Direct observation of the anomalous zeeman effect at the X → B transition of molecular iodine by the method of nonlinear laser spectroscopy

Direct observation of the magnetic structure of transitions in molecular iodine is first reported. Using the method of saturated absorption spectroscopy in an external cell with I₂ vapour located in a longitudinal magnetic field we resolved the magnetic structure of the components of the hyperfine structure of the transition

Zeeman effect in α-quartz

The helical crystal structure in α-quartz acts as the natural micro-solenoids for an electromagnetic wave passing through them, producing a longitudinal magnetic field in the direction of the optical axis. The longitudinal magnetic field further induces the Larmor frequency for the rotation of the bound electrons. The calculated Larmor frequency was experimentally confirmed by monitoring a line splitting of the infrared OH-band in the transmission spectra of α-quartz. A shift in the resonance frequency of the OH-band is equal to the Larmor frequency induced by the natural Zeeman effect.     

Texture transition in Al–Mg alloys: effect of magnesium

ABSTRACT

The evolution of deformation texture and microstructure in commercially pure Al (cp-Al) and two Al–Mg alloys (Al–4Mg and Al–6Mg) during cold rolling to a very large strain (true strain ε_t? ≈?3.9) was investigated. The development of deformation texture in cp-Al, after rolling, can be considered as pure metal or Copper-type, which is characterised mainly by the presence of Cu {112}<111>, Bs {110}<112> and S {123}<634> components. The deformation microstructure clearly indicates that deformation mechanism in this case remains slip dominated throughout the deformation range. In the Al–4Mg alloy, the initial slip mode of deformation is finally taken over by mechanism involving both slip and Copper-type shear bands, at higher deformation levels. In contrast, in the Al–6Mg alloy, the slip and twin mode of deformation in the initial stage is replaced by slip and Brass-type shear bands at higher deformation levels. Although a Copper-type deformation texture forms in the two Al–Mg alloys at the initial stage of deformation, there is a significant increase in the intensity of the Bs component and a noticeable decrease in the intensity of the Cu component at higher levels of deformation, particularly in the Al–6Mg alloy. This phenomenon indicates the possibility of transition of the deformation texture from Cu-type to Bs-type, which is concurrent with the addition of Mg. Using visco-plastic self-consistent modelling, the evolution of deformation texture could be simulated for all three materials.     

The mass effect of the quark phase transition in supernova core

Constituent quark mass model is adopted as a tentative one to study the phase transition between two-flavour quark matter and more stable three-flavour quark matter in the core of supernovae. The result shows that the transition has a significant influence on the increasing of the core temperature, the neutrino abundance and the neutrino energies, which contributes to the enhancement of the successful probability of supernova explosion. However, the equilibrium values of these parameters （except the temperature） from the constituent quark mass model in this work are slightly bigger than those obtained from the other model. And we find that the constituent quark mass model is also applicable to describing the transition in the supernova core.     

Theoretical study of LiCl− and LiBr− molecular ions

The molecular structures and spectroscopic constants of the ground electronic states of LiCl^? and LiBr^? are investigated with the coupled-cluster method. To improve the accuracy of our calculations, we have employed the extrapolation schemes as well as corrections of the core–valence correlation and scalar relativistic effect. The equilibrium parameters, potential energy curves, force constants, vibrational energy levels and spectroscopic parameters of both molecular ions are derived, in which those of LiBr^? are reported for the first time. The electron affinities and vertical detachment energies of neutral and anionic LiCl and LiBr are also evaluated.     

Band structure and pressure-induced metallic transition in iodine – GW calculation

We have studied the band structure and the band gap closure in phase I of solid iodine under high pressure, using the methods based on the quasiparticle theory, i.e. GW approximation. Our calculations show that the band gap in the Cmca structure, which is the structure of the phase I of solid iodine, closes around 20 GPa. This pressure is near the upper boundary of phase I. We discuss the possible metallic transition in the molecular phase of solid iodine and the possible changes of the crystal structure.     

Green's function theory of the spin-Peierls transition in X−Y chains

Using a Green's function formalism, we derive from a new microscopic Hamiltonian, the transition temperature equation for the spin-Peierls transition in X−Y quasi-one-dimensional (1D) spin systems. The obtained equation has already been obtained by Beni and Pincus [1] in a different fashion.     

Magnetic-field-depressed phase transition in Sm1−xGdxS

The results of experiments where the onset of the first order phase transformation of SmS has been varied by chemical substitution and application of high magnetic fields lead to the conclusion that the hybridization of the localized 4f states of Sm²⁺ with the 5d levels at the neighbor cations is the fundamental parameter controlling the phase transformation.     

Elasticity of the B2 phase and the effect of the B1–B2 phase transition on the elasticity of MgO

A study of the high-pressure anisotropy of MgO was conducted using first-principles calculations based on density functional theory within the generalized gradient approximations. The pressure dependence of the elastic stiffness coefficients and the anisotropy parameters, in both B1 and B2 phases, shows that for high-hydrostatic compression the easiest deformation is the shear along (100) plane and the the material's response to deformation and to shearing strains is quite the same. According to the calculations of the velocities of propagation of elastic waves, we deduced that MgO develop an elastic anisotropy, especially, in the B1 phase. We present the B2 phase elastic properties which are not already studied under high pressure.     

Modeling of a structural phase transition in La2−x SrxCuO4

The structural, vibrational, and elastic properties of La₂CuO₄ are calculated using a model for calculating the energy of the crystal based on interionic potentials with the multiparticle Jahn-Teller contribution included explicitly. The microscopic reasons for the structural instability of the La₂CuO₄ lattice relative to rotations of the oxygen octahedra are investigated. A structural phase transition from the orthorhombic phase (space group D _2h ¹⁸ ) into the tetragonal phase (space group D _4h ¹⁷ ) under hydrostatic compression of an La_2−x Sr_xCuO₄ crystal is modeled. The (P,x) structural phase diagram for La_2−x Sr_xCuO₄ is constructed. Fiz. Tverd. Tela (St. Petersburg) 41, 1096–1102 (June 1999)     

Electronic transition of C3H− in the vicinity of the lowest photodetachment threshold

The electronic spectrum of the C³H(D)^? anion has been studied near the lowest electron detachment threshold associated with the chain isomer. On the basis of the vibrational and rotational analyses, the photodetachment spectrum is assigned to the ³A″ ← [Xtilde]³A″ electronic transition of the cumulene-like C³H(D)^? anion. The spectrum is characterized by a rich vibrational structure leading to the determination of almost all fundamental frequencies. The vibrational progression involving the CCH(D) in plane bending mode (V¹ ₆) is fitted with a 1-dimensional potential energy curve along the CCH(D) angle. This fit and the rotational analysis enable the geometry of the upper state to be determined. Although this excited state is expected to have dipole bound character, its neutral counterpart has a significantly different structure. The observation of an excited triplet state near the electron detachment threshold and close to the the calculated transition state for the electron catalysed isomerization reaction leads to new insight into this process.     

Specific features of magnetoresistance during the antiferromagnet—paramagnet transition in Tm1 − x Yb x B12

The transverse magnetoresistance Δρ/ρ(H, T) of Tm_{1 ? x} Yb _x B₁₂ single crystals is studied in the ytterbium concentration range corresponding to the antiferromagnet-paramagnet transition in a magnetic field up to 80 kOe at low temperatures. A magnetic H-T phase diagram is constructed for the antiferromagnetic state of substitutional Tm_{1 ? x} Yb _x B₁₂ solid solutions with x ≤ 0.1. The contributions to the magnetoresistance in the antiferromagnetic and paramagnetic phases of the dodecaborides under study are separated. Along with negative quadratic magnetoresistance -Δρ/ρ ∝ H ₂, the magnetically ordered phase of these compounds is found to have component Δρ/ρ ∝ H that linearly changes in a magnetic field. The negative contribution to the magnetoresistance of Tm_{1 ? x} Yb _x B₁₂ is analyzed in terms of the Yosida model for a local magnetic susceptibility.     

Mössbauer effect of iodine at pressures to 30 GPa

We report the first high pressure¹²⁹I Mössbauer measurements with elemental iodine at pressures to 30 GPa. A 20 mg/cm^{2 129}I₂ absorber was mounted in a diamond anvil cell with an effective diameter of 0.21 mm. The source used was Mg₃ ^129mTeO₆. Experiments were performed mainly at 4 K and the pressure was monitored by the ruby fluorescence method. With increasing pressure we observe a gradual decrease in ¦e²qQ¦ and an increase in IS and values of the low pressure, molecular phase; at 16 GPa a new phase (HP1) is detected characterized by a change in sign of e²qQ and a smaller value of ¦e²qQ¦, and a substantial increase in . At 24 GPa a new phase (HP2) is formed that is characterized by a smaller value of . In general the population of the molecular phase decreases from 1.0 near 15 GPa to a value of 0.4 at 30 GPa. The fraction of the high pressure phase (HP1 + HP2) increases at the expense of the molecular phase and that of the HP2 at the expense of the HP1 phase. These observations are discussed in relation to the onset of a metallic phase near 16 GPa and recent x-ray diffraction studies.Work performed under the auspices of the U.S. Department of Energy.     

Optical study of semiconductor to metal transition in Sm1−xLnxS and SmS1−xAsx films

We have optically probed the Semiconductor to Metal transition (SC-MT) in Sm_1−xLn_xS and SmS_1−xAs_x films. For Ln = Yb, Sm²⁺4f⁶→4f⁵5d transitions (E₁, E₂) are well preserved for 0 ⩽ x ⩽ 1 showing the stability of Sm²⁺ and the absence of a SC-MT. For Ln = Tm, the definition of E₁ and E₂ disappears as x increases from 0 to 0.3, the 4f levels of Sm²⁺ seem to broaden or 5d band gets filled up leading to a SC-MT. For As substitution, SC-MT occurs for x ⩽ 0.10.     

Giant rotating magnetocaloric effect in the region of spin-reorientation transition in the NdCo₅ single crystal

We have investigated the anisotropy of the magnetocaloric effect in a NdCo? single crystal in a wide range of temperatures, including the spin-reorientation temperature region. In the field μ(0)H =1.3 T in the spin-reorientation region 250-310 K, we discovered a giant rotating magnetocaloric effect of ~ 1.6 K, caused by rotation of the magnetization vector. The calculations of the anisotropy magnetocaloric effect for the field μ(0)H =1.3 T have been carried out.     

Analysis of the properties of the molecular–cluster xenon mixture in the mesoscopic phase transition region

We report on the results of calculation of the concentrations of cluster subcomponents in a molecular–cluster xenon mixture at temperatures and pressures at which the gas experiences a mesoscopic phase transition. The existence of such a transition follows from singularities of the temperature dependence of viscosity, from the behavior of the cluster thermodiffusion coefficient, and from the features of the distributions of cluster subcomponents in the centrifuge. The mesoscopic phase transition is manifested in the intermediate position of the molecular–cluster mixture between the gas and the liquid judging from its properties in the transition region.     

Hall effect of noncrystalline Zr−Cu films

Quench condensed Zr _x Cu_1–x films offer a wide concentration range (0.1x0.9) for measurements of the Hall coefficientR _H of amorphous Zr–Cu alloys.R _H changes sign as a function of composition, from negative to positive, as the Zr concentration is increased. The sign change is observed in a narrow concentration range at aboutx=0.22, without any peculiarity of the conductivity at this crossover concentration. The Hall coefficient of the unannealed Zr-rich films is nearly independent of temperature. However, both, the values ofR _H and of the temperature dependence ofR _H change with a heat treatment well below the crystallization temperature. This is most obvious for the films with a composition close to the cross-over concentration.Dedicated to B. Mühlschlegel on the occasion of his 60th birthday