One-dimensional Bi<Subscript>2</Subscript>Mo<Subscript>x</Subscript>W<Subscript>1-x</Subscript>O<Subscript>6</Subscript> sosoloids: controllable synthesis by electrospinning process and enhanced photocatalytic performance

One-dimensional Bi₂Mo_xW_1-xO₆ (x = 0, 0.2, 0.5, 0.67, and 1) photocatalysts have been successfully synthesized for the first time by a straightforward electrospinning technique with a calcination process. The as-formed Bi₂Mo_xW_1-xO₆ nanofibers are composed of inter-linked nanosheets of 30–50 nm in size and characterized by thermogravimetric and differential scanning calorimetric, Fourier transform infrared, Raman spectra, X-ray powder diffraction, scanning electron microscope, Brunauer-Emmett-Teller, transmission electron microscope, UV-Vis spectroscopy, photoluminescence, HPLC, and EIS. The photodegradation behaviors towards organic dyes, including rhodamine B (RhB) and methylene blue (MB) are investigated, and the results illustrate that Bi₂Mo_0.25W_0.75O₆ nanofibers exhibit the highest photocatalytic performance under visible light irradiation than Bi₂Mo_xW_1-xO₆ (x = 0, 0.2, 0.5, 0.67, and 1) samples. The possible mechanisms of the enhanced photocatalytic properties are discussed in detail.     

Dielectric relaxation in BiLi<Subscript>0.6</Subscript>W<Subscript>0.4</Subscript>O<Subscript>3</Subscript> ceramics

The low-frequency process of dielectric relaxation in the new lead-free compound BiLi_0.6W_0.4O₃ prepared by conventional ceramic technology is studied. The features of dielectric relaxation are discussed in terms of a model of interaction between the domain boundaries and point defects of a crystalline lattice.     

Genesis,structural, and transport properties of La<Subscript>2</Subscript>Mo<Subscript>2-x</Subscript>W<Subscript>x</Subscript>O<Subscript>9</Subscript> prepared via mechanochemical activation

Fast oxide-ion conductors La₂Mo_2-xW_xO₉ (x = 0–1) have been prepared using mechanochemical activation (MA) of starting oxides in a high-power planetary ball mill. Studies of La₂Mo_2-xW_xO₉ genesis and structural properties using thermal analysis, XRD, SEM, IR, and Raman spectroscopy have revealed that MA results in the formation of an amorphous precursor, while the cubic β-phase is formed after calcination at 700–900 °C. Due to a high dispersion of powders, high-density pellets of W-LAMOX ceramics have been obtained already after sintering at 950 °C. Their electrical conductivity measured by the impedance spectroscopy depends on the W concentration being sufficiently high (up to 5.6?10^?3 S/cm at 630 °C) at temperatures below 650 °C.     

Dielectric and acoustic properties of the new lead-free BiLi<Subscript>0.6</Subscript>W<Subscript>0.4</Subscript>O<Subscript>3</Subscript> ceramic

The properties of the new lead-free compound BiLi_0.6W_0.4O₃, obtained using ceramic technology, were studied by dielectric and mechanical spectroscopy. The anomalies of internal friction are, along with the elastic and dielectric properties observed experimentally at a temperature of 350°C, related to its structural phase transition. Dielectric and mechanical relaxation due to processes of interaction between crystal lattice defects was revealed in the low-temperature phase.     

Magnetic properties of the tetranitrosyl-iron complex Fe<Subscript>2</Subscript>(SC<Subscript>3</Subscript>H<Subscript>5</Subscript>N<Subscript>2</Subscript>)<Subscript>2</Subscript>(NO)<Subscript>4</Subscript>

The magnetic properties of the binuclear nitrosyl-iron complexes Fe₂(SC₃H₅N₂)₂(NO)₄ are investigated. It is demonstrated that several types of particles, such as dimers with a pair of spins 1/2, dimers with a pair of spins 5/2, and paramagnetic particles with spin 3/2, make a contribution to the magnetic properties of the complexes. A decrease in the temperature below 25 K leads to a change in the shape of the EPR spectra corresponding to these dimers, so that Lorentzian lines (homogeneous broadening) transform into Gaussian lines (inhomogeneous broadening). This is accompanied by a stepwise change in the EPR line width and g factors. The change in the line shape indicates that complexes become asymmetric at low temperatures, possibly, due to the decrease in the spin exchange frequency below the frequency of the microwave field of the spectrometer.     

Preparation,Structure, and Dielectric and Magnetic Properties of SrFe<Subscript>2/3</Subscript>W<Subscript>1/3</Subscript>O<Subscript>3</Subscript> Ceramics

Polycrystalline samples of SrFe_2/3W_1/3O₃ (SFWO) ceramic were obtained by solid-phase reactions with subsequent sintering using conventional ceramic technology. X-ray diffraction analysis showed that at room temperature, the SFWO ceramic is single-phase and has a perovskite-type structure with tetragonal symmetry and parameters a = 3.941(9) Å, c = 3.955(6) Å, and c/a = 1.0035. In studying the magnetic properties and the Mössbauer effect in SFWO ceramics, it is found that the material is a ferrimagnet, and the iron ions are only in the valence state of Fe³⁺. It is suggested that in the temperature range of T = 150–210°C, a smeared phase transition from a cubic (paraelectric) phase to a tetragonal (ferroelectric) phase takes place in SFWO with decreasing temperature.     

Superconducting properties of molybdenum ruthenium alloy Mo<Subscript>0.63</Subscript>Ru<Subscript>0.37</Subscript>

Resistance, magnetization and specific heat measurements were performed on Mo_0.63Ru_0.37 alloy. All of them confirm that Mo_0.63Ru_0.37 becomes superconducting at about 7.0 K with bulk nature. Its upper critical field behavior fits to Werthamer-Helfand-Hohenberg (WHH) model quite well, with an upper critical field of μ₀H_c2(0) = 8.64 T, less than its Pauli limit. Its electronic specific heat is reproduced by Bardeen-Cooper-Schriffer (BCS)-based α-model with a gap ratio Δ₀ = 1.88k _B T _c , which is a little larger than the standard BCS value of 1.76. We concluded that Mo_0.63Ru_0.37 is a fully gapped isotropic s-wave superconductor, with its features are mostly consistent with the conventional theory.     

Mn-doped Bi<Subscript>26</Subscript>Mo<Subscript>10</Subscript>O<Subscript>69-d</Subscript>: synthesis and characterization

In this work, we research two series of Mn-substituted bismuth molybdates: Bi_26-2xMn_2xMo₁₀O_69-d and Bi₂₆Mo_10-2yMn_2yO_69-d. The synthesis of powder samples is performed by the conventional solid state technology. Samples are characterized by X-ray diffraction, scanning electron microscopy, and chemical analysis methods, and it is shown that single phase Bi_26-2xMn_2xMo₁₀O_69-d and Bi₂₆Mo_10-2yMn_2yO_69-d complex oxides form up to x = 0.8 and y = 0. We use densitometry, grain size measurements and scanning electron microscopy to study the morphology of ceramic pellets and powders. This issue reveals formation of dense ceramic samples with low porosity (≤3%). High-temperature X-ray diffraction is used to define small deviation of unit cell parameters from their linear dependence on temperature. Measurement of electrical conductivity is made using a.c. impedance spectroscopy method. We observe the decrease of electrical conductivity in Bi_26-2xMn_2xMo₁₀O_69-d series depending on dopant concentration.     

Muon-spin-relaxation investigation of EuMn<Subscript>2</Subscript>O<Subscript>5</Subscript>

The magnetic properties of the EuMn₂O₅ multiferroic (samples consisting of single crystals and ceramic samples) have been investigated by the muon-spin-relaxation (μSR) method in the temperature range of 10–300 K. Below the magnetic ordering temperature T _N = 40 K, the loss of the polarization of muons and the effect of the external magnetic field have been observed. Both phenomena can be explained by an additional channel of the depolarization of muons owing to the appearance of muons in a medium with a low electron density due to the charge separation process (the redistribution of the electron density in the phase transition process). The “memory” phenomenon has been revealed in a sample in the external magnetic field; the memory relaxation time depends on the size of the structure units of the samples (single crystals or ceramic grains).     

Thermal conductivity of Na<Subscript>2</Subscript>W<Subscript>2</Subscript>O<Subscript>7</Subscript> crystal

The thermal conductivity of Na₂W₂O₇ single crystal has been studied along the main crystallographic directions at temperatures of 50–573 K. A low thermal conductivity is found to correlate with a significant difference in the cation weight.     

Contactless density measurement of high-temperature BiFeO<Subscript>3</Subscript> and BaTiO<Subscript>3</Subscript>

The density of liquid and undercooled BiFeO₃ and high-temperature solid, liquid, and undercooled BaTiO₃ was measured with an electrostatic levitation furnace. The density was obtained with an ultraviolet-based imaging technique that allowed excellent sample contrast throughout all phases of processing, including at elevated temperatures. Over the 1250- to 1490-K temperature range, the density of liquid BiFeO₃ can be expressed as _L(T)=6.70×10³–1.31(T-T_m)(kgm^-3) (±2 per cent) with T_m=1423 K, yielding a volume coefficient of thermal expansion _L(T)=1.9×10^-4 K^-1. For BaTiO₃, the density of the solid can be expressed as _S(T)=5.04×10³–0.21(T-T_m) (T_m=1893 K) over the 1220- to 1893-K range, yielding a volume coefficient of thermal expansion _S(T)=4.2×10^-5 K^-1, whereas that of the liquid can be expressed as _L(T)=4.04×10³-0.34(T-T_m) over the 1300- to 2025-K range with _L(T)=8.4×10^-5 K^-1. PACS 77.84.-s; 81.05.Je; 81.20.n     

Photoaccumulating film systems based on TiO<Subscript>2</Subscript>/MoO<Subscript>3</Subscript> and TiO<Subscript>2</Subscript>/MoO<Subscript>3</Subscript>:V<Subscript>2</Subscript>O<Subscript>5</Subscript> nanoheterostructures

The thin-film photocatalysts TiO₂/MoO₃ and TiO₂/MoO₃:V₂O₅ obtained by a combination of sol–gel and sintering techniques were studied using the photooxidation of probing dyes, EPR spectroscopy, X-ray diffraction analysis, and electron microscopy. It was shown that due to charge accumulation caused by UV irradiation, these photocatalysts retain their oxidative activity and ability for self-sterilization in the dark for a long time after irradiation was terminated (up to 5 h for TiO₂/MoO₃:V₂O₅).     

Temperature evolution of the dielectric response function of Pb(Fe<Subscript>0.95</Subscript>Sc<Subscript>0.05</Subscript>)<Subscript>2/3</Subscript>W<Subscript>1/3</Subscript>O<Subscript>3</Subscript> relaxor ceramics in a wide frequency range

Electrodynamic properties of Pb(Fe_0.95Sc_0.05)_2/3W_1/3O₃ solid solution belonging to A(B'B'')O₃ perovskite structural family have been investigated by broadband dielectric spectroscopy in a wave-number range of (4 × 10^–9–4 × 10³) cm^–1 and a temperature range of 100–600 K. The influence of low-frequency relaxations on the vibrational spectrum is determined within the four-parameter factorized dispersion model. Anomalies in the behavior of the dielectric response function are found near the temperature-diffuse maximum of permittivity.     

Investigation of luminescence spectra of the Y<Subscript>3</Subscript>Al<Subscript>5</Subscript>O<Subscript>12</Subscript> and Y<Subscript>3</Subscript>Al<Subscript>5</Subscript>O<Subscript>12</Subscript>:Ce single-crystal films

The luminescence spectra of single-crystal films and bulk crystals of yttrium-aluminum garnet Y₃Al₅O₁₂ and Ce³⁺-activated Y₃Al₅O₁₂ were investigated. It was shown that the room-temperature luminescence intensity of the Ce³⁺-free single-crystal Y₃Al₅O₁₂ film was considerably lower than that of the bulk crystals, while the luminescence intensity of the Ce³⁺ ions in the Y₃Al₅O₁₂:Ce films was considerably higher than that one for the corresponding bulk crystal.     

Radiation Resistance of Yb:LaSc<Subscript>3</Subscript>(BO<Subscript>3</Subscript>)<Subscript>4</Subscript> and Yb:LuYSiO<Subscript>5</Subscript> Laser Crystals

The optical transmission (OT) spectra of Yb:LaSc₃(BO₃)₄ and Yb:LuYSiO₅ laser crystals have been analyzed before and after irradiation from a ⁶⁰Co source with doses up to 45 Mrad. The OT spectra of the Yb:LuYSiO₅ crystal are found to be the same (within the measurement error) before and after irradiation. The irradiation of the 10 at.%Yb:LaSc₃(BO₃)₄ crystal significantly changes its OT spectra in a wide spectral range (330 to 700 nm). A 975-nm laser based on a previously irradiated 4 at.%Yb:LuYSiO₅ crystal has exhibited a differential efficiency of 23% under diode pumping. The up-conversion luminescence spectra in the visible range of the crystals under study have been explained.     

Modification of the “Transcritical” state in Ni<Subscript>75</Subscript>Fe<Subscript>16</Subscript>Cu<Subscript>5</Subscript>Mo<Subscript>4</Subscript> films produced by RF sputtering

The saturation magnetization, the perpendicular and rotational anisotropy constants, and the coercitivity of Ni₇₅Fe₁₆Cu₅Mo₄ thin magnetic films produced by rf sputtering are measured in the initial state and after annealing. A relation between the presence of perpendicular anisotropy and the “transcritical” state in the films is established. It is shown that, after additional thermal treatment, the magnetic softness of the films can be improved.     

Magnetic and Mössbauer Studies of Fe<Subscript>76</Subscript>Mo<Subscript>8</Subscript>Cu<Subscript>1</Subscript>B<Subscript>15</Subscript> Nanocrystalline Alloy

The influence of different degrees of crystallinity on the magnetic behaviour of heat-treated nanocrystalline Fe₇₆Mo₈Cu₁B₁₅ alloy has been investigated using a combination of Mössbauer spectrometry and magnetic measurements. The evolution of magnetically active regions and their growth with rising contents of nanocrystals are followed by distributions of hyperfine interactions. Combined electric quadrupole and magnetic dipole interactions corresponding to non-magnetic and magnetic regions inside the amorphous phase, respectively, were revealed. A deterioration of the soft-magnetic properties takes place for the samples exhibiting low fraction of crystallinity. The very good soft-magnetic behaviour is regained for the samples where the primary crystallization process is almost finished.     

Magnetoelectric Cr<Subscript>2</Subscript>O<Subscript>3</Subscript> and relativity theory

Based on the dielectric continuum phonon model, uniaxialmodel and force balance equation the mobility of two dimensional electrongas in wurtzite Al_xGa_1-xN/GaN/Al_xGa_1-xN quantum wells isdiscussed theoretically within the temperature range dominated by opticalphonons. The dependences of the electron mobility on temperature, Al molarfraction and electron sheet density are presented including hydrostaticpressure effect. The built-in electric field is also taken into account. Itis found that under normal pressure the main contribution to the mobility isfrom the scattering of interface optical phonons in narrow (for well widthd < 12 Å) and wide (for d > 117 Å and d > 65 Å for finitelythick barriers and infinitely thick ones, respectively) wells, whereas thatis from the scattering of confined optical phonons in a well with anintermediate width. It is shown that the electron mobility decreases withincreasing Al molar fraction and temperature, whereas increases obviouslywith increasing electron sheet density. The theoretical calculated electronmobility is 978 cm²/V?s which is higher than an available experimentaldata 875 cm²/V?s when x equals to 0.58 at room temperature. Theresults under hydrostatic pressure considering the modification of strainindicate that the mobility increases slightly as hydrostatic pressureincreases from 0 to 10 GPa.     

Magnetic properties of the Gd<Subscript>2</Subscript>V<Subscript>0.67</Subscript>Mo<Subscript>1.33</Subscript>O<Subscript>7</Subscript> and Y<Subscript>2</Subscript>VMoO<Subscript>7</Subscript> pyrochlore compounds

It is demonstrated that 50% substitution of vanadium for molybdenum in the pyrochlore lattice of the complex oxide Y₂(V _x Mo_{1 ? x} )₂O₇ results in a transition from the spin-glass ground state (at x = 0) to the ferromagnetic state in Y₂VMoO₇ (a = 10.1645(2) Å, T _C = 55 K). The Gd₂V_0.67Mo_1.33O₇ compound (a = 10.2862(3) Å) is a ferromagnet with T _C (84 K) exceeding that of undoped Gd₂MnO₂O₇.