Atomic beam magnetic resonance investigations in the3 F 2 Ground State of177Hf,179Hf and180Hf

The 5d ²6s ^{2 3} F ₂ ground state of¹⁷⁷Hf,¹⁷⁹Hf and¹⁸⁰Hf has been studied using the atomic beam magnetic resonance method. The atomic beam was produced by an universal evaporation technique described in a previous paper. The results are¹⁸⁰Hfg _j (³ F ₂)=0.695812 (10)¹⁷⁷Hf Δv(³ F ₂;F=11/2?F=9/2)=991.7917 (10) MHz Δv(³ F ₂;F=9/2?F=7/2)=477.0081 (10) MHz Δv(³ F ₂;F=7/2?F=5/2)=162.8890 (10) MHz¹⁷⁹HfΔv(³ F ₂;F=13/2?F=11/2)=82.1320 (10) MHz Δv(³ F ₂;F=11/2?F=9/2)=392.8498 (10) MHz. The magnetic dipole and electric quadrupole moments of the¹⁷⁷Hf and¹⁷⁹Hf nuclear ground states as calculated from these hyperfine structure measurements are the following: μ(177)=0.75(8)μ _k , Q(177)=4.34 (65) barns μ(179)=?0.61 (6)μ _k , Q(179)=4.90 (75) barns.     

High resolution two-photon spectroscopy of the 6p 23 P o-7p 3 P o transition in stable lead isotopes

Dopplerfree two-photon speatroscopy was used to investigate isotope shifts in the 6p^{2 3}P_o — 6p7p³P_o transition of the stable lead isotopes Pb 204, 206, 207, and 208. Two-photon transitions were induced by the 450,4 nm cw radiation of a frequency stabilized ring laser.     

Laser excited population redistribution in the 2p3p multiplet in neon

Using neon hollow cathode lamp and employing laser optogalvanic technique, we have studied population redistribution in the 2p⁵3p multiplet. The spectra recorded in the laser energy region of 23300 cm^− 1 -23600 cm^− 1 show transitions originating from both the laser excited levels as well as from an adjacent level whose population builds up as a result of collisional deactivation. Employing the optical delay technique, we have been able to extract decay rates associated with the collisional population mixing of the p levels.     

Levels in 13N examined by 12C p elastic resonance scattering with thick target

The elastic resonance scattering of 12C p has been studied in inverse kinematics via a novel thick target method at GIRAFFE facility of HI-13 tandem accelerator laboratory, Beijing. The recoil protons were measured by a △E-E counter telescope based on a large area double-sided silicon strip detector at laboratory angles around θ0 = 15°. The excitation function for 12C(p,p) elastic scattering has been obtained over a wide energy range of Ec.m.=0.31—3.45 MeV, which was explained quite well by the R-matrix calculation with known resonance parameters of the first three levels in 13N nucleus. Thus it is demonstrated that the present setup can be directly applied to the study of elastic resonance scattering with secondary radioactive beams.     

Levels in 13N examined by 12C+p elastic resonance scattering with thick target

The elastic resonance scattering of 12C+p has been studied in inverse kinematics via a novel thick target method at GIRAFFE facility of HI-13 tandem accelerator laboratory,Beijing.The recoil protons were measured by a △E-E counter telescope based on a large area double-sided silicon strip detector at laboratory angles around θ0=15°.The excitation function for 12C(p,p)elastic scattering has been obtained over a wide energy range of Ec.m.=0.31-3.45 MeV,which was explained quite well by the R-matrix calculation with known resonance parameters of the first three levels in 13N nucleus.Thus it is demonstrated that the present setup can be directly applied to the study of elastic resonance scattering with secondary radioactive beams.     

Measurements of theg J -factors of12C in the3 P 1 and3 P 2 states

Using the atomic beam magnetic resonance method the Zeeman interactions of¹²C in the³ P ₁ and³ P ₂ states at magnetic fields of about 3.4 kOe have been measured. The measured quantities areg _J (³ P ₁)?g_J(³ P ₂)=15.4(1.0)·10^?6 g _J (³ P ₂)=1.5010616 (50), from which the following value for g_J(³P₁) can be calculated:g _J (³ P ₁)=1.5010770 (50). The experimental results are in moderate agreement with theoretical calculations.     

Nuclear magnetic resonance in noncollinear antiferromagnet Mn3Al2Ge3O12

The ⁵⁵Mn nuclear magnetic resonance spectrum of noncollinear 12-sublattice antiferromagnet Mn₃Al₂Ge₃O₁₂ has been studied in the frequency range of 200–640 MHz in the external magnetic field H ‖ [001] at T = 1.2 K. Three absorption lines have been observed in fields less than the field of the reorientation transition H _c at the polarization h ‖ H of the rf field. Two lines have been observed at H > H _c and h ⊥ H. The spectral parameters indicate that the magnetic structure of manganese garnet differs slightly from the exchange triangular 120-degree structure. The anisotropy of the spin reduction and (or) weak antiferromagnetism that are allowed by the crystal symmetry lead to the difference of ≈3% in the magnetization of sublattices in the field H < H _c. When the spin plane rotates from the orientation perpendicular to the C ₃ axis to the orientation perpendicular to the C ₄ axis, all magnetic moments of the electronic subsystem decrease by ≈2% from the average value in the zero field.     

Properties of isomeric states and the πd 3/2-vi 13/2 multiplet in194Au

The level structure of¹⁹⁴Au has been studied by observing prompt and delayedγ-rays following¹⁹⁴Pt(p,n) and¹⁹⁵Pt(p,2n) reactions. The conversion electron andγ-ray spectra from the decay of the 0.42s (10^?) and 0.60s (5⁺) isomers at 476 keV and 107.4 keV, respectively, have been measured using the He-jet method. The half-lives of the 6⁺ (278.2 keV, 1.1±0.4 ns), 7⁺ (224.6 keV, 2.6±0.2 ns) and 8⁺ (406.8 keV, 2.9±0.4 ns) members of theπd _3/2-vi _13/2 multiplet have been obtained from the time distributions between cyclotron beam pulses andγ-rays depopulating these levels. A calculation made assuming a pure two-particle configuration for the multiplet predicts very well theB(E2) values for the transitions between the levels of this multiplet but the calculatedB(M1) values are not in agreement with experimental results.     

High-resolution resonance study of the12C+n total cross section in the region of13CT=3/2 states

The¹²C+n total cross section has been studied in the region of the lowestT=3/2 states of¹³C. The firstT=3/2 state at (15108.2±1.2) keV excitation is observed as a weak resonance anomaly. The deduced resonance parameters agree with previous results. At higher excitation energies four sharp anomalies have been observed at (17534±3) keV, (18082±3) keV, (20057±4) keV and (21703±4) keV excitation with total widths between 12 keV and 20 keV. The results are discussed with respect to a possibleT=3/2 assignment. An upper limit of the elasticity (J+1/2) Γ_no/gG is deduced for thoseT=3/2 levels which do not appear as resonance anomalies.     

31P and 13C chemical shielding tensors in the phosphoenolpyruvate moiety from rotary resonance recoupling 13C and 31P MAS and single crystal 31P NMR

A ³¹P and ¹³C NMR study of powder and single crystal samples of two phosphoenolpyruvate (PEP) compounds, the tris-ammonium salt monohydrate (NH₄)₃(PEP)·H₂O (1), and the mono-ammonium-salt (NH₄)(H₂PEP) (2) is presented. The P chemical shielding tensors in 1 are measured by ³¹P single crystal NMR on four minuscule samples and assigned without ambiguity by exploiting the orientation-dependent ³¹P-³¹p dipolar splittings of the resonance lines. The orientation of the ³¹P chemical shielding tensor is discussed in terms of the C_2v — and C₃-type distortions of the phosphate PO₄-coordination sphere. From ¹³C MAS NMR experiments with ³¹P rotary resonance recoupling on polycrystalline powder samples the orientations of the ³¹P chemical shielding tensors in 1 and 2 are obtained, for 1 in very good agreement with the ³¹P single crystal NMR results. Only some of the orientational parameters of the three ¹³C chemical shielding tensors in the PEP moiety of 1 could be derived from ¹³C MAS NMR experiments with ³¹P rotary resonance recoupling.     

Polarization of protons in C12(d,p)C13 reaction

The angular distributions of the polarization of protons from C¹²(d,p)C¹³(g.s) reaction were measured at 200 keV intervals for deuteron energies from 1.40 to 2.40 MeV. Elastic scattering on C¹² at 45 ° (lab) was used to analyze the polarization. Positive sign of the polarization corresponds to the vector productK _d ×K _p . The maximum polarization observed is about 30%. The results are not similar to those obtained from the mirror reaction C¹²(d,n)N¹³ in the same deuteron energy range.     

Mean lives of the 2p P, 3p P, 4p P, and 5p P levels in He I

The beam-foil technique was used to measure the mean lives of four excited levels in the singlet system of neutral helium.     

Reconstruction of randomly under-sampled spectra for in vivo 13C magnetic resonance spectroscopy

PurposeOver the past decade, many techniques have been developed to reduce radiofrequency (RF) power deposition associated with proton decoupling in in vivo Carbon-13 (¹³C) magnetic resonance spectroscopy (MRS). In this work we propose a new strategy that uses data under-sampling to achieve reduction in RF power deposition.Materials and methodsEssentially, proton decoupling is required only during randomly selected segments of data acquisition. By taking advantage of the sparse spectral pattern of the carboxylic/amide region of in vivo ¹³C spectra of brain, we developed an iterative algorithm to reconstruct spectra from randomly under-sampled data. Fully sampled data were used as references. Reconstructed spectra were compared with the fully sampled references and evaluated using residuals and relative signal intensity errors.ResultsNumerical simulations and in vivo experiments at 7 Tesla demonstrated that this novel decoupling and data processing strategy can effectively reduce decoupling power deposition by greater than 30%.ConclusionThis study proposes and evaluates a novel approach to acquire ¹³C data with reduced proton decoupling power deposition and reconstruct in vivo ¹³C spectra of carboxylic/amide metabolite signals using randomly under-sampled data. Because proton decoupling is not needed over a significant portion of data acquisition, this novel approach can effectively reduce the required decoupling power and thus SAR. It opens the possibility of performing in vivo ¹³C experiments of human brain at very high magnetic fields.     

Hyperfine structure measurements in the ground states4 F 3/2,4 F 5/2 and4 F 7/2 of Ta181 with the atomic beam magnetic resonance method

Applying a recently developed evaporation technique for refractory elements the following results have been obtained for Ta¹⁸¹ in an atomic beam magnetic resonance experiment studying the hyperfine structure of 3 levels of the ground state multiplet⁴ F: $$\begin{gathered} g_J (^4 F_{3/2} ) = 0.45024 (4) \hfill \\ \Delta v (^4 F_{3/2} ;F = 5 \leftrightarrow F = 4) = 1822.389 (6) MHz \hfill \\ \Delta v (^4 F_{3/2} ;F = 4 \leftrightarrow F = 3) = 2325.537 (2) MHz \hfill \\ \Delta v (^4 F_{5/2} ;F = 6 \leftrightarrow F = 5) = 1451.476 (7) MHz \hfill \\ \Delta v (^4 F_{5/2} ;F = 5 \leftrightarrow F = 4) = 1537.530 (8) MHz \hfill \\ \Delta v (^4 F_{5/2} ;F = 4 \leftrightarrow F = 3) = 1444.685 (2) MHz \hfill \\ \Delta v (^4 F_{7/2} ;F = 4 \leftrightarrow F = 3) = 1218.372 (2) MHz. \hfill \\ \end{gathered}$$ From these measurements the following constants of the magnetic dipole interaction (A) and the electric quadrupole interaction (B) have been derived: $$\begin{gathered} A (^4 F_{3/2} ) = 509.0801 (8) MHz \hfill \\ B (^4 F_{3/2} ) = - 1012.251 (8) MHz \hfill \\ A (^4 F_{5/2} ) = 313.4681 (8) MHz \hfill \\ B (^4 F_{5/2} ) = - 834.820 (12) MHz. \hfill \\ \end{gathered}$$      

Photoionization cross section of Xe+ ion in the pure 5p5 2P3/2 ground level

Coupling an ion trap with synchrotron radiation is shown here to be a powerful approach to measure photoionization cross sections on ionic species relaxed in their ground state. The photoionization efficiency curve of Xe+ ions stored in a Fourier transform ion cyclotron resonance ion trap was recorded at ELETTRA in the 20-23 eV photon energy range. Absolute cross sections were derived by comparison of the photoionization yield of Xe+ with measurements from the ASTRID merged-beam experiment. Multiconfiguration Dirac-Fock calculations were performed for the interpretation of these new data.     

Atomic beam measurement of the lifetime of the3 P 1 metastable states of Mg and Ca

The lifetime of the metastable level³ P ₁ of Mg and Ca have been measured in an atomic beam experiment. We excite the atoms to the³ P ₁ state by electron collisions and we measure the decay length of the light emitted by the beam. The velocity distribution of the atoms is also measured by a time-of-flight technique. The decay length and the velocity measurements are then combined to compute the required lifetimes. The results are (2.4±0.2)×10^?3 sec for Mg and (0.55±0.04)×10^?3 sec for Ca.     

Continuous measurements of stable carbon isotopes in CO2 with a near-IR laser absorption spectrometer

A near-IR laser absorption spectrometer using a technique of wavelength modulation spectroscopy is used to measure stable carbon isotope ratios of ambient CO₂ (δ¹³C) via the absorption lines ¹²CO₂ R(17) (2ν₁ + ν¹₂ − ν¹₂ + ν₃) at 4978.205 cm⁻¹ and ¹³CO₂ P(16) (ν₁ + 2ν₂ + ν₃) at 4978.023 cm⁻¹. The isotope ratios are measured with a reproducibility of 0.02‰ (1σ) in a 130-s integration time over a 12-h period. The humidity effect on δ¹³C values has been evaluated in laboratory experiments. The δ¹³C values of CO₂ in ambient air were measured continuously over 8 days and agreed well with those from isotope ratio mass spectrometry of canister samples. The spectrometer is thus capable of real-time, in situ measurements of stable carbon isotope ratios of CO₂ under ambient conditions.     

Hyperfine structure measurements in the ground states5 F 5,5 F 4,5 F 3 and5F2 of99Ru and101Ru with the atomic beam magnetic resonance method

The hyperfine structure of the four lowest levels⁵ F _{5, 4, 3, 2} of the⁵ F ground state multiplet arising from the configuration 4d ⁷ 5s in⁹⁹Ru and¹⁰¹Ru has been studied by the atomic — beam magnetic — resonance technique. After applying corrections due to the effects of off-diagonal hyperfine mixing we obtain the following multipole interaction constants:⁹⁹Ru:A(⁵ F ₅)=?204.5514(33) MHzB(⁵ F ₅)=27.281 (62) MHzA ⁵ F ₄=?163.6845(36) MHzB(⁵ F ₄)=17.455(52) MHzA ⁵ F ₃=?135.0294(37) MHzB(⁵ F ₃)=10.164(50) MHzA(⁵ F ₂)=? 82.5325(27) MHzB(⁵ F ₂)=5.457(22) MHz¹⁰¹Ru:A(⁵ F ₅)=?229.2881(33) MHzB(⁵ F ₅)=158.934(62) MHzA(⁵ F ₄)=?183.4744(36) MHzB(⁵ F ₄)=101.799(52) MHzA(⁵ F ₃)=?151.3502(38) MHzB(⁵ F ₃)=59.323(50) MHzA(⁵ F ₂)=?92.4974(27) MHzB(⁵ F ₂)=31.869(23) MHz. The magnetic dipole and the electric quadrupole moments of the⁹⁹Ru and¹⁰¹Ru nuclear ground states as calculated from these constants are the following:μ _I (⁹⁹Ru)=?0.594(119) nmQ(⁹⁹Ru)=0.077 (15) barnsμ _I (¹⁰¹Ru)=?0.666(133)nmQ(¹⁰¹Ru)=0.45 (9) barns. From measurements of the Zeeman effect in the even isotope¹⁰²Ru we find the followingg _J -factors for the⁵ F ground multiplet:g _J (⁵ F ₅)=1.397741(20)g _J (⁵ F ₄)=1.347604(20)g _J (⁵ F ₃)=1.248988(20)g _J (⁵ F ₂)=1.001120(3).