Kinetic cooling of a moving gas

A study is made of the effects that arise when a moving gas absorbs electromagnetic radiation whose frequency is in resonance with the frequency of the center of a spectral line of a vibrational-rotational transition of molecules of the mixture. It is shown that the variation of the gas-dynamic parameters depends on the relationships between the rates of the stimulated transitions, intramolecular V — V exchange, and V — T relaxation, and the maximal effects are attained in the neighborhood of the sonic point.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 3, pp. 127–138, May–June, 1982.     

Influence of the macrotransport processes in gases on the change in the hydrodynamic parameters in the presence of a resonance radiation pulse

The effect of a resonance radiation pulse on the gas parameters is investigated. It is assumed that the pulse duration is large enough for the diffusion and heat conduction to be taken into account. It is shown that the diffusion and heat conduction may be significantly influenced by the processes of excitation of the internal degrees of freedom of the molecules.Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No.4, pp. 120–128, July–August, 1992.     

Motion of a gas shock layer with a free boundary under nonadiabatic conditions

This paper is a study of the effect of heat input (removal) on the characteristics of a shock layer produced by a gas at high supersonic velocity encountering a mobile boundary, which for generality is assumed to be free. We will use the Chernyi method, which was employed previously to solve the problem of a shock layer in an adiabatic flow [1, 2]. The results obtained can be useful for analysis of the effect of radiation (absorption) and processes involving the relaxation of internal degrees of freedom of molecules, condensation, chemical reactions, etc., whose effect on the gasdynamics of the flow in a shock layer may be similar to heat input or removal [3–5].Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 3, pp. 152–154, May–June, 1976.The author thanks A. K. Rebrov for discussion of the results.     

Propagation of small disturbances in a relaxing and radiating diatomic gas in vibrational nonequilibrium

In radiation gasdynamical problems, where the primary object of investigation is a moving gas, the influence of radiation on the parameters of the gas flow is usually neglected to avoid overcomplication of the problem. The growth and behavior of initial disturbances in a scattering, radiating, absorbing, viscous, heat-conducting gas characterized by local thermodynamic equilibrium has been investigated previously [1]. However, for low pressures (p10^–4 to 10^–3 technical atm) and fairly high temperatures of the active molecular degrees of freedom (T10³ to 3·10³K) the distribution of the molecules among the vibrational levels can differ markedly from the equilibrium distribution due to the or der-of-magnitude closeness of the vibrational relaxation time _c associated with collisions and the radiative deactivation time * of excited molecules [2, 3]. We now analyze normal modes in a vibrationally nonequilibrium medium with allowance for radiation scattering in the vibrational-rotational band. We formulate a dispersion relation and discuss some limiting cases.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 5, pp. 168–171, September–October, 1976.The author is grateful to V. I. Kruglov, Yu. V. Khodyko, and M. A. El'yashevich for their interest and discussions.     

Vibrational relaxation of diatomic molecules in a non-Boltzmann thermostat

The action of resonance IR laser radiation on a molecular gas leads, at high-power absorption intensity, to a breakdown in the equilibrium (Boltzmann) energy distribution in the internal degrees of freedom [1]. Under realistic conditions, molecular gases usually are (due to small amounts of impurities or isotopic components) multicomponent systems. In this case resonance IR laser radiation (or other methods of selective action), disturbing the distribution function of the primary gas, does not interact directly with impurities. The problem thus arises of determining the distribution function of the impurity gas interacting with the nonequilibrium (non-Boltzmann) thermostat. The present paper, devoted to the solution of this problem, treats the distribution function of harmonic oscillators A, consisting of a small amount of impurities in a system of harmonic oscillators B with given nonequilibrium distribution functions of vibrational energy. The behavior of a system in a nonequilibrium thermostat was first considered in [2, 3] where, as well as in [4, 5], it was shown that in a non-Maxwellian thermostat with a small amount of harmonic oscillator impurities, a Boltzmann distribution in harmonic oscillator vibrational energies is established under stationary conditions, with a temperature differing from the gas-kinetic temperature of the thermostat, defined in terms of the mean-square velocity. The behavior of a small amount of impurities (heavy monoatomic particles and harmonic oscillators) in a non-Maxwellian thermostat of a light gas was further investigated in [6–8]. Unlike the papers mentioned, the present one considers the behavior of a small amount of harmonic oscillator impurities in a thermostat with a Maxwellian velocity distribution and with a nonequilibrium (non-Boltzmann) distribution in vibrational energies.Translated from Zhurnal Prikladnoi Mekhaniki i Tekhnicheskoi Fiziki, No. 5, pp. 3–10, September–October, 1978.     

Analysis of Nonequilibrium Dissociation Kinetics in a Boundary Layer Using Various Reaction Models

Values of the nonequilibrium macroscopic reaction rate for a nonisothermal boundary layer of a monatomic diluent gas are calculated using a number of models for thermal dissociation of diatomic molecules — anharmonic Morse oscillators. Analysis is performed for conditions where the diffusive transfer of excited molecules has a significant effect on the population of their upper vibrational levels, which does not only amount to change in vibrational temperature. Under the joint influence of diffusive transfer of molecules, vibrational exchanges, and reactions involving vibrationally excited particles, the local vibrational distribution functions are substantially nonequilibrium. The kinetic models considered take into account the possible contribution of the energy of molecular translational and rotational degrees of freedom to the energy required to overcome the reaction threshold. The effect of multiquantum vibrational—translational exchanges on the distribution of dissociating molecules in their upper vibrational levels is taken into account approximately.     

Transonic outflow of an imperfect gas from a vessel with plane walls

Transonic isentropic imperfect gas flows^* were investigated in the one-dimensional formulation in [2–5]. The problem of the transonic outflow of a jet of thermally perfect gas with equilibrium excitation of the vibrational degrees of freedom of the molecules (calorically imperfect gas) was investigated in the two-dimensional formulation in [6]. Below the problem of the transonic outflow of a real (thermally and calorically imperfect) gas from a vessel with plane walls is considered. A method of solution is proposed. Calculation results characterizing the effect of the angle between the walls and the stagnation parameters on the transonic outflow of air are presented.Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No.6, pp. 88–95, November–December, 1993.The authors are grateful to G. Yu. Stepanov for his interest in their work.     

Population inversion of vibrational levels in the case of kinetic cooling of a moving gas

An analysis is made of the possibility of using kinetic cooling of a gas moving at a low subsonic or supersonic velocity in a field of continuous resonance radiation to produce a medium with population inversion.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 5, pp. 139–144, September–October, 1982.     

Modification of the first approximation of the Chapman-Enskog method for a gas mixture

The authors propose a transformation of the equations of the first approximation of the Chapman-Enskog method for a gas mixture with frozen internal degrees of freedom. As a result, the solution for the perturbation of the distribution functions can be written in terms of the diffusion velocities and temperature gradient, and the derivation of the Stefan-Maxwell relations and the heat flux calculations can be much simplified. The transformations are extended to a mixture of polyatomic gases with nonequilibrium excitation of the internal degrees of freedom of the molecules. The modification of the first approximation of the Chapman-Enskog method does not affect the relations used for calculating the viscosity of the mixture. Accordingly, that part of the solution is not considered.Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No.4, pp. 178–185, July–August, 1992.     

Transonic flow of a gas jet from a vessel with plane walls

The problem of transonic flow of a gas jet with equilibrium excitation of the vibrational degrees of freedom of the molecules from an infinite symmetrical vessel with plane walls is reduced to a generalized Tricomi boundary-value problem for an equation of Chaplygin type. It is solved using a difference scheme [13] based on the decomposition of the difference operator in accordance with the type of differential operator. Calculation results are presented for a mixture of oxygen and nitrogen simulating air. The effect of the angle between the walls, the stagnation temperature and the back-pressure coefficient on the flow coefficient is investigated.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 6, pp. 128–135, November–December, 1987.The authors are grateful to F. Yu. Stepanov for his useful comments.     

Effect of Transitional Nonequilibrium on the Molecular–Dissociation Rate in a Hypersonic Shock Wave

The problem of the influence of a nonequilibrium (non–Maxwellian( distribution of translational energy over the degrees of freedom of molecules on the rate of their dissociation in a hypersonic shock wave is considered. An approximate beam—continuous medium model, which was previously applied to describe a hypersonic flow of a perfect gas, was used to study translational nonequilibrium. The degree of dissociation of diatomic molecules inside the shock–wave front, which is caused by the nonequilibrium distribution over the translational degrees of freedom, is evaluated. It is shown that the efficiency of the first inelastic collisions is determined by the dissociation rate exponentially depending on the difference in the kinetic energy of beam molecules and dissociation barrier.     

Nonequilibrium condensation of metal vapor mixed with an inert gas in nozzle expansion in cluster beam generators

A closed mathematical model of flows of a mixture consisting of a homogeneously condensible vapor and an inert gas is described. This model is a further development of the pure metal vapor condensation model [1 – 4] and, as distinct from the latter, makes it possible to take into account the effect of molecules of inert gas not only on the thermodynamics of the mixture but on the detailed kinetics of the processes of the cluster formation and breakdown. The results of numerical calculations of the formation of iron and silver clusters in experimental installations are presented.Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No. 3, pp. 80–91, May–June, 1995.     

Formation of a pulsed jet behind a supersonic nozzle when the gas can relax at the entrance to the nozzle

The formation of a pulsed jet behind supersonic nozzles is considered when relaxation processes take place in the gas entering the nozzle. In a general formulation, the problem of the motion of the front of the exhausting matter and the disturbances accompanying it in the process of formation of a pulsed jet is determined by a large number of parameters, which characterize the exhausting gas and the residual gas of the pressure chamber and also the geometry of the flow conditions. A reliable computational model of a pulsed jet does not exist. To construct such a model, experiments are required in a wide range of boundary and initial conditions. An investigation was made into flow of shockheated argon, nitrogen, and carbon dioxide out of nozzles set up at the end of a shock tube. Generalized dependences were obtained for describing the motion of the front of the nonstationary jet and the wave in front of it in a wide range of the initial pressure-difference parameters and variation of the stagnation temperatures. The choice of the generalized parameters when relaxation of the excited internal degrees of freedom of the molecules of the gas can occur at the entrance to the nozzle is discussed.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 6, pp. 129–135, November–December, 1980.     

Inverted population of Co2 molecules in expanding gas streams

The system of equations of hydrodynamics, which describes the process of escape of the mixtures CO₂ + N₂ + He, H₂O from a nozzle, is solved numerically in conjunction with the equations of the kinetics of the excitation of the vibrational degrees of freedom of the molecules. It is found that an inverted population of the CO₂ molecules with respect to the transition [00 °1] – [10 °0], is produced under certain conditions at the exit from the nozzle. The magnitude of the inversion depends both on the nozzle configuration and on the initial values of the gas temperature and pressure. It is shown that for a specified nozzle configuration there exist optimal values of these parameters, at which the inverted population of the CO₂ molecules reaches approximately 10¹⁵ cm^–3.Translated from Zhumal Prikladnoi Mekhaniki i Tekhnicheskoi Fiziki, No. 5, pp. 24–34, September–October, 1971.     

Initiation of Combustion in a Supersonic Hydrogen-Air Mixture Flow by CO<Subscript>2</Subscript>-Laser Radiation

Features of the ignition kinetics of an H₂/air mixture in the supersonic flow behind an inclined shock front are analyzed when asymmetric vibrations of a small amount (<1%) of O₃ molecules specially introduced into the initial mixture are excited by 9.7 μm wavelength radiation. It is shown that this radiation leads to intensification of the chain reactions and makes it possible to organize combustion at small distances from the front (of the order of 1 m) of even relatively weak shocks at small values of the laser radiation energies absorbed by the gas. This method of initiating combustion in a supersonic flow is 10–100 times more efficient than the thermal method.__________Translated from Izvestiya Rossiiskoi Academii Nauk, Mekhanika Zhidkosti i Gaza, No. 2, 2005, pp. 157–167.Original Russian Text Copyright © 2005 by Lukhovitskii, Starik, and Titova.     

Determination of optimum nozzle parameters in a gasdynamic laser

In connection with the use of supersonic nozzles to create lasers, the question arises of the optimum parameters of the nozzle and the gas mixture from the aspect of obtaining the greatest population inversion of the energy levels of internal degrees of freedom of molecules of the working gas and the greatest output power of the lasers. A rather complete concept of the kinetic processes taking place during the escape of a relaxing gas mixture containing carbon dioxide through a supersonic nozzle has now been developed on the basis of calculated and experimental data. In [1–4] the problems of optimization of the parameters of a CO₂-N₂-H₂O-He mixture and of the shape of the nozzle were set up and solved in a one-dimensional steady-state formulation. The influence of the two-dimensionality of the stream in an optimum nozzle on the laser characteristics is studied in the present report. The method of through calculation suggested in [5] is used to calculate the two-dimensional flow of a relaxing gas.Translated from Zhurnal Prikladnoi Mekhaniki i Tekhnicheskoi Fiziki, No. 5, pp. 23–26, September–October, 1978.     

Spherical flow of a diatomic gas from an evaporating drop

The spherical expansion of gas from an evaporating drop is investigated on the basis of the numerical solution to a model kinetic equation for a gas with rotational degrees of freedom. Examples considered are the stationary evaporation of a drop with given temperature into the vacuum and evaporation of a drop into a gas-filled space under the condition of an energy balance on the drop surface.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 4, pp. 184–187, July–August, 1980.     

Influence of excitation of internal degrees of freedom of molecules on the process of weak evaporation or condensation

A study is made of the process of weak evaporation (or condensation) with allowance for excitation of vibrational and rotational degrees of freedom of diatomic molecules. The solution to the corresponding Knudsen layer problem is obtained on the basis of a model kinetic equation of the type of the Morse equation [1]. A relation is obtained that establishes the connection between the rate of evaporation (or condensation) and the parameters of the surface and the gas above it. The boundary conditions of slip for the equations of gas dynamics are analyzed. The results are compared with the evaporation or condensation in the case of a monatomic gas. The introduction of accommodation coefficients for an evaporating surface is considered.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 6. pp. 98–110, November–December, 1979.     

Theoretical investigation of nonequilibrium flow of a H2O-H2-O2 mixture in a profiled nozzle

In the approximation of a two-dimensional flow of a nonequilibrium gas, a study is made of inversion in the vibrational-rotational transitions of the H₂O molecule during expansion of a H₂O-H₂-O₂ mixture in a two-dimensional profiled nozzle. A comparison with the one-dimensional theory is made.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 1, pp. 106–111, January–February, 1982.     

Effect of inelastic collisions on the first-order slip coefficients for a diatomic gas with rotational degrees of freedom

When solving problems of inhomogeneous gas dynamics in the slip regime, it is necessary to know the boundary conditions for the velocity, temperature, heat fluxes, etc., that is, the boundary conditions for the gas macroparameters. In particular, such problems arise in developing the theory of thermophoresis of moderately large aerosol particles [1].The problem of monatomic and molecular (di- and polyatomic) gas slip along a boundary surface is considered in many publications (see, for example, [2–8]). The first-order effects include the isothermal and thermal gas slips characterized by the coefficients C_m and K_TS, respectively.In contrast to a monatomic gas, the molecules of diatomic and polyatomic gases have internal degrees of freedom, which considerably complicates the kinetic equation [9]. The lack of reliable models for the intermolecular interaction potential predetermines the need to construct model kinetic equations [10].In this study, for a diatomic gas whose molecules have rotational degrees of freedom, we propose a model kinetic equation obtained by developing the approach described in [6]. With the use of this model equation, the problem of diatomic gas slip along a plane surface is solved. As a result, for diatomic gases the coefficients C_m and K_TS, which depend on the thermophysical gas parameters and the intensity of inelastic collisions, are obtained.Translated from Izvestiya Rossiiskoi Academii Nauk, Mekhanika Zhidkosti i Gaza, No. 6, 2004, pp. 176–182. Original Russian Text Copyright © 2004 by Poddoskin.