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A mild and selective procedure for the bromination of activated arenes using o-iodoxybenzoic acid and tetraethylammonium bromide is presented. The reactions were carried out at room temperature and gave moderate to excellent yields. 相似文献
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A simple, efficient, and mild method for selective bromination of some activated aromatic compounds using potassium bromide in the presence of benzyltriphenylphosphonium peroxodisulfate in nonaqueous solution is reported. The results obtained revealed good to excellent selectivity between ortho and para positions of phenols and methoxyarenes. 相似文献
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Bromination of alkenes, alkynes, and aromatic amines has efficiently been carried out at room temperature in short reaction times using HIO3/KBr in CH2Cl2/H2O (1:1) to prepare corresponding brominated compounds in excellent yields. 相似文献
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N-Benzyl-DABCO tribromide, a stable, solid organic ammonium tribromide, has been used as a bromine source for the regioselective and high-yielding bromination of aromatic amines and phenols. Mono-bromination proceeds well in the presence of a stoichiometric amount of bromine source at room temperature. 相似文献
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二氧化硅负载磷钨酸铵催化苯酚氧化溴代反应 总被引:1,自引:0,他引:1
以溶胶-凝胶法制备的二氧化硅负载磷钨酸铵为催化剂,溴化钾为溴源,双氧水为氧化剂,冰醋酸为溶剂,实现了苯酚的催化氧化溴代反应。 探讨了催化剂负载量、催化剂用量和反应时间等反应参数对氧化溴代反应的影响。 结果表明,溶胶-凝胶法制备的负载磷钨酸铵仍具有典型的Keggin结构;在室温的温和条件下,该催化剂表现出较强的催化苯酚氧化溴代反应活性和较高的对溴苯酚选择性,在实验优化条件下,苯酚转化率达到95.4%,对邻比达到3.2;而且催化剂易回收,重复4次使用后,催化活性有所降低,苯酚转化率为87.4%,对邻比为1.6。 相似文献
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芳香胺和酚溴化的新工艺 总被引:1,自引:0,他引:1
研究了在室温下,N-溴丁二酰亚胺对芳香胺和酚的溴化工艺,在CHCl3、EtOH或EtOH/CHCl3溶剂中,用等摩尔的N-溴丁二酰亚胺可将某些芳香胺和酚(考察了5种反应底物)选择性地一溴化,产率92%~98%,N-溴丁二酰亚胺和反应底物摩尔比为2∶1;某些芳香胺和酚被专一地二溴化(考察了5种反应底物),产率90%~97%。 反应无须催化剂,投料后室温搅拌,反应条件温和,产品只需过滤洗涤即可纯化,操作简便。 相似文献
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季铵盐掺杂聚苯胺电极的电容性能 总被引:1,自引:2,他引:1
采用循环伏安法,在铂电极表面聚合制备了季铵盐[CnH2n+1N(CH3)3]Cl(n=12,14,16,18)掺杂的聚苯胺修饰电极。 利用扫描电子显微镜、红外光谱以及X射线衍射对复合电极的表面形貌和结构进行了表征。 用循环伏安法、交流阻抗和恒电流充放电测试对电极的电化学性质和电容行为进行了系统研究。 结果表明,其中[C18H37N(CH3)3]Cl季铵盐掺杂的聚苯胺复合电极比表面积大,电容性能好,在2×10-3 A的充电电流下,初始比电容高达329.6 F/g,未掺杂电极比电容为199.0 F/g。 而且,复合电极的循环稳定性良好,经30次循环后比电容保持为252.4 F/g。 相似文献
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Wei Liang XU* Jun WU Chun Ling FU Department of Chemistry Zhejiang University Hua jia chi section Hangzhou 《中国化学快报》2001,(12)
Chitosan has a wide scale of applications1-3. Interestingly, some antibacterial and antifungal activities have been described with chitosan and modified chitosan derivatives4-6. In polycationic biocides, generally, it is reasonably assumed7 that the charge density of the polyelectrolyte increases with increase in the molecular weight of its single coil, which leads to the enhanced adsorption of polycations onto the negatively charged cell surface. This is also favorable for the binding of t… 相似文献
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金刚烷基甜菜碱型和季铵盐阳离子型表面活性剂的合成研究 总被引:1,自引:0,他引:1
以金刚烷胺为起始反应物,首先在过量甲酸存在下,与甲醛发生埃斯韦勒-克拉克甲基化反应合成了N,N-二甲基金刚烷叔胺,在此基础上通过N,N-二甲基金刚烷叔胺与氯乙酸钠、溴代正丁烷、溴代正辛烷、溴代十二烷、溴代十六烷等一系列季铵化试剂的季铵化反应,分别合成了N,N-二甲基金刚烷甜菜碱型表面活性剂及N-(1-金刚烷基)-N,N-二甲基正丁基溴化铵、N-(1-金刚烷基)-N,N-二甲基辛基溴化铵、N-(1-金刚烷基)-N,N-二甲基十二烷基溴化铵、N-(1-金刚烷基)-N,N-二甲基十六烷基溴化铵等金刚烷季铵盐阳离子型表面活性剂,产率分别为75%,75%,61%,44%,54%.采用元素分析,IR,1H NMR等分析手段对5种产物进行了结构鉴定,测试了各种金刚烷表面活性剂水溶液的表面张力. 相似文献
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Synthesis of alkyl aryl ethers via copper‐catalyzed etherizations of electron‐deficient aryl fluorides with quaternary ammonium bromides and water has been developed. In the presence of Cu(OAc)2, POPh3 ( L4 ) and Cs2CO3, a variety of electron‐deficient aryl fluorides underwent the reaction with quaternary ammonium bromides and H2O in moderate to good yields. The mechanism was also discussed. 相似文献
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Gergely N. Nagy Lívia Marton Alicia Contet Dr. Olivér Ozohanics Laura‐Mihaela Ardelean Dr. Ágnes Révész Prof. Károly Vékey Prof. Florin Dan Irimie Dr. Henri Vial Dr. Rachel Cerdan Beáta G. Vértessy 《Angewandte Chemie (International ed. in English)》2014,53(49):13471-13476
Cation–π interactions to cognate ligands in enzymes have key roles in ligand binding and enzymatic catalysis. We have deciphered the key functional role of both charged and aromatic residues within the choline binding subsite of CTP:phosphocholine cytidylyltransferase and choline kinase from Plasmodium falciparum. Comparison of quaternary ammonium binding site structures revealed a general composite aromatic box pattern of enzyme recognition sites, well distinguished from the aromatic box recognition site of receptors. 相似文献
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溴化四丁铵催化苯乙烯一步合成苯乙烯环状碳酸酯 总被引:1,自引:0,他引:1
以溴化季铵盐为催化剂, 通过苯乙烯的环氧化和CO2的加成反应一步直接合成出苯乙烯环状碳酸酯, 详细考察了催化剂的用量、氧化剂的种类、反应温度、反应时间和CO2压力等因素对反应主产物收率的影响. 结果表明, 以溴化四丁铵为催化剂, 于80 ℃和1 MPa CO2下反应6 h, 环状碳酸酯的收率达到38%, 这是季铵盐阳离子和亲核性阴离子协同催化的结果. 相似文献