Interactions between dislocations and γ/γ' interfaces in superalloys

In situ transmission electron microscopy observations of the dislocation motion at vicinity of the /' interfaces in a Ni-base superalloy have been performed. They allow to identify the elemental mechanisms, under stress and at different temperatures, of the deformation propagation across the interfaces. It is shown that some of the mechanisms already analyzed in the literature occur. Moreover, new processes are revealed such as the formation of small dislocation pile-ups on the /' interfaces. Such a configuration, which increases the local stress, favors the overcoming of the interface.These observations together with new considerations on stresses are taken into account for proposing a new equilibrium equation for a dislocation abutting on a /' interface. This equation involves all the stress components acting on a dislocation: the applied stress, the misfit stress, the friction stress, the stress concentration due to the dislocation pile-up and the image stress.     

Intersubjectivity,relativistic covariance,and conditionals: response to C. I. J. M. Stuart

A misunderstanding persists between Stuart and me, which I do my best to clarify. Bayesian inverse subjectivities versus relativistic covariance and physical intersubjectivity are discussed. A joint number of chances formalism taking care of the propagation of the probability of causes is proposed.     

Space Videophotometric System for Recording Optical Radiations in the Earth Atmosphere

This paper describes the VFS-3M videophotometric system designed for automatic remote recording of images and parameters of optical radiations following lightning discharges from aboard the Russian segment of the International space station. The characteristics of the system and the possibilities of recording such types of radiation as Red Sprites and Blue Jets are given.     

Diffusion of interacting particles on a percolating lattice

The diffusion has been simulated by the Monte Carlo method on a random lattice. As in the ant in the labyrinth problem the particles move by stepping to allowed, randomly chosen neighboring fields. The particle interaction has been defined by the constraint that only one particle can occupy a site at a time. Biased diffusion means that one of the directions will be chosen with a greater probability than the others. It was shown that, with an increasing number of walkers, the displacement of the particles first of all increases to a maximum value and then decreases. This filling-up effect will not occur with small bias fields and on lattices with a high concentration of allowed sites.     

The maximum entropy principle as a consequence of the principle of Laplace

The maximum entropy principle states that the probability distribution which best represents our information is the one which maximizes the entropy with the given evidence as constraints. We prove that this principle is implied from the Laplace principle of equiprobabilities applied to the setS of allN-term sequences of results which are compatible with the given evidence. We generalize to the information gain method of Kullback.     

Gravitational Waves in Matter

The theory of gravitational waves in matter is given. This covers the questions of constitutive relation, number of independent polarizations, index of refraction, reflection and refraction at an interface, etc. The theory parallels the familiar optics of electromagnetic waves in material media, but there are some striking differences. The use of the Campbell-Morgan formalism in which the gauge-invariant tidal force dyads E and B rather than the gauge-dependent metric perturbations are the unknowns is essential. The main justification of the theory at the moment is as a theoretical exercise worth doing. The assumption: size L of the medium gravitational wave length (infinite medium) rules out application to the already well-understood detection problem, but there may be an application to gravitational wave propagation through molecular gas clouds of galactic or inter-galactic size.     

Monte Carlo study of the ising model phase transition in terms of the percolation transition of “physical clusters”

Finite squareL×L Ising lattices with ferromagnetic nearest neighbor interaction are simulated using the Swendsen-Wang cluster algorithm. Both thermal properties (internal energyU, specific heatC, magnetization |M|, susceptibility) and percolation cluster properties relating to the physical clusters, namely the Fortuin-Kasteleyn clusters (percolation probability P , percolation susceptibility _p, cluster size distributionn _l) are evaluated, paying particular attention to finite-size effects. It is shown that thermal properties can be expressed entirely in terms of cluster properties, P being identical to |M| in the thermodynamic limit, while finite-size corrections differ. In contrast, _p differs from even in the thermodynamic limit, since a fluctuation in the size of the percolating net contributes to, but not to _p. NearT _c the cluster size distribution has the scaling properties as hypothesized by earlier phenomenological theories. We also present a generalization of the Swendsen-Wang algorithm allowing one to cross over continuously to the Glauber dynamics.     

Determination of Microwave Parameters of Isotropic Mediums by Using an Open Quasi-Optical Spherical Resonator

The technique for determination of dielectric parameters of substances is submitted on a base of using a high-Q whispering gallery oscillations in a quasi-optical spherical resonator. The function ability of a method is shown on an example of measurement of permittivity for several substances in the 8 mm wave band.     

Synthesis of peptidomimetics using a polymer-bound Boc-linker

Boc-resin-bound -hydroxy--amino-aldehydes are accessible starting from N-terminally bound amino acidesters by using Dondoni's C₁-homologationreaction sequence. The conversion of these synthons totwo different peptide mimetics – 2-hydroxy-1,3-ethyl-diamines and -hydroxy--amino-vinyl sulfones – hasbeen investigated. The successful transfer of thecomplex -amino acid homologation reactionsequence into solid-phase chemistry demonstrates thepotentials of the Boc-resin for synthesis of peptidomimetics.     

Specific Features of Light Scattering in [N(CH3)4]2CuCl4 Crystals with an Incommensurable Phase

We present the results of investigation of the optical birefringence and intensity of the main light beam that passed through an [N(CH₃)₄]₂CuCl₄ crystal under the conditions of viscous interaction of the incommensurable structure with defects. A nonmonotonic temperature dependence of the basic signal is revealed. The observed temperature dependence of the intensity (in the form of irregular steps) is related to different periods of the incommensurable structure. In transitions between adjacent metastable states the periodicity of the incommensurable structure changes. It is shown that in transition regions for the central beam one observes an anomalous decrease in the light intensity due to the appearance of a perturbation lattice with the wave vector q.     

Calculation of Out‐of‐Plane Vibrations of a Porphin Molecule

Using the DFT/B3LYP method with the base set 631G^**, we carried out calculation of the frequencies of the normal vibrations of porphin and of its five isotopic types. Scaling of force constants for outofplane vibrations has been performed in independent natural coordinates. The symmetry coordinates are introduced and a force field for outof plane vibrations of a porphin molecule in independent coordinates of symmetry is obtained. A new correlation of the frequencies of vibrations in the type of the symmetry B _1u for the isotopic type of the d ₂ porphin molecule is suggested on the basis of discrete analysis of the distribution of a potential energy.     

Infrared Spectroscopic Study of N,N‐Dimethylthioformamide Complexes of the Hofmann Type

Four new Hofmanntype complexes, M(DMTF)₂Ni(CN)₄, (where DMTF is dimethylthioformamide, M=Mn, Cd, Co, or Ni) were synthesized and their structure was determined by an elemental analysis and infrared spectroscopy. The IR spectra of DMTF and its nickel tetracyanine complexes with Mn(II), Cd(II), Co(II), and Ni(II) have been investigated within the range 4000–400 cm^–1. The frequency shifts in the metal complexes agree with the assignment of the CS and CN frequencies. The complexes consist of infinite planar polymer layers of |MNi(CN)₄|. Ndimethylthioformamide is coordinated to this layer from above and below; it is a monodentate ligand and is Sbonded through the metal atom in these complexes.     

Updated Analysis of Gallium Chelate and Vanadium Chelate Solutions with 4‐(2‐Pyridylazo)Resorcinol and Xylenol Orange

The characteristic factors of the gallium and vanadium chelates with the ligands 4(2pyridylazo)resorcinol (PAR) and xylenol orange (XO) have been determined with the aid of the principle of correction, which makes it possible to eliminate the influence of the surplus ligand in the solution of its chelate with methane (which makes calculation easier) and thereby provides a more acceptable method in comparison with others. The real molar coefficients of extinction of the chelates Ga and V with PAR and XO have been determined and a detailed calculation of the stoichiometric ratios of chelates has been made. The results have shown that the chelates formed have the following structure: Ga(PAR), Ga(XO), V(PAR)₂, and V(XO).     

Raman scattering of light in doped cubic boron nitride

The Raman spectra of single crystals of cubic boron nitride (cBN) doped with beryllium and also synthesized in the absence of dopants are investigated. It is shown that the wide bands at 215 and 535 cm^–1 can be registered in the Raman spectra of the ( ) faces of undoped cBN crystals and that the Be impurity penetrates into the cBN crystals predominantly in the direction of these faces. In the spectra of the investigated cBN samples doped with Be, the contour of the TO and LO phonon lines does not take the Fano shape, in contrast to diamond, which can point to an insufficient concentration of the dopant for attaining the Fano interference or to the absence of it in cBN. The wide bands have been investigated on the assumption that they are boson-like and result from small-size disorders in both undoped and doped cBN samples with the sp ³ bond deformed by Be.Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 71, No. 6, pp. 803–809, November–December, 2004.This revised version was published online in April 2005 with a corrected cover date.     

Two-dimensional commensurate soliton structures

A phase diagram of pinned soliton structures in two dimensions has been found for a repulsive interactionU(x) between solitons withU(x)>0. The critical fugacity of the commensurate soliton structure is shown to be proportional toU(l), wherel is the period of this structure.     

Microwave Photonic Signal Down‐Conversion Using a Novel Two‐Frequency Bragg Grating Based Brillouin Fiber Laser

A simple technique using a novel twofrequency Bragg grating based Brillouin fiber laser to downconvert high frequency microwave photonic signals is presented. The mechanism of the Brillouin fiber laser and the principle of this technique for microwave photonic signal downconversion are analyzed. The 12GHz microwave photonic signals are experimentally downconverted to 1.13GHz IF signal with the technique.     

Calculation of Quantum‐Chemical Characteristics of the Ground and Excited Electronic States of Porphin and Its Tetrapyrrole Isomers

Using the CNDO/S method, we have performed quantumchemical calculations of the ground and excited electronic states of porphin molecules (symmetry D _2h ) and a number of porphin isomers: porphycene (C_2h ), hemiporphycene, corphycene (C_2v ), isoporphycene, and three nonsynthesized structural isomers of the porphin skeleton by its bridge groups —(CH) _meso —. The results of the calculations are compared with the corresponding data for the freebase porphin molecule (H₂P). Near the boundary between the occupied and vacant orbitals the isomers form rows of singleelectron levels with similar energy characteristics. For the MOs of these isomers, the H₂P MOs closest in distribution on the comparable atomic centers are given. The weak (Q) and strong (B) transitions in the visible and near UV regions point to the porphyrin type of spectra of all the isomers. The calculation data on the excited electronic states of N, g, and ntype H₂P near and above the B states are given; the presence of such states in other isomers is shown. The calculation does not point to a difference in the position of the first singlet transitions in the first five isomers. The calculation data on the lower singlettriplet transitions are also reported.     

Luminescence of Trivalent Thulium Ions in Complexes with β-Diketones

It is established that a fairly intense luminescence of thulium can be observed in solutions (suspensions of residues) of different-ligand complexes that include -diketone and an organic base. The luminescence characteristics of Tm compounds are determined in the series of acetyl acetone derivatives with different substituents, including fluorinated ones, of different length and structure. A relationship is found between I, , and of the Tm complexes and the character of the substituents in a -diketone molecule.     

Spectral‐Luminescence and Generation Properties of 1‐Aza‐2‐Methyl‐6‐Aminopyrene and of Its Protolytic Forms

Spectral manifestations of protolytic forms of 1aza2methyl6aminopyrene in ethanol and aqueous solutions are investigated. The ionization constants of the protolytic forms are determined. The generation properties and photostability of a neutral molecule and a cation in excitation by an excimer XeCl laser are studied.     

High-spin isomer in 93Mo

The high-spin states of ⁹³Mo have been studied by a ⁸²Se( ¹⁶O, 5n) ⁹³Mo reaction at a beam energy of 100 MeV using techniques of in-beam -ray spectroscopy. Measurements of -t, --t coincidences, -ray angular distributions and -ray linear polarizations were performed. The high-spin isomer was found as a (39/2^-) state at about 9.7 MeV. The near-yrast states in ⁹³Mo were interpreted using the weak-coupling picture of a d_5/2 neutron to a neutron magic core nucleus ⁹²Mo.