Tb0.3Dy0.7(Fe1-xAlx)1.95合金的磁致伸缩、自旋重取向和穆斯堡尔谱研究

系统研究了室温下Tb0.3Dy0.7(Fe1-xAlx)1.95(x=0,0.05,0.1,0.15,0.2,0.25,0.3,0.35)合金中金属Al替代Fe对晶体结构、磁致伸缩、各向异性和自旋重取向的影响.结果发现,x<0.4时,Tb0.3Dy0.7(Fe1-xAlx)1.95完全保持MgCl2立方Laves相结构,晶格常量a随Al含量x的增加而增大.磁致伸缩测量发现,随着替代量x的增多磁致伸缩减小,x>0.15时超磁致伸缩效应消失 x<0.15时磁致伸缩在低场下(H≤4kAm)有小幅增加,高场下迅速减小,而且易趋于饱和,说明添加少量Al有助于减小磁晶各向异性.内禀磁致伸缩λ111随Al替代量x的增加大幅度降低.对于0≤x<0.15,穆斯堡尔效应表明,随Al含量的增加Tb0.3Dy0.7(Fe1-xAlx)1.95合金中发生了自旋重取向,易磁化方向经历了[111]→[uv0]→[uvw]的转变.由相对磁化率随温度的变化关系可以看出,Al替代Fe使自旋重取向温度降低.当x=0.15时,Tb0.3Dy0.7(Fe1-xAlx)1.95合金中出现了少量非磁性相 x>0.15时,合金在室温下呈现顺磁性 关键词： 磁致伸缩 立方Laves相 自旋重取向 各向异性 穆斯堡尔谱     

Tb0.3Dy0.7(Fe0.9T0.1)1.95合金的结构、自旋重取向和穆斯堡尔谱

系统研究了室温下Tb_0.3Dy_0.7(Fe_0.9T_0.1)_1.95(过渡金属元素T=Mn，Fe，Co，B，Al，Ga)合金中ⅢA族金属和过渡金属元素T替代Fe对结构、自旋重取向和穆斯堡尔谱的影响.结果发现，不同金属T替代Fe，Tb_0.3Dy_0.7(Fe_0.9T_0.1)_1.95，合金具有相同的MgCu₂型立方Laves相结构；Al，Ga替代使Tb_0.3Dy_0.7(Fe_0.9T_0.1)_1.95合金的易磁化方向在{110}面逐渐偏离了立方晶体的主对称轴，即自旋重取向，B，Mn，Co替代未使易磁化轴发生明显转动；Al，Ga元素替代使超精细场H_hf略有下降，B，Mn替代对超精细场H_hf的影响不大，而Co元素替代使超精细场H_hf有较大增加；所有元素替代使同质异能移IS有所增加；B，Al，Ga和Mn替代使四极劈裂Q_s增加，而Co替代使四极劈裂Q_s下降. 关键词： 立方Laves相 自旋重取向 穆斯堡尔谱     

Tb0.3 Dy0.7(Fe0.9 T0.1)1.95合金的结构、自旋重取向和穆斯堡尔谱

系统研究了室温下Tb0.3Dy0.7(Fe0.9T0.1195(过渡金属元素T=Mn,Fe,Co,B,Al,Ga)合金中ⅢA族金属和过渡金属元素T替代Fe对结构、自旋重取向和穆斯堡尔谱的影响.结果发现,不同金属T替代Fe,Tb0.3Dy0.7(Fe009T0.11.95,合金具有相同的MgCu2型立方Laves相结构;Al,Ga替代使Tb0.3Dy0.7(Fe09T0.11.95合金的易磁化方向在{110}面逐渐偏离了立方晶体的主对称轴,即自旋重取向,B,Mn,Co替代未使易磁化轴发生明显转动;Al,Ga元素替代使超精细场Hhf略有下降,B,Mn替代对超精细场Hhf的影响不大,而Co元素替代使超精细场Hhf有较大增加;所有元素替代使同质异能移IS有所增加;B,Al,Ga和Mn替代使四极劈裂Qs增加,而Co替代使四极劈裂Qs下降.     

Tb0.3Dy0.7(Fe1-xAlx)1.95合金的磁致伸缩、自旋重取向和穆斯堡尔谱研究

系统研究了室温下Tb0.3Dy0.7(Fe1-xAlx)1.95(x=0,0.05,0.1,0.15,0.2,0.25,0.3,0.35)合金中金属Al替代Fe对晶体结构、磁致伸缩、各向异性和自旋重取向的影响.结果发现,x<0.4时,Tb0.3Dy0.7(Fe1-xAlx)1.95完全保持MgCl2立方Laves相结构,晶格常量a随Al含量x的增加而增大.磁致伸缩测量发现,随着替代量x的增多磁致伸缩减小,x>0.15时超磁致伸缩效应消失;x<0.15时磁致伸缩在低场下(H≤4kA/m)有小幅增加,高场下迅速减小,而且易趋于饱和,说明添加少量Al有助于减小磁晶各向异性.内禀磁致伸缩λ111随Al替代量x的增加大幅度降低.对于0≤x<0.15,穆斯堡尔效应表明,随Al含量的增加Tb0.3Dy0.7(Fe1-xAlx)1.95合金中发生了自旋重取向,易磁化方向经历了[111]→[u v 0]→[u v w]的转变.由相对磁化率随温度的变化关系可以看出,Al替代Fe使自旋重取向温度降低.当x=0.15时,Tb0.3Dy0.7(Fe1-xAlx)1.95合金中出现了少量非磁性相;x>0.15时,合金在室温下呈现顺磁性.     

Tb0.3Dy0.6Pr0.1(Fe1-xAlx)1.95合金的磁性、磁致伸缩和穆斯堡尔谱研究

系统研究了室温下Tb0.3Dy0.6Pr0.1(Fe1-xAlx)1.95(x=0.05,0.1,0.15,0.2,0.25,0.3)合金中元素Al替代Fe对结构、磁性、磁致伸缩性能和自旋重取向的影响.测量结果发现,x<0.2时Tb0.3Dy0.6Pr0.1(Fe1-xAlx)1.95合金基本上是纯的单相,x=0.2时出现其他杂相,杂相随Al替代量的增加不断增多.随Al替代量x的增加,点阵常数a接近于线性增大,Curie温度TC逐渐下降,而矫顽力Hc急剧下降.振动样品磁强计(VSM)测量发现,磁化强度M随Al替代量x的变化较为复杂.VSM计和磁致伸缩效应测量共同表明,少量Al的替代有利于降低磁晶各向异性,而且随着Al替代量x的增多磁致伸缩系数快速减小,x>0.15时巨磁致伸缩效应消失.穆斯堡尔效应研究发现,随Al含量的增加Tb0.3Dy0.6Pr0.1(Fe1-xAlx)1.95合金中易磁化轴可能在{110}面逐渐偏离了立方晶体的主对称轴,发生自旋重取向,从而引起合金宏观磁性、磁致伸缩性能的变化.     

Tb0.3Dy0.7(Fe1-xAlx)1.95合金的自旋重取向和穆斯堡尔

系统研究了室温和77K温度时Tb0.3Dy0.7(Fe1-xAlx)1.95(x=0,0.05,0.1,0.15,0.2,0.25,0.3,0.35)合金中金属Al替代Fe对自旋重取向和穆斯堡尔谱的影响. 结果发现,Tb0.3Dy0.7(Fe1-xAlx)1.95合金的易磁化方向随成分和温度在{110}面逐渐偏离了立方晶体的主对称轴,即自旋重取向. 室温下,当x=0.15时,Tb0.3Dy0.7(Fe1-xAlx)1.95合金中出现了少量非磁性相;x>0.15时,合金完全呈顺磁性;而77K温度下,x=0.2时合金仍然呈磁性相. 在室温和77K温度时,超精细场Hhf均随Al元素的增加而减小,而同质异能移IS随Al元素的增加而增加,四极劈裂QS随Al含量呈无规律的变化.     

Tb$lt;sub$gt;0.3$lt;/sub$gt;Dy$lt;sub$gt;0.6$lt;/sub$gt;Pr$lt;sub$gt;0.1$lt;/sub$gt;(Fe$lt;sub$gt;1-$lt;i$gt;x$lt;/i$gt;$lt;/sub$gt;Al$lt;sub$gt;$lt;i$gt;x$lt;/i$gt;$lt;/sub$gt;)$lt;sub$gt;1.95$lt;/sub$gt;合金的磁性、磁致伸缩和穆斯堡尔谱研究

系统研究了室温下Tb_0.3Dy_0.6Pr_0.1（Fe_1-xAl_x）_1.95 （x=0.05,0.1,0.15,0.2,0.25,0.3）合金中元素Al替代Fe对结构、磁性、磁致伸缩性能和自旋重取向的影响.测量结果发现,x<0.2时Tb_0.3Dy_0.6Pr_0.1（Fe_1-xAl_x）_1.95合金基本上是纯的单相,x=0.2时出现其他杂相,杂相随Al替代量的增加不断增多.随Al替代量x的增加,点阵常数a接近于线性增大,Curie温度T_C逐渐下降,而矫顽力H_c急剧下降.振动样品磁强计（VSM）测量发现,磁化强度M随Al替代量x的变化较为复杂.VSM计和磁致伸缩效应测量共同表明,少量Al的替代有利于降低磁晶各向异性,而且随着Al替代量x的增多磁致伸缩系数快速减小,x>0.15时巨磁致伸缩效应消失.穆斯堡尔效应研究发现,随Al含量的增加Tb_0.3Dy_0.6Pr_0.1（Fe_1-xAl_x）_1.95合金中易磁化轴可能在{110}面逐渐偏离了立方晶体的主对称轴,发生自旋重取向,从而引起合金宏观磁性、磁致伸缩性能的变化. 关键词： 磁致伸缩 立方Laves相 自旋重取向 穆斯堡尔谱     

离轴磁场退火后Tb0.3Dy0.7Fe1.95〈110〉取向晶体的磁致伸缩"跳跃"效应

将〈110〉取向Tb_0.3Dy_0.7Fe_1.95合金棒放在与轴向成35°夹角的外磁场中退火处理,研究其在0—30 MPa预压应力σpre作用下的磁致伸缩效应.结果表明,σpre=0条件下的饱和磁致伸缩值λs由退火前的1023×10^-6提高到1650×10^-6;σpre 关键词： 磁致伸缩 磁场退火 磁致伸缩"跳跃"效应     

纳米SnO2材料的穆斯堡尔谱研究

通过X射线衍射,透射电子显微镜和穆斯堡尔谱测量,确定了在本研究中用水热法制备的半导体SnO₂材料为纳米材料,实验给出该材料的结构特点和Sn原子核的超精细参量,并发现600℃时纳米的SnO₂会转变成晶态大颗粒的SnO₂。 关键词：     

Structure, spin reorientation and M(o)ssbauer effect studies of Tb0.3Dy0.7(Fe1-xAlx)1.95 alloys

The effect of Al substitution for Fe on crystal structure, magnetostriction and spontaneous magnetostriction, anisotropy and spin reorientation of a series of polycrystalline Tb0.3Dy0.7(Fe1-xAlx)1.95 alloys (x = 0, 0.05, 0.1, 0.15, 0.20, 0.25, 0.30, 0.35) at room temperature and 77 K was investigated systematically. It was found that the primary phase of Tb0.3Dy0.7(Fe1-xAlx)1.95 is the MgCu2-type cubic Laves phase structure when x < 0.4 and the lattice constant a of Tb0.3Dy0.7(Fe1-xAlx)1.95 increases approximately and monotonically with the increase of x. The substitution of Al leads to the fact that the magnetostriction ( inceases slightly in a low magnetic field (H ≤ 40 kA/m), but decreases sharply and is easily close to saturation in a high applied field as x increases, showing that a small amount of Al substitution is beneficial to a decrease in the magnetocrystalline anisotropy. It was also found that the spontaneous magnetostriction (ζ)111 decreases greatly with x increasing. The analysis of the M(o)ssbauer spectra indicated that the easy magnetization direction in the {110} plane deviates slightly from the main axis of symmetry with the changes of composition and temperature, namely spin reorientation. A small amount of non-magnetic phase exists for x = 0.15 in Tb0.3Dy0.7(Fe1-xAlx)1.95 alloys and the alloys become paramagnetic for x > 0.15 at room temperture, but at 77 K the alloys still remain magnetic phase even for x = 0.2. At room temperature and 77 K, the hyperfine field decreases and the isomer shifts increase with Al concentration increasing.     

A structural, magnetostrictive and M(o)ssbauer study of Tb0.3Dy0.7(Fe0.9T0.1)1.95 alloys

The effect of ⅢA metal and transition metal T substitution for Fe on crystal structure, magnetostriction and spontaneous magnetostriction, anisotropy and spin reorientation of a series of polycrystalline Tb0.3Dy0.7(Fe0.9T0.1)1.95 (T = Mn, Fe, Co, B, Al, Ga) alloys at room temperature were investigated systematically. It was found that the primary phase of the Tb0.3Dy0.7(Fe0.9T0.1)1.95 alloys is the MgCu2-type cubic Laves phase structure for different substitution. The magnetostriction λs decrases greatly for the substitution of IIIA metal B, Al and Ga, but is saturated more easily for Al and Ga substitution, showing that the Al and Ga substitution is beneficial to a decrease in the magnetocrystalline anisotropy of Tb0.3Dy0.7(Fe0.9T0.1)1.95 alloys. However, the substitution of transition metal Mn and Co decreases slightly the magnetostriction λs. It was also found that the effect of different substitutions on the spontaneous magnetostriction λ111 is distinct. The analysis of the Mossbauer spectra indicates that the easy magnetization direction in the {110} plane deviates slightly from the main axis of symmetry for Al and Ga substitution, namely spin reorientation, but it does not change evidently for B, Mn and Co substitution.     

Structure, spin reorientation and M?ssbauer effect studies of Tb0.3Dy0.7(Fe1?xAlx)1.95 alloys

The effect of Al substitution for Fe on crystal structure, magnetostriction and spontaneous magnetostriction, anisotropy and spin reorientation of a series of polycrystalline Tb_0.3Dy_0.7(Fe_1−x Al_x)_1.95 alloys (x = 0, 0.05, 0.1, 0.15, 0.20, 0.25, 0.30, 0.35) at room temperature and 77 K was investigated systematically. It was found that the primary phase of Tb_0.3Dy_0.7(Fe_1−x Al_x)_1.95 is the MgCu₂-type cubic Laves phase structure when x < 0.4 and the lattice constant a of Tb_0.3Dy_0.7(Fe_1−x Al_x)_1.95 increases approximately and monotonically with the increase of x. The substitution of Al leads to the fact that the magnetostriction λ inceases slightly in a low magnetic field (H ⩽ 40 kA/m), but decreases sharply and is easily close to saturation in a high applied field as x increases, showing that a small amount of Al substitution is beneficial to a decrease in the magnetocrystalline anisotropy. It was also found that the spontaneous magnetostriction λ ₁₁₁ decreases greatly with x increasing. The analysis of the M?ssbauer spectra indicated that the easy magnetization direction in the {110} plane deviates slightly from the main axis of symmetry with the changes of composition and temperature, namely spin reorientation. A small amount of non-magnetic phase exists for x = 0.15 in Tb_0.3Dy_0.7(Fe_1−x Al_x)_1.95 alloys and the alloys become paramagnetic for x > 0.15 at room temperature, but at 77 K the alloys still remain magnetic phase even for x = 0.2. At room temperature and 77 K, the hyperfine field decreases and the isomer shifts increase with Al concentration increasing.     

A structural, magnetostrictive and M?ssbauer study of Tb0.3Dy0.7(Fe0.9 T 0.1)1.95 alloys

The effect of IIIA metal and transition metalT substitution for Fe on crystal structure, magnetostriction and spontaneous magnetostriction, anisotropy and spin reorientation of a series of polycrystalline Tb_0.3 Dy_0.7 (Fe_0.9 T _0.1)_1.95 (T=Mn, Fe, Co, B, Al, Ga) alloys at room temperature were investigated systematically. It was found that the primary phase of the Tb_0.3 Dy_0.7 (Fe_0.9 T _0.1)_1.95 alloys is the MgCu₂-type cubic Laves phase structure for different substitution. The magnetostriction λ{ins} decrases greatly for the substitution of IIIA metal, B, Al and Ga, but is saturated more easily for Al and Ga substitution, showing that the Al and Ga substitution is beneficial to a decrease in the magnetocrystalline anisotropy of Tb_0.3 Dy_0.7 (Fe_0.9 T _0.1)_1.95 alloys. However, the substitution of transition metal Mn and Co decreases slightly the magnetostriction λ{ins}. It was also found that the effect of different substitutions on the spontaneous magnetostriction λ{in111} is distinct. The analysis of the M?ssbauer spectra indicates that the easy magnetization direction in the {110} plane deviates slightly from the main axis of symmetry for Al and Ga substitution, namely spin reorientation, but it does not change evidently for B, Mn and Co substitution.     

Magnetic investigations of Dy(Fe0.9M0.1)2 (M=B,Al, Ga) cubic laves phases

The magnetic properties of the pseudo-binary compounds Dy(Fe_0.9M_0.1)₂ (M=B, Al, Ga) have been investigated. Substitution of M atoms for Fe atoms decreases the Curie temperature and varies the magnetic moment of the Fe atom. The coercivity of the samples increases very rapidly with decreasing temperature. This increase is considerably enhanced by the substitution elements. Pronounced thermomagnetic history effects are observed in the temperature dependence of the magnetization. These effects may be explained as an exponential increase in magnetic hardness on lowering the temperature.     

Mössbauer spectroscopy studies of Dy(Fe,M)12 (M=Si,V,Ti) alloys

The⁵⁷Fe Mössbauer spectra have shown that the hyperfine field of DyFe₁₀Si₂ alloy and its quadrupole splitting at the 8i sites change steeply at 210 K, which are attributed to the spin reorientation transition. The stabilizing elements for the formation of the ThMn₁₂-structure can affect on the spin reorientation transition temperature. The differences of spin reorientation transition temperature of DyFe₁₀Si₂, DyFe₁₀V₂ and DyFe₁₁Ti alloys had been discussed. The quadrupole splitting at 8i sites of DyFe₁₀Si₂ alloy changes its sign at 210 K.     

Mössbauer effect studies of Fe(phen)2(NCBH3)2 - a spin triplet

Mössbauer spectroscopy and magnetic moment measurements have been used to study the compound Fe(phen)₂(NCBH₃)₂ in conjunction with other octahedral Fe(II) complexes. The result of both sets of measurements indicate that Fe(phen)₂(NCBH₃)₂ is an intermediate spin (S = 1) complex at room temperature. Intermediate spin Fe(II) complexes are relatively unknown and very few, if any, are conclusively reported in the literature.