Time resolved spectroscopic studies of a FXR discharge

Time resolved spectroscopic studies of some electrode material lines and an impurity line have been performed in a flash X-ray (FXR) discharge. The results indicate that the breakdown takes place in impurities and adsorbed gases released from the electrodes. Thereafter, a front of anode material propagating with a velocity of (1–2)×10⁶ cm/sec moves towards the cathode. A cloud of cathode material is localized outside the cathode during an early stage of the discharge. The anode front and the cathode cloud penetrate each other after current maximum and a “metallic arc” is formed between the electrodes     

Control of the clustering process in molecular beams using IR lasers

The prebreakdown stage of a gas discharge in a diode with strongly overloaded cathode is studied by laser methods (by simultaneous use of multiframe interferometry and shadow and schlieren photographing) at atmospheric pressure. The spatial resolution of the methods is about 20 μm. A probing pulse of a laser (LS-2151 Nd: YAG laser with a half amplitude duration of 70 ps and a pulse energy of up to 40 mJ) is synchronized with a voltage pulse with accuracy of about 1 ns. High field strength at the cathode is achieved due to the use of thin individual metal tips on the electrodes. It is shown that the initial stage of breakdown of a discharge gap is accompanied by the emergence of a dense plasma cloud at the end of a tip with electron density of about 5 × 10¹⁹ cm^–3 with a size of tens of microns, as well as by a sharp increase in the total current through the diode. After the emergence of a dense plasma cloud at the end of a cathode tip, a similar cloud is formed on the surface of the anode; sometime later, these clouds join together and form a tubular current channel. The dynamics of the breakdown, as well as the parameters of the plasma are studied by the abovementioned techniques in three independent optical channels.     

The binding of CO molecule with small Wn(n = 2−9) clusters: a DFT investigation

The effect of water conductivity on electrospraying of water was studied in combination with positive DC corona discharge generated in air. We used a point-to-plane geometry of electrodes with a hollow syringe needle anode opposite to the metal mesh cathode. We employed total average current measurements and high-speed camera fast time-resolved imaging. We visualized the formation of a water jet (filament) and investigated corona discharge behavior for various water conductivities. Depending on the conductivity, various jet properties were observed: pointy, prolonged, and fast spreading water filaments for lower conductivity; in contrast to rounder, broader, and shorter quickly disintegrating filaments for higher conductivity. The large acceleration values (4060 m/s² and 520 m/s² for 2 μS/cm and 400 μS/cm, respectively) indicate that the process is mainly governed by the electrostatic force. In addition, with increasing conductivity, the breakdown voltage for corona-to-spark transition was decreasing.     

Grid control over high currents in a cesium discharge with a cathode spot

We report on the results of investigation of a plasma switch with complete grid control in a discharge with a cathode spot on the liquid-metal cesium cathode without grid diaphragming. The retention of the working area of the grid relative to the anode area leads to an order-of-magnitude increase in the switching anode current (up to 20 A/cm² over the anode area) and a substantial (up to 100 V and higher) increase in the switching voltages. The use of the cathode jet makes it possible to reduce the working pressures of cesium vapor (down to 10^–3 Torr). We discuss the results of analysis of peculiarities of grid discharge quenching in such a switch, which make it possible to determine possible reasons for limitation of the working parameters of the switch and the ways of their further increase.     

The effect of external visible light on the breakdown voltage of a long discharge tube

The breakdown characteristics of a discharge tube with a configuration typical of gas-discharge light sources and electric-discharge lasers (a so-called “long discharge tube”) filled with argon or helium at a pressure of 1 Torr have been investigated. A breakdown has been implemented using positive and negative voltage pulses with a linear leading edge having a slope dU/dt ~ 10–10⁷ V/s. Visible light from an external source (halogen incandescent lamp) is found to affect the breakdown characteristics. The dependences of the dynamic breakdown voltage of the tube on dU/dt and on the incident light intensity are measured. The breakdown voltage is found to decrease under irradiation of the high-voltage anode of the tube in a wide range of dU/dt. A dependence of the effect magnitude on the light intensity and spectrum is obtained. Possible physical mechanisms of this phenomenon are discussed.     

Plasma-volume generation of H<Superscript>−</Superscript> ions in a low-voltage xenon-hydrogen discharge. II

A low-voltage xenon-hydrogen discharge is considered theoretically at an interelectrode distance of L = 1 cm and cathode emission current densities of j _s = 2–20 A/cm². Basic parameters of the discharge plasma, in particular, the total hydrogen and xenon densities, are optimized to attain the maximum possible density of negative hydrogen ions \(N_{H^ - } (L)\) at the plasma-anode boundary. The distributions of the plasma parameters over the discharge gap are calculated for optimized regimes. According to calculations, at intermediate cathode emission current densities (j _s ≈ 5–10 A/cm²) in optimized discharge regimes, the density of negative hydrogen ions in the anode region of the plasma is \(N_{H^ - } (L)\) ≈ (1.5–2.5) × 10¹² cm^?3 and the total plasma pressure is p ₀ = 0.5–0.6 Torr.     

Some Investigations of the Ignition and Development of Breakdown in Cylindrical Hollow Cathode Glow Discharges

The breakdown behaviour of a hollow cathode glow discharge is investigated in a cylindrical, hollow cathode structure having an internal diameter of 2 cm. The anode is a plane electrode across one end of the cathode cylinder. Pressures of argon between 20 and 107 Pa were used (0.15 to 0.80 torr), and applied voltages between 800 and 2500 V. It is shown that the statistical time lag for breakdown is in the range of ～ 1 ms and depends on the applied voltage, the gas pressure, and the history of operation of the discharge tube. The rise time of the discharge current ranges from about 10 ns at high pressure and voltage to about 200 ns at the lowest pressure and voltage used. The discharge propagates along the cathode axis at a speed of about 10⁸ cm s^?1. From the obtained data, a qualitative model of the first stage of the discharge is derived. Based on this model, a simple calculation gives values of Townsend modified first coefficient η at high values of E/N, 10⁴ < E/N < 8 · 10⁴ Td which fit well at the lowest E/N, where they approach the data of PENNING and KRUITHOF in argon. In contrast to the extremely short initial current-rise times, in the submicrosecond range, the discharge currents reach steady-state values only after about 300 μs.     

Micro-gated-field emission arrays with single carbon nanotubes grown on Mo tips

Using our approach previously reported, we have fabricated relatively large area micro-gated-field emission arrays with carbon nanotube (CNT) grown on Mo tips. By redesigning the device and fabrication processes, the percentage of single CNTs increased to about 50-70% with a substantial improvement in leakage current between gate and cathode and gate interceptive current. The I-V measurement of a 11000 cell array at a gate to cathode voltage of 92 V showed an anode current of 1.2 mA, corresponding to a current density of 0.57 A/cm², with a gate current only 3.3% of the anode current.     

Effect of the configuration of the discharge chamber of the plasma focus on the neutron yield

Preliminary probe experiments on the Filippov-type plasma focus with the energy E = 70 kJ and a current of about 1 MA show significant stray currents flowing near the insulator. To suppress them and optimize the discharge circuit, the main discharge chamber elements, i.e., the insulator, anode and cathode liner, were changed. As a result, a 30-fold increase in the setup neutron yield to Y _n = 5· 10¹⁰ neutrons per pulse was detected.     

Emission properties of a plasma cathode based on a glow discharge for generating nanosecond electron beams

The emission properties of a plasma cathode based on a nanosecond pulsed glow discharge with currents of up to 200A at a pressure of 5×10⁻² Pa are studied experimentally. Stable ignition and burning of the discharge are ensured if the current in the auxiliary pulsed discharge is 25–30% of that in the main discharge and its pulse duration exceeds that of the main discharge by more than an order of magnitude. Emission current pulses from the cathode with amplitudes of up to 140A fully reproduce the discharge current and are determined by the transparency of the grid anode. Zh. Tekh. Fiz. 69, 62–65 (November 1999)     

Das Eindringen der Glimmentladung in Spalte

The fractional area of the cathode covered by the negative glow in low pressure hydrogen discharges has been studied using a special co - planar anode - cathode configuration. The cathode was a steel bar of 2×2×64 cm, sectionalised into 32 insulated parts. An identical electrode mounted directly above the cathode at a variable separation facilitated the simulation of screening effects of insulating or conducting walls and of hollow cathode conditions. The depth of penetrationξ of the discharge into this gap was studied for various conditions. In general for the insulating wall condition,ξ is approximately proportional to the applied voltage and depends on the gap width and pressure. The electron current in the negative glow parallel to the cathode surface as well as the cathode current density at any distancex from the anode vary exponentially withη=ξ-?. The potential of the negative glow in the gap decreases slowly with? to the “normal” cathode fall at?=ξ. In the case of the conducting wall, the discharge can penetrate to any depth, provided the wall is maintained at a potential ≧ the “normal” cathode fall. For a hollow cathodeξ is small, but the current density near the anode reaches extremely high values.     

Photographic appearance of high-current vacuum arcs prior to and during anode spot formation

This article presents the results of research on the photographic appearance of a highcurrent vacuum arc between butt type copper electrodes a of 30–80 mm diameter and a fixed gap of 10 mm. Current pulses of up to 30 kA peak amplitude at an initial value of (di/dt)₀ from 1–10kA/ms and a duration of approximately 14 ms were applied. Arcs were photographed with a high-speed framing camera, mostly at 10⁴ frames/s. A detailed study of discharge modes in phase transition from a high-current diffuse arc to a constricted arc with an anode spot was conducted. Most of the measurements were obtained at a peak current slightly in excess of 10 kA for electrodes of 55 mm diameter. It was found that at peak current exceeding moderately the threshold value of the onset of anode spot formation, the arc is characterized by the following main features: the formation of an anode spot and an anode plasma jet occurs concurrently with a local concentration of cathode spots; the anode spot is, most often, formed on the electrode edge; the coexistence of very varied structures of spots on the cathode; the lack of considerable constriction of the cathode discharge; the pseudo-periodic shrinking and expansion of the area occupied by cathode spots; the existence of a relatively dark space separates the anode plasma jet from the plasma sheath near the cathode surface; the plasma space distribution in the interelectrode gap is non-uniform and non-stationary.This work was supported by State Committee for Scientific Research within the research project No. 3 P40101507.     

Experimental Studies on Low-Pressure Plane-Parallel Hollow Cathode Discharges

Hollow cathode discharge (HCD) is widely used in material processing and plasma emission spectroscopy due to several advantages over other plasma sources. Basically, the HCD consists of a cathode with a hollow structure (cavity, hole, or parallel faces) and an anode of arbitrary shape. In this investigation, experimental studies on low-pressure plane-parallel HCD operated at different process conditions are reported. Herein, we investigate the dependence of the discharge current on the product of the gas pressure and inter-cathode distance (pD). In addition, the electron temperature and density were inferred from the current-voltage characteristics of a single cylindrical Langmuir probe positioned between the cathodes, on the discharge axis. The measurements were carried out at different gas pressures, magnetic field intensities, working gases, inter-cathode distances, cathode materials, and discharge voltages. The results showed that, at different gas pressures, the maximum discharge current (I_d,max) is not only a function of the product pD, but also of the pressure itself. Application of a uniform longitudinal magnetic field improved plasma confinement between cathodes, leading to a substantial increase in I_d,max in most of the situations considered in this study. However, for oxygen discharge, a strong discharge current reduction after the application of the magnetic field was observed. In relation to the Langmuir probe studies, it was observed that the uniform longitudinal magnetic field reduced the electron temperature, but this behavior depends strictly on pD. The typical values of electron density and electron temperature in the case of the nitrogen discharge were n_e?=?10¹⁷ m^?3 and T_e?=?2.5 eV, respectively. Finally, our experiments showed that the pD range for hollow cathode effects was between 0.2–5 Pa m.     

Exploding wires in air and vacuum

An apparatus for studies of wire explosions in air at atmospheric as well as reduced pressures is described. A theoretical treatment of the discharge circuit is presented. In this treatment the external resistance and inductance as well as the wire inductance (all as functions of time) have been taken into consideration. It is then possible to calculate the wire variables — current, resistance, resistive voltage drop, effect, and energy input — as functions of time from thedI/dt waveform experimentally obtained. Wire variables of Ni- and W-wires exploded both in air and vacuum are presented as well as a discussion of these.     

Droplet spot as a new object in physics of vacuum discharge

It is established experimentally that the burning of a low-current (several and tens of amperes) pulsed (microseconds) vacuum discharge is accompanied by the formation of plasma microbunches around some of the droplets leaving the cathode spot. The parameters of these bunches (electron concentration n _e～10²⁶ m^?3 and equilibrium temperature T _e～1 eV) are close to the parameters of cathode-spot plasma. The data obtained suggest that the initial temperature of droplets and the thermionic emission from them play a key role in the formation of such plasma microbunches. By analogy with the well-known cathode and anode spots in vacuum discharges, these droplet plasma formations are classified as “droplet spots.” This work reports the first results on studying the formation dynamics and the characteristics of the droplet spots. It is noted that the concept of droplet spots will require a certain refinement of the plasma formation mechanism in vacuum discharges.     

Sulfur/microporous carbon composites for Li-S battery

A commercial carbon black with microporous framework is used as carbon matrix to prepare sulfur/microporous carbon (S/MC) composites for the cathode of lithium sulfur (Li-S) battery. The S/MC composites with 50, 60, and 72 wt.% sulfur loading are prepared by a facile heat treatment method. Electrochemical performance of the as-prepared S/MC composites are measured by galvanostatic charge/discharge tests, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS), with carbonate-based electrolyte of 1.0 M LiPF₆/(PC-EC-DEC). The composite with 50 wt.% sulfur presents the optimized electrochemical performance, including the utilization of active sulfur, discharge capacity, and cycling stability. At the current density of 50 mA g^?1, it can demonstrate a high initial discharge capacity of 1624.5 mAh g^?1. Even at the current density of 800 mA g^?1, the initial capacity of 1288.6 mAh g^?1 can be obtained, and the capacity can still maintain at 522.8 mAh g^?1 after 180 cycles. The remarkably improved electrochemical performance of the S/MC composite with 50 wt.% sulfur are attributed to the carbon matrix with microporous structure, which can effectively enhance the electrical conductivity of the sulfur cathode, suppress the loss of active material during charge/discharge processes, and restrain the migration of polysulfide ions to the lithium anode.     

Measurement of electrode overpotentials for direct hydrocarbon conversion fuel cells

Cathodic and anodic overpotentials were measured using current interruption and AC impedance spectroscopy for two separate solid oxide fuel cells (SOFCs). The fuel cells used yttria-stabilized zirconia (YSZ) as the electrolyte, strontium-doped lanthanum manganite (LSM) as the cathode, and a porous YSZ layer impregnated with copper and ceria as the anode. The Cu/CeO₂/YSZ anode is active for the direct conversion of hydrocarbon fuels. Overpotentials measured using both current interruption and impedance spectroscopy for the fuel cell operating at 700 °C on both hydrogen and n-butane fuels are reported. In addition to providing the first electrode overpotential measurements for direct conversion fuel cells with Cu-based anodes, the results demonstrate that there may be significant uncertainties in measurements of electrode overpotentials for systems where there is a large difference between the characteristic frequencies of the anode and cathode processes and/or complex electrode kinetics.     

Growth of the spark current at the breakdown of short vacuum gaps at steady voltage

The growth time of the spark current at the time of breakdown in vacuum at the constant voltage and pressure existing during this period was investigated with high time resolution. It was shown that, as in the case of a pulsed breakdown: 1) the growth time t_c of the current increases in proportion to the length d of the gap and the ratio d/t_c is 2.5·10⁶ cm/sec; 2) the transition to a rapid rate of current growth (di/dt > 10⁸ A/sec) takes place in 1–3 nsec; 3) during the period of current growth, x-ray radiation appears and a transfer of anode material to the cathode is observed. These results serve as evidence that the origin of current growth is connected with the appearance of efficient electron sources on the cathode. These, as in the case of pulsed breakdowns, are evidently cathode flares, the formation of which has an explosive character and can be identified with the act of breakdown initiation. In essence this event does not change with the rate at which voltage is supplied across the gap and consists of the explosive disintegration of emitting microspikes on the cathode. The appearance of cathode flares indicates the start of an irreversible breakdown of vacuum insulation. The emergence of a burst of x-rays and the erosion of the anode are explained by the action on the anode of a powerful stream of electrons that are emitted from the cathode flares, providing the spark current.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii Fizika, No. 9, pp. 93–97, September, 1971.The authors thank G. A. Mesyats for his constant attention to the work.     

Initiation of ecton processes by interaction of a plasma with a microprotrusion on a metal surface

Evolution of rapid (～10 ns) Ohmic overheating of a microprotrusion on a surface in contact with a plasma by emission current is studied taking into account the energy carried by plasma ions and electrons, as well as Ohmic heating, emissive source of energy release (Nottingham effect), and heat removal due to heat conduction. Plasma parameters were considered in the range of n = 10¹⁴?10²⁰ cm^?3 and T _e = 0.1 eV?10 keV. The threshold value of energy transferred to the surface from the plasma is found to be 200 MW/cm²; above this value, heating becomes explosive (namely, an increase in the temperature growth rate (δ² T/δt ² > 0) and in passing current (δJ/δt > 0) is observed in the final stage at T ～ 10⁴ K and j ～ 10⁸ A/cm²). In spite of the fact that Ohmic heating does not play any significant role for plasmas with a density lower than 10 18 cm^?3 because the current is limited by the space charge of electrons, rapid overheating of top of microprotrusion is observed much sooner (over a time period of ～1 ns) when the threshold is exceeded. In this case, intense ionization of vapor of the wall material leads to an increase in the plasma density at the surface, and the heating becomes of the Ohmic explosion type. Such conditions for the formation of a micr?xplosion on the surface and of an ecton accompanying it can be created during the interaction of a plasma with the cathode, anode, or an insulated wall and may lead to the formation of cathode and anode spots, as well as unipolar arcs.     

有机薄膜电致发光器件载流子注入和传输性质的研究

制备了不同电极、不同厚度、以8-羟基喹啉铝螯合物(Alq3)为发光层的有机薄膜电致发光(TFEL)器件。分析了它们的电流密度-电压关系。不同阳极器件的电流变化很大,而改变阴极时电流密度的变化较小,说明电流以空穴为主。根据不同阴极器件的电致发光效率的比较,说明电子是决定器件电致发光效率的少数载流子。从不同厚度的器件的结果讨论了载流子的传输性质,认为在ITO/Alq3/Al器件中的电流符合陷阱限制的空间电荷电流.