The absorptive pion-nucleus optical potential

We calculate s-wave and p-wave absorptive pion-nucleus optical potentials assuming that a pion is absorbed by a pair of nucleons. Employing a model which takes into account both a single nucleon absorption with nucleon-nucleon correlations and rescattering, we obtain simple analytic expressions for Im B₀ sid Im C₀ of the pion-nucleus optical potential. The off-shell effect on the s-wave pion absorption is examined and shown to be strongly modified by short range correlations. The result for the p-wave absorptive part Im C₀ clearly shows the importance of the tensor correlations. The enhanced nn emission after π^? absorption is shown to be related with a large p-wave πN scattering length a₃₃ via the tensor correlations.     

Optical absorption in sputtered amorphous phosphorus

Optical absorption measurements are reported on r.f. sputtered films of a-P prepared at variable substrate temperatures. With decreasing substrate temperature the absorption spectra shift to lower frequencies and the energy gap decreases. The form of the spectra are, however, similar both in the band edge and Urbach tail regions. The Urbach slope is found to differ substantially from that of a-As, indicating that factors other than coordination number may influence this parameter. The changes in the absorption spectra are suggestive of a possible role of intermediate range order on the electronic states in a-P.     

Optimal properties of semimagnetic compound Pb1−xGdxTe with x=0.01 and 0.025

Reflectivity and transmission spectra of a new semimagnetic compound Pb_1−xGd_xTe with x=0.01 in the 300-77K temperature range are reported.From reflectivity data the high dielectric constant ϵ(∞) is deduced. Lyddane-Sachs-Teller relation gives the static dielectric constant ϵ(0). The conductivity effective mass m¹_c measured from the plasma frequency agrees well with the one deduced from absorption measurements α vs the wavelength in the short wavelength range.The energy gap as well as its temperature dependence is given by absorption data. The introduction of low concentration magnetic ion Gd does not affect drastically the optical properties of the material comparatively to the optical PbTe ones.     

Analysis of two particle rapidity correlations at ISR energies

The short range two particle rapidity correlations at ISR energies are interpreted in terms of clustering effects in the central rapidity region. It is shown that the experimental data give an indication that large clusters are produced, and as a consequence one should observe short range correlation between π^?′s. The energy dependence of the data is also simply explained.     

Rapidity correlations in π+ p,K + p andpp interactions at 250 GeV/c

Two- and three-particle rapidity correlations are analyzed inK ⁺ p and π⁺ p-interactions at 250 GeV/c. The main contribution to the two- and three-particle correlation functions comes from mixing of events of different multiplicity. The (short range) two-particle correlation remaining after exclusion of mixing is significantly larger for (+?) than for the equal charge combinations, and is positive for a wider range in rapidity difference. FRITIOF and a 2-string DPM are excluded by our data. A quark-gluon (multi-)string model can describe our inclusive correlation function, but needs to be tuned on the short range part. The multiplicity mixing part increases much faster with increasing energy than the short range part. In the central region, our correlation is similar to that observed ine ⁺ e ^? and μp collisions at similar energy.     

Absorption spectra near the absorption edge of the system HgxZn1−xCr2Se4

Optical absorption spectra near the absorption edge of the system Hg_xZn_1?xCr₂Se₄ have been measured for various compositions in the temperature range between room and liquid helium temperatures. A correlation between the optical properties and magnetic structures becomes obvious from the measurements of the energy at the absorption edge and the change in the magnetic property with composition variation, and by measuring the optical absorption spectra under the applied magnetic field.     

Semiconducting properties of CuIn5S8 single crystals II. Near infrared absorption

Near infrared absorption spectra of n-type CuIn₅S₈ single crystals were measured. Two structures were found in the spectra in the photon energy range from ?ω ? 0.3 eV?1.2 eV. One of them is the free carrier absorption below 0.6 eV in which the absorption coefficient increases as the third power of the wavelength. It was found that this absorption was associated with the multiple scattering mechanisms. Another structure seems, from its temperature and carrier-concentration dependences, to be associated with an absorption due to a transition from a lower lying conduction band to an upper one.     

Giant red shift of the absorption spectra due to nonstoichiometry in GdCoO<Subscript>3–δ</Subscript>

The GdCoO_3–δ perovskite is a semiconductor with the energy gap E _g ≈ 0.5 eV from electrical transport measurements. It reveals unusual optical absorption spectra without transparency window expected for semiconductors. Instead we have measured the narrow transmittance peak at the photon energy ε₀ = 0.087 eV. To reconcile the transport and optical data we have studied the effect of oxygen vacancies on the electronic structure of the GdCoO_3–δ. We have found that oxygen vacancies result in the in-gap states inside the charge-transfer energy gap of the GdCoO₃. It is a multielectron effect due to strong electron correlations forming the electronic structure of the GdCoO_3–δ. These in-gap states decrease the transparency window and result in a narrow absorption minimum. The predicted temperature dependence of the absorption spectra has been confirmed by our measurements.     

Spallative ablation of dielectrics by X-ray laser

A short laser pulse in wide range of wavelengths, from infrared to X-ray, disturbs electron–ion equilibrium and increases pressure in a heated layer. The case where the pulse duration τ _L is shorter than acoustic relaxation time t _s is considered in the paper. It is shown that this short pulse may cause thermomechanical phenomena such as spallative ablation regardless of wavelength. While the physics of electron–ion relaxation strongly depends on wavelength and various electron spectra of substances: there are spectra with an energy gap in semiconductors and dielectrics opposed to gapless continuous spectra in metals. The paper describes entire sequence of thermomechanical processes from expansion, nucleation, foaming, and nanostructuring to spallation with particular attention to spallation by X-ray pulse.     

X-Ray M5 absorption limits of Au,Tl, Pb and Bi

The combination defects of the X-ray M₄ and M₅ absorption limits of Ta to Bi have been studied, and the energies of the absorption limits compared with the level energies obtained by XPS. The M₅ absorption spectra of Au, T1, Pb and Bi in the metallic state have been investigated carefully, and, as expected, a weak subsidiary absorption discontinuity found on the low energy side of the apparent M₅ absorption discontinuity in the respective spectra. Finally, it has been shown that the absorption limit on the subsidiary absorption discontinuity gives the true M₅ absorption limit for these elements.     

Optical absorption near the melting point of LiNO3 crystal

Temperature dependence of the absorption spectrum in the ultraviolet region below 4.2 eV is measured in the temperature range from room temperature to just below the melting point T_M of LiNO₃ crystal. Anomalous behaviors in the observed spectra are found on approaching to T_M. The low energy tails of the spectra are analyzed by using Urbach rule. The steepness parameter σ(T), derived from the experimental results, also shows anomalous temperature change near T_M.     

Critical relaxation of short range correlations in the mixed crystal Rb1-x (ND4)x D2PO4

We have used thermal neutron scattering to investigate the possible dynamical origin of the short range correlations being typical for the glass phase of the mixed crystals Rb_1–x(ND₄)_xD₂PO₄. A quasielastic spectrum has been found for these correlations on top of a very broad spectrum associated with local correlations. The temperature dependence of these spectra together with their elastic components has been determined with an energy resolution of 0.14 meV. A common freezing temperature of about 100 K is observed below which the spatial correlations stop to increase and the scattering becomes elastic within the instrumental time scale.Dedicated to K. Dransfeld on the occasion of his 60th birthday     

Specific features of the electronic structure and spectral properties of NdNi5 − x Cu x compounds

The spectral properties of the intermetallic compounds NdNi_{5 ? x} Cu _x (x = 0, 1, 2) have been studied using optical ellipsometry in the wavelength range 0.22–16 μm. It has been established that substitution of copper atoms for nickel leads to noticeable changes in the optical absorption spectra, plasma frequencies, and relaxation frequencies of conduction electrons. Spin-polarized calculations of the electronic structure of these compounds have been performed in the local spin density approximation allowing for strong electron correlations (LSDA + U method) in the 4f shell of the rare-earth ion. The calculated electron densities of states have been used to interpret the experimental dispersion curves of optical conductivity in the interband light absorption region.     

Identification of singlet excited electronic states of hydroxybenzoic acid isomers

The photoelectron spectra of benzoic and para-, meta-, and ortho-hydroxybenzoic acids and their UV absorption spectra in ethanol are obtained. The photoelectron spectra in the energy region up to 15.5 eV are interpreted based on the B3LYP/6-311+G(d, p) calculations. Based on the TDDFT B3LYP/6-311+G(d, p) calculations and taking into account the obtained interpretation of photoelectron spectra, the UV absorption bands are assigned to particular singlet transitions. For each transition, the electron configuration that makes the main contribution to the transition is determined. It is shown that the transition energy depends on the energy gap between the corresponding occupied and unoccupied molecular orbitals.     

Fundamental absorption spectra of transition metal chlorides

The optical absorption spectra of MnCl₂, FeCl₂, CoCl₂, and NiCl₂ have been measured over the energy range from 2 to 30 eV. The gross features of the spectra, especially broad bands above 10eV, are alike in all of the four materials. The charge transfer bands due to the electronic transitions from the 3p level of chlorine to the 3d and 4s levels of metal ions and the band due to the 3d → 4s transition are assigned in the spectra.     

Time-resolved luminescence of LaBr3-Ce scintillation crystals upon selective UV-VUV-XUV excitation

The time-resolved photoluminescence (PL) of LaBr₃-Ce scintillation spectrometric crystals produced in Russia is measured upon excitation using synchrotron radiation with photon energies of 3.7–21 and 45–290 eV at temperatures of 295 and 7.5 K. The PL spectra and decay curves are measured for excitation in the transparency range, at the edge of fundamental absorption, at the interband transitions, and in the range of inner-shell absorption. It is demonstrated that the PL yield is not proportional to the excitation energy, and that the PL decay curves are modified in the range of photoionization of the 3d (Br) and 4d (La) inner shells and, especially, in the range of giant resonance.     

Three particle correlation function of metal ions in tetrahedral coordination determined by XANES

The three particle correlation function of local atomic distribution at metal ion sites in solutions has been extracted from XANES (X-ray absorption near edge structure) spectra of [CrO₄]²⁻ and [MnO₄]⁻ ions measured by using synchrotron radiation. The absorption cross section for 1s core level excitation is calculated in the real space multiple scattering approach using the Hedin and Lundqvist energy dependent potential. We show that in these systems the expansion of the total absorption cross section in terms of contributions of higher order scattering processes is possible over a large energy range. This gives a unified theory of XANES and EXAFS and allows the third order correlation function to be extracted from experimental data.     

Electron scattering from some even fp- and N50-shell nuclei with implanting the influence of short-range correlation functions

The influence of two body short range correlations on elastic electron scattering charge form factors, charge densities as well as root mean square charge radii of some fp-shell nuclei (for example, ⁴⁸Ca, ⁵⁰Cr, ⁵⁴Fe, ⁵⁸Ni, ⁷⁰Ge and ⁷⁴Se) and some N50-shell nuclei (for example, ⁸⁸Sr and ⁹⁰Zr) is analyzed using the one- and two-body terms in the cluster expansion together with the single particle harmonic oscillator wave functions. The Jastrow-type correlation function is utilized to embed the effect of short range correlations into elastic charge form factors F(q) and charge densities ρ(r). Both F(q) and ρ(r) depend upon the harmonic oscillator parameter b and the correlation parameter β (which initiates from the Jastrow correlation function). Here, the parameters b and β are determined via the fitting to the measured charge form factors. The embedding of short range correlations imitates the measured charge form factors at the high momentum transfers (q ≥ 2 fm⁻¹). It is noticed that the implanting of short range correlations is required for obtaining a remarkable alteration in the computed elastic charge form factors which in turn leads to explain the data of electron scattering astonishingly throughout the entire range of considered momentum transfers.     

Energy structure and absorption spectra of colloidal CdS nanocrystals in gelatin matrix

We investigate the energy structure of colloidal CdS nanocrystals by measuring the UV–vis absorption spectra. Nanocrystals were synthesized by sol–gel method in a gelatin matrix in the size range from 2.5 to 3.9 (±0.2) nm. In order to interpret the UV–vis absorption spectra we calculate the energy spectrum of electron quasi-stationary states using the model of open nanocrystal as well as the hole stationary spectrum in a two-band approach. It is shown that the main contribution to the absorption spectrum is made by interband transitions 1S_3/2→1S_e and 1P_3/2→1P_e, and its shape is determined by the size distribution of nanoparticles. For this system the estimated values of the effective masses of the heavy hole and light hole are 1.44m₀ and 0.28m₀, respectively.     

Energy gap and optical dielectric constant of Pb1−xCdxSe films

The transmission spectra of laser-deposited Pb_1−xCd_xSe films (x = 0, 0.02, 0.05, 0.08 and 0.12) have been measured over the energy range 0.1–0.65 eV at two different temperatures 90 and 300 K. From these spectra the dispersion of the refractive index and the absorption coefficient-energy dependence have been obtained. Thus the dependences of the gap and the optical dielectric constant on the Cd content x have been investigated. The experimental results have been discussed in the framework of the recently developed theoretical model by Volkov and Pankratov et al^1,2.