共查询到20条相似文献,搜索用时 31 毫秒
1.
C.-W. Chen C.-H. Lin H.-P. Chiang Y.-C. Liu P.T. Leung W.S. Tse 《Applied Physics A: Materials Science & Processing》2007,89(2):377-380
The temperature dependence of the sensitivity of an optical sensor based on long-range surface plasmon resonance (LRSPR) is
studied via theoretical modeling. Both the ‘angular interrogation’ and the ‘wavelength interrogation’ modes of operation are
studied. In addition, the variation of the full width at half maximum of the LRSPR ‘reflectance dip’ is also studied as a
function of temperature, which ultimately determines the temperature dependence of the sensitivity of the sensor when the
reflectance is monitored at a fixed incident angle (‘reflectance interrogation’). It is found that while most of the time
only the ‘reflectance interrogation’ mode leads to improved sensitivity for the LRSPR sensor compared to a conventional SPR
sensor, the temperature stability of the operation of the LRSPR sensor is generally higher than (or at least comparable to)
that of the SPR sensor.
PACS 73.20.Mf; 07.07.Df 相似文献
2.
Controlled plasmon coupling is observed in nanoparticle assemblies composed of 20 nm silver ‘satellite’ nanoparticles tethered
by reconfigurable duplex DNA linkers to a 50 nm gold ‘core’ particle. The assemblies incorporate silver nanoparticle–oligonucleotide
conjugates prepared using a new conjugation method in which the recognition strand is anchored by a 10 base pair, double strand
spacer that presents adjacent 3’- and 5’-thiols to the silver surface. Reconfiguration of the DNA linkers from a compact to
an extended state results in decreased core–satellite coupling and a blue-shift in the gold core plasmon resonance. The structural
basis for the observed resonance modulation is investigated through simulation of the scattering spectra of binary assemblies
with various core–satellite separations. Additional simulations of core–satellite assemblies composed of gold satellite particles
bound to silver cores and of assemblies composed entirely of silver particles are used to clarify the dependence of the coupling
response on the composition of the components and their distribution within the assembly.
Electronic Supplementary Material The online version of this article () contains supplementary material, which is available to authorized users. 相似文献
3.
Zhen Guo Li Liang Jia-Jie Liang Yan-Feng Ma Xiao-Ying Yang Dong-Mei Ren Yong-Sheng Chen Jian-Yu Zheng 《Journal of nanoparticle research》2008,10(6):1077-1083
Novel β-cyclodextrin covalently modified single-walled carbon nanotubes have been synthesized via a ‘click’ coupling reaction.
The product was fully characterized with Raman, FTIR, XRD, UV-Vis-NIR spectra as well as TEM and TGA measurements. The effective
functionalization via ‘click’ coupling has set up a facile and versatile route for modular preparation of SWNTs based functional
materials. The inclusion complexation behavior of this artificial receptor with quinine has been investigated in aqueous solution
by fluorescence spectroscopy. 相似文献
4.
Y. Ben-Aryeh 《Foundations of Physics Letters》2006,19(7):747-756
Pseudo-Hermitian Hamiltonians and pseudo-Hermitian coupling between two electromagnetic modes are analyzed by using similarity
transformations of Hermitian Hamiltonians or of Hermitian operators, including a special metric and biorthogonal relations
replacing the usual orthogonal relations used in quantum mechanics. The coupling between two electromagnetic (em) modes including
certain decay and amplification processes is related to a coupling matrix G which has parity-time (PT) symmetry and which obeys the pseudo-Hermiticity condition ηGη−1 = G
† where η is a metric. The linear equations representing the pseudo-Hermitian coupling between the two em modes are diagonalized,
in the interaction picture, by introducing ‘dressed’ αˉ and β~ operators which have real or pure imaginary eigenfrequencies.
The commutation-relations (CR) for the α~ and β~ operators and for the two-mode operators ā and b~, in the interaction picture
and under the condition of real eigenfrequencies are obtained by the use of the pseudo-Hermiticity property of the G matrix. These CR for real eigenfrequencies, are preserved in time without any Langevin noise terms. 相似文献
5.
A theoretical study on the conformation of allyl halides from the calculation of nuclear spin-spin coupling constants by adopting
the finite perturbation theory (FPT), is carried out in terms of the self-consistent, semi-empirical INDO (intermediate neglect
of differential overlap) approximation of molecular orbital theory. Results of the calculations performed using ‘s’ and ‘p’ valence orbitals alone (‘sp’ basis) at INDO level approximation seem to replicate the experimental trend quite satisfactorily. Despite the overall agreement
of the theoretical values with the experimental ones, the uncertainties in the INDO parametrization scheme lead to overestimation
of certain coupling constants. The calculations also show that the orientation of the coupled protons with respect to the
substituent halogen atom is an important factor to be considered. 相似文献
6.
Ruth E. Kastner 《Foundations of Physics》2012,42(8):1094-1113
A recent ontological variant of Cramer’s Transactional Interpretation, called “Possibilist Transactional Interpretation” or
PTI, is extended to the relativistic domain. The present interpretation clarifies the concept of ‘absorption,’ which plays
a crucial role in TI (and in PTI). In particular, in the relativistic domain, coupling amplitudes between fields are interpreted
as amplitudes for the generation of confirmation waves (CW) by a potential absorber in response to offer waves (OW), whereas
in the nonrelativistic context CW are taken as generated with certainty. It is pointed out that solving the measurement problem
requires venturing into the relativistic domain in which emissions and absorptions take place; nonrelativistic quantum mechanics
only applies to quanta considered as ‘already in existence’ (i.e., ‘free quanta’), and therefore cannot fully account for
the phenomenon of measurement, in which quanta are tied to sources and sinks. 相似文献
7.
Subodh R Shenoy 《Pramana》2002,58(2):385-397
We obtain the dynamics in number and phase difference, for Bose condensates that tunnel between two wells of a double-well
atomic trap, using the (nonlinear) Gross-Pitaevskii equation. The dynamical equations are of the canonical form for the two
conjugate variables, and the Hamiltonian corresponds to that of a momentum-shortened pendulum, supporting a richer set of tunneling oscillation modes than for a superconductor Josephson junction, that has a
fixed-length pendulum as a mechanical model. Novel modes include ‘inverted pendulum’ oscillations with an average angle of
π; and oscillations about a self-maintained population imbalance that we term ‘macroscopic quantum self-trapping’. Other systems
with this phase-number nonlinear dynamics include two-component (interconverting) condensates in a single harmonic trap, and
He3B superfluids in two containers connected by micropores. 相似文献
8.
A.I. Karanikas C.N. Ktorides 《The European Physical Journal C - Particles and Fields》2008,54(1):159-168
The validity of the Bianchi identity, which is intimately connected with the zig zag symmetry, is established, for piecewise
continuous contours, in the context of Polakov’s gauge field–string connection in the large ’t Hooft coupling limit, according
to which the chromoelectric ‘string’ propagates in five dimensions with its ends attached on a Wilson loop in four dimensions.
An explicit check in the wavy line approximation is presented. 相似文献
9.
In the present communication, we report a model Hamiltonian to study the interplay between the two long range orders of anti-ferromagnetism
(AFM) and superconductivity (SC) in cuprate superconductors in presence of the intersite pairing effect. The BCS type but
non-phonon pairing mechanism is considered among the electrons of two equivalent ‘Cu’ sites. The pairing among the electrons of two nearest neighbour non-equivalent ‘Cu’ sites is included in the Hamiltonian and its effect on the interplay of SC and AFM is investigated. The Hamiltonian is solved
by the Green’s function method and the corresponding gap equations are calculated and solved selfconsistently. The influence
of model parameters like AFM coupling (λ), SC couling (λ
1) and the coupling (λ
2) for intersite superconducting interactions on the gaps (SC and AFM) are studied numerically and the results are reported. 相似文献
10.
We discuss questions pertaining to the definition of ‘momentum’, ‘momentum space’, ‘phase space’ and ‘Wigner distributions’;
for finite dimensional quantum systems. For such systems, where traditional concepts of ‘momenta’ established for continuum
situations offer little help, we propose a physically reasonable and mathematically tangible definition and use it for the
purpose of setting up Wigner distributions in a purely algebraic manner. It is found that the point of view adopted here is
limited to odd dimensional systems only. The mathematical reasons which force this situation are examined in detail 相似文献
11.
Within the context of traditional logarithmic grand unification atM
GUT ≈ 1016 GeV, we show that it is nevertheless possible to observe certain GUT states such asX andY gauge bosons at lower scales, perhaps even in the TeV range. We refer to such states as ‘GUT precursors’. Such states offer
an interesting alternative possibility for new physics at the TeV scale, even when the scale of gauge coupling unification
remains high, and suggest that it may be possible to probe GUT physics directly even within the context of high-scale gauge
coupling unification. More generally, our results also suggest that it is possible to construct self-consistent ‘hybrid’ models
containing widely separated energy scales, and give rise to a Kaluza-Klein realization of non-trivial fixed points in higher-dimensional
gauge theories. 相似文献
12.
Summary The data for 3.8 million compounds from structural databases of 32 providers were gathered and stored in a single chemical database. Duplicates are removed using the IUPAC International Chemical Identifier. After this, 2.6 million compounds remain. Each database and the final one were studied in term of uniqueness, diversity, frameworks, ‘drug-like’ and ‘lead–like’ properties. This study also shows that there are more than 87 000 frameworks in the database. It contains 2.1 million ‘drug-like’ molecules among which, more than one million are ‘lead-like’. This study has been carried out using ‘ScreeningAssistant’, a software dedicated to chemical databases management and screening sets generation. Compounds are stored in a MySQL database and all the operations on this database are carried out by Java code. The druglikeness and leadlikeness are estimated with ‘in–house’ scores using functions to estimate convenience to properties; unicity using the InChI code and diversity using molecular frameworks and fingerprints. The software has been conceived in order to facilitate the update of the database. ‘ScreeningAssistant’ is freely available under the GPL license. 相似文献
13.
This review details a now established area within the isonitrile multi-component reaction (IMCR) field of study, namely employing
bi-functional reagents in the Ugi reaction for the construction of screening sets with the additional element or even possibly
‘metric’ of enhanced ‘iterative efficiency potential’ The concept of ‘iterative efficiency’ will be briefly introduced, coupled
with discussion on new synthetic routes to select bi-functional IMCR precursors and their use in the generation of pharmacologically
relevant ‘molecular diversity’ 相似文献
14.
15.
The potential for measuring the Z‘WW coupling with the ATLAS detector at the LHC is investigated under conditions of low and high luminosity. It is estimated
that detection of the decay channel Z’ → WW → lν
l
jj is possible with 300 fb
−1, for a Z’ boson with sequential model couplings and with a mass up to 2.2 TeV. 相似文献
16.
Dipak Ghosh Argha Deb Asok Kumar Mallick Sharmil Asarkar Krishnadas Purkait Ranjan Sengupta 《Pramana》2004,63(5):963-968
In this paper intermittent behaviour of the pions from ‘cold’ and ‘hot’ classes of events from12C-AgBr interactions at 4.5 A GeV has been studied, separately. The results reveal strong intermittent pattern in case of ‘cold’
class of events. 相似文献
17.
A novel d.c. polarization/self-depolarization study and electret-type effect in AgI are reported. AgI pellets of varying thicknesses,
placed between two blocking (graphite) electrodes, were subjected to an external d.c. potential. A state of complete polarization
was attained within ∼10 min, irrespective of the sample thickness. At this state, the potential difference, developed across
the sample pellet as a result of polarization/accumulation of mobile Ag+ ions at the bulk/negative electrode interface, was measured experimentally. The potential difference, obtained immediately
after the removal of the external d.c. source, has been referred to as ‘instant peak potential (Vp)’. As soon as the external voltage source is switched off, a process of self-depolarization is initiated due to the chemical/self
diffusion of polarized mobile Ag+ ions throughout the bulk. ‘Vp’ gives a direct information regarding the extent of mobile ion concentration (n). ‘Vp’ measurements were carried out as a function of temperature and ‘Log Vp vs 1/T’ variation was compared with the ‘Log n vs 1/T’ Arrhenius plot, reported earlier in an entirely independent study.
The two variations are almost analogous. This, in turn, supported as an earlier assertion that the abrupt conductivity increase
in α-AgI, after β→α-phase transition at ∼147 °C, is predominantly due to the excessive increase in ‘n’. Furthermore, it has
also been revealed that the Ag+ ions play another unique role which led to the existence of ‘persistent polarization’ states in AgI. These states are identical
to the ‘electret-type effects’, observed in a number of dielectric materials. The polarization state persisted for very long
time in ‘thermally stimulated polarized’ sample. A detailed investigation of the persistence/retention of polarization in
the thermally-stimulated-polarized sample is reported. 相似文献
18.
The phenomenon of quantum superposition, which allows a physical system to exist in different states ‘simultaneously’, is
one of the most bizarre notions in physics. Here we illustrate an even more bizarre example of it: a superposed state of a
physical system consisting of both an ‘older’ version and a ‘younger’ version of that system. This can be accomplished by
exploiting the special relativistic effect of time dilation featuring in Einstein’s famous twin paradox. 相似文献
19.
Eric A Lord 《Pramana》1975,4(4):164-170
A new generalisation of Einstein’s theory is proposed which is invariant under conformal mappings. Two scalar fields are introduced
in addition to the metric tensor field, so that two special choices of gauge are available for physical interpretation, the
‘Einstein gauge’ and the ‘atomic gauge’. The theory is not unique but contains two adjustable parameters ζ anda. Witha=1 the theory viewed from the atomic gauge is Brans-Dicke theory (ω=−3/2+ζ/4). Any other choice ofa leads to a creation-field theory. In particular the theory given by the choicea=−3 possesses a cosmological solution satisfying Dirac’s ‘large numbers’ hypothesis. 相似文献
20.
X. Rottenberg R. Jansen C. Van Hoof H. A. C. Tilmans 《Applied Physics A: Materials Science & Processing》2011,103(3):869-875
This paper presents a meta-material-based design method for bulk acoustic wave (BAW) resonators with enhanced characteristics
compared to those obtained with the typical bulk material implementation. We demonstrate the novel use of empty inclusions
(i.e., ‘holes’) in bulk materials for engineering their acoustic (mechanical) properties (e.g. Young’s modulus E, Poisson’s ratio ν and mass density ρ) to tune and achieve optimal acoustical performance/characteristics. Inclusions have been demonstrated before to produce
phononic band gaps for wave trapping. We focus on the propagation characteristics of the meta-materials brought into being
by these inclusions. We implement patterns of holes with different sizes and distributions, to effectively scatter acoustic
waves in bar-type BAW resonators and to devise the desired resonator properties, e.g., the resonant frequency. While the available
bulk material is homogeneous and isotropic, the bar consists of an equivalent non-homogeneous material that can for example
be distributed by design in order to shrink the overall resonator size, enhance electromechanical transduction coefficients
or reject spurious modes. Our paper compares two extraction methods for the equivalent material properties of a periodically
hole-punched material: the steady-state mechanical simulation of a unit cell and its ‘phase delay’ counterpart. We discuss
their validity and practical use for the design of bar resonators. 相似文献