多孔硅激光染料镶嵌膜的荧光光谱研究

本文对以多孔硅为载体，镶嵌激光染料形成复合膜的光致发光进行了研究，比较了镶嵌膜与其他不同状态下染料发光的差异，发现镶嵌染料荧光光谱线型较其他状态下明显趋于对称，同时考察了衬底情况的改变对镶嵌膜发光的影响。通过对实验结果的分析指出，这种硅基镶嵌膜中的染料的发光主要来自单体的荧光发射。     

染料溶液中微微秒超荧光光谱的动力学研究

本文介绍采用时间分辨的频率上转换法研究染料溶液中微微秒超荧光光谱动力学过程的装置和实验结果.实验研究了超荧光的脉宽压缩,荧光中心波长的位移和增益带宽对泵浦光参量以及染料溶液浓度的依赖关系.     

飞秒荧光亏蚀光谱技术研究液相体系取向弛豫

溶液中分子的快速弛豫过程直接反映了溶液中溶质和周围溶剂分子间的相互作用[1- 3 ] .在液相体系中分子取向通常是随机分布的 .当溶质分子被线偏振光激发至激发态时 ,其分子取向将由原来各向同性的球形分布瞬间变成各向异性的椭球分布 .由于溶质分子周围大量溶剂分子的存在 ,通过二者之间相互作用 ,激发态溶质分子在一定方向上的取向优势将很快弛豫掉 .这种溶液中的取向弛豫过程通常是几个到几百皮秒[1- 3 ] .飞秒分辨荧光亏蚀光谱原理和实验方法见文献[4 - 7] .当溶液中的溶质分子被线偏振飞秒激光脉冲激发至电子激发态时 ,经过一定的延迟…     

介电微球对oxazine溶液荧光的调制

研究了染料恶嗪（oxazine 1)溶液中掺有高折射率玻璃微球时，微球表面附近染料荧光的荧光光谱特性，发现微球外表面附近染料分子的荧光光谱也会象球内情况一样形成结构共振，用Mie散射理论和微腔理论对此实验现象进行了分析，实验与理论计算结果符合得较好。     

Stilbene 420激光染料的光谱特性分析

配制了Stilbene 420染料溶液。测量了其吸收光谱。以调Q倍频Nd∶YAG激光为抽运源,实现了对Stilbene 420染料的激光光谱和荧光光谱的分析。激光光谱在425 nm处获得最强峰值,半峰高宽(FWHM)为1 nm,光谱范围为420～440 nm。荧光光谱峰值在428.5 nm,与激光最强峰值相差3.5 nm。最高染料转换效率为9.26%。     

多孔铝激光染料镶嵌膜的荧光光谱研究

以多孔阳极氧化铝为基底,将激光染料分子RhB有效地嵌入多孔铝的孔中,获得多孔铝激光染料镶嵌膜。镶嵌膜的荧光光谱类似于低浓度液相染料的荧光光谱,但光谱线型更趋于对称。通过改变多孔铝孔的直径和深度及染料溶液深度,研究光谱的变化关系,初步提出了多也铝镶嵌染料膜的理想模型。     

染料在聚乙二醇介质中的荧光光谱和溶剂效应研究

本文研究了激光染料Ｃｏｕｍａｒｉｎ－４８０，Ｏｘａｚｉｎｅ－７２０，Ｏｘａｚｉｎｅ－７２５在聚乙二醇介质中的荧光光谱。结果表明荧光光强度随着聚乙二醇浓度的不断增大而增强，荧光发射的最大峰位有较明显的红移，表明染料分子与聚乙二醇分子间形成了分子缔合物，缔合物愈稳定，荧光强度增强愈大，红移愈大。     

溴化亚铜激光泵浦的可调谐微微秒染料激光

本文首次报道了利用脉宽为25ns重复率为10kHz的溴化亚铜激光泵浦混有饱和吸收体DODCI的超短腔染料激光,产生出30ps光脉冲.在理论上对混入DODCI的超短腔染料激光脉冲压缩效应作了分析计算,计算结果与实验基本一致.在实验上又通过一个放大-色散系统实现对此染料激光脉冲的同步放大和调谐,并达到傅里叶变换极限.     

阴阳离子菁染料J-聚集体的荧光光谱研究

采用荧光光谱技术,研究了两种阴阳离子菁染料及对应的阴离子和阳离子菁染料在溴碘化银立方体颗粒上形成的J-聚集体的荧光光谱特性,并与其在溴碘化银立方体上的光谱增感率进行了实验对比。结果表明：阴阳离子菁染料的荧光光谱峰值明显低于阴离子、阳离子菁染料,说明其吸收光子后,大部分电子转移到溴碘化银表面。因此具有较高的光谱增感效率。     

光场的非傍轴性对光谱移动和光谱开关的影响

利用瑞利衍射积分公式，推导出多色高斯光束被硬边光阑衍射后光谱的解析公式，傍轴近似的光谱公式可作为特例得到.着重研究了束腰宽度与中心波长之比w₀/λ₀和截断参数δ对光谱移动和光谱开关的影响.结果表明，只有当w₀/λ₀和δ满足一定条件时，傍轴近似结果才与非傍轴结果一致.光场的非傍轴性会引起光谱移动不同和产生光谱开关的临界位置变化. 关键词： 非傍轴光场 高斯光束 光谱移动 光谱开关     

A time-dependent Fourier grid Hamiltonian-based formulation of time-dependent multi-configuration Hartree method

We propose a variant of the time-dependent multi-configuration Hartree method within the framework of Fourier grid Hamiltonian method. The workability of the method proposed is demonstrated with a well-known coupled two-mode problem.     

Quark-antiquark scattering phase shift and meson spectral function in pion superfluid

We study the quark-antiquark scattering phase shift and meson spectral function in the pion superfluid described by the Nambu-Jona-Lasinio model. Meson mixing in the pion superfluid dramatically changes the full scattering phase shift and significantly broadens the spectral function of some collective modes.     

超短脉冲厄米-高斯光束在湍流大气中的光谱移动和光谱跃变

基于广义惠更斯-菲涅尔原理，推导出了超短脉冲厄米-高斯(H-G)光束在湍流大气中的光谱传输方程，研究了其光谱移动和光谱跃变特性，并给予了合理的物理解释.研究表明，超短脉冲H-G 光束通过湍流大气传输其光谱特性由大气折射率结构常数、厄米多项式阶数、脉冲宽度和观察点位置坐标等因素共同决定.轴上点光谱为蓝移，随着离轴距离的增大，光谱由蓝移变为红移，无光谱移动点的位置坐标与脉冲宽度无关.此外，当湍流增强到一定程度时离轴点还存在光谱跃变现象.自由空间与湍流大气中的光谱跃变行为存在很大的差异，本文对此进行了详细的分析. 关键词： 超短脉冲厄米-高斯(H-G)光束 湍流大气 光谱移动 光谱跃变     

碲化铅/硫化锌红外多层滤光片的光谱漂移研究

采用碲化铅和硫化锌作为镀膜材料,研制了空间红外光学系统使用的红外多层带通滤光片。本文首次利用导纳轨迹图解技术,当在空间低温条件下使用时,对由碲化铅的折射率变化引起的光谱漂移机理进行了研究。根据多层膜各膜层间存在的光学厚度的补偿效应,建立了光谱漂移模型。并对设计的滤光片采用对分法计算了它在低温条件下波长的漂移量,计算结果与研制出的滤光片实测结果吻合很好。并成功地将研究结果应用于滤光片的设计,对原设计结果进行了准确的修正,使得最终研制的滤光片在低温下完全满足使用要求。     

Humidity-induced spectral shift in a cross-dispersion echelle spectrometer and its theoretical investigation

The relationship between ambient relative humidity H and the position shift of a spectral line was in-vestigated both experimentally and theoretically. An echelle-based ICP emission spectrometer equipped with a CID detector was used for experimental verification of the derived model. The shift of a spectral line is quanti-tatively described by two defined spectral shift functions. △λx (x,λ, H) (in the x direction of the CID detec-tor) and △λy(y, λ, H) (in the y direction of the CID detector). Experimental results indicate that △λx(x, λ, H) does not change with a variation in ambient relative humidity, but △λy(y, λ, H) does. A spectral shift e-quation, i.e. an empirical second-order polynomial equation, can be used to describe the relationship between △λy(y, λ, H) and H. Based on the classical dipole model, classical mechanics and electrodynamics the empiri-cal spectral-shift equation involving △λx(y, λ, H) and H was theoretically deduced. The theoretical result is in good agreement with the experimental findings. The theoretical results indicate that the coefficients of the em-pirical spectral-shift equation are related to the basic physical parameters of materials and the geometric config-uration of the echelle CID ICP-AES, and also provide physical meaning to the coefficients of the empirical shift equation obtained experimentally.     

Picosecond spectroscopy of intermolecular interactions in dye solutions

Some new experimental data on the time development of ultrashort superfluorescence (SF) in the dye solution are presented. The correlation between temporal behaviour change and the change of the spectral and spatial intensity distribution gives direct evidence of the important role of the selffocusing phenomenon in the formation of the ultrashort SF pulse synchronized with the pumping one. The oriental relaxation of solvent molecules in the dye solution not only influences the duration of the dye SF via the selffocusing mechanism but also causes a temporal change of spontaneous emission spectrum. At least two different relaxation times were found in the fluorescence spectrum of the dye in several polar solutions.     

Phase shift of the population oscillation and population trapping

Using our recently developed time-dependent multilevel approach, we have calculated the phase shift of the population oscillation of the excited potassium atom in frequency-modulated fields when the modulation amplitude is suddenly changed. The numerical results are in good agreement with the measurements. A new way of realizing population trapping is suggested.     

Theoretical analysis of collisional shift and broadening of antiprotonic helium spectral lines

Effect of medium density on shift and broadening of ( ) spectral lines is considered in the framework of binary-collision approximation with an effective ( )–He potential including the long-range attraction and short-range repulsion. Quantum calculations of the scattering phase shifts at reasonable values of the potential parameters allow to explain the main features of the observed density effect on the shape of ( ) spectral lines in low-temperature helium. This revised version was published online in August 2006 with corrections to the Cover Date.     

A farinfrared study of trichloroethane-cyclohexane solutions

Results for the absorption coefficient and the refractive index are presented for trichloroethane and three solutions of trichloroethane in cyclohexane. They are analyzed in term of the Lobo, Robinson, Rodriguez formula. The integrated absorption is computed and compared with the theoretical value. The excess absorption is estimated to be about 30%.