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1.
Included (Si, Ca) and added (Li, B) internal standards (IS) have been used comparatively in LA-ICP-AES of silicates and limestones to improve both precision and accuracy. A Q-switched Nd:YAG laser (355 nm, 10 Hz, 10 mJ per shot) has been applied for ablation. Samples have been prepared by fusion with Li2B4O7 and measured using a Perkin-Elmer Optima 3000 ICP system. Both types of IS have given a relative standard deviation (RSD) less than 2–1%, which improved the repeatability by a factor of 2–10 and calibration graphs have been linear over the whole concentration range.  相似文献   

2.
Functionalized o-carboranes are interesting ligands for transition metals. Reaction of LiC2B10H11 with Me2NCH2CH2Cl in toluene afforded 1-Me2NCH2CH2-1,2-C2B10H11 (1). Treatment of 1 with 1 equiv. of n-BuLi gave [(Me2NCH2CH2)C2B10H10]Li ([1]Li), which was a very useful synthon for the production of bisfunctional o-carboranes. Reaction of [1]Li with RCH2CH2Cl afforded 1-Me2NCH2CH2-2-RCH2CH2-1,2-C2B10H10 (R = Me2N (2), MeO (3)). 1 and 2 were also prepared from the reaction of Li2C2B10H10 with excess Me2NCH2CH2Cl. Treatment of [1]Li with excess MeI or allyl bromide gave the ionic salts, [1-Me3NCH2CH2-2-Me-1,2-C2B10H10][I] (4) and [1-Me2N(CH2=CHCH2)CH2CH2-2-(CH2=CHCH2)-1,2-C2B10H10][Br] (6), respectively. Interaction of [1]Li with 1 equiv. of allyl bromide afforded 1-Me2NCH2CH2-2-(CH2=CHCH2)-1,2-C2B10H10 (5). Treatment of [1]Li with excess dimethylfulvene afforded 1-Me2NCH2CH2-2-C5H5CMe2-1,2-C2B10H10 (7). Interaction of [1]Li with excess ethylene oxide afforded an unexpected product 1-HOCH2CH2-2-(CH2=CH)-1,2-C2B10H10 (8). 1 and 3 were conveniently converted into the corresponding deborated compounds, 7-Me2NHCH2CH2-7,8-C2B9H11 (9) and 7-Me2NHCH2CH2-8-MeOCH2CH2-7,8-C2B9H10 (10), respectively, in MeOH-MeOK solution. All of these compounds were characterized by various spectroscopic techniques and elemental analyses. The solid-state structures of 4 and 6-10 were confirmed by single-crystal X-ray analyses.  相似文献   

3.
The structural chemistry of boron is dominated by 3D structures (polyhedra), while in carbon structural chemistry the planar aromatic structures are more abundant. In this Communication we present results of ab initio calculations showing that the polyhedral boranes can be flattened into planar aromatic structures similar to their carbon analogues. We predicted that a B6H62- octahedron (in Li2B6H6), a B5H52- trigonal bipyramid (in Li2B5H5), a B7H72- pentagonal bipyramid (in Li2B7H7), and a B10H84- bioctahedron with a joint edge (in Li4B10H8) can be reduced to a planar aromatic B6H66- hexagon (in Li6B6H6), to a planar pentagon B5H56- (in Li6B5H5), to a planar heptagon B7H76- (in Li6B7H7), and to a naphthalene-like B10H810- (in Li10B10H8). Ab initio prediction of these new planar aromatic boranes shows that a large new family of planar aromatic all-boron molecules is possible.  相似文献   

4.
This article reports on the development and spectral results of Eu(3+) and Tb(3+) ions doped cadmium lithium alumino fluoro boro tellurite (CLiAFBT) glasses in the following composition. 40TeO2-30B2O3-10CdO-10Li2O-10AlF3 (Hostglass) (40-x)TeO2-30B2O3-10CdO-10Li2O-10AlF3-xEu2O3 (40-x)TeO2-30B2O3-10CdO-10Li2O-10AlF3-xTb4O7 where x=0.25, 0.50, 0.75, 1.0, 1.25 mol%. Glass amorphous nature and thermal properties have been studied using the XRD and DSC profiles. From the emission spectra of Eu(3+):glasses, five emission transitions have been observed at 578 nm, 592 nm, 612 nm, 653 nm, 701 nm and are assigned to the transitions (5)D(0)→(7)F(0), (7)F(1,)(7)F(2), (7)F(3) and (7)F(4), respectively, with λ(exci)=392 nm ((7)F(0)→(5)L(6)). In case of Tb(3+):glasses, four emission transitions ((5)D(4)→(7)F(6,)(7)F(5), (7)F(4) and (7)F(3)) are observed at 488 nm, 543 nm, 584 nm and 614 nm, respectively, with λ(exci)=376 nm. Decay curves and energy level diagrams have been plotted to evaluate the life times and to analyze the emission mechanism.  相似文献   

5.
Adiabatic and diabatic potential energy curves and the permanent and transition dipole moments of the low-lying electronic states of the LiRb molecule dissociating into Rb(5s, 5p, 4d, 6s, 6p, 5d, 7s, 6d) + Li(2s, 2p) have been investigated. The molecular calculations are performed with an ab initio approach based on nonempirical pseudopotentials for Rb(+) and Li(+) cores, parametrized l-dependent core polarization potentials and full configuration interaction calculations. The derived spectroscopic constants (R(e), D(e), T(e), ω(e), ω(e)x(e), and B(e)) of the ground state and lower excited states are in good agreement with the available theoretical works. However, the 8-10(1)Σ(+), 8-10(3)Σ(+), 6(1,3)Π, and 3(1,3)Δ excited states are studied for the first time. In addition, to the potential energy, accurate permanent and transition dipole moments have been determined for a wide interval of internuclear distances. The permanent dipole moment of LiRb has revealed ionic characters both relating to electron transfer and yielding Li(-)Rb(+) and Li(+)Rb(-) arrangements. The diabatic potential energy for the (1,3)Σ(+), (1,3)Π, and (1,3)Δ symmetries has been performed for this molecule for the first time. The diabatization method is based on variational effective Hamiltonian theory and effective metric, where the adiabatic and diabatic states are connected by an appropriate unitary transformation.  相似文献   

6.
X-ray data on single crystals of the quaternary metal hydride near the composition LiB(0.33)N(0.67)H(2.67), previously identified as "Li3BN2H8", reveal that its true composition is Li4BN3H10. The structure has body-centered-cubic symmetry [space group I2(1)3, cell parameter a = 10.679(1)-10.672(1) Angstroms] and contains an ordered arrangement of BH4- and NH2- anions in the molar ratio 1:3. The borohydride anion has an almost ideal tetrahedral geometry (angleH-B-H approximately 108-114 degrees), while the amide anion has a nearly tetrahedral bond angle (angleH-N-H approximately 106 degrees). Three symmetry-independent Li atom sites are surrounded by BH4- and NH2- anions in various distorted tetrahedral configurations, one by two B and two N atoms, another by four N atoms, and the third by one B and three N atoms. The Li configuration around B is nearly tetrahedral, while that around N resembles a distorted saddlelike configuration, similar to those in LiBH4 and LiNH2, respectively.  相似文献   

7.
Reaction of the lithium salt of 1-(2'-pyridyl)-ortho-carborane, Li[1-R-1,2-C(2)B(10)H(10)](R = 2'-NC(5)H(4)), with sulfur, followed by hydrolysis, gave the mercapto-o-carborane, 1-R-2-SH-1,2-C(2)B(10)H(10) which forms chiral crystals containing helical chains of molecules linked by intermolecular S-H...N hydrogen bonds. The cage C(1)-C(2) and exo C(2)-S bond lengths (1.730(3) and 1.775(2)[Angstrom], respectively) are indicative of exo S=C pi bonding. The tin derivative 1-R-2-SnMe(3)-1,2-C(2)B(10)H(10), prepared from Li[1-R-1,2-C(2)B(10)H(10)] and Me(3)SnCl, crystallises with no significant intermolecular interactions. The pyridyl group lies in the C(1)-C(2)-Sn plane, oriented to minimise the NSn distance (2.861(3)[Angstrom]). The tin environment is distorted trigonal bipyramidal with axial N and Me. The gold derivative 1-R-2-AuPPh(3)-1,2-C(2)B(10)H(10), prepared from Li[1-R-1,2-C(2)B(10)H(10)] and AuCl(PPh(3)), reveals no NAu interaction in its crystal structure.  相似文献   

8.
The geometric structures of neutral and cationic Si(n)Li(m)(0/+) clusters with n = 2-11 and m = 1, 2 are investigated using combined experimental and computational methods. The adiabatic ionization energy and vertical ionization energy (VIE) of Si(n)Li(m) clusters are determined using quantum chemical methods (B3LYP/6-311+G(d), G3B3, and CCSD(T)/aug-cc-pVxZ with x = D,T), whereas experimental values are derived from threshold photoionization experiments in the 4.68-6.24 eV range. Among the investigated cluster sizes, only Si(6)Li(2), Si(7)Li, Si(10)Li, and Si(11)Li have ionization thresholds below 6.24 eV and could be measured accurately. The ionization threshold and VIE obtained from the experimental photoionization efficiency curves agree well with the computed values. The growth mechanism of the lithium doped silicon clusters follows some simple rules: (1) neutral singly doped Si(n)Li clusters favor the Li atom addition on an edge or a face of the structure of the corresponding Si(n)(-) anion, while the cationic Si(n)Li(+) binds with one Si atom of the bare Si(n) cluster or adds on one of its edges, and (2) for doubly doped Si(n)Li(2)(0/+) clusters, the neutrals have the shape of the Si(n+1) counterparts with an additional Li atom added on an edge or a face of it, while the cations have both Li atoms added on edges or faces of the Si(n)(-) clusters.  相似文献   

9.
Two mechanisms of doping Li(3)NbO(4), which has an ordered, rock salt superstructure, have been established. In the "stoichiometric mechanism", the overall cation-to-anion ratio is maintained at 1:1 by means of the substitution 3Li(+) + Nb(5+) --> 4Ni(2+). In the "vacancy mechanism", Li(+) ion vacancies are created by means of the substitution 2Li(+) --> Ni(2+). Solid solution ranges have been determined for both mechanisms and a partial phase diagram constructed for the stoichiometric join. On the vacancy join, the substitution mechanism has been confirmed by powder neutron diffraction; associated with lithium vacancy creation, a dramatic increase in Li(+) ion conductivity occurs with increasing Ni content, reaching a value of 5 x 10(-4) Omega(-1) cm(-1) at 300 degrees C for composition x= 0.1 in the formula Li(3-2x)Ni(x)NbO(4). This is the first example of high Li(+) ion conductivity in complex oxides with rock salt-related structures.  相似文献   

10.
Phantoms for the calibration of local bone mineral densities by micro-computed tomography (microCT), consisting of lithium tetraborate (Li(2)B(4)O(7)) with increasing concentrations of hydroxyapatite [HAp, Ca(10)(PO(4))6(OH)2] have been prepared and characterized for homogeneity. Large-scale homogeneity and concentration of HAp in the phantom materials was determined using laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS), while homogeneity on the micrometer scale was assessed through microCT. A series of standards was prepared by fusion of pure HAp with Li(2)B(4)O(7) in a concentration range between 0.12 and 0.74 g cm(-3). Furthermore, pressed and sintered pellets of pure HAp were prepared to extend the calibration range towards densities of up to 3.05 g cm(-3). A linear calibration curve was constructed using all individual standard materials and the slope of the curve was in good agreement with calculated absorption coefficients at the effective energy of the microCT scanner.  相似文献   

11.
1INTRODUCTION As is well known,the Yb3 ion has some advan-tages in comparison with Nd3 as laser active ion,for it has only two manifolds,i.e.,the ground2F7/2state and the excited2F5/2state.There is no excited state absorption reducing effective laser cross-section,no concentration quenching,no up-conversion,and three or four times longer emission lifetime than Nd3 ion.Yb3 ion exhibits a strong and broad ab-sorption band at ca.970nm and can be easily pumped with InGaAs diode lasers.The …  相似文献   

12.
The syntheses of macrocyclic species composed of carborane derivatives joined via their carbon vertices by electrophilic mercury atoms are described. The reaction of closo-1,2-Li(2)[C(2)B(10)H(10)(-)(x)()R(x)()] with HgI(2) gives Li(2)[(1,2-C(2)B(10)H(10)(-)(x)()R(x)()Hg)(4)I(2)] [R = Et, x = 2 (5.I(2)Li(2)); R = Me, x = 2 (6.I(2)Li(2)); R = Me, x = 4 (7.I(2)Li(2))]. 6.I(2)(K.[18]dibenzocrown-6)(2) crystallizes in the monoclinic space group C2/m [a = 28.99(2) ?, b = 18.19(1) ?, c = 13.61(1) ?, beta = 113.74(2) degrees, V = 6568 ?(3), Z = 4, R = 0.060, R(w) = 0.070]; 7.I(2)(NBu(4))(2) crystallizes in the monoclinic space group P2(1)/c [a = 12.77(1) ?, b = 21.12(2) ?, c = 20.96(2) ?, beta = 97.87(2) degrees, V = 5600 ?(3), Z = 2, R = 0.072, R(w) = 0.082]. The precursor to 7, closo-8,9,10,12-Me(4)-1,2-C(2)B(10)H(8) (4), is made in a single step by reaction of closo-1,2-C(2)B(10)H(12) with MeI in trifluoromethanesulfonic acid. The free hosts 5, 6, and 7 are obtained by reaction of the iodide complexes with stoichiometric quantities of AgOAc. A (199)Hg NMR study indicates that sequential removal of iodide from 5.I(2)Li(2) and 6.I(2)Li(2) with aliquots of AgOAc solution leads to formation of two intermediate host-guest complexes in solution, presumed to be 5(6)ILi and 5(2)(6)(2).ILi. Crystals grown from a solution of 6.I(2)Li(2) to which 1 equiv of AgOAc solution had been added proved to be an unusual stack structure with the formula 6(3).I(4)Li(4) [tetragonal, I4/m, a = 21.589(2) ?, c = 21.666(2) ?, V = 10098 ?(3), Z = 2, R = 0.058, R(w) = 0.084]. Addition of 2 equiv of NBu(4)Br ion to 5 or 6 gives 5.Br(2)(NBu(4))(2) and 6.Br(2)(NBu(4))(2), respectively, while addition of 1 equiv of KBr to 6 forms 6.BrK. 5.Br(2)(NBu(4))(2) crystallizes in the triclinic space group P&onemacr;, [a = 10.433(1) ?, b = 13.013(1) ?, c = 15.867(2) ?, alpha = 91.638(2) degrees, beta = 97.186(3) degrees, gamma = 114.202(2) degrees, V = 1492 ?(3), Z = 1, R = 0.078, R(w) = 0.104]. The hosts 5 and 6 form 1:1 supramolecular adducts with the polyhedral anions B(10)I(10)(2)(-) and B(12)I(12)(2)(-) in solution.  相似文献   

13.
利用DV-Xα法计算了arachno-(PH3)4M2B8H8(u-H)2(M:Ni,Pd,Pt)和closo-(PH3)2MB10H8X2(M:Fe,Ru,Os;X:Cl,Br,I,OH,Li)系列分子的电子结构。结果表明在2类arachno-P4M2B8和closo-MB10X2主干结构中均有类似的2种M--B键合:一是金属原子d轨道相对配体原子轨道形成了全对称匹配分子轨道(MOs);二是部分  相似文献   

14.
The reaction of [Li(THF)(4)][1,8-mu-(Mes(2)B)C(10)H(6)] with HgCl(2) affords [1,1'-(Hg)-[8-(Mes(2)B)C(10)H(6)](2)] () or [1-(ClHg)-8-(Mes(2)B)C(10)H(6)] (), depending on the stoichiometry of the reagents. These two new compounds have been characterized by (1)H, (13)C, (11)B and (199)Hg NMR, elemental analysis and X-ray crystallography. The cyclic voltammogram of in THF shows two distinct waves observed at E(1/2) -2.31 V and -2.61 V, corresponding to the sequential reductions of the two boron centers. Fluoride titration experiments monitored by electrochemistry suggest that binds tightly to one fluoride anion and more loosely to a second one. Theses conclusions have been confirmed by a UV-vis titration experiment which indicates that the first fluoride binding constant (K(1)) is greater than 10(8) M(-1) while the second (K(2)) equals 5.2 (+/- 0.4) x 10(3) M(-1). The fluoride binding properties of have been compared to those of [1-(Me(2)B)-8-(Mes(2)B)C(10)H(6)] () and [1-((2,6-Me(2)-4-Me(2)NC(6)H(2))Hg)-8-(Mes(2)B)C(10)H(6)] (). Both experimental and computational results indicate that its affinity for fluoride anions is comparable to that of but significantly lower than that of the diborane . In particular, the fluoride binding constants of , and in chloroform are respectively equal to 5.0 (+/- 0.2) x 10(5) M(-1), 1.0 (+/- 0.2) x 10(3) M(-1) and 1.7 (+/- 0.1) x 10(3) M(-1). Determination of the crystal structures of the fluoride adducts [S(NMe(2))(3)][-mu(2)-F] and [S(NMe(2))(3)][-mu(2)-F] along with computational results indicate that the higher fluoride binding constant of arises from a strong chelate effect involving two fluorophilic boron centers.  相似文献   

15.
The dilithiated boraamidinate complexes [Li(2)[PhB(NDipp)(2)](THF)(3)] (7a) (Dipp = 2,6-diisopropylphenyl) and [Li(2)[PhB(NDipp)(N(t)Bu)](OEt(2))(2)] (7b), prepared by reaction of PhB[N(H)Dipp][N(H)R'] (6a, R' = Dipp; 6b, R' = (t)Bu) with 2 equiv of (n)BuLi, are shown by X-ray crystallography to have monomeric structures with two terminal and one bridging THF ligands (7a) or two terminal OEt(2) ligands (7b). The derivative 7a is used to prepare the spirocyclic group 13 derivative [Li(OEt(2))(4)][In[PhB(NDipp)(2)](2)] (8a) that is shown by an X-ray structural analysis to be a solvent-separated ion pair. The monoamino derivative PhBCl[N(H)Dipp] (9a), obtained by the reaction of PhBCl(2) with 2 equiv of DippNH(2), serves as a precursor for the synthesis of the four-membered BNCN ring [[R'N(H)](Ph)B(mu-N(t)Bu)(2)C(n)Bu] (10a, R' = Dipp). The X-ray structures of 6a, 9a, and 10a have been determined. The related derivative 10b (R' = (t)Bu) was synthesized by the reaction of [Cl(Ph)B(mu-N(t)Bu)(2)C(n)Bu] with Li[N(H)(t)Bu] and characterized by (1)H, (11)B, and (13)C NMR spectra. In contrast to 10a and 10b, NMR spectroscopic data indicate that the derivatives [[DippN(H)](Ph)B(NR')(2)CR(NR')] (11a: R =( t)Bu, R' = Cy; 11b: R = (n)Bu, R' = Dipp) adopt acyclic structures with three-coordinate boron atoms. Monolithiation of 10a produces the novel hybrid boraamidinate/amidinate (bamam) ligand [Li[DippN]PhB(N(t)Bu)C(n)Bu(N(t)Bu)] (12a).  相似文献   

16.
Single crystals of Li(6)CuB(4)O(10) have been synthesized, and its crystal structure has been determined. Li(6)CuB(4)O(10) crystallizes in the non-centrosymmetric triclinic space group P1 (No. 1). The structure consists of isolated [CuB(4)O(10)](6)(-) polyanions that are bridged by six LiO(4) tetrahedra. Li(6)CuB(4)O(10) is a congruently melting compound. It produces SHG intensity similar to that produced by KH(2)PO(4) and is phase-matchable.  相似文献   

17.
Here, we present the Li(+) insertion behavior of mesoporous ordered TiO(2)(B) nanoparticles (meso-TiO(2)(B)). Using presynthesized 4 nm TiO(2)(B) nanoparticles as building blocks and a commercially available ethylene glycol-propylene glycol block copolymer (P123) as a structure-directing agent, we were able to produce mesoporous structures of high-purity TiO(2)(B) with nanocrystallinity and mesopore channels ranging from 10 to 20 nm in diameter. We compared the Li(+) insertion properties of nontemplated TiO(2)(B) nanoparticles (nano-TiO(2)(B)) to meso-TiO(2)(B) via voltammetry and galvanostatic cycling and found significant increases in overall Li(+) insertion capacity for the latter. While nano-TiO(2)(B) and meso-TiO(2)(B) both show surface charging (pseudocapacitive) Li(+) insertion behavior, meso-TiO(2)(B) exhibits a higher overall capacity especially at high charge rates. We attribute this effect to higher electrode/electrolyte contact area as well as the improved electron and ion transport in meso-TiO(2)(B). In this study, we have demonstrated the influence of both nanostructuring and mesoporosity on Li(+) insertion behavior by rationally controlling the overall architecture of the TiO(2)(B) materials.  相似文献   

18.
[Structure: see text]. N(CH2CH2OCH3)2 are as follows: T = CHCH(CH3)2, 6; T = (CH2)2, 10; T = (CH2)3, 14. The results of NOE NMR experiments for 6, 10, and 14 together with X-ray crystallography of 14 support internally coordinated monomeric structures for all three compounds. Models have been constructed for 6, 10, and 14 from modifications of an internally solvated allylic lithium compound at the B3LYP level of theory using basis set 6-311G*. The resulting structural features are very similar to those obtained from the NMR and crystallographic data. In addition, 13C NMR shifts obtained with the GIAO procedure using the results of the B3LYP/6-311G* calculations are closely similar to the experimental shifts, which validate B3LYP as a suitable model for these compounds. The Li+ centroid distance of ca. 1.9 A to 2.0 A obtained for 6, 10, and 14 is common to most crystallographic data for externally solvated Cp-Li+ compounds as well as one which incorporates a (CpLiCp)- triple ion. It is concluded that the ligand tether and the stereochemistry around Li+ accommodate to maintain the structural integrity of Cp-Li+. NMR and crystallography show 14 to be chiral. Carbon-13 NMR line shape changes are attributed to inversion via a lateral wobble mechanism with DeltaH++ = 6 kcal x mol(-1) and DeltaS++ = -2 eu. It is also shown that a 6,6-dimethylfulvene is deprotonated at methyl by LiN(CH2CH2OCH3)3 as well as by butyllithium in the presence of PMDTA producing isopropenyl Cp-Li+ compounds 24 and 25, respectively. NMR line shape changes of the sample containing 24 have been qualitatively interpreted to result from a combination of fast transfer of coordinated ligand between faces of the carbanion plane as well as a lithium-exchange process.  相似文献   

19.
Yoshikuni N 《Talanta》1989,36(6):709-710
Fusion with 1.0 g of Li(2)B(4)O(7)Li(2)SO(4) (2:1) mixture in a platinum crucible at 1000 degrees will decompose 0.1 g of silicate rock in less than 10-15 min, and the cooled fusion cake can be completely dissolved by 20 ml of 1.2M hydrochloric acid at 90-100 degrees in approximately 5 min.  相似文献   

20.
在B3LYP/6-311+ +G(2d,2p)水平上,优化得到硝基甲烷CH3NO2的10种异构体和23个异构化反应过渡态,并用G2MP2方法进行了单点能计算.根据计算得到的G2MP2相对能量,探讨了CH3NO2势能面上异构化反应的微观机理.研究表明,反应初始阶段的CH3NO2异构化过程具有较高的能垒,其中CH3NO2的两个主要异构化反应通道,即CH3NO2→CH3ONO和CH3NO2→CH2N(O)OH的活化能分别为270.3和267.8 kJ/mol,均高于CH3NO2的C-N键离解能.因而,从动力学角度考虑, CH3NO2的异构化反应较为不利.  相似文献   

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