeability

In a previous paper (Dehghanpour et al., Phys Rev E 83:065302, 2011a), we showed that relative permeability of mobilized oil, $k_\mathrm{ro}$ , measured during tertiary gravity drainage, is significantly higher than that of the same oil saturation in other tests where oil is initially a continuous phase. We also showed that tertiary $k_\mathrm{ro}$ strongly correlates to both water saturation, $S_\mathrm{w}$ , water flux (water relative permeability), $k_\mathrm{rw}$ , and the change in water saturation with time, $\mathrm{d}S_\mathrm{w}/\mathrm{d}t$ . To develop a model and understanding of the enhanced oil transport, identifying which of these parameters ( $S_\mathrm{w},\,k_{\mathrm{rw}}$ , or $\mathrm{d}S_\mathrm{w}/\mathrm{d}t$ ) plays the controlling role is necessary, but in the previous experiments these could not be deconvolved. To answer the remaining question, we conduct specific three-phase displacement experiments in which $k_{\mathrm{rw}}$ is controlled by applying a fixed water influx, and $S_\mathrm{w}$ develops naturally. We obtain $k_{\mathrm{ro}}$ by using the saturation data measured in time and space. The results suggest that steady-state water influx, in contrast to transient water displacement, does not enhance $k_{\mathrm{ro}}$ . Instead, reducing water influx rate results in excess oil flow. Furthermore, according to our pore scale hydraulic conductivity calculations, viscous coupling and fluid positioning do not sufficiently explain the observed correlation between $k_{\mathrm{ro}}$ and $S_{\mathrm{w}}$ . We conclude that tertiary $k_{\mathrm{ro}}$ is controlled by the oil mobilization rate, which in turn is linked to the rate of water saturation decrease with time, $\mathrm{d}S_\mathrm{w}/\mathrm{d}t$ . Finally, we develop a simple model which relates tertiary $k_{\mathrm{ro}}$ to transient two-phase gas/water relative permeability.     

Predominant Gas Transport in Microporous Hydrotalcite–Silica Membrane

The prepared microporous hydrotalcite (HT)–silica membrane was found to exhibit the molecular sieving characteristic of pristine silica material and high $\mathrm{CO}_{2}$ adsorption capacity of HT. The combined properties made enhanced $\mathrm{CO}_{2}$ permeability and separability from $\mathrm{CH}_{4}$ possible. The gas transport in the membrane was predominantly surface adsorption. The porous membrane overcame the Knudsen limitation and yielded the highest separation selectivity of 120 at 40 % $\mathrm{CO}_{2}$ feed concentration, $30\,^{\circ }\mathrm{C}$ operating temperature, and 100 kPa pressure difference.