共查询到20条相似文献,搜索用时 15 毫秒
1.
2.
1 INTRODUCTION The crystal engineering and design of solid-state coordination polymers have become a very attrac- tive field in recent years[1~4]. Many interesting fra- meworks with intriguing potential applications have been obtained through the self-assembly of selected metal centers and carboxylate ligands[5, 6]. Compared with aromatic carboxylate ligands such as terephtha- lic acid[7, 8], benzene tricarboxylic acid[9, 10], benzene tetracarboxylic acid[11, 12] and so on, those ligands … 相似文献
3.
A new one-dimensional polymeric complex [Cd(SCN)2(H2O)]L (L = N,N?-bis(furan- 2-ylmethylene)hydrazine) has been synthesized and characterized by IR, UV spectra, TG-DTA technique and single-crystal X-ray diffraction analysis. It crystallizes in triclinic, pace group P1 with a = 5.9268(8), b = 10.8678(15), c = 13.3671(19) , α = 109.295(2), β = 95.092(2), γ = 97.8580(10)°, V = 796.70(19) 3, Z = 2, C12H10CdN4O3S2, Mr = 434.76, μ = 1.648 mm–1, Dc = 1.812 g/cm3, F(000) = 428, R = 0.0308 and wR = 0.0769. The crystal structure reveals that the structure of [Cd(SCN)2(H2O)]n features di-μ-1,3-thiocyante bridges and 1D chains. The octahedrally coordinated Cd atom is surrounded by one oxygen atom from water molecule, three S atoms and two Natoms from five di-μ-1,3 thiocyanato bridges. The Cd atoms are connected by two di-μ-1,3 thiocyanato bridges with the Cd(1)…Cd(1A) separation of 4.239(1) and Cd(1)…Cd(1B) of 5.852(1). In addition, the one-dimensional straight chain structure is further connected by multiform intermolecular N-H…O hydrogen bonds and π…π interactions to form a three-dimensional supramolecular structure. 相似文献
4.
A newcoordination polymer [Cd(bimc)2]n was obtained by the reaction of Hbimc with Cd(NO3)2·4H2O in NaOH solution,and characterized by elemental analysis,IR and single-crystal X-ray diffraction. The crystal belongs to orthorhombic, space group Pbcn with a = 12.533(4),b = 15.705(5), c = 15.200(5) (A), V= 2991.8(15) (A)3, Mr = 434.68, Z = 8, Dc = 1.930 g/cm3, F(000) =1712, μ(MoKa) = 1.492 mm-1, the final R = 0.0410 and wR = 0.0804 for 166l observed reflections (I>2σ(I)). The Cd atom exhibits a distorted six-coordinate CdN2O4 octahedral coordination geometry. The complex molecules are linked by both μ2-(η2-O, O-), Nl and μ2-(η2-O, O-), N3 coordination modes of ligands to form cross-like wave (4, 4) layer structures which are further stacked through interlayer hydrogen bonds and π-π stacking interactions in an offset fashion to form a 3D supramolecular structure. 相似文献
5.
A binuclear zinc(Ⅱ) complex with 2-carboxycinnamic acid (2-ccm) and dipyrido-[3,2-a:2',3'-c]phenazine (DPPZ), {[Zn2(2-ccm)2(DPPZ)2]·2H2O}n, was synthesized and charac-terized by elemental analysis, IR, single-crystal X-ray diffraction, thermal gravimetry and fluo-rescent emission. It crystallizes in monoclinic, space group P21/c with a = 13.409(4), b = 25.530(7), c = 13.952(4) A, β = 99.554(3)°, V= 4710(2) A3, Z= 4, C56H36N8O10Zn2, Mr= 1111.67, Dc = 1.568 g/cm3,μ(MoKa) = 1.093 mm-1, F(000) = 2272, R = 0.0422 and wR = 0.0895. In the crystal, the basic unit of 1 is a binuclear Zn2 entity which is linked by 2-ccm ligand to form a ID double chain along the α axis. The O-H…O hydrogen bonding and π-π interactions lead to a 3D supramolecular motif. In addition, thermal and luminescent properties of complex 1 have also been investigated. 相似文献
6.
A three-dimensional complex [Cd(μ1,3-SCN)2(dmpo)]n has been synthesized with μ1,3-SCN- and dmpo as mixed bridge ligands. The crystal belongs to monoclinic, space group C2/c with a = 15.648(2), b = 15.126(2), c = 11.9773(15) (A), β= 112.416(2)°, V= 2620.7(6) (A)3, Z= 8,C9H9CdN3OS2, Mr = 351.71, Dc = 1.783 g/cm3, F(000) = 1376 and μ = 1.967 mm-1. The structure was refined to R = 0.0260 and wR = 0.0647 for 2186 observed reflections (1 > 2σ(Ⅰ)). In the crystal the Cd(Ⅱ) ions are coordinated byμ1,3-SCN- bridge ligands to form the crossing chains on the adjacent planes, and these chains are further joined by μ-dmpo mono-dentate bridge ligands leading to a three-dimensional structure. The complex exhibits strong fluorescent emission property. 相似文献
7.
Syntheses and Crystal Structures of Two Cadmium(Ⅱ) Compounds Linked by N,N-Bis(3-pyridylmethyl)amine
Two cadmium(Ⅱ) compounds linked by a flexible dipyridyl ligand {[Cd2(Hbpma) Cl5(H2O)]·2H2O}n 1 and [Cd(Hbpma)Cl(H2O)2]2·2SO4·3H2O 2 (bpma = N,N-bis(3-pyridylmethyl)amine) have been synthesized and structurally characterized by single-crystal X-ray diffraction. Complex 1 crystallizes in triclinic, space group P with a = 9.5612(6), b = 11.3401(7), c = 11.5069(12), α = 112.8540(10), β = 106.5330(10), γ = 101.6680(10)°, V = 1030.77(14)3, C12H20Cd2Cl5N3O3, Mr = 656.36, Z = 2, Dc = 2.115 g/cm3, μ(MoKα) = 2.727 mm-1, F(000) = 636, S = 1.059, the final R = 0.0319 and wR = 0.0822 for 3443 observed reflections (I > 2σ(I)). For complex 2, it belongs to triclinic, space group P with a = 10.9487(4), b = 11.4197(4), c = 15.4288(5), α = 94.7470(10), β = 104.1000(10), γ = 104.42°, V = 1790.76(11)3, C24H42Cd2Cl2N6O15S2, Mr = 1014.46, Z = 2, Dc = 1.881 g/cm3, μ(MoKα) = 1.529 mm-1, F(000) = 1020, S = 1.050, the final R = 0.0178 and wR = 0.0451 for 6026 observed reflections (I > 2σ(I)). Complex 1 is found to have tetranuclear Cd(Ⅱ) clusters which are bridged by the protonated bpma ligands leading to one-dimensional coordination polymers, whereas complex 2 consists of binuclear Cd(Ⅱ) structures linked by the protonated bpma ligands. Both complexes are assembled into three-dimensional supramolecular structures through hydrogen bonding interactions. 相似文献
8.
Two novel complexes [Zn(NIT3-py)(ip)]n 1 and [Zn(im3-py)(ip)]n 2 (NIT3-py =2-(3"-pyridyl)-4,4,5,5,-tetramethylimidazoline-1-oxyl-3-oxide, im3-py = 2-(3'-pyridyl)-4,4,5,5-te-tramethylimidazoline-1-oxyl, ip = isophthalate) have been synthesized and structurally determinedby X-ray diffraction.Crystal data for 1: C32H36N6O8Zn, Mr= 698.04, monoclinic, space group C with a = 23.600(3), b = 10.2073(12), c = 13.4027(16)(A), β= 92.586(2)°, V = 3225.3(7) (A)3, Dc=1.438 g/cm3, F(000) = 1456,μ(MoKα) = 0.822 mm-1, Z = 4, the final R = 0.0390 and wR = 0.1032 for 6037 independent reflections with Rint=0.0214.Crystal data for 2: C32H36N6O6Zn, Mr = 666.04,monoclinic, space group C2/c with a = 24.434(4), b = 13.543(2), c = 10.2379(16)(A), β= 109.024(2)°,V= 3202.8(9)(A)3, Dc= 1.381 g/cm3, F(000) = 1392,μ(MoKα) = 0.820 mm-1, Z= 4,the final R = 0.0304 and wR = 0.0658 for 2833 independent reflections with Rint = 0.0307.X-ray analysis reveals that both Zn(Ⅱ) ions are four-coordinated by two pyridyl-N atoms from nitroxide radicals and two carboxylate oxygen atoms to form distorted tetrahedral geometries.Each iso-phthalate dianion binds two Zn(Ⅱ) ions in a monodentate mode, leading to a 1-D chain structure. 相似文献
9.
Three heterobinuclear complexes were synthesized, namely [Cu (oxpn) Co (L)2] (ClO4)2·xH2O(L= 2,2'-bipyridyl(bpy), 1,10-phenanthroline(phen) , and 5-nitro-1, 10-phenanthroline (NO2-phen)), where oxpn represents N, N'-bis(3-aminopropyl) oxam-ido. Based on 1R, elemental analysis, conductivity measurement and electronic spectra, these complexes were characterized by an extended oxamido-bridged structure with Cu(Ⅱ) in a planar environment and Co(Ⅱ) in a octahedral environment. The symmetry of the cation is very close to C2v.The complexes were also characterized with variable temperature (4~300K) magnetic susceptibility, and the data were fit for the susceptibility equation derived from spin Hamilton, H= -2JS1.S2-DSx12 by least square strategy. The exchange integral, J, was found to be -22.36 cm-1 (for bpy);-15.45 cm-1 (for phen); -19. 10cm-1(for NO2-phen), indicating that there is a weak antiferromagnetic spin-exchange interaction between the metal ions. 相似文献
10.
Three new Zn(Ⅱ)/Cd(Ⅱ) coordination polymers based on 2-mercaptonicotinic acid (H2mna) with 1,2-di(4-pyridyl)ethylene (dpe) introduced as a bridging ligand have been synthesized via hydrothermal method and structurally characterized by single-crystal X-ray diffraction as well as elemental analysis and IR. As reported in this paper, [Zn2(dpe)0.5(mna)2] (1) can be classified as a two-dimensional layer structure in which the 1D chain composed of Zn(Ⅱ) and mna ligands is bridged by dpe ligands, while the complex named [Zn4(dpe)4(mna)4] (2) is a tetra-nuclear cluster compound. These two compounds are further extended to three-dimensional structures by hydrogen bonds along with C-H…π and π…π interactions. Compound 3 with general formular [Cd2(dpe)0.5(mna)2]·H2O belongs to a three-dimensional porous structure in which the 2D metal layers formed by the coordination of Cd(Ⅱ) and mna ligands are connected with the bridging of dpe ligands. 相似文献
11.
The three-dimensional complex [Cd(μ1,3-SCN)(μ3-pco)]n has been synthesized with μ1,3-SCN- and pco as mixed bridged ligands. The crystal belongs to monoclinic, space group P21/n with a = 10.3777(16), b = 6.2592(9), c = 13.150(2) (A), β= 97.317(2)°, V=847.2(2) (A)3, Z= 4,C6H3CdN3O3S, Mr = 309.575, Dc = 2.427 g/cm3, F(000) = 592 and μ = 2.804 mm-1. The structure was refined to R = 0.0255 and wR = 0.0550 for 1712 observed reflections (I>2σ(I)). In the crystal the Cd(Ⅱ) ions are coordinated by μ1,3-SCN- and μ3-pco bridge ligands to form a three-dimensional structure. 相似文献
12.
13.
Two homochiral metallosalen complexes,Ni(salen) (salen=(1R,2R)-(-)-diaminocyclohexane-N,N'-bis(3-tert-butyl-5-(4'-benzoic acid)-salicylidene) 1 and Cu(salen) 2,have been synthesized and characterized by IR,microanalysis,TGA,powder and single-crystal X-ray crystallography. Both 1 and 2 crystallize in orthorhombic space group P2_12_12 with Z=4. For 1,α= 12.082(2),b = 15.447(3),c = 18.784(4)(A),V= 3505.7(12) (A)~3,M_r = 731.50,D_c = 1.386 g/cm~3,μ= 0.606 mm~(-1),F(000)=1544,the final GOOF=1.043,R=0.0496 and wR=0.1248 for 4791 observed reflections with Ⅰ> 2σ(Ⅰ). For 2,α=12.181(2),b=15.501(3),c=18.877(4)(A),V= 3564.3(12)(A)~3,M_r=736.33,Dc = 1.372 g/cm~3,μ=0.665 mm~(-1),F(000)=1548,the final GOOF= 1.062,R=0.0575 and wR=0.1508 for 4562 observed reflections with Ⅰ> 20(Ⅰ). The crystal structures of 1 and 2 are isostructural with very similar supramolecular structures. An infinite two-dimensional network is generated by hydrogen bonding interactions and intermolecular π…π interactions. 相似文献
14.
15.
16.
1 INTRODUCTION The metal-organic coordination polymers have proved to be promising in developing new mate- rials[1]. It is crucial to select or synthesize the suita- ble bridging organic ligand. Some simple rigid li- gands are skillfully employed[2~4].… 相似文献
17.
Modified α and β bis(salicylaldoxime)copper(Ⅱ) have been obtained by recrystallization from ethyl acetate(CCDC Nos. 212157 & 212158). The X-ray analysis reveals that the two modificated forms have the same structure with different geometric parameters. The α form crystallizes in the P2(1)/c space group and the β form in the P1 space group. Both the crystal structures consist of centrosymmetric monomeric molecules of Cu(OC6H4CNOH)2. The IR spectra are in agreement with the structural data. 相似文献
18.
SHI Jing-min LIAO Dai-zheng CHENG Peng JIANG Zong-hui MIAO Ming-ming WANG Geng-lin. 《高等学校化学研究》1996,(1)
IntroductionThestudyofmagneticexchangeinteractionbetweenparamagneticcenterspropagatedbymulti-atombridgesisofcurrentinterestduetounderstandingthepathwayofelectrontransferinbio1ogicalsystemandobtainingsomeusefulin-formationaboutdesigningmolecule-basedmagnets.Manypapers['-'Jdealingwithphthalato,isophthalatoandterephthalatoligandsasamulti-atombridgeshavebeenpublished.1thasbeenrevealedbythevariable-temperaturemagneticsusceptibilityinvestigationthatlong-rangemagneticcouplingoccursbetweentwoparamagne… 相似文献
19.
合成了3种新型配合物[Cu(samen)Mn(NO_(2-)Phen)_2](1)、[Cu(sampn)Mn(NO_(2-)Phen)_2](2)和[Cu(samen)CO(terp)](3)(samen~(4-)、sampn~(4-)、NO_(2-)Phen和terp分别表示N,N′-乙二水杨酰胺根阴离子、N,N′-1,2-丙二水杨酰胺根阴离子、5-硝基-1,10-菲绕啉和联三吡啶),测得配合物的变温磁化率,求出交换积分,J分别为-63cm~(-1)(1)、—65cm~(-1)(2)和—7.68cm~(-1)(3),表明金属离子间有反铁磁超交换作用。 相似文献
20.
A two-dimensional(2D) 44 topological ZnⅡ coordination polymer {[Zn2Cl2(L)(4bpy)2]}∞(H2L = anthracene-9,10-dicarboxylic acid, 4bpy = 4,4ˊ-bipyridine) based on binuclear [Zn2Cl2] nodes has been synthesized and characterized by IR, elemental analysis, X-ray powder diffraction and single-crystal X-ray diffraction analysis. Moreover, the luminescent properties of the correspon- ding compound have been briefly investigated. 相似文献